WO2002010101A1 - Process for producing alcohol with transition metal complex having amide compound as ligand - Google Patents

Process for producing alcohol with transition metal complex having amide compound as ligand Download PDF

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Publication number
WO2002010101A1
WO2002010101A1 PCT/JP2001/006478 JP0106478W WO0210101A1 WO 2002010101 A1 WO2002010101 A1 WO 2002010101A1 JP 0106478 W JP0106478 W JP 0106478W WO 0210101 A1 WO0210101 A1 WO 0210101A1
Authority
WO
WIPO (PCT)
Prior art keywords
ligand
transition metal
metal complex
amide compound
producing alcohol
Prior art date
Application number
PCT/JP2001/006478
Other languages
French (fr)
Japanese (ja)
Inventor
Moriyasu Masui
Yasushi Hasegawa
Original Assignee
Shionogi & Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shionogi & Co., Ltd. filed Critical Shionogi & Co., Ltd.
Priority to JP2002516234A priority Critical patent/JP5041501B2/en
Priority to AU2001276690A priority patent/AU2001276690A1/en
Publication of WO2002010101A1 publication Critical patent/WO2002010101A1/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/143—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/04—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
    • C07D207/10—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D207/16—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
    • C07F15/0046—Ruthenium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/643—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of R2C=O or R2C=NR (R= C, H)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium

Abstract

A process for producing an alcohol represented by the general formula (IIa) IIa (wherein R?1a' and R2a¿' each represents hydrogen, an organic residue, or a group formed by reducing the organic residue, provided that R?1a' and R2a¿' may be bonded to each other to form an optionally substituted cyclic group) which comprises reducing a compound represented by the general formula (Ia) Ia (wherein R?1a and R2a¿ each represents hydrogen or an organic residue, provided that R?1a and R2a¿ may be bonded to each other to form an optionally substituted cyclic group) in the presence of a transition metal complex having an a-aminocarboxamide compound as a ligand and of a base and a hydrogen-donating compound.
PCT/JP2001/006478 2000-08-01 2001-07-27 Process for producing alcohol with transition metal complex having amide compound as ligand WO2002010101A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP2002516234A JP5041501B2 (en) 2000-08-01 2001-07-27 Method for producing alcohol using transition metal complex having amide compound as ligand
AU2001276690A AU2001276690A1 (en) 2000-08-01 2001-07-27 Process for producing alcohol with transition metal complex having amide compound as ligand

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2000232725 2000-08-01
JP2000-232725 2000-08-01

Publications (1)

Publication Number Publication Date
WO2002010101A1 true WO2002010101A1 (en) 2002-02-07

Family

ID=18725360

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2001/006478 WO2002010101A1 (en) 2000-08-01 2001-07-27 Process for producing alcohol with transition metal complex having amide compound as ligand

Country Status (3)

Country Link
JP (1) JP5041501B2 (en)
AU (1) AU2001276690A1 (en)
WO (1) WO2002010101A1 (en)

Cited By (35)

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JP2007182419A (en) * 2005-12-07 2007-07-19 Tokyo Univ Of Science Proline derivative and optically active anti-selection promoting catalyst
WO2008114891A1 (en) 2007-03-22 2008-09-25 Sumitomo Chemical Company, Limited Reductase, gene thereof and method of using the same
WO2008114892A1 (en) 2007-03-22 2008-09-25 Sumitomo Chemical Company, Limited Reductase, gene thereof and method of using the same
WO2009005024A1 (en) * 2007-07-03 2009-01-08 Hamari Chemicals, Ltd. Method for producing optically active amine
WO2010093059A1 (en) * 2009-02-16 2010-08-19 住友化学株式会社 Method for producing phenylacetamide compound
EP2228377A1 (en) * 2009-03-12 2010-09-15 Kanto Kagaku Kabushiki Kaisha Novel organometallic complex and process for preparing amine compound
WO2011108751A2 (en) 2010-03-03 2011-09-09 Sumitomo Chemical Company, Limited Plant disease controlling composition and method for controlling plant disease
WO2011108759A2 (en) 2010-03-03 2011-09-09 Sumitomo Chemical Company, Limited Plant disease controlling composition and method for controlling plant disease
WO2011108752A2 (en) 2010-03-03 2011-09-09 Sumitomo Chemical Company, Limited Plant disease controlling composition and method for controlling plant disease
WO2011108758A2 (en) 2010-03-03 2011-09-09 Sumitomo Chemical Company, Limited Plant disease controlling composition and method for controlling plant disease
WO2011108753A2 (en) 2010-03-03 2011-09-09 Sumitomo Chemical Company, Limited Plant disease controlling composition and method for controlling plant disease
WO2011108754A2 (en) 2010-03-03 2011-09-09 Sumitomo Chemical Company, Limited Plant disease controlling composition and method for controlling plant disease
WO2011108749A2 (en) 2010-03-03 2011-09-09 Sumitomo Chemical Company, Limited Plant disease controlling composition and method for controlling plant disease
WO2011108763A2 (en) 2010-03-03 2011-09-09 Sumitomo Chemical Company, Limited Plant disease controlling composition and method for controlling plant disease
WO2011108760A2 (en) 2010-03-03 2011-09-09 Sumitomo Chemical Company, Limited Plant disease controlling composition and method for controlling plant disease
WO2011108748A2 (en) 2010-03-03 2011-09-09 Sumitomo Chemical Company, Limited Plant disease controlling composition and method for controlling plant disease
EP2431353A1 (en) 2010-09-15 2012-03-21 Kanto Kagaku Kabushiki Kaisha Process for preparing amine compound
WO2012046877A2 (en) 2010-10-07 2012-04-12 Sumitomo Chemical Company, Limited Plant disease controlling composition and method for controlling plant disease
WO2012046876A2 (en) 2010-10-07 2012-04-12 Sumitomo Chemical Company, Limited Plant disease controlling composition and method for controlling plant disease
WO2012050234A2 (en) 2010-10-14 2012-04-19 Sumitomo Chemical Company, Limited Pest controlling composition and method for controlling pest
WO2012050235A2 (en) 2010-10-14 2012-04-19 Sumitomo Chemical Company, Limited Pest controlling composition and method for controlling pest
WO2012050233A2 (en) 2010-10-14 2012-04-19 Sumitomo Chemical Company, Limited Pest controlling composition and method for controlling pest
WO2012050228A2 (en) 2010-10-14 2012-04-19 Sumitomo Chemical Company, Limited Pest controlling composition and method for controlling pest
WO2012050232A2 (en) 2010-10-14 2012-04-19 Sumitomo Chemical Company, Limited Pest controlling composition and method for controlling pest
WO2012057366A2 (en) 2010-10-28 2012-05-03 Sumitomo Chemical Company, Limited Pest controlling composition and method for controlling pest
WO2012117572A1 (en) 2011-03-01 2012-09-07 Sumitomo Chemical Company, Limited Pest controlling composition and method for controlling pests
US8399684B2 (en) 2007-09-17 2013-03-19 State Of Oregon Acting By And Through The State Board Of Higher Education On Behalf Of Oregon State University Sulfonamide-based organocatalysts and method for their use
WO2013061999A1 (en) * 2011-10-25 2013-05-02 浜理薬品工業株式会社 Method for producing optically active alcohol
WO2014013842A1 (en) 2012-07-20 2014-01-23 住友化学株式会社 Composition for controlling plant disease and application therefor
WO2014013841A1 (en) 2012-07-20 2014-01-23 住友化学株式会社 Composition for controlling plant disease and application therefor
WO2014098201A1 (en) 2012-12-21 2014-06-26 住友化学株式会社 Method for increasing number or weight of crop seeds or fruits
WO2015122502A1 (en) * 2014-02-14 2015-08-20 高砂香料工業株式会社 Method for producing optically active compound, and novel metal-diamine complex
JP2017095462A (en) * 2011-07-15 2017-06-01 浜理薬品工業株式会社 Method for producing optically active tetrahydroquinolines
KR101807773B1 (en) 2010-09-21 2017-12-11 다카사고 고료 고교 가부시키가이샤 Method for producing alcohol and/or amine from amide compound
JP2018199103A (en) * 2017-05-26 2018-12-20 国立研究開発法人産業技術総合研究所 Catalyst used for hydrogenation of carbon dioxide, formic acid manufacturing method, and storage method of hydrogen

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Non-Patent Citations (1)

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CORMA A. ET AL.: "Heterogenized catalysts on zeolites. Synthesis of new chiral Rh(I) complexes with (2S,4R)-trans-4-RCOO-2-(t-butylaminocarbonyl)pyrrolidines and (2S,4S)-cis-4-RCONH-2-(t-butylaminocarbonyl)pyrrolidines. Heterogenization on .... olefins", J. ORGANOMET. CHEM., vol. 544, no. 2, 1997, pages 147 - 156, XP002948563 *

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JP2007182419A (en) * 2005-12-07 2007-07-19 Tokyo Univ Of Science Proline derivative and optically active anti-selection promoting catalyst
WO2008114891A1 (en) 2007-03-22 2008-09-25 Sumitomo Chemical Company, Limited Reductase, gene thereof and method of using the same
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US9174899B2 (en) * 2011-10-25 2015-11-03 Hamari Chemicals, Ltd. Method for producing optically active alcohols
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JPWO2013061999A1 (en) * 2011-10-25 2015-04-02 浜理薬品工業株式会社 Method for producing optically active alcohol
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Publication number Publication date
JP5041501B2 (en) 2012-10-03
AU2001276690A1 (en) 2002-02-13

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