WO2001077242A2 - Adhesif resistant a l'eau - Google Patents

Adhesif resistant a l'eau Download PDF

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Publication number
WO2001077242A2
WO2001077242A2 PCT/GB2001/001671 GB0101671W WO0177242A2 WO 2001077242 A2 WO2001077242 A2 WO 2001077242A2 GB 0101671 W GB0101671 W GB 0101671W WO 0177242 A2 WO0177242 A2 WO 0177242A2
Authority
WO
WIPO (PCT)
Prior art keywords
composition
composition according
binding agent
adhesive
water
Prior art date
Application number
PCT/GB2001/001671
Other languages
English (en)
Other versions
WO2001077242A3 (fr
Inventor
Christine Mullock
Original Assignee
Bostik Findley Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bostik Findley Ltd. filed Critical Bostik Findley Ltd.
Priority to AU2001246733A priority Critical patent/AU2001246733A1/en
Priority to EP01919673A priority patent/EP1328604A2/fr
Publication of WO2001077242A2 publication Critical patent/WO2001077242A2/fr
Publication of WO2001077242A3 publication Critical patent/WO2001077242A3/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02—Macromolecular compounds
    • C04B26/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/06—Acrylates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04—Homopolymers or copolymers of esters
    • C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09J133/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/0045—Polymers chosen for their physico-chemical characteristics
    • C04B2103/0065—Polymers characterised by their glass transition temperature (Tg)
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00637—Uses not provided for elsewhere in C04B2111/00 as glue or binder for uniting building or structural materials
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20—Resistance against chemical, physical or biological attack
    • C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/28—Non-macromolecular organic substances
    • C08L2666/44—Silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/54—Inorganic substances

Definitions

  • the present invention relates to a water-resistant, and preferably lightweight, adhesive that is particularly useful for fixing ceramic and other tiles, especially to vertical surfaces .
  • the present invention addresses this concern.
  • the problem is to produce an adhesive, particularly suitable as a tile adhesive, and preferably of reduced specific gravity, that has suitable water-resistance without significantly impairing the other properties required of such adhesives.
  • the specific gravity of an adhesive can be reduced by the incorporation of hollow filler and/or micro-spheres and/or an air-entrainment agent, together with fibres where necessary to counteract the reduction in cohesive strength or other structural impairment that might otherwise result.
  • careful selection of the base polymer or binding agent can lead to the desired water- resistance .
  • a first embodiment of the invention therefore provides a composition suitable for use as a water-resistant tile adhesive (preferably one meeting BS 5980:1980 Class AA) or grout, comprising:
  • an aqueous organic binding agent preferably as an aqueous dispersion and including a poly (acrylic ester) or copolymer thereof, particularly a copoly er comprising an acrylate and a methacrylate ;
  • a poly (acrylic ester) or copolymer thereof particularly a copoly er comprising an acrylate and a methacrylate ;
  • a second embodiment of the invention provides a composition suitable for use as a water-resistant tile adhesive (again, preferably one meeting BS 5980:1980 Class AA) or grout, comprising: an aqueous organic binding agent preferably as an aqueous dispersion and comprising a copolymer comprising an acrylate and a methacrylate; an adhesion promoter, preferably a silane; and sufficient filler and/or micro- spheres to result in a specific gravity of the composition of less than 1 g/cm 3 , and preferably less than 0.75g/cm 3 ; and preferably also fibres .
  • the invention provides for the use of a copolymer comprising an acrylate and a methacrylate as an organic binding agent in a tile adhesive or grout containing filler and/or micro- spheres and as a means of increasing water-resistance .
  • the filler and/or microspheres are preferably hollow.
  • the binding agent preferably comprises a copolymer comprising an acrylate and a methacrylate, although other comparable repeat units may be provided instead or in addition.
  • At least 70 mol %, especially at least 85 mol%, particularly at least 95 mol % and most particularly substantially all of the polymer is made up of acrylate and methacrylate repeat units.
  • the copolymer preferably comprises 40-60 mol%, especially 45-55 mol% of each of the acrylate and the methacrylate . More than one type of acrylate and more than one type of methacrylate may be present, although at present it is preferred at least 75 mol% and preferably at least 85 mol% of each of the acrylate and methacrylate be of a single type.
  • the acrylate be 2 -ethyl hexyl acrylate and/or butyl acrylate (and if both preferably a minor quantity, say less than 10 mol%, of the latter)
  • the methacrylate be methyl methacrylate and/or butyl methacrylate (and if both preferably a minor quantity, say less than 10 mol%, of the latter) .
  • binding agent may be present.
  • acrylic acid and/or methacrylic acid may be present.
  • the preferred amount of the total of these two materials is less than 5, particularly less than 1.5, for example 0.5-5, especially 0.75-1.5, say about 1, mol % based on the number of moles of acrylate and methacrylate in the copolymer.
  • the binding agent may also include, in addition to a base polymer (preferably that referred to above) one or more of the following :
  • a coalescing solvent such as a glycol ether for example 2 butoxy ethanol
  • an antifoaming agent for example a silicone
  • surfactant which if present is preferably polymerizable or polymeric or otherwise becomes inactive once the adhesive or grout has been installed (polymeric compositions which contain such surfactants may be referred to as
  • surfactant free since the surfactant is not available in the installed product
  • the adhesion promoter is in general an important component of the composition. Its role in preferred compositions is to stabilize some form of association between the polymer of the binding agent and the substrate (tile or wall or other surface) and/or the filler. This will usually be by means of a simple chemical bond. In this way, adhesion is promoted.
  • Preferred materials comprise silanes such as a ⁇ - glycidoxypropylmethyldiethoxy silane such as that marketed under the trade mark Witco Y15078. Preferred amounts are from 0.5-2% by weight based on the total weight of the composition.
  • the binding agent preferably contains particles of "diameter" 0.01-1.0, particularly 0.05- 0.5, especially about O.l ⁇ m.
  • the particles need not of course be precisely spherical, although they preferably are smooth having substantially no sharp edges, and may therefore be regarded as preferably substantially spherical.
  • a diameter we refer to the diameter of spherical particles of the same volume as the actual particles.
  • the particle size distribution is not critical, but we prefer that at least 50%, more preferably at least 75%, especially at least 90%, and usually substantially all, of the particles are within the diameters ranges given above.
  • the binding agent (together with the other component if appropriate) preferably gives the overall composition a pH of 7-9.
  • the binding agent preferably has good UV resistance and good cement resistance, in addition to the good water resistance for which is was primarily selected.
  • the binding agent preferably comprises a material having a minimum film forming temperature of 10°C or less, especially 5°C or less, for example about 3°C.
  • the binding agent preferably has a glass transition temperature (Tg) of less than room temperature, more preferably 9 to 17°C, especially 11 to 15°C and most especially about 13°C.
  • a preferred binding agent is an ionic aqueous emulsion marketed by Rhodia under the trademark Rhoximat DEC 27.
  • the adhesive is particularly useful for bonding ceramic tiles, and also for attaching tiles to vertical surfaces. It may also be used as a grout.
  • the adhesive conform to British Standard BS 5980:1980 Class AA and/or to EN 12004.
  • the adhesive be a Type 2 adhesive.
  • Type 2 adhesives are manufactured as ready-for-use mixtures, and they consist of organic binding agents as an aqueous emulsion or latex, generally with mineral filling materials.
  • organic binding agents may be used in addition to or in place of the ones mentioned above: one or more homo- or co-polymers of acrylic acid, methacrylic acid, acrylamide, methacrylic esters, vinyl esters, itaconic esters, vinyl ethers, olefins such as ethylene, styrene, butadiene, acrylonitrile or vinylidene chloride.
  • homo- or co-polymers we include carboxylated versions of the basic polymers, such as carboxylated styrene butadiene acrylonitrile.
  • Acrylic or styrene acrylate co-polymers are preferred for some uses.
  • the amount of conventional particulate inorganic fillers be kept to a minimum. Most preferably, we prefer that such fillers be substantially absent from the adhesive. A preferred maximum amount of such fillers may be taken as 30% by weight based on the total weight of the composition. A more preferred maximum is 10% by weight.
  • the micro-spheres may comprise any suitable material, the most important characteristic being their specific gravity.
  • the micro-spheres will, in general, be hollow (in which case they may then constitute said hollow filler) , and preferably closed. They will thus trap within them air or other generally inert gas depending on their method of formation.
  • the term "micro-spheres" is well-known, and it will be appreciated that their shape need not be precisely spherical in a mathematical sense. Hollow filler of tubular or ellipsoidal shape may be used. Their size is not critical although we prefer they be sufficiently small that the texture of the adhesive is not adversely effected, and that they be sufficiently small in relation to their wall thickness that they be resistant to crushing during manufacture, use and service life of the adhesive.
  • micro-spheres present in any given sample of adhesive need not, of course, be of identical size.
  • the average diameter of the micro-spheres be from 10 to 500 microns; and we prefer that at least 50% preferably at least 75%, especially at least 90%, and most preferably substantially all, of the micro-spheres be within that range.
  • the micro-spheres or hollow filler are not spherical, one may take as their diameter the diameter of a sphere of identical volume.
  • the material from which the micro-spheres are made may be selected from a wide variety of possibilities, thermoplastic polymers, glasses and ceramics all being acceptable.
  • borosilicate particularly soda lime borosilicate, glass shells in the form of bubbles or beads
  • Those marketed under the trademark “Scotchlite” are preferred, but a product marketed under the trade mark “Expancel”, which is made from a thermoplastic polymer encapsulating a gas may also be useful.
  • Particularly preferred versions are known by the trademarks "Scotchlite Kl” and "Expancel 551 WE”.
  • micro-spheres can be combined with an organic binding agent to form an aqueous dispersion to provide a composition having the physical properties desired of a tile adhesive. Due to the very low specific gravity of the micro-spheres, the overall specific gravity of the composition is considerably reduced. For many purposes up to 40% by weight, generally from 10 to 40% by weight of micro-spheres may be provided based on the total weight of solids in the composition. Design of adhesives is inevitably a compromise, and as the content of micro-spheres increases the structural properties of the composition are likely to deteriorate somewhat. It is surprising, however, that significant reductions in specific gravity can be achieved at such little cost to these structural properties.
  • micro-spheres are desirable, or where some property such as cohesive strength, elongation or modulus is critical, we prefer that a certain quantity of fibre be added to the composition. In this way, we are able to compensate for any deleterious effect that the substitution of micro- spheres for conventional inorganic fillers may otherwise cause.
  • a variety of types of fibre, organic or inorganic may be used.
  • An example of inorganic fibres includes silica whiskers.
  • organic fibres such as cellulose, polyacrylonitrile and polyethylene. The length, thickness, size distribution and overall amount of the fibres will depend on exactly which physical properties of the composition are most important.
  • a weight range based on the total weight of the composition, of from 1 to 20% especially from 2 to 10%, may be taken as typical.
  • Preferred fibres are those of length between 50 and 1500 microns, and we prefer that 50% of the fibres be in that range, more preferably that at least 75% by weight of the fibres have lengths from 100 to 1000 microns.
  • the composition may include an air-entrainment agent, which serves to stabilise a froth-like or foam-like characteristic of the adhesive composition.
  • air entrainment agents include soaps, emulsifying or foaming agents, which may act by forming a binding network in bubble walls. Examples include fatty acid ether sulfates, aliphatic carboxylic acid derivatives, and alkyl phenol ethoxylate.
  • a further useful component is a coalescing solvent which acts to reduce the ambient temperature at which the adhesive composition forms a film.
  • Suitable coalescing solvents include butyl diglycol acetate, di-isobutyl glutarate, and ethylene glycol .
  • the amount of the coalescing solvent is preferably from 0.5 to S%, more preferably 1 to 2%, by weight based on the total weight of the composition. In general, the amount required will depend upon the amount and nature of the organic binding agent .
  • compositions of the invention may be classified as dispersion adhesives since they are based on organic binding materials in the form for example of aqueous emulsions or latexes. In some circumstances, however, aqueous solutions may be used. In any case, water will be present. The amount of water will usually be more than 20%, particularly more than 40% and often more than 50% by weight based on the total weight of the composition. Nonetheless, a solids content of from 10 to 60 percent based on the total weight of the composition will usually produce good results.
  • the composition may be manufactured by mixing together various components, some of which are themselves emulsions, dispersions or solutions. The percentages of water just quoted of course include water added as such during manufacture and water added as part of such other components .
  • the structural characteristics of the adhesive composition may be improved, not only by the addition of the fibres, but also by the addition of one or more swelling clay minerals.
  • swelling clay minerals may reduce or prevent slip. These minerals should be homogeneously distributed throughout the composition. As a result, structure is improved by thickening the composition.
  • the clay may be of synthetic or natural origin and may exhibit a wide range of swelling ability. Preferred materials are smectite minerals such as montmorillonite when in calcium or magnesium form, or hectorite or laponite when in sodium form.
  • Alternative swelling clays are attapulgite and sepiolite.
  • the quantity of swelling clay thickener is preferably at least 0.2 and more preferably at least 0.5%, and is preferably less than 10%, more preferably less than 5%, based on the total weight of the composition.
  • the amount added will depend in part on the swelling ability of the clay.
  • Additional thickeners may be added such as polyacrylic acid polymers and/or cellulose thickeners, examples of which include methyl hydroxy propyl cellulose, carboxy methyl cellulose and ethyl hydroxy cellulose.
  • the preferred amount of such thickeners is from 0.1 to 5% by weight based on the total weight of the composition.
  • a cationic scavenger may be added in order to reduce or to prevent thickening of the adhesive composition during storage.
  • a suitable cationic scavenger is a phosphate material, for example sodium hexametaphosphate .
  • additives may be provided depending upon the precise use of the composition.
  • one may include one or more fungicides, one or more pigments, one or more dispersants, one or more cross-linking agents for the copolymer of the binding agent, silica, and other additives conventionally used in the adhesives industry.
  • compositions have an appearance of a mousse and were suitable for application to a vertical surface at a thickness of 0.5 cm without slump. In general, all examples showed excellent viscosity, low density, non-slip capability, flexibility and wetting character.
  • An adhesive composition was prepared from the following components. The trade names for each component listed are explained below.
  • the standard EN 12004 is at present provisional.
  • the adhesive of this example performs very similar to the requirements under that standard too.
  • An adhesive composition was prepared from the following components .
  • An adhesive composition was prepared from the following components .
  • the adhesive satisfied BS 5980:1980 for Type 2 Class B and Class AA.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

Un adhésif léger résistant à l'eau, destiné notamment à être utilisé en tant qu'adhésif ou mortier pour carreaux est produit par l'addition d'un promoteur d'adhésion plus une charge et/ou des microsphères creuses à un agent de liaison organique aqueux contenant un ester acrylique particulier sous la forme d'une dispersion aqueuse.
PCT/GB2001/001671 2000-04-12 2001-04-12 Adhesif resistant a l'eau WO2001077242A2 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
AU2001246733A AU2001246733A1 (en) 2000-04-12 2001-04-12 Water-resistant grout and title adhesive composition
EP01919673A EP1328604A2 (fr) 2000-04-12 2001-04-12 Adhesif resistant a l'eau

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB0009017.5 2000-04-12
GBGB0009017.5A GB0009017D0 (en) 2000-04-12 2000-04-12 Water-resistant adhesive

Publications (2)

Publication Number Publication Date
WO2001077242A2 true WO2001077242A2 (fr) 2001-10-18
WO2001077242A3 WO2001077242A3 (fr) 2003-05-22

Family

ID=9889771

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB2001/001671 WO2001077242A2 (fr) 2000-04-12 2001-04-12 Adhesif resistant a l'eau

Country Status (4)

Country Link
EP (1) EP1328604A2 (fr)
AU (1) AU2001246733A1 (fr)
GB (1) GB0009017D0 (fr)
WO (1) WO2001077242A2 (fr)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005056489A1 (fr) * 2003-12-05 2005-06-23 Speciality Construction Brands, Inc. Compositions de coulis a base de polymeres
US7005462B2 (en) 2003-12-05 2006-02-28 Specialty Construction Brands, Inc. Polymer grout compositions
US7303068B2 (en) 2003-12-05 2007-12-04 Specialty Construction Brando, Inc. Polymer grout compositions
WO2010133468A1 (fr) * 2009-05-18 2010-11-25 Wacker Chemie Ag Matériaux de construction sous forme de pâtes fibreuses
DE102009003281A1 (de) 2009-05-20 2010-11-25 Wacker Chemie Ag Verwendung von Polymerisaten in Bauklebern
US7981962B1 (en) 2007-10-31 2011-07-19 Specialty Construction Brand, Inc. Polymer grout compositions
WO2012007057A1 (fr) * 2010-07-16 2012-01-19 Parexlanko Composition sèche redispersable de couche de finition polymère
WO2012114129A1 (fr) * 2011-02-25 2012-08-30 Tuffbau Limited Mélanges de liant améliorés
GB2497558A (en) * 2011-12-14 2013-06-19 Bostik Ltd Tile adhesive
EP2886523A1 (fr) * 2013-12-19 2015-06-24 Bostik Sa Composition d'enduit pour mur et plafond ayant des propriétés d'isolation thermique
IT201700010948A1 (it) * 2017-02-01 2018-08-01 Lucini Antonio Una colla per incollare la ceramica a pareti e pavimenti dotata di proprietà atermiche e fonoisolanti, procedimento per la sua preparazione e uso della stessa
WO2020006434A1 (fr) * 2018-06-29 2020-01-02 Laticrete International Inc. Technologie prête à l'emploi (rtu) à base de dispersion présentant la performance d'une résine réactive
CN112662349A (zh) * 2020-12-31 2021-04-16 江西省宜春正大化工胶粘剂有限公司 一种瓷砖胶粘剂及其制备方法
FR3108351A1 (fr) * 2020-03-17 2021-09-24 Produits De Revetement Du Batiment Procédé de pose de revêtement céramique et composition pour la pose dudit revêtement sur un support

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GB2497559A (en) * 2011-12-14 2013-06-19 Bostik Ltd A tile adhesive containing crushed glass

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EP0199921A2 (fr) * 1985-04-04 1986-11-05 PCI Polychemie GmbH Masse de remplissage et de jointoyage déformable et son utilisation
EP0214696A1 (fr) * 1985-09-10 1987-03-18 Dsm Resins B.V. Composition à base d'une dispersion aqueuse d'un polymère d'addition
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EP0544569A1 (fr) * 1991-11-27 1993-06-02 Rhone-Poulenc Chimie Dispersions aqueuses de polymères styrène/acrylate carboxylés et leurs utilisations comme liant dans des compositions adhésives et de revêtement
EP0857772A1 (fr) * 1997-02-06 1998-08-12 Wacker-Chemie GmbH Compositions de jointoiement à coefficient d'élasticité élevé
EP0924250A1 (fr) * 1997-12-15 1999-06-23 Witco Corporation Materiau d'étanchéité à base de latex contenant des epoxysilanes
JPH11189764A (ja) * 1997-12-26 1999-07-13 Mitsui Chem Inc タイル用接着剤組成物
WO2000006611A1 (fr) * 1998-07-28 2000-02-10 Stepan Company Revetements, agents de scellement, adhesifs et elastomeres ameliores utilisant des latex polymeres derives des sels amines insatures

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Publication number Priority date Publication date Assignee Title
US4590230A (en) * 1982-03-05 1986-05-20 Mitsui Toatsu Chemicals, Incorporated Adhesive composition for ceramic tiles
EP0199921A2 (fr) * 1985-04-04 1986-11-05 PCI Polychemie GmbH Masse de remplissage et de jointoyage déformable et son utilisation
EP0214696A1 (fr) * 1985-09-10 1987-03-18 Dsm Resins B.V. Composition à base d'une dispersion aqueuse d'un polymère d'addition
EP0220841A2 (fr) * 1985-10-25 1987-05-06 DAP Inc. Adhésifs à base de latex acrylique
EP0256144A2 (fr) * 1986-07-02 1988-02-24 National Starch and Chemical Corporation Emulsions alcalines durcissantes dans des mélanges cimentaires
US5124384A (en) * 1990-11-16 1992-06-23 Air Products And Chemicals, Inc. Transparent caulks containing fumed silica
EP0502573A1 (fr) * 1991-02-27 1992-09-09 Dsm N.V. Usage d'une dispersion résineuse comme adhésif et utilisation de cette dispersion comme une base pour adhésif
EP0544569A1 (fr) * 1991-11-27 1993-06-02 Rhone-Poulenc Chimie Dispersions aqueuses de polymères styrène/acrylate carboxylés et leurs utilisations comme liant dans des compositions adhésives et de revêtement
EP0857772A1 (fr) * 1997-02-06 1998-08-12 Wacker-Chemie GmbH Compositions de jointoiement à coefficient d'élasticité élevé
EP0924250A1 (fr) * 1997-12-15 1999-06-23 Witco Corporation Materiau d'étanchéité à base de latex contenant des epoxysilanes
US6001907A (en) * 1997-12-15 1999-12-14 Witco Corporation Latex sealants containing epoxysilanes
JPH11189764A (ja) * 1997-12-26 1999-07-13 Mitsui Chem Inc タイル用接着剤組成物
WO2000006611A1 (fr) * 1998-07-28 2000-02-10 Stepan Company Revetements, agents de scellement, adhesifs et elastomeres ameliores utilisant des latex polymeres derives des sels amines insatures

Cited By (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005056490A1 (fr) * 2003-12-05 2005-06-23 Specialty Construction Brands, Inc. Compositions de coulis au ciment polymere
US7005462B2 (en) 2003-12-05 2006-02-28 Specialty Construction Brands, Inc. Polymer grout compositions
US7303068B2 (en) 2003-12-05 2007-12-04 Specialty Construction Brando, Inc. Polymer grout compositions
AU2004297194B2 (en) * 2003-12-05 2009-11-19 Speciality Construction Brands, Inc. Polymer grout compositions
AU2004297204B2 (en) * 2003-12-05 2010-09-16 Specialty Construction Brands, Inc. Polymer grout compositions
WO2005056489A1 (fr) * 2003-12-05 2005-06-23 Speciality Construction Brands, Inc. Compositions de coulis a base de polymeres
US7981962B1 (en) 2007-10-31 2011-07-19 Specialty Construction Brand, Inc. Polymer grout compositions
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GB0009017D0 (en) 2000-05-31
EP1328604A2 (fr) 2003-07-23
WO2001077242A3 (fr) 2003-05-22
AU2001246733A1 (en) 2001-10-23

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