WO2001036323A3 - Catalyseurs a base de cobalt et procede de production de gaz de synthese - Google Patents

Catalyseurs a base de cobalt et procede de production de gaz de synthese Download PDF

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Publication number
WO2001036323A3
WO2001036323A3 PCT/US2000/031451 US0031451W WO0136323A3 WO 2001036323 A3 WO2001036323 A3 WO 2001036323A3 US 0031451 W US0031451 W US 0031451W WO 0136323 A3 WO0136323 A3 WO 0136323A3
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WO
WIPO (PCT)
Prior art keywords
cobalt
conversion
hydrocarbon feedstock
synthesis gas
based catalysts
Prior art date
Application number
PCT/US2000/031451
Other languages
English (en)
Other versions
WO2001036323A2 (fr
Inventor
Anne M Gaffney
Roger Song
Robert Oswald
David Corbin
Original Assignee
Conoco Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Conoco Inc filed Critical Conoco Inc
Priority to AU17679/01A priority Critical patent/AU1767901A/en
Priority to CA002392106A priority patent/CA2392106A1/fr
Priority to EP00980414A priority patent/EP1230146A2/fr
Publication of WO2001036323A2 publication Critical patent/WO2001036323A2/fr
Publication of WO2001036323A3 publication Critical patent/WO2001036323A3/fr

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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/005—Spinels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8913—Cobalt and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/386—Catalytic partial combustion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0261—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005—Arrangement or shape of catalyst
    • C01B2203/1023—Catalysts in the form of a monolith or honeycomb
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005—Arrangement or shape of catalyst
    • C01B2203/1029—Catalysts in the form of a foam
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1082—Composition of support materials
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1094—Promotors or activators
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

L'invention concerne un procédé d'oxydation catalytique partielle d'hydrocarbures légers tels que le méthane. Ledit procédé consiste à convertir une charge d'hydrocarbure en mettant en contact un courant d'alimentation comprenant la charge d'hydrocarbure et un gaz contenant de l'oxygène avec un catalyseur dans une zone de réaction maintenue dans des conditions favorisant la conversion dans un réacteur, avec un temps de contact d'une milliseconde, afin d'obtenir un courant d'effluent contenant essentiellement du monoxyde de carbone et de l'hydrogène. Certains catalyseurs préférés de l'invention comprennent du métal de cobalt et/ou des composés contenant du cobalt, un promoteur, et un support réfractaire pouvant produire de façon efficace un gaz de synthèse à haute sélectivité pour les produits de CO et de H2.
PCT/US2000/031451 1999-11-17 2000-11-15 Catalyseurs a base de cobalt et procede de production de gaz de synthese WO2001036323A2 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
AU17679/01A AU1767901A (en) 1999-11-17 2000-11-15 Cobalt-based catalysts and process for producing synthesis gas
CA002392106A CA2392106A1 (fr) 1999-11-17 2000-11-15 Catalyseurs a base de cobalt et procede de production de gaz de synthese
EP00980414A EP1230146A2 (fr) 1999-11-17 2000-11-15 Catalyseurs a base de cobalt et procede de production de gaz de synthese

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US16598199P 1999-11-17 1999-11-17
US60/165,981 1999-11-17
US71260700A 2000-11-14 2000-11-14
US09/712,607 2000-11-14

Publications (2)

Publication Number Publication Date
WO2001036323A2 WO2001036323A2 (fr) 2001-05-25
WO2001036323A3 true WO2001036323A3 (fr) 2002-02-14

Family

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Family Applications (1)

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PCT/US2000/031451 WO2001036323A2 (fr) 1999-11-17 2000-11-15 Catalyseurs a base de cobalt et procede de production de gaz de synthese

Country Status (4)

Country Link
EP (1) EP1230146A2 (fr)
AU (1) AU1767901A (fr)
CA (1) CA2392106A1 (fr)
WO (1) WO2001036323A2 (fr)

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US6958309B2 (en) * 2002-08-01 2005-10-25 Conocophillips Company Hydrothermal pretreatment for increasing average pore size in a catalyst support
US7041621B2 (en) 2003-01-17 2006-05-09 Conocophillips Company Sulfided catalysts for improved performance in hydrocarbon processing
EP1703979B1 (fr) 2003-12-18 2011-05-25 Chiyoda Corporation Catalyseur pour la fabrication d'un gaz de synthese et procede de fabrication d'un gaz de synthese au moyen dudit catalyseur
RU2483799C2 (ru) * 2010-12-24 2013-06-10 Российская Федерация, от имени которой выступает Министерство промышленности и торговли Российской Федерации (Минпромторг России) Способ получения катализатора паровой конверсии метансодержащих углеводородов
EA025547B1 (ru) 2011-06-23 2017-01-30 СТАМИКАРБОН Б.В. ЭКТИНГ АНДЕР ДЗЕ НЕЙМ ОФ ЭмТи ИННОВЕЙШН СЕНТЕР Способ производства промежуточного синтетического газа, подходящего для производства водорода
WO2012177137A1 (fr) 2011-06-23 2012-12-27 Stamicarbon B.V. Acting Under The Name Of Mt Innovation Center Procédé de production d'ammoniac et d'urée
CN103889891B (zh) 2011-10-26 2016-09-14 代表Mt创新中心的斯塔米卡邦有限公司 生产用于生产甲醇的合成气的方法
NO2771274T3 (fr) 2011-10-26 2018-06-30
CA2859678C (fr) 2011-12-19 2019-07-30 Stamicarbon B.V. Acting Under The Name Of Mt Innovation Center Procede de production d'ammoniac et d'uree
KR101437072B1 (ko) * 2011-12-26 2014-09-03 한국화학연구원 효율적인 이산화탄소 전환 촉매 및 이의 제조 방법
CN105188915B (zh) 2013-05-09 2021-03-09 沙特基础工业全球技术公司 碱土金属/金属氧化物负载型催化剂
US9499403B2 (en) 2013-07-10 2016-11-22 Saudi Arabian Oil Company Catalyst and process for thermo-neutral reforming of liquid hydrocarbons
EP3027311A2 (fr) 2013-07-31 2016-06-08 Saudi Basic Industries Corporation Catalyseur et procédé pour la production d'oléfines à partir de syngaz
CN103464164B (zh) * 2013-08-27 2015-11-18 中国华能集团清洁能源技术研究院有限公司 酒石酸络合法制备甲烷化催化剂的方法
CN103586028B (zh) * 2013-10-25 2015-05-20 中国华能集团清洁能源技术研究院有限公司 葡萄糖络合法制备甲烷化催化剂的方法
US20170080407A1 (en) * 2014-03-14 2017-03-23 Basf Se Yttrium-containing catalyst for high-temperature carbon dioxide hydration, combined high-temperature carbon dioxide hydration, and reforming and/or reforming, and a method for high-temperature carbon dioxide hydration, combined high-temperature carbon dioxide hydration and reforming and/or reforming
US10196348B2 (en) 2014-07-15 2019-02-05 Stamicarbon B.V. Method for revamping a urea production complex
DK3362405T3 (da) 2015-10-15 2022-11-21 Stamicarbon B V Acting Under The Name Of Mt Innovation Center Fremgangsmåde og produktionsenhed til fremstilling af methanol
US10046309B2 (en) 2016-06-28 2018-08-14 Yasin Khani Supported nanocatalyst for catalytic reforming reactions
CN109678551B (zh) * 2019-01-21 2021-04-20 河北工业大学 一种多孔烧绿石陶瓷复合材料及其制备方法
CN112675863B (zh) * 2019-10-17 2023-04-28 中国石油化工股份有限公司 一种甲烷燃烧的催化剂及其制备方法和应用
CN111185165B (zh) * 2020-03-20 2022-09-20 北京工业大学 一种以水滑石和碳前体制备的铝镁钬复合氧化物负载钐铂催化剂的制备方法和应用
CN111889101B (zh) * 2020-08-13 2021-10-12 清华大学 用于VOCs和NO协同净化的改性复合氧化物催化剂及其制备方法
CN114984959A (zh) * 2022-06-07 2022-09-02 福州大学 一种甲烷催化燃烧铜钴尖晶石催化剂及其制备方法
CN116393132A (zh) * 2023-04-17 2023-07-07 中国科学技术大学 四氧化三钴/铜单原子复合材料、其制备方法及其应用

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US3385670A (en) * 1964-12-29 1968-05-28 Pullman Inc Steam reforming of hydrocarbons and catalyst therefor containing a cobalt component on a zirconia support
JPS58207946A (ja) * 1982-05-29 1983-12-03 Toyota Central Res & Dev Lab Inc 炭化水素の部分酸化用触媒およびその製造方法
EP0656317A1 (fr) * 1993-11-29 1995-06-07 Shell Internationale Researchmaatschappij B.V. Procédé d'oxydation partielle catalytique d'hydrocarbones
US5756421A (en) * 1992-09-10 1998-05-26 Council Of Scientific & Industrial Research Composite catalysts containing transitional and alkaline earth metal oxides useful for oxidative conversion of methane (or natural gas) to carbon monoxide and hydrogen (or synthesis gas)

Patent Citations (4)

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US3385670A (en) * 1964-12-29 1968-05-28 Pullman Inc Steam reforming of hydrocarbons and catalyst therefor containing a cobalt component on a zirconia support
JPS58207946A (ja) * 1982-05-29 1983-12-03 Toyota Central Res & Dev Lab Inc 炭化水素の部分酸化用触媒およびその製造方法
US5756421A (en) * 1992-09-10 1998-05-26 Council Of Scientific & Industrial Research Composite catalysts containing transitional and alkaline earth metal oxides useful for oxidative conversion of methane (or natural gas) to carbon monoxide and hydrogen (or synthesis gas)
EP0656317A1 (fr) * 1993-11-29 1995-06-07 Shell Internationale Researchmaatschappij B.V. Procédé d'oxydation partielle catalytique d'hydrocarbones

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CHEMICAL ABSTRACTS, vol. 131, no. 10, 6 September 1999, Columbus, Ohio, US; abstract no. 135150, CIMINO, ALESSANDRO ET AL: "High and low surface area NiO-MgO and CoO-MgO solid solutions: a study of XPS surface composition and CO oxidation activity" XP002159881 *
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KINET. CATAL. (1998), 39(3), 400-410, 1998 *
M. P. MAKOA ET AL.: "Characterisation of Co/Mg/Al2O3 high pressure partial oxidation catalysts", CATALYSIS TODAY, vol. 49, 24 February 1999 (1999-02-24), pages 11 - 16, XP002159880 *
PATENT ABSTRACTS OF JAPAN vol. 008, no. 052 (C - 213) 9 March 1984 (1984-03-09) *
TOP. CATAL. (1999), 8(3,4), 171-178, 1999 *

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