WO2002009849A2 - Recuperation de co2 tres pur dans des fumees - Google Patents
Recuperation de co2 tres pur dans des fumees Download PDFInfo
- Publication number
- WO2002009849A2 WO2002009849A2 PCT/NL2001/000580 NL0100580W WO0209849A2 WO 2002009849 A2 WO2002009849 A2 WO 2002009849A2 NL 0100580 W NL0100580 W NL 0100580W WO 0209849 A2 WO0209849 A2 WO 0209849A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- absorber
- desorber
- depleted
- solvent
- stream
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 50
- 239000003546 flue gas Substances 0.000 title claims abstract description 47
- 238000011084 recovery Methods 0.000 title claims abstract description 14
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title claims description 27
- 238000009434 installation Methods 0.000 title claims description 16
- 239000002904 solvent Substances 0.000 claims abstract description 78
- 239000006096 absorbing agent Substances 0.000 claims abstract description 42
- 239000007789 gas Substances 0.000 claims abstract description 42
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000012190 activator Substances 0.000 claims abstract description 10
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 claims abstract description 9
- 238000010521 absorption reaction Methods 0.000 claims abstract description 7
- 238000003795 desorption Methods 0.000 claims abstract description 7
- 239000007864 aqueous solution Substances 0.000 claims abstract description 3
- 238000001914 filtration Methods 0.000 claims description 15
- 229910052799 carbon Inorganic materials 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 11
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 9
- 239000001301 oxygen Substances 0.000 claims description 9
- 229910052760 oxygen Inorganic materials 0.000 claims description 9
- 238000002485 combustion reaction Methods 0.000 claims description 8
- 150000002500 ions Chemical class 0.000 claims description 7
- 238000005342 ion exchange Methods 0.000 claims description 4
- 239000012530 fluid Substances 0.000 claims description 3
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 claims description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical group NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 2
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 claims description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 2
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 claims description 2
- 229940043276 diisopropanolamine Drugs 0.000 claims description 2
- 235000013305 food Nutrition 0.000 abstract description 21
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 103
- 239000000243 solution Substances 0.000 description 18
- 150000003839 salts Chemical class 0.000 description 9
- PVXVWWANJIWJOO-UHFFFAOYSA-N 1-(1,3-benzodioxol-5-yl)-N-ethylpropan-2-amine Chemical compound CCNC(C)CC1=CC=C2OCOC2=C1 PVXVWWANJIWJOO-UHFFFAOYSA-N 0.000 description 8
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 8
- QMMZSJPSPRTHGB-UHFFFAOYSA-N MDEA Natural products CC(C)CCCCC=CCC=CC(O)=O QMMZSJPSPRTHGB-UHFFFAOYSA-N 0.000 description 7
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
- 238000010586 diagram Methods 0.000 description 5
- 230000008929 regeneration Effects 0.000 description 5
- 238000011069 regeneration method Methods 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 239000005864 Sulphur Substances 0.000 description 4
- 150000001450 anions Chemical class 0.000 description 4
- 239000007857 degradation product Substances 0.000 description 4
- 239000003345 natural gas Substances 0.000 description 4
- 229910017464 nitrogen compound Inorganic materials 0.000 description 4
- 150000002830 nitrogen compounds Chemical class 0.000 description 4
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
- 230000002745 absorbent Effects 0.000 description 3
- 239000002250 absorbent Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 238000011144 upstream manufacturing Methods 0.000 description 3
- LJDSTRZHPWMDPG-UHFFFAOYSA-N 2-(butylamino)ethanol Chemical compound CCCCNCCO LJDSTRZHPWMDPG-UHFFFAOYSA-N 0.000 description 2
- OPKOKAMJFNKNAS-UHFFFAOYSA-N N-methylethanolamine Chemical compound CNCCO OPKOKAMJFNKNAS-UHFFFAOYSA-N 0.000 description 2
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000000498 cooling water Substances 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 239000002803 fossil fuel Substances 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000010413 mother solution Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- KODLUXHSIZOKTG-UHFFFAOYSA-N 1-aminobutan-2-ol Chemical compound CCC(O)CN KODLUXHSIZOKTG-UHFFFAOYSA-N 0.000 description 1
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 1
- NSMWYRLQHIXVAP-UHFFFAOYSA-N 2,5-dimethylpiperazine Chemical compound CC1CNC(C)CN1 NSMWYRLQHIXVAP-UHFFFAOYSA-N 0.000 description 1
- MIJDSYMOBYNHOT-UHFFFAOYSA-N 2-(ethylamino)ethanol Chemical compound CCNCCO MIJDSYMOBYNHOT-UHFFFAOYSA-N 0.000 description 1
- RILLZYSZSDGYGV-UHFFFAOYSA-N 2-(propan-2-ylamino)ethanol Chemical compound CC(C)NCCO RILLZYSZSDGYGV-UHFFFAOYSA-N 0.000 description 1
- JOMNTHCQHJPVAZ-UHFFFAOYSA-N 2-methylpiperazine Chemical compound CC1CNCCN1 JOMNTHCQHJPVAZ-UHFFFAOYSA-N 0.000 description 1
- CJNRGSHEMCMUOE-UHFFFAOYSA-N 2-piperidin-1-ylethanamine Chemical compound NCCN1CCCCC1 CJNRGSHEMCMUOE-UHFFFAOYSA-N 0.000 description 1
- PTHDBHDZSMGHKF-UHFFFAOYSA-N 2-piperidin-2-ylethanol Chemical compound OCCC1CCCCN1 PTHDBHDZSMGHKF-UHFFFAOYSA-N 0.000 description 1
- SOYBEXQHNURCGE-UHFFFAOYSA-N 3-ethoxypropan-1-amine Chemical compound CCOCCCN SOYBEXQHNURCGE-UHFFFAOYSA-N 0.000 description 1
- FAXDZWQIWUSWJH-UHFFFAOYSA-N 3-methoxypropan-1-amine Chemical compound COCCCN FAXDZWQIWUSWJH-UHFFFAOYSA-N 0.000 description 1
- UVLSCMIEPPWCHZ-UHFFFAOYSA-N 3-piperazin-1-ylpropan-1-amine Chemical compound NCCCN1CCNCC1 UVLSCMIEPPWCHZ-UHFFFAOYSA-N 0.000 description 1
- JMUCXULQKPWSTJ-UHFFFAOYSA-N 3-piperidin-1-ylpropan-1-amine Chemical compound NCCCN1CCCCC1 JMUCXULQKPWSTJ-UHFFFAOYSA-N 0.000 description 1
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- 125000005263 alkylenediamine group Chemical group 0.000 description 1
- LHIJANUOQQMGNT-UHFFFAOYSA-N aminoethylethanolamine Chemical compound NCCNCCO LHIJANUOQQMGNT-UHFFFAOYSA-N 0.000 description 1
- IMUDHTPIFIBORV-UHFFFAOYSA-N aminoethylpiperazine Chemical compound NCCN1CCNCC1 IMUDHTPIFIBORV-UHFFFAOYSA-N 0.000 description 1
- 239000003957 anion exchange resin Substances 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 235000013405 beer Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003729 cation exchange resin Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- IUNMPGNGSSIWFP-UHFFFAOYSA-N dimethylaminopropylamine Chemical compound CN(C)CCCN IUNMPGNGSSIWFP-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- DDRPCXLAQZKBJP-UHFFFAOYSA-N furfurylamine Chemical compound NCC1=CC=CO1 DDRPCXLAQZKBJP-UHFFFAOYSA-N 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- GKQPCPXONLDCMU-CCEZHUSRSA-N lacidipine Chemical compound CCOC(=O)C1=C(C)NC(C)=C(C(=O)OCC)C1C1=CC=CC=C1\C=C\C(=O)OC(C)(C)C GKQPCPXONLDCMU-CCEZHUSRSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005374 membrane filtration Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 235000014214 soft drink Nutrition 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 1
- RAOIDOHSFRTOEL-UHFFFAOYSA-N tetrahydrothiophene Chemical compound C1CCSC1 RAOIDOHSFRTOEL-UHFFFAOYSA-N 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1456—Removing acid components
- B01D53/1475—Removing carbon dioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1493—Selection of liquid materials for use as absorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/62—Carbon oxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/50—Carbon dioxide
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2
Definitions
- CO 2 has a multiplicity of industrial applications.
- CO 2 is used for, inter alia, carbonating soft drinks, beers and mineral water and the rapid freezing of foods.
- the requirements imposed by the food industry on the purity of the CO2 to be used are high.
- CO 2 product that meets these requirements is hereinafter referred to as food grade CO 2 .
- CO 2 of (very) high purity is required; such as various analytical and medical applications and use as a coolant. Because of the stringent requirements imposed on food grade and high purity CO 2 , there is a shortage, despite the large quantities that are produced.
- CO2 recovery takes place on a large scale in ammonia processes. By further purifying this CO2 it can be made suitable for use in the food industry. Since there are not always ammonia plants in the vicinity of the numerous areas where there is a demand for CO2, it is not possible to meet the entire demand in this way.
- the invention provides a method for the recovery of very pure CO2 from flue gases, which method comprises the following steps: a) absorption of CO2 from the flue gases in a solvent in an absorber, a CO2-depleted gas stream and a CO2-rich solvent stream leaving the absorber; b) desorption of the absorbed CO2 in a desorber, a CO2-rich gas stream and a CO2- depleted solvent stream leaving the desorber; wherein the solvent used is an aqueous solution that contains an alkanolamine and an activator.
- the activator concentration is 1 to 20 wt.%, preferably 2 - 8 wt.%, in the undiluted mother solution.
- This mother solution which in general will also contain MDEA, is generally diluted 0 to 4 times, preferably 1.5 to 3 times, with water before it is fed to the absorber.
- flue gases are understood to be the off-gases from the combustion of carbon-containing substances. Examples of these are the flue gases from power stations or flue gases originating from combined heat and power plants, gas turbines or utility centres.
- heat stable salts can be removed with this method.
- These heat stable salts are alkanolamine salts, in particular of MDEA, which cannot be regenerated by means of heat (such as steam stripping). These salts lower the efficiency of the treatment with
- the present invention also provides an installation for carrying out the abovementioned process, which installation comprises: an absorber, which absorber is provided with a feed for flue gases, a feed for a solvent for CO2, a discharge for a CO2-depleted gas stream, a discharge for a CO2-rich solvent stream and a feed for make-up water; a desorber, provided with a feed for the CO2-rich solvent stream, a discharge for CO2-rich gas stream and a discharge for a CO 2 -depleted solvent stream.
- An outgoing CO 2 -depleted gas stream (3) issues from the absorber (A).
- This gas stream in general has a residual CO2 content of only 0.5 % (V/V). Because this stream contains more water (vapour) than the incoming gas stream, make-up water (2) is metered in.
- the CO2-rich solvent stream leaves the absorber via (4) and is fed via heat exchanger (J) to desorber (B). In the heat exchanger (J) the CO 2 -rich solvent stream (4) is heated by means of CO2-depleted solvent stream (5).
- Filtration unit (K) consists, successively, of a first mechanical filter, an active carbon filter and a second mechanical filter.
- the first mechanical filter removes the components that could contaminate the active carbon filter.
- the active carbon filter binds all organic degradation products.
- the second mechanical filter prevents carbon that has been flushed out from passing into downstream equipment.
- the filtered solvent is returned to the system.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Inorganic Chemistry (AREA)
- Biomedical Technology (AREA)
- Treating Waste Gases (AREA)
- Gas Separation By Absorption (AREA)
Abstract
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP01967856A EP1303344A2 (fr) | 2000-07-27 | 2001-07-27 | Recuperation de co 2? tres pur dans des fumees |
AU2001288142A AU2001288142A1 (en) | 2000-07-27 | 2001-07-27 | Recovery of pure co2 from flue gases |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL1015827 | 2000-07-27 | ||
NL1015827A NL1015827C2 (nl) | 2000-07-27 | 2000-07-27 | Winning van zuiver CO2 uit rookgassen. |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2002009849A2 true WO2002009849A2 (fr) | 2002-02-07 |
WO2002009849A3 WO2002009849A3 (en) | 2002-04-25 |
Family
ID=19771818
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/NL2001/000580 WO2002009849A2 (fr) | 2000-07-27 | 2001-07-27 | Recuperation de co2 tres pur dans des fumees |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP1303344A2 (fr) |
AU (1) | AU2001288142A1 (fr) |
NL (1) | NL1015827C2 (fr) |
WO (1) | WO2002009849A2 (fr) |
Cited By (36)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2003013699A1 (fr) * | 2001-08-10 | 2003-02-20 | Basf Aktiengesellschaft | Procede et agent d'absorption destines a l'extraction de gaz acides dans des fluides |
WO2003031028A1 (fr) * | 2001-10-08 | 2003-04-17 | Canterprise Limited | Appareil d'absorption continue de dioxyde de carbone |
WO2004110595A2 (fr) * | 2003-06-12 | 2004-12-23 | Cansolv Technologies Inc. | Procede de recuperation de co2 dans des flux gazeux |
WO2005087350A1 (fr) * | 2004-03-09 | 2005-09-22 | Basf Aktiengesellschaft | Procede d'elimination du dioxyde de carbone dans les gaz de fumee |
WO2005087349A1 (fr) * | 2004-03-09 | 2005-09-22 | Basf Aktiengesellschaft | Procede d'elimination du dioxyde de carbone dans des courants gazeux a faibles pressions partielles de dioxyde de carbone |
WO2007135100A1 (fr) * | 2006-05-19 | 2007-11-29 | Basf Se | Prémélange pour la fabrication d'un agent d'absorption pour l'élimination de gaz acides de courants de fluide |
WO2007144372A1 (fr) * | 2006-06-13 | 2007-12-21 | Basf Se | Élimination de dioxyde de carbone dans des fumées |
WO2008080221A1 (fr) * | 2006-12-28 | 2008-07-10 | Cansolv Technologies Inc. | Procédé de récupération du dioxyde de carbone à partir d'un flux de gaz |
EP2036602A1 (fr) * | 2006-06-06 | 2009-03-18 | Mitsubishi Heavy Industries, Ltd. | Liquide absorbant et appareil et procédé pour l'élimination de co2 ou h2s de gaz utilisant le liquide absorbant |
WO2009073422A1 (fr) * | 2007-12-05 | 2009-06-11 | Alstom Technoloby Ltd | Système et procédé à base d'ammoniac refroidi activé par un promoteur d'élimination de co2 d'un courant de gaz de combustion |
WO2009156271A1 (fr) | 2008-06-23 | 2009-12-30 | Basf Se | Agent absorbant et procédé pour éliminer des gaz acides contenus dans des flux de fluide, en particulier des gaz de fumée |
AU2009230803B1 (en) * | 2009-06-04 | 2010-12-16 | Mitsubishi Heavy Industries, Ltd. | CO2 recovering apparatus |
EP2283911A1 (fr) * | 2009-08-11 | 2011-02-16 | Shell Internationale Research Maatschappij B.V. | Procédé pour l'élimination de CO2 et/ou de H2S d'un gaz comprenant du CO2 et/ou du H2S |
WO2011018479A1 (fr) * | 2009-08-11 | 2011-02-17 | Shell Internationale Research Maatschappij B.V. | Composition absorbante et procédé délimination du co2 et/ou du h2s dun gaz comprenant du co2 et/ou du h2s |
US7938889B2 (en) | 2008-02-01 | 2011-05-10 | Mitsubishi Heavy Industries, Ltd. | CO2 recovery system and method of cleaning filtration membrane apparatus |
US8034166B2 (en) | 2006-05-18 | 2011-10-11 | Basf Se | Carbon dioxide absorbent requiring less regeneration energy |
US8075673B2 (en) | 2005-10-20 | 2011-12-13 | Basf Se | Absorption medium and method for removing carbon dioxide from gas streams |
US8192530B2 (en) | 2007-12-13 | 2012-06-05 | Alstom Technology Ltd | System and method for regeneration of an absorbent solution |
EP2529824A1 (fr) * | 2011-05-30 | 2012-12-05 | Kabushiki Kaisha Toshiba | Agent absorbant de gaz acides, procédé d'élimination de gaz acide et dispositif d'élimination de gaz acide |
US8388738B2 (en) | 2007-11-15 | 2013-03-05 | Basf Se | Method for removing carbon dioxide from fluid flows, in particular combustion exhaust gases |
US8398749B2 (en) | 2005-12-12 | 2013-03-19 | Basf Se | Process for the recovery of carbon dioxide |
US8728209B2 (en) | 2010-09-13 | 2014-05-20 | Alstom Technology Ltd | Method and system for reducing energy requirements of a CO2 capture system |
US8764892B2 (en) | 2008-11-04 | 2014-07-01 | Alstom Technology Ltd | Reabsorber for ammonia stripper offgas |
US8864878B2 (en) | 2011-09-23 | 2014-10-21 | Alstom Technology Ltd | Heat integration of a cement manufacturing plant with an absorption based carbon dioxide capture process |
US8864879B2 (en) | 2012-03-30 | 2014-10-21 | Jalal Askander | System for recovery of ammonia from lean solution in a chilled ammonia process utilizing residual flue gas |
US8911538B2 (en) | 2011-12-22 | 2014-12-16 | Alstom Technology Ltd | Method and system for treating an effluent stream generated by a carbon capture system |
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DE2551717C3 (de) * | 1975-11-18 | 1980-11-13 | Basf Ag, 6700 Ludwigshafen | und ggf. COS aus Gasen |
JP2925619B2 (ja) * | 1988-05-24 | 1999-07-28 | エルフ・エクスプロラシオン・プロデユクシオン | 第三級アルカノールアミン成分及びco2吸収活性剤を含有する酸性ガス吸収液体並びにco2及び任意にその他の酸性ガスを含むガスの脱酸へのその使用 |
US5618506A (en) * | 1994-10-06 | 1997-04-08 | The Kansai Electric Power Co., Inc. | Process for removing carbon dioxide from gases |
-
2000
- 2000-07-27 NL NL1015827A patent/NL1015827C2/nl not_active IP Right Cessation
-
2001
- 2001-07-27 EP EP01967856A patent/EP1303344A2/fr not_active Withdrawn
- 2001-07-27 AU AU2001288142A patent/AU2001288142A1/en not_active Abandoned
- 2001-07-27 WO PCT/NL2001/000580 patent/WO2002009849A2/fr not_active Application Discontinuation
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Also Published As
Publication number | Publication date |
---|---|
NL1015827C2 (nl) | 2002-02-01 |
AU2001288142A1 (en) | 2002-02-13 |
WO2002009849A3 (en) | 2002-04-25 |
EP1303344A2 (fr) | 2003-04-23 |
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