WO2002006392A1 - Compositions stabilisante comprenant un derive de dihydropyridine monomere et utilisation de ces compositions - Google Patents

Compositions stabilisante comprenant un derive de dihydropyridine monomere et utilisation de ces compositions Download PDF

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WO2002006392A1
WO2002006392A1 PCT/EP2001/007560 EP0107560W WO0206392A1 WO 2002006392 A1 WO2002006392 A1 WO 2002006392A1 EP 0107560 W EP0107560 W EP 0107560W WO 0206392 A1 WO0206392 A1 WO 0206392A1
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composition
polymer
weight
stabilizer
stabilizer composition
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PCT/EP2001/007560
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English (en)
Inventor
Hendrikus Luitjes
Daniël Stephan VAN ES
Johannes Cornelis Jansen
Gerard Hubert Frans Schemts
Franciscus Jeannette Maria Leonardus Peters
Erica Gertruda Arnolda Kroon
Gerardus Catharina Marie Heyman
Hendrik Willem Huisman
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Akzo Nobel N.V.
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Priority to AU2001275691A priority Critical patent/AU2001275691A1/en
Publication of WO2002006392A1 publication Critical patent/WO2002006392A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/05—Alcohols; Metal alcoholates
    • C08K5/053—Polyhydroxylic alcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
    • C08K5/3432—Six-membered rings

Definitions

  • the present invention relates to novel stabilizer compositions for polymers and the use thereof for the stabilization of polymers.
  • the present invention further pertains to a stabilized polymer so obtained, to a process for preparing the stabilized polymer, the use thereof for the production of moulded articles, as well as the resulting moulded articles.
  • Organic polymers decompose to a greater or lesser extent at higher temperatures, e.g., during the manufacture of polymer articles and/or under the influence of oxygen, light, and moisture. This decomposition not only results in an unwanted discoloration, but also in a reduction of the mechanical properties, leading, e.g., to a reduction of the residual stability in the plastic article produced, which in turn influences the durability of the article.
  • stabilizers are incorporated into or mixed with the organic polymers.
  • renewable stabilizer components i.e. components that can be produced by natural processes, such as natural polyols and derivatives, to reduce the impact on the environment and the amount of exhaustible raw materials used.
  • thermal stabilization can be achieved with natural polyols
  • the colour stability of a polymer article, particularly a polyvinyl chloride article, containing natural polyols is low. It is therefore an object of the present invention to provide stabilizer compositions which comprise a renewable stabilizer component and which, at the same time, show a good thermal stability and a good colour stability.
  • a stabilizer composition comprising renewable stabilizer components is disclosed, e.g., in EP-A-0 716 123.
  • a stabilizer composition for polyvinyl chloride comprising a polydihydropyridine, a hydrotalcite, and a natural polyol.
  • a stabilizer composition for polyvinyl chloride comprising a polydihydropyridine, a hydrotalcite, and a natural polyol.
  • the heat and colour stability of the thus stabilized polyvinyl chloride is insufficient.
  • EP-A-0 362 012 discloses a stabilizer composition which comprises at least one beta-diketone, at least one hydrotalcite, and at least one dihydropyridine.
  • a polyol is mentioned as further optional stabilizer component.
  • the price-performance ratio of the stabilization compositions as disclosed herein is insufficient. There is no suggestion that (renewable) polyols, or derivatives thereof, can be used instead of the more expensive beta-diketone.
  • EP-A-0 049 699 mentions a combination of a beta-aminocrotonate and a dihydropyridine as heat stabilizer for polyvinyl chloride.
  • beta-aminocrotonates have the disadvantage that ammonia is released at higher temperatures.
  • a stabilizer composition which is essentially free of a beta-diketone and which comprises 1.5 - 23 per cent by weight (%w/w) of at least one polyol, 1.5 - 46 %w/w of at least one acid scavenger, 3.0 - 31 %w/w of at least one monomeric dihydropyridine derivative selected from the group of substituted or unsubstituted dihydropyridine dicarboxylic acid esters, ester amides, and diamides, 0-5 %w/w of one or more oxidizing agents, and 0-94 %w/w of one or more additives, all weight percentages being based on the total weight of the stabilizer composition.
  • the polyol-containing stabilizer composition of the present invention leads to good heat as well as good colour stability.
  • the stabilizer composition of the present invention in particular has a better stabilizing effect than the stabilizer composition of EP-A-0 716 123, which contains a polydihydropyridine derivative instead of the monomeric dihydropyridine derivative of the present invention.
  • “monomeric” means that the dihydropyridine derivative of the present invention contains only one dihydropyridine moiety.
  • the monomeric dihydropyridine derivative can be used in combination with polymeric dihydropyridine derivatives, particularly dimeric
  • the present invention relates to stabilizer compositions for polymers which are essentially free of a beta-diketone and comprise 1.5 - 23 %w/w of at least one (preferably renewable) polyol or derivative thereof, 1.5 - 46 %w/w of at least one acid scavenger, and 3.0 - 31 %w/w of at least one monomeric dihydropyridine derivative selected from the group of substituted or unsubstituted dihydropyridine dicarboxylic acid esters, ester amides and diamides, optionally 0-5 %w/w of one or more oxidizing agents, and 0 - 94 %w/w of one or more additives, all based on the total weight of the stabilizer composition.
  • polyol The (preferably renewable) polyol or derivative thereof, hereinafter referred to as "polyol", as used in the stabilizer compositions of the present invention is preferably selected from the group consisting of pentaerithritol, dipentaerithritol, tripentaerythritol, bistrimethylol-propane, bistrimethylol- ethane, trimethylol-propane, trimethylol-ethane, tris-(hydroxyethyl)- isocyanurate (THEIC), tetramethylol cyclohexanol, tetramethylol cyclopentanol, tetramethylol cyclopyranol, carbohydrates such as sugars, sugar alcohols, the dehydration products of sugar alcohols, non-reducing oligo- and polysaccharides, and di-, oligo-, and polysaccharides the reducing unit of which has been reduced, cyclic polyalcohols and
  • Suitable sugars are, e.g., glucose, galactose, fructose, iso(maltulose), leucrose, lactose, sucrose, glucose oligomers, such as maltose, isomaltose, cellobiose, maltotriose, (cyclo)dextrins, fructose oligomers, and mixed oligomers and mixtures of these sugars, as well as glycosides of reducing sugars.
  • glucose oligomers such as maltose, isomaltose, cellobiose, maltotriose, (cyclo)dextrins, fructose oligomers, and mixed oligomers and mixtures of these sugars, as well as glycosides of reducing sugars.
  • Suitable sugar alcohols are, e.g., xylitol, arabinitol, sorbitol, mannitol, galactitol, lactitol, maltitol, (iso)maltitol, and maltotriol, with sorbitol being preferred.
  • Suitable dehydration products of sugar alcohols are, e.g., sorbitan, galactitan, and mannitan.
  • Suitable cyclic polyalcohols are, e.g., polyfructoses such as inulin and levan.
  • Suitable polysaccharides are, e.g., cellulose or starch.
  • the polyol comprises and more preferably consists essentially of a naturally occurring polyol.
  • An acid scavenger in the sense of the present invention is any compound which, when present in a polymer, can de-activate the acidic substances present in said polymers.
  • Such acidic substances are, e.g., acidic residues of Ziegler Natta catalysts in polyethylene, or any acidic compounds which can be formed during the processing of halogen-containing polymers, such as PVC.
  • the acid scavenger can be selected from the group of (a) natural and/or basic (mixed) metal compounds derived from inorganic and organic acids, such as substituted or unsubstituted, aliphatic or aromatic acids and phenols, (b) metal oxides and/or hydroxides, (c) layered ionic materials such as clays, (d) organic acid scavenging compounds, (e) silicates and/or (f) (bi)carbonates, such as chalk.
  • Preferred acid scavengers are selected from the compounds of groups (a)-(e), compounds of the groups (a)-(d) being most preferred.
  • Suitable (mixed) metal compounds are, e.g., calcium hydrogen phosphite, calcium carbonate, calcium stearate, calcium p-tert-butylbenzoate, calcium benzoate-lactate, calcium lactate-stearate, calcium p-octylphenolate, calcium aluminium hydroxyphosphite, and similar compounds wherein magnesium is substituted for the calcium.
  • Suitable metal oxides and/or hydroxides are, e.g., calcium hydroxide, calcium oxide, similar compounds wherein magnesium is substituted for the calcium, and aluminium hydroxide.
  • Suitable ionic layered materials are, e.g., magnesium-aluminium hydrotalcites, zeolites, and dawsonites.
  • suitable organic compounds are, e.g., dicyandiamides, amines, melamines or urea derivatives.
  • the acid scavenger is selected from one or more compounds of the group of natural and/or basic (mixed) metal compounds as described above, and layered ionic clays. More preferably, the acid scavenger comprises and most preferably consists essentially of a layered ionic clay, which preferably is a hydrotalcite.
  • the hydrotalcite preferably satisfies formula (I)
  • M 2+ represents one or more divalent metal cations selected from, e.g., zinc, calcium, iron and/or magnesium, with magnesium being most preferred.
  • M 3+ stands for one or more trivalent metal cations selected from, e.g., aluminium, iron, cobalt and/or chromium, with aluminium being most preferred.
  • a n represents one or more n valent anions, such as hydroxide, chloride, bromide, iodide, perchlorate, sulphate, bicarbonate, carbonate, oxalate, hexacyanoferrate and/or monocarboxylic acid moieties RCOO " with, e.g., 2 - 22 carbon atoms, wherein R represents a cyclic, branched or linear, saturated or non-saturated alkyl or aryl group.
  • a typical carboxylate is acetate.
  • Index x is a positive number preferably satisfying 1.5 ⁇ x ⁇ 5, n, s, and q preferably satisfy 1 ⁇ n ⁇ 4, 0 ⁇ s ⁇ 4, and 0 ⁇ q ⁇ 4, respectively.
  • the monomeric dihydropyridine derivative is selected from the group of substituted or unsubstituted dihydropyridine dicarboxylic acid esters, dihydropyridine ester amides, and dihydropyridine diamides.
  • Substituted dihydropyridine moieties may carry substituents either on the dihydropyridine ring and/or, in the case of ester amides or amides, on the amide groups.
  • the monomeric dihydropyridine dicarboxylic acid esters, ester amides, and diamides can generally be described by the following formula (II)
  • X and Y may be independently chosen from O or NR, representing the dihydropyridine dicarboxylic acid esters, amides, and ester amides, respectively, with R being selected from the group of substituted or unsubstituted alkyl, alkenyl, cycloalkyl, optionally containing heteroatom(s), such as O, S or N, in the ring, aryl, alkaryl or arylalkyl groups having up to 20 carbon atoms, or hydrogen.
  • R 1 and R 2 are independently selected from the group of substituted or unsubstituted alkyl, aikenyl, cycloalkyl, optionally containing heteroatom(s), such as O, S or N, in the ring, aryl, aikaryi or arylalkyl groups having up to 20 carbon atoms, or hydrogen in the case of X and/or Y being NR.
  • R 3 , R 4 , R 5 , and R 6 are independently selected from hydrogen or substituted or unsubstituted alkyl, aikenyl, cycloalkyl, aryl, aikaryi or arylalkyl groups having up to 22 carbon atoms.
  • Suitable substituents for the alkyl, aikenyl, cycloalkyl, aryl, aikaryi or arylalkyl groups of R 1 and R 2 are, e.g., hydroxy, ether, thioether, ester, halogen or (meth)acryloyloxy groups.
  • Examples of preferred groups for R 1 and/or R 2 are ethyl, tert. butyl, undecyl, 2-ethylhexyl, propenyl, hydroxyethyl, methoxyethyl, 2-phenoxyethyl, benzyl, and a benzoic acid ethyl ester group.
  • preferred cycloalkyl groups containing heteroatom(s) in the ring are a hindered amine satisfying formula (IV)
  • R 1 and R 2 independently are ethyl and/or benzyl groups.
  • Suitable substituents for the alkyl, aikenyl, cycloalkyl, aryl, aikaryi or arylalkyl groups of R 3 , R 4 , R 5 , and R 6 are, e.g., hydroxy and/or nitro groups.
  • R 3 and R 4 preferably are not both H and still more preferably are both methyl.
  • R 5 preferably is selected from hydrogen, alkyl, aryl or aikaryi groups and R 6 in formula (II) preferably is selected from hydrogen, benzyl or hydroxyethyl.
  • Compound (XX) is particularly preferred, being particularly suitable as it does not bloom from plastic articles prepared from a polymer composition comprising it.
  • the stabilizer composition of the present invention does not comprise any beta-diketone. Not only is the use of such compounds costly and ineffective, they also have to be combined with a metal, such as
  • the stabilizer composition of the present invention comprises one or more polyols, one or more monomeric dihydropyridine derivatives, one or more acid scavengers, and optionally one or more oxidizing agents. More preferably, the compositions according to the invention do not comprise any further colour stability improving components such as triketones, beta-aminocrotonates, and beta-keto esters. It is further preferred, particularly when the stabilizer is used in rigid PVC grades, that also no further heat stability improving components, such as epoxy compounds, are comprised in the stabilizer compositions of the present invention.
  • the oxidizing agents that are optionally used in accordance with the present invention are of the conventional type.
  • one or more oxidizing agents are used that are selected from the group consisting of Li, K, Na, Ca, Mg, Ba, Sr, Zn, Al, La or Ce perborates, perchlorates, persulfates, and/or percarbonates as well as peroxides, including inorganic peroxides like Ca0 2 , organic hydroperoxides, and peroxyacids, including perlauric acid and metachloro perbenzoic acid. If a peroxide is chosen, care has to be taken that it is not fully decomposed during the initial processing of the PVC, so that sufficient peroxide is left to be active during the formation of the finished PVC article.
  • peroxides are to be used with a half life, measured in the conventional way, of 0.1 hour at temperatures above 170°C, preferably above 180°C.
  • the strong oxidizing agent is used in such an amount that there is no residual oxidizing agent in the finished article.
  • the oxidizing agents may be used in a "dissolved” form wherein they are (pre)mixed with one or more of the other ingredients of the stabilizer composition.
  • the oxidizing agents may be used in a "dissolved” form wherein they are (pre)mixed with one or more of the other ingredients of the stabilizer composition.
  • perchlorates such as potassium and sodium perchlorate. They may be used in the pure, hydrated, or dissolved form, depending on the circumstances.
  • the oxidizing agent, or combination of oxidizing agents is used in an amount of 0-5 %w/w, preferably 0-2 %w/w.
  • the stabilizer composition of the present invention is free of any heat and colour stability improving components apart from the polyol, monomeric dihydropyridine derivative, acid scavenger, and optional perchlorate.
  • the present invention is directed to a stabilizer composition consisting essentially of 1.5 - 23 %w/w of at least one polyol, 1.5 - 46 %w/w of at least one acid scavenger, such as hydrotalcite, 3.0 - 31 %w/w of at least one monomeric dihydropyridine derivative selected from the group of substituted or unsubstituted dihydropyridine dicarboxylic acid esters, ester amides, and diamides, optionally 0 - 5 %w/w of one or more oxidizing agents, and 0 - 94 %w/w of one or more additives, based on the total weight of the stabilizer composition, with an "additive" in the sense of the present invention being any compound different from any of the above colour stability
  • Suitable additives are UV stabilizer, antioxidants, lubricants, plasticizers, reinforcing materials, optical brighteners, fillers, pigments, gelling agents, peroxide scavengers, antistatic agents, flame retardants, foaming agents, and IR absorbers, such as carbon fibrils.
  • UV stabilizers including HALS stabilizers
  • Conventional UV stabilizers are 2-hydroxy-4-n-octyloxy- benzophenone, benzotriazols, such as 2-(2'-hydroxy-5'-methylphenyl)- benzotriazoi, salicylates, such as 4 tert-butyl salicylate, acrylates, such as -cyano- ⁇ , ⁇ '-diphenyiacrylic acid isooctyl ester, nickel compounds, e.g., nickel-bis[o-ethyl(3,5-di-tert-butyl-4-hydroxybenzyl)phosphonate], diamides, e.g., 4,4'-dioctyloxy-oxanilide, triazines, such as 2,4,6-tris(2-hydroxy-4- octyloxyphenyl)-1 ,3,5-triazin
  • HALS stabilizers are, e.g., bis(2,2,6,6-tetramethyl-4-piperidinyl)-sebacate, thiodipropionic acid bis- (2,2,6, 6-tetramethyl-4-piperidinyl) ester.
  • Suitable antioxidants are, e.g., pentaerythrityl-tetrakis[ ⁇ -(3,5-di-tert-butyl-4- hydroxyphenyl)-propionate], diglyceryl-bis[ ⁇ -(3,5-di-tert-butyl-4- hydroxyphenyl)propionate], phosphonates, phosphonites, and organic phosphites.
  • Suitable pigments are, e.g., titanium dioxide, phthalo pigments, and iron oxide (Fe 2 0 3 ).
  • Suitable lubricants are, e.g., waxes such as montan wax or polyethylene wax, fatty acid esters and fatty acid amides, such as sorbitol-1 ,6-bis-(C 12 -
  • C 22 fatty acid) esters fatty alcohols, distearyl phthalate, amide waxes, chloroparaffins, glycerol esters, or metal soaps, such as calcium, zinc or aluminium carboxylates.
  • plasticizers examples include bis(2-ethylhexyl)phthalate, and isosorbide bis(octanoate).
  • Suitable fillers may be selected from chalk, kaolin, China clay, talc, silicates, glass fibres, glass spheres, wood flour, metal oxides, metal hydroxides, soot or graphite.
  • esters of thiodipropionic acid such as lauryl, stearyl, myristyl, or tridecyl esters, mercaptobenzimidazole, and the zinc salt thereof, zinc-butyl-dithiocarbamate, dioctadecyl sulphide, pentaerythritol-tetrakis(beta-dodecylmercapto)-propionate, ethylene glycol bismercaptoacetate, or thiodipropionic acid bis(2,2,6,6-tetramethyl-4- piperidyl) ester.
  • esters of thiodipropionic acid such as lauryl, stearyl, myristyl, or tridecyl esters, mercaptobenzimidazole, and the zinc salt thereof, zinc-butyl-dithiocarbamate, dioctadecyl sulphide, pentaerythritol-t
  • Suitable antistatic agents are, e.g., glycerol monostearate or sulphonates.
  • Suitable flame retardants are, e.g., aluminium hydroxide, borates, mixed metal hydroxycarbo nates.
  • the stabilizer composition contains less than 30,000 ppm of zinc, still more preferably the stabilizer composition contains less than 30,000 ppm of heavy metals, and most preferably it is essentially free of any heavy metal-containing compounds.
  • any discoloration it may be considered to omit any calcium hydroxide from the stabilizer composition, if present, in particular when the monomeric dihydropyridine derivative comprises the benzyl ester of dihydropyridine dicarboxylic acid.
  • Another alternative in cases of discoloration may be to introduce or increase the level of oxidizing agent and/or to add (further) UV stabilizers.
  • the stabilizer composition of the invention contains 20 - 80 %w/w and even more preferably 30 - .50 %w/w of these further additives, based on the total weight of the stabilizer composition.
  • the invention further pertains to the use of the stabilizer composition of the present invention for the stabilization of polymers, especially halogen- containing polymers, e.g., vinyl resins, such as polyvinyl chloride, and copolymers with vinyl chloride or non-vinyl (co)polymers, polyolefin (co)polymers, and/or blends of different copolymers.
  • polymers especially halogen- containing polymers, e.g., vinyl resins, such as polyvinyl chloride, and copolymers with vinyl chloride or non-vinyl (co)polymers, polyolefin (co)polymers, and/or blends of different copolymers.
  • the polymer is polyvinyl chloride.
  • the present invention additionally pertains to beta-diketone-free polymer compositions comprising the stabilizer composition of the present invention.
  • the stabilizer composition is used in an amount of 1 - 10 %w/w, more preferably 2 - 4 %w/w, based on the total weight of the polymer composition.
  • the polymer composition comprises 0.1 - 2.0, more preferably 0.2 - 1.0, and most preferably 0.3 - 0.6 parts by weight of the polyol, 0.1 - 3.0, more preferably 0.1 - 2.0, and most preferably 0.1 - 0.8 parts by weight of the acid scavenger, such as hydrotalcite, 0.2 - 1.5, more preferably 0.2 - 1.0, and most preferably 0.3 - 0.5 parts by weight of the monomeric dihydropyridine derivative, and 0 - 1 , more preferably 0.001 - 0.5, and most preferably 0.005 - 0.1 part by weight of a perchlorate, per 100 parts by weight of the polymer(s) contained in the polymer composition.
  • the acid scavenger such as hydrotalcite
  • the polymer composition of the invention contains less than 700 ppm of zinc, more preferably less than 700 ppm of any heavy metals, and most preferably is (essentially) free of heavy metals. It is further preferred that the polymer composition does not comprise any colour stability improving components other than the monomeric dihydropyridine derivative, the acid scavenger, the polyol, and optional perchlorate. It is further preferred that the polymer composition does not comprise any heat stability improving components apart from the monomeric dihydropyridine derivative, the acid scavenger, and the polyol. Even more preferably, the polymer composition does not comprise any heat and colour stability improving components apart from the monomeric dihydropyridine derivative, the acid scavenger, and the polyol.
  • the monomeric dihydropyridine derivatives contained in the stabilizer composition of the present invention are generally oxidized to a minor extent to the corresponding pyridine derivative during or after incorporation into the polymer composition. Therefore, the polymer composition of the present invention will generally contain a small amount of the corresponding pyridine derivative. It is further noted that if the stabilizer composition comprises, e.g., sorbitol, the sorbitol may be reduced in part to sorbitan and/or isosorbide, and the polymer composition may contain small amounts of these reduced components.
  • the present invention is directed to a process for preparing the polymer composition of the invention comprising mixing the polymer(s) with the stabilizer composition.
  • This is a conventional process which can be carried out using, e.g. calenders, mixers, compounders, extruders, and the like.
  • the present invention also pertains to the use of the polymer composition of the present invention for the production of moulded articles, such as extrudates and mouldings, e.g., films, fittings, hollow bodies, such as bottles, profiles, sheets, pipes, cables, and household articles.
  • the polymer composition can be brought to the desired shape by means of conventional processes such as extrusion, injection moulding, calendering, coating, and slush moulding. If the article is prepared by extrusion, the dibenzyl ester of the dihydropyridine derivative is particularly preferred as part of the stabilizer composition, as in this case plate out during extrusion can be successfully prevented.
  • the present invention is directed to any of the above moulded articles such as films, fittings, hollow bodies, such as bottles, profiles, sheets, pipes, cables, and household articles comprising the polymer composition of the invention.
  • a composition as given in Table I below was mixed and subsequently homogenized during gelation on a rolling mill for 5 minutes at 190°C. After the milling time, the samples were removed as sheets. The colour stability of the samples was then characterized by determining the CIE values L, a, and b, and the yellowness index Yl.
  • the CIE values were determined on press plates in accordance with DIN-5033 and DIN- 6174, using a Minolta Chromameter with a DP 301 data processor. The rating is done according to the CIE-L-a-b system (CIE: Commission International d'Eclairage).
  • the Yellowness index (Yl) was determined on press plates in accordance with ASTM 1925-70.
  • the thermal stability was characterized by means of the static heat stability.
  • test pieces of 15 mm x 250 mm were cut from the prepared sheets and placed in a Mathis Thermotester Type LTE-T at 200°C.
  • the static heat stability was measured as the time in minutes until complete blackening of the test pieces occurred.
  • a polyvinyl chloride composition was prepared as described above.
  • the resulting polyvinyl chloride composition contained as heat and colour stability improving components 0.8 part by weight of 1 ,4-dihydropyridine- 2,6-dimethyl-3,5-diethyl carboxylate, 1.2 parts by weight of a magnesium- aluminium hydrotalcite (Alcamizer®-1 ex Kyowa), and 0.4 part by weight of sorbitol, based on 100 parts by weight of polyvinyl chloride (PVC).
  • the stability of this composition is given in the Table II below.
  • a polyvinyl chloride composition was prepared in a way identical to that of
  • Example 1 except that the stabilizer composition additionally comprised 0.1 part by weight of a beta-diketone, viz. benzoyl-stearoyl-methane (Rhodiastab® 50 ex Rhone Poulenc).
  • the polyvinyl chloride composition of Comparative Example A thus comprised as heat and colour stability improving components 0.8 part by weight of 1 ,4-dihydropyridine-2,6- dimethyl-3,5-diethyl carboxylate, 1.2 parts by weight of the magnesium- aluminium hydrotalcite, 0.4 part by weight of sorbitol, and 0.1 part by weight of a beta-diketone, based on 100 parts by weight of polyvinyl chloride.
  • a polyvinyl chloride composition was prepared in a way identical to that of Example 1 , except that the stabilizer composition comprised a beta- diketone, viz. benzoyl-stearoyl-methane (Rhodiastab® 50 ex Rhone Poulenc) instead of the sorbitol.
  • the polyvinyl chloride composition of Comparative Example B thus comprised as heat and colour stability improving components 0.8 part by weight of 1 ,4-dihydropyridine-2,6- dimethyl-3,5-diethyl carboxylate, 1.2 parts by weight of the magnesium- aluminium hydrotalcite, 0.4 part by weight of the beta-diketone, based on 100 parts by weight of polyvinyl chloride.
  • This polyvinyl chloride composition thus was prepared as claimed in EP-A-0 362 012. As can be seen from Table II below, the static heat stability and the yellow index are significantly worse than those of Example 1. Comparative Example C
  • a polyvinyl chloride composition was prepared in a way identical to that of Example 1, except that the stabilizer composition contained 0.8 part by weight of the polydihydropyridine of the only Example of EP-A-0 716 123 (Synesal® M ex Lagor) instead of the monomeric dihydropyridine derivative of Example 1.
  • the polyvinyl chloride composition of Comparative Example C thus contained as heat and colour stability improving components 0.8 part by weight of the polydihydropyridine, 1.2 parts by weight of the magnesium-aluminium hydrotalcite, and 0.4 part by weight of sorbitol, based on 100 parts by weight of polyvinyl chloride.
  • the stability of this composition is given in Table II below.
  • a polyvinyl chloride composition was prepared in a way identical to that of
  • Example 1 except that 0.8 part by weight of a beta-diketone, viz. benzoyl- stearoyl-methane (Rhodiastab® 50 ex Rhone Poulenc) was used instead of the monomeric dihydropyridine derivative.
  • the polyvinyl chloride composition of Comparative Example D thus contained as heat and colour stability improving components 0.8 part by weight of the beta-diketone, 1.2 parts by weight of the magnesium-aluminium hydrotalcite, and 0.4 part by weight of the sorbitol, based on 100 parts by weight of polyvinyl chloride.
  • the stability of this composition is given in Table II below. This Table shows that the stability of the composition of Comparative Example D is significantly worse than that of Example 1. Consequently, if the monomeric dihydropyridine derivative is replaced by a beta-diketone, the stability of the polymer composition is reduced considerably.
  • Comparative Example E A polyvinyl chloride composition was prepared in a way identical to that of Example 1 , except that the stabilizer composition did not contain any hydrotalcite or sorbitol. As heat and colour stability improving component the polyvinyl chloride composition thus exclusively contained 0.8 part by weight of the 1 ,4-dihydropyridine-2,6-dimethyl-3,5-diethylcarboxylate. The stability of this composition is given in Table II below. As can be seen from this Table, the stability is significantly worse than that of Example 1.
  • a polyvinyl chloride composition was prepared in a way identical to that of Example 1 , except that the stabilizer composition did not contain any dihydropyridine derivative or sorbitol.
  • the polyvinyl chloride composition thus exclusively contained 1.2 parts by weight of the magnesium-aluminium hydrotalcite, based on 100 parts by weight of polyvinyl chloride.
  • the stability of this composition is given in Table II below. As can be seen from this Table, the stability is significantly worse than that of Example 1.
  • a polyvinyl chloride composition was prepared in a way identical to that of Example 1 , except that the stabilizer composition did not contain any dihydropyridine derivative or hydrotalcite.
  • the polyvinyl chloride composition thus exclusively contained 0.4 part by weight of the sorbitol, based on 100 parts by weight of polyvinyl chloride.
  • the stability of this composition is given in Table II below. As can be seen from this Table, the stability is significantly worse than that of Example 1.
  • a polyvinyl chloride composition was prepared in a way identical to that of Example 1 , except that the stabilizer composition did not contain any sorbitol.
  • the polyvinyl chloride composition thus exclusively contained 0.8 part by weight of the 1 ,4-dihydropyridine-2,6-dimethyl-3,5-diethyl carboxylate and 1.2 parts by weight of the magnesium-aluminium hydrotalcite, based on 100 parts by weight of polyvinyl chloride.
  • the stability of this composition is given in Table II below. As can be seen from this Table, the stability is significantly worse than that of Example 1.
  • a polyvinyl chloride composition was prepared in a way identical to that of Example 1 , except that the stabilizer composition did not contain any hydrotalcite.
  • the polyvinyl chloride composition thus exclusively contained 0.8 part by weight of the 1 ,4-dihydropyridine-2,6-dimethyl-3,5-diethylcarboxylate and 0.4 part by weight of the sorbitol, based on 100 parts by weight of polyvinyl chloride.
  • the stability of this composition is given in Table II below. As can be seen from this Table, the static heat stability of the composition is about 8 minutes worse than that of the composition of Example 1. Comparative Example J
  • a polyvinyl chloride composition was prepared in a way identical to that of Example 1 , except that the stabilizer composition did not contain any 1 ,4- dihydropyridine-2,6-dimethyl-3,5-diethylcarboxylate.
  • the polyvinyl chloride composition thus exclusively contained 1.2 parts by weight of the magnesium-aluminium hydrotalcite and 0.4 part by weight of the sorbitol, based on 100 parts by weight of polyvinyl chloride.
  • the stability of this composition is given in Table II below. As can be seen from this Table, the stability is significantly worse than that of Example 1.
  • a polyvinyl chloride composition was prepared as described in the general procedure.
  • the resulting polyvinyl chloride composition contained as heat and colour stability improving components 0.4 part by weight of 1 ,4- dihydropyridine-2,6-dimethyl-3,5-dibenzyl carboxylate, 0.3 part by weight of a magnesium-aluminium hydrotalcite (Alcamizer®-1 ex Kyowa), and 0.3 part by weight of sorbitol, based on 100 parts by weight of polyvinyl chloride.
  • the static heat stability of this composition was 33.0 minutes, the yellow index was 47.8, L was 85.5, a was -5.3, and b was 29.9.
  • This Example shows the suitability of the dibenzyl ester of the dihydropyridine derivative in the stabilizer composition of the present invention.
  • a polyvinyl chloride composition was prepared as described in the general procedure.
  • the resulting polyvinyl chloride composition contained as heat and colour stability improving components 0.4 part by weight of 1 ,4- dihydropyridine-2,6-dimethyi-3,5-dibenzyl carboxylate, 0.3 part by weight of a magnesium-aluminium hydrotalcite (Alcamizer®-1 ex Kyowa), and 0.3 part by weight of inulin, based on 100 parts by weight of polyvinyl chloride.
  • the static heat stability of this composition was 30.1 minutes, the yellowness index was 60.1 , L was 84.5, a was -3.0, and b was 36.9.
  • This Example shows the suitability of the dibenzyl ester of the dihydropyridine derivative and of inulin in the stabilizer composition of the present invention.

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

La présente invention concerne une composition stabilisante pour des polymères, comprenant 1,5 à 23 % en poids d'au moins un polyol, 1,5 à 46 % en poids d'au moins un fixateur acide, 3,0 à 31 % en poids d'au moins un dérivé de dihydropyridine monomère choisi dans le groupe comprenant des esters d'acides carboxyliques dihydropyridine substitués ou non-substitués, des esteramides, et des diamides, 0 à 5 % en poids d'un ou de plusieurs agents oxydants, et 0 à 94 % en poids d'un ou de plusieurs additifs, en fonction du poids total de la composition stabilisante, laquelle composition stabilisante étant exempte de bêta-dicétone. La présente invention concerne également l'utilisation de cette composition stabilisante pour la stabilisation des polymères. Enfin, cette invention concerne une composition polymère stabilisée contenant la composition stabilisante; un procédé de préparation associé; l'utilisation d'une telle composition pour la production d'articles moulés; et les articles moulés ainsi obtenus.
PCT/EP2001/007560 2000-07-14 2001-07-02 Compositions stabilisante comprenant un derive de dihydropyridine monomere et utilisation de ces compositions WO2002006392A1 (fr)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1466941A2 (fr) * 2003-04-11 2004-10-13 Rohm And Haas Company Composition de stabilisateur thermique pour polymères vinyliques halogénés
EP1621576A1 (fr) * 2004-07-30 2006-02-01 Rohm and Haas Company Compositions de stabilisateur thermique pour polymères vinyliques halogénés
EP1645592A1 (fr) * 2004-10-07 2006-04-12 Rohm and Haas Company Compositions de stabilisateurs thermiques pour polymères vinyliques halogénés
CN104262830A (zh) * 2014-09-10 2015-01-07 苏州新区枫盛塑料制品厂 环保pvc塑料胶粒配方
CN109608890A (zh) * 2018-12-13 2019-04-12 西南科技大学 一种硅橡胶辐射防护纳米复合材料的制备方法
CN115246986A (zh) * 2021-04-26 2022-10-28 中国石油化工股份有限公司 一种热稳定剂、透明pvc树脂及制备方法
CN115594886A (zh) * 2022-10-10 2023-01-13 潍坊亚星化学股份有限公司（Cn） 一种用于阻燃abs生产的氯化聚乙烯用稳定剂及其制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0419794A1 (fr) * 1989-09-26 1991-04-03 Hüls Aktiengesellschaft Costabilisateurs pour masses à mouler à base de polymérisats de chorure de vinyl
EP0524354A1 (fr) * 1990-05-22 1993-01-27 Witco Corporation Composition de chlorure de polyvinyl et stabilisateurs
EP0716123A2 (fr) * 1994-12-09 1996-06-12 Ciba-Geigy Ag Chlorure de polyvinyle stabilisé

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0419794A1 (fr) * 1989-09-26 1991-04-03 Hüls Aktiengesellschaft Costabilisateurs pour masses à mouler à base de polymérisats de chorure de vinyl
EP0524354A1 (fr) * 1990-05-22 1993-01-27 Witco Corporation Composition de chlorure de polyvinyl et stabilisateurs
EP0716123A2 (fr) * 1994-12-09 1996-06-12 Ciba-Geigy Ag Chlorure de polyvinyle stabilisé

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1466941A2 (fr) * 2003-04-11 2004-10-13 Rohm And Haas Company Composition de stabilisateur thermique pour polymères vinyliques halogénés
EP1466941A3 (fr) * 2003-04-11 2005-11-23 Rohm And Haas Company Composition de stabilisateur thermique pour polymères vinyliques halogénés
EP1621576A1 (fr) * 2004-07-30 2006-02-01 Rohm and Haas Company Compositions de stabilisateur thermique pour polymères vinyliques halogénés
US7488433B2 (en) 2004-07-30 2009-02-10 Rohm And Haas Company Thermal stabilizer compositions for halogen-containing vinyl polymers
EP1645592A1 (fr) * 2004-10-07 2006-04-12 Rohm and Haas Company Compositions de stabilisateurs thermiques pour polymères vinyliques halogénés
CN104262830A (zh) * 2014-09-10 2015-01-07 苏州新区枫盛塑料制品厂 环保pvc塑料胶粒配方
CN109608890A (zh) * 2018-12-13 2019-04-12 西南科技大学 一种硅橡胶辐射防护纳米复合材料的制备方法
CN115246986A (zh) * 2021-04-26 2022-10-28 中国石油化工股份有限公司 一种热稳定剂、透明pvc树脂及制备方法
CN115246986B (zh) * 2021-04-26 2023-08-11 中国石油化工股份有限公司 一种热稳定剂、透明pvc树脂及制备方法
CN115594886A (zh) * 2022-10-10 2023-01-13 潍坊亚星化学股份有限公司（Cn） 一种用于阻燃abs生产的氯化聚乙烯用稳定剂及其制备方法
CN115594886B (zh) * 2022-10-10 2023-06-23 潍坊亚星化学股份有限公司 一种用于阻燃abs生产的氯化聚乙烯用稳定剂及其制备方法

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