WO2001062987A1 - Einrichtung zum zerstäuben von flüssigen schmelzen - Google Patents
Einrichtung zum zerstäuben von flüssigen schmelzen Download PDFInfo
- Publication number
- WO2001062987A1 WO2001062987A1 PCT/AT2001/000036 AT0100036W WO0162987A1 WO 2001062987 A1 WO2001062987 A1 WO 2001062987A1 AT 0100036 W AT0100036 W AT 0100036W WO 0162987 A1 WO0162987 A1 WO 0162987A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- lance
- nozzle
- outlet opening
- steam
- slag
- Prior art date
Links
- 239000000155 melt Substances 0.000 title claims abstract description 18
- 239000007788 liquid Substances 0.000 title claims abstract description 13
- 239000002893 slag Substances 0.000 claims abstract description 25
- 239000007789 gas Substances 0.000 claims abstract description 12
- 239000011521 glass Substances 0.000 claims abstract description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 11
- 229910002804 graphite Inorganic materials 0.000 claims description 9
- 239000010439 graphite Substances 0.000 claims description 9
- 229910000831 Steel Inorganic materials 0.000 claims description 6
- 239000007921 spray Substances 0.000 claims description 6
- 239000010959 steel Substances 0.000 claims description 6
- 238000006073 displacement reaction Methods 0.000 claims description 4
- 229910010293 ceramic material Inorganic materials 0.000 claims description 3
- 239000004020 conductor Substances 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 abstract description 4
- 238000002347 injection Methods 0.000 abstract 1
- 239000007924 injection Substances 0.000 abstract 1
- 238000000889 atomisation Methods 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 230000008023 solidification Effects 0.000 description 5
- 238000007711 solidification Methods 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 239000003380 propellant Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 2
- UOUJSJZBMCDAEU-UHFFFAOYSA-N chromium(3+);oxygen(2-) Chemical class [O-2].[O-2].[O-2].[Cr+3].[Cr+3] UOUJSJZBMCDAEU-UHFFFAOYSA-N 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 208000012868 Overgrowth Diseases 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000010891 electric arc Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 235000013980 iron oxide Nutrition 0.000 description 1
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B5/00—Treatment of metallurgical slag ; Artificial stone from molten metallurgical slag
- C04B5/06—Ingredients, other than water, added to the molten slag or to the granulating medium or before remelting; Treatment with gases or gas generating compounds, e.g. to obtain porous slag
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B3/00—General features in the manufacture of pig-iron
- C21B3/04—Recovery of by-products, e.g. slag
- C21B3/06—Treatment of liquid slag
- C21B3/08—Cooling slag
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B2400/00—Treatment of slags originating from iron or steel processes
- C21B2400/02—Physical or chemical treatment of slags
- C21B2400/022—Methods of cooling or quenching molten slag
- C21B2400/024—Methods of cooling or quenching molten slag with the direct use of steam or liquid coolants, e.g. water
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B2400/00—Treatment of slags originating from iron or steel processes
- C21B2400/02—Physical or chemical treatment of slags
- C21B2400/022—Methods of cooling or quenching molten slag
- C21B2400/026—Methods of cooling or quenching molten slag using air, inert gases or removable conductive bodies
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B2400/00—Treatment of slags originating from iron or steel processes
- C21B2400/05—Apparatus features
- C21B2400/062—Jet nozzles or pressurised fluids for cooling, fragmenting or atomising slag
Definitions
- the invention relates to a device for atomizing liquid melts, in particular oxidic slags or glasses, with a slag tundish and an outlet opening into which a lance for injecting gases or steam is immersed to form an annular gap.
- the lance for injecting gases or steam was either arranged above the liquid melt level and thus subjected to less wear, which means that the ejection characteristic is naturally was largely dependent on the height of the slag bath or the height of the molten bath.
- naturally high-temperature-resistant materials have to be used, whereby compliance with a defined jet geometry and a defined atomization is made more difficult by the fact that solidification in the area of the outlet opening changes the gap geometry and changes the Particle size distribution of the atomized droplets leads.
- the device according to the invention essentially consists in that the lance is formed by two coaxial tubes which can be adjusted separately from one another in the axial direction and can be fixed in their respective axial displacement position.
- the inlet gap width for the liquid melt with the outer tube can be adjusted by a relative displacement of these two tubes to each other, whereas the desired jet parameters by appropriate adjustment of the inner tube to the specifications, such as pressure or type of propellant medium can be adjusted.
- the lance from two coaxial tubes to use different materials and, for example, to arrange a sleeve or an outer tube made of high-temperature-resistant ceramic or inexpensive graphite, whereas the inner tube of the lance can consist of correspondingly high-temperature-resistant steel or likewise of ceramic material and through the sleeve is protected from excessive corrosive or thermal attack by the melt.
- a sleeve as a wearing part, it is possible to significantly reduce the operating costs of such a device and, at the same time, the parameters for the desired droplet formation or jet formation within wide limits.
- graphite is only suitable as a material for the sleeve if carbon cannot be dissolved in the melt to be atomized. This applies to melts that contain neither metals nor iron or chromium oxides.
- Graphite as a material for the outer tube represents a particularly inexpensive wear part, which at the same time offers the possibility of effectively countering an increase in the outlet opening.
- the design according to the invention is such that the outlet opening as a nozzle block and the outer tube or the sleeve of the lance consist of electrically conductive material, in particular graphite, and then, if the nozzle block is also formed of electrically conductive material, in a simple manner electrical heating, for example by forming an arc between the sleeve and the nozzle block in the area of the inlet opening and the application of the driving steel, can take place, so that a constant nozzle geometry can be ensured during operation.
- electrical heating for example by forming an arc between the sleeve and the nozzle block in the area of the inlet opening and the application of the driving steel
- the basic principle is that the droplets or the corresponding solidifying particles become finer as the vapor temperature rises, which can be attributed, among other things, to a corresponding improvement in the rheology of the droplets.
- high final steam temperatures generally require a correspondingly complex steam generation and a correspondingly complex supply of high-temperature steam to the lance. Due to the fact that the steam is finally heated or finally overheated, for example by an electric arc, the steam can be overheated to a maximum of 1600 ° C with significantly lower steam temperatures and, for example, with steam temperatures of about 700 ° C and a steam pressure of 10 bar maximum. Steam generation is therefore correspondingly more cost-effective and the temperature load steam lance is greatly reduced.
- the central tube of the lance is made of ceramic material or of high-grade steel, which makes it easier to maintain the conditions for an exact jet geometry. While with conventional lances made of steel thermal deformation and possibly even melting of the mouth of the lance must be expected, the use of a sleeve made of temperature-resistant material enables the slag to act directly from the mouth of the central pipe or Keep the inner tube away so that the consistency of the jet geometry can be maintained over a longer period of time.
- the design is such that the nozzle block has a conical inlet opening and an oppositely conical outlet opening which diverges towards the mouth, thereby ensuring that the inlet gap and the essential atomization parameters can be set in a simple manner by a corresponding axial displacement ,
- the geometry of the outlet opening can be kept free from influences, for example an overgrowth by solidification, and it therefore corresponds to a preferred embodiment that the nozzle block and the outer tube or the sleeve also a power source to form an electrical heater in the area of the nozzle block.
- the size of the atomized melt droplets can be reduced even further in that, as is in a preferred embodiment, at least one ring nozzle is arranged coaxially to the outlet opening in a spray chamber connected to the slag tundish, the axes of the nozzle outlet openings preferably being essentially parallel to the Axis of the lance or are diverging. A thread formation cannot be prevented in the area of the sprayed melt droplets emerging from the tundish, which is mainly due to the increased surface tension of the solidifying melt droplets.
- FIG. 1 shows a partial view of a slag tundish with an outlet opening and FIG. 2 shows a slag tundish with a connected spray chamber.
- FIG. 1 shows a partial view of a slag tundish with an outlet opening and
- FIG. 2 shows a slag tundish with a connected spray chamber.
- the bottom and a side wall of a slag tundish is denoted by 1.
- the lance 3 consists of an inner tube 4 made of high-temperature-resistant steel and an outer tube or a sleeve 5 made of graphite.
- nozzle block 6 which in turn can itself be made of graphite, wherein when using graphite for the material of the sleeve 5 or the nozzle block 6, all that needs to be taken into account is that the melt 2 does not contain materials, in which carbon is soluble. This applies in particular when the melt is not an iron melt and when the melt contains neither iron oxides nor chromium oxides.
- the two components of the lance 3, namely the inner tube 4 and the sleeve 5, can each be adjusted separately in the direction of the double arrow 7 in the height direction.
- a shift of the outer sleeve 5 defines the width of the inlet gap for liquid melts.
- graphite for the material of the sleeve 5 and the nozzle block 6, a stable arc can be established between these two components which act as electrodes, so that the geometry and the defined gap width cannot be impaired by solidification processes.
- the jet geometry can now be set within wide limits and adapted to the respective propellant.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Metallurgy (AREA)
- Nozzles (AREA)
- Manufacture Of Iron (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
Abstract
Description
Claims
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA002370806A CA2370806C (en) | 2000-02-22 | 2001-02-15 | Device for atomizing liquid melts |
AT01905476T ATE262597T1 (de) | 2000-02-22 | 2001-02-15 | Einrichtung zum zerstäuben von flüssigen schmelzen |
AU33476/01A AU769996B2 (en) | 2000-02-22 | 2001-02-15 | Device for atomising liquid melts |
DE50101749T DE50101749D1 (de) | 2000-02-22 | 2001-02-15 | Einrichtung zum zerstäuben von flüssigen schmelzen |
BRPI0104578-4A BR0104578B1 (pt) | 2000-02-22 | 2001-02-15 | dispositivo para a pulverização de fusões lìquidas. |
EP01905476A EP1203102B1 (de) | 2000-02-22 | 2001-02-15 | Einrichtung zum zerstäuben von flüssigen schmelzen |
US09/959,060 US6660223B2 (en) | 2000-02-22 | 2001-02-15 | Device for atomizing liquid melts |
JP2001561795A JP2003523824A (ja) | 2000-02-22 | 2001-02-15 | 融液のアトマイズ装置 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ATA275/2000 | 2000-02-22 | ||
AT0027500A AT408437B (de) | 2000-02-22 | 2000-02-22 | Einrichtung zum zerstäuben von flüssigen schmelzen |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2001062987A1 true WO2001062987A1 (de) | 2001-08-30 |
Family
ID=3670611
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/AT2001/000036 WO2001062987A1 (de) | 2000-02-22 | 2001-02-15 | Einrichtung zum zerstäuben von flüssigen schmelzen |
Country Status (11)
Country | Link |
---|---|
US (1) | US6660223B2 (de) |
EP (1) | EP1203102B1 (de) |
JP (1) | JP2003523824A (de) |
AT (1) | AT408437B (de) |
AU (1) | AU769996B2 (de) |
BR (1) | BR0104578B1 (de) |
CA (1) | CA2370806C (de) |
DE (1) | DE50101749D1 (de) |
PT (1) | PT1203102E (de) |
WO (1) | WO2001062987A1 (de) |
ZA (1) | ZA200108337B (de) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1400602A2 (de) * | 2002-09-10 | 2004-03-24 | Tribovent Verfahrensentwicklung GmbH | Verfahren zum Zerstäuben und Granulieren von Schmelzen sowie Vorrichtung zur Durchführung dieses Verfahrens |
WO2004081237A1 (de) * | 2003-03-11 | 2004-09-23 | Holcim Ltd. | Vorrichtung zum zerstäuben von schmelzen |
WO2005094153A1 (de) * | 2004-04-01 | 2005-10-13 | Patco Engineering Gmbh | Einrichtung und verfahren zum oxidieren, reduzieren, kalzinieren, sintern oder schmelzen von stäuben unter verwendung eines dosierzyklons mit brennstofflanze |
US7240520B2 (en) * | 2002-08-29 | 2007-07-10 | Holcim Ltd. | Method and device for pulverizing and granulating melts |
WO2018091959A1 (de) * | 2016-11-15 | 2018-05-24 | Radmat Ag | Verfahren und vorrichtung zur aufarbeitung einer eisenoxid und phosphoroxide enthaltenden schmelze |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT409136B (de) * | 2000-05-19 | 2002-05-27 | Tribovent Verfahrensentwicklg | Einrichtung zum zerstäuben und zerkleinern von flüssigen schmelzen |
AT410640B (de) * | 2000-07-07 | 2003-06-25 | Tribovent Verfahrensentwicklg | Verfahren und vorrichtung zum zerstäuben von metallschmelzen |
DE10107553A1 (de) * | 2001-02-17 | 2002-09-05 | Messer Griesheim Gmbh | Vorrichtung und Verfahren zum Pulverisieren von Werkstoffen, insbesondere Gläsern |
GB0417378D0 (en) * | 2004-08-04 | 2004-09-08 | Boc Group Plc | Gas abatement |
WO2007045089A1 (en) * | 2005-10-17 | 2007-04-26 | National Research Council Of Canada | Reactive spray formation of coatings and powders |
GB0902221D0 (en) * | 2009-02-11 | 2009-03-25 | Edwards Ltd | Pilot |
JP5503518B2 (ja) * | 2010-12-20 | 2014-05-28 | 株式会社神戸製鋼所 | 高炉スラグ顕熱回収装置 |
SK500452011A3 (sk) | 2011-11-04 | 2013-09-03 | Igor Kocis | Method for rock dislodging by melting and interaction with water streams |
GB2508200B (en) * | 2012-11-23 | 2015-08-05 | Siemens Vai Metals Tech Gmbh | Slag granulation system and method of operation |
DE102015107876A1 (de) * | 2015-05-19 | 2016-11-24 | Technische Universität Bergakademie Freiberg | Vorrichtung und Verfahren zum Zerstäuben von Schmelzen |
CN107694777A (zh) * | 2017-09-08 | 2018-02-16 | 安徽省振华科技工业有限公司 | 一种达克罗涂覆处理过程的全方位喷涂装置 |
CN111218533A (zh) * | 2020-01-08 | 2020-06-02 | 西安建筑科技大学 | 一种钢渣资源化处理方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4502633A (en) * | 1982-11-05 | 1985-03-05 | Eastman Kodak Company | Variable capacity gasification burner |
US4993691A (en) * | 1988-09-28 | 1991-02-19 | Arbed S.A. | Oxygen injection lance |
US5667147A (en) * | 1993-12-03 | 1997-09-16 | Holderbank Financiere Glarus Ag | Process and device for granulating and crushing molten materials and grinding stocks |
AT403927B (de) * | 1996-09-17 | 1998-06-25 | Holderbank Financ Glarus | Verfahren zum aufarbeiten von verbrennungsrückständen |
WO1999042623A1 (de) * | 1998-02-18 | 1999-08-26 | 'holderbank' Financiere Glarus Ag | Verfahren zum granulieren und zerkleinern von flüssigen schlacken sowie einrichtung zur durchführung dieses verfahrens |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ID21879A (id) * | 1997-09-15 | 1999-08-05 | Holderbank Financ Glarus | Proses peningkatan terak baja berikut pengemban besi untuk medapatkan besi kasar dan terak yang aman bagi lingkungan |
AT406262B (de) * | 1998-06-29 | 2000-03-27 | Holderbank Financ Glarus | Verfahren und vorrichtung zum granulieren und zerkleinern von flüssigen schlacken |
WO2000044942A1 (de) * | 1999-01-28 | 2000-08-03 | 'holderbank' Financiere Glarus Ag | Verfahren und vorrichtung zum granulieren und zerkleinern von flüssigen schlacken |
EP1190996A3 (de) * | 2000-09-20 | 2003-01-15 | Tribovent Verfahrensentwicklung GmbH | Einrichtung zum Zerstäuben von Schmelzen |
-
2000
- 2000-02-22 AT AT0027500A patent/AT408437B/de not_active IP Right Cessation
-
2001
- 2001-02-15 PT PT01905476T patent/PT1203102E/pt unknown
- 2001-02-15 AU AU33476/01A patent/AU769996B2/en not_active Ceased
- 2001-02-15 CA CA002370806A patent/CA2370806C/en not_active Expired - Fee Related
- 2001-02-15 BR BRPI0104578-4A patent/BR0104578B1/pt not_active IP Right Cessation
- 2001-02-15 US US09/959,060 patent/US6660223B2/en not_active Expired - Fee Related
- 2001-02-15 EP EP01905476A patent/EP1203102B1/de not_active Expired - Lifetime
- 2001-02-15 DE DE50101749T patent/DE50101749D1/de not_active Expired - Lifetime
- 2001-02-15 WO PCT/AT2001/000036 patent/WO2001062987A1/de active IP Right Grant
- 2001-02-15 JP JP2001561795A patent/JP2003523824A/ja not_active Withdrawn
- 2001-10-10 ZA ZA200108337A patent/ZA200108337B/en unknown
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4502633A (en) * | 1982-11-05 | 1985-03-05 | Eastman Kodak Company | Variable capacity gasification burner |
US4993691A (en) * | 1988-09-28 | 1991-02-19 | Arbed S.A. | Oxygen injection lance |
US5667147A (en) * | 1993-12-03 | 1997-09-16 | Holderbank Financiere Glarus Ag | Process and device for granulating and crushing molten materials and grinding stocks |
AT403927B (de) * | 1996-09-17 | 1998-06-25 | Holderbank Financ Glarus | Verfahren zum aufarbeiten von verbrennungsrückständen |
WO1999042623A1 (de) * | 1998-02-18 | 1999-08-26 | 'holderbank' Financiere Glarus Ag | Verfahren zum granulieren und zerkleinern von flüssigen schlacken sowie einrichtung zur durchführung dieses verfahrens |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7240520B2 (en) * | 2002-08-29 | 2007-07-10 | Holcim Ltd. | Method and device for pulverizing and granulating melts |
EP1400602A2 (de) * | 2002-09-10 | 2004-03-24 | Tribovent Verfahrensentwicklung GmbH | Verfahren zum Zerstäuben und Granulieren von Schmelzen sowie Vorrichtung zur Durchführung dieses Verfahrens |
EP1400602A3 (de) * | 2002-09-10 | 2004-07-21 | Tribovent Verfahrensentwicklung GmbH | Verfahren zum Zerstäuben und Granulieren von Schmelzen sowie Vorrichtung zur Durchführung dieses Verfahrens |
WO2004081237A1 (de) * | 2003-03-11 | 2004-09-23 | Holcim Ltd. | Vorrichtung zum zerstäuben von schmelzen |
WO2005094153A1 (de) * | 2004-04-01 | 2005-10-13 | Patco Engineering Gmbh | Einrichtung und verfahren zum oxidieren, reduzieren, kalzinieren, sintern oder schmelzen von stäuben unter verwendung eines dosierzyklons mit brennstofflanze |
US7678167B2 (en) | 2004-04-01 | 2010-03-16 | Patco Engineering Gmbh | Device and method for oxidizing, reducing, calcining, sintering, or melting dusts |
WO2018091959A1 (de) * | 2016-11-15 | 2018-05-24 | Radmat Ag | Verfahren und vorrichtung zur aufarbeitung einer eisenoxid und phosphoroxide enthaltenden schmelze |
Also Published As
Publication number | Publication date |
---|---|
BR0104578B1 (pt) | 2010-08-10 |
DE50101749D1 (de) | 2004-04-29 |
ZA200108337B (en) | 2003-01-10 |
US6660223B2 (en) | 2003-12-09 |
AT408437B (de) | 2001-11-26 |
AU3347601A (en) | 2001-09-03 |
EP1203102A1 (de) | 2002-05-08 |
US20020158376A1 (en) | 2002-10-31 |
EP1203102B1 (de) | 2004-03-24 |
JP2003523824A (ja) | 2003-08-12 |
CA2370806C (en) | 2009-02-03 |
ATA2752000A (de) | 2001-04-15 |
BR0104578A (pt) | 2002-01-08 |
PT1203102E (pt) | 2004-08-31 |
AU769996B2 (en) | 2004-02-12 |
CA2370806A1 (en) | 2001-08-30 |
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