CA2392106A1 - Catalyseurs a base de cobalt et procede de production de gaz de synthese - Google Patents

Catalyseurs a base de cobalt et procede de production de gaz de synthese Download PDF

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Publication number
CA2392106A1
CA2392106A1 CA002392106A CA2392106A CA2392106A1 CA 2392106 A1 CA2392106 A1 CA 2392106A1 CA 002392106 A CA002392106 A CA 002392106A CA 2392106 A CA2392106 A CA 2392106A CA 2392106 A1 CA2392106 A1 CA 2392106A1
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CA
Canada
Prior art keywords
cobalt
catalyst device
catalyst
reactant gas
gas mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002392106A
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English (en)
Inventor
David M. Minahan
Joe D. Allison
Sriram Ramani
Roger Song
Robert Oswald
David Corbin
Anne M. Gaffney
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ConocoPhillips Co
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Individual
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Publication of CA2392106A1 publication Critical patent/CA2392106A1/fr
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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002Mixed oxides other than spinels, e.g. perovskite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/005Spinels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74Iron group metals
    • B01J23/75Cobalt
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8913Cobalt and noble metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/386Catalytic partial combustion
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00Constitutive chemical elements of heterogeneous catalysts
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/025Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0261Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005Arrangement or shape of catalyst
    • C01B2203/1023Catalysts in the form of a monolith or honeycomb
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005Arrangement or shape of catalyst
    • C01B2203/1029Catalysts in the form of a foam
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1047Group VIII metal catalysts
    • C01B2203/1052Nickel or cobalt catalysts
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1082Composition of support materials
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1094Promotors or activators
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205Composition of the feed
    • C01B2203/1211Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235Hydrocarbons
    • C01B2203/1241Natural gas or methane
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

L'invention concerne un procédé d'oxydation catalytique partielle d'hydrocarbures légers tels que le méthane. Ledit procédé consiste à convertir une charge d'hydrocarbure en mettant en contact un courant d'alimentation comprenant la charge d'hydrocarbure et un gaz contenant de l'oxygène avec un catalyseur dans une zone de réaction maintenue dans des conditions favorisant la conversion dans un réacteur, avec un temps de contact d'une milliseconde, afin d'obtenir un courant d'effluent contenant essentiellement du monoxyde de carbone et de l'hydrogène. Certains catalyseurs préférés de l'invention comprennent du métal de cobalt et/ou des composés contenant du cobalt, un promoteur, et un support réfractaire pouvant produire de façon efficace un gaz de synthèse à haute sélectivité pour les produits de CO et de H¿2?.
CA002392106A 1999-11-17 2000-11-15 Catalyseurs a base de cobalt et procede de production de gaz de synthese Abandoned CA2392106A1 (fr)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US16598199P 1999-11-17 1999-11-17
US60/165,981 1999-11-17
US71260700A 2000-11-14 2000-11-14
US09/712,607 2000-11-14
PCT/US2000/031451 WO2001036323A2 (fr) 1999-11-17 2000-11-15 Catalyseurs a base de cobalt et procede de production de gaz de synthese

Publications (1)

Publication Number Publication Date
CA2392106A1 true CA2392106A1 (fr) 2001-05-25

Family

ID=26861844

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002392106A Abandoned CA2392106A1 (fr) 1999-11-17 2000-11-15 Catalyseurs a base de cobalt et procede de production de gaz de synthese

Country Status (4)

Country Link
EP (1) EP1230146A2 (fr)
AU (1) AU1767901A (fr)
CA (1) CA2392106A1 (fr)
WO (1) WO2001036323A2 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10046309B2 (en) 2016-06-28 2018-08-14 Yasin Khani Supported nanocatalyst for catalytic reforming reactions

Families Citing this family (24)

* Cited by examiner, † Cited by third party
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GB0214383D0 (en) 2002-06-21 2002-07-31 Isis Innovation Catalyst
US6958309B2 (en) 2002-08-01 2005-10-25 Conocophillips Company Hydrothermal pretreatment for increasing average pore size in a catalyst support
US7041621B2 (en) 2003-01-17 2006-05-09 Conocophillips Company Sulfided catalysts for improved performance in hydrocarbon processing
US7888282B2 (en) 2003-12-18 2011-02-15 Chiyoda Corporation Catalyst for manufacturing synthesis gas and method of manufacturing synthesis gas using the same
RU2483799C2 (ru) * 2010-12-24 2013-06-10 Российская Федерация, от имени которой выступает Министерство промышленности и торговли Российской Федерации (Минпромторг России) Способ получения катализатора паровой конверсии метансодержащих углеводородов
EP2723676B1 (fr) 2011-06-23 2018-12-05 Stamicarbon B.V. acting under the name of MT Innovation Center Procédé de production d'ammoniac et d'urée
CA2837773C (fr) 2011-06-23 2018-10-16 Stamicarbon B.V. Acting Under The Name Of Mt Innovation Center Procede de production d'un gaz de synthese constituant un bon intermediaire pour la production d'hydrogene
US9394219B2 (en) 2011-10-26 2016-07-19 Stamicarbon B.V. Method for producing synthesis gas for methanol production
DK2771275T3 (da) 2011-10-26 2019-08-19 Stamicarbon B V Acting Under The Name Of Mt Innovation Center Fremgangsmåde til fremstilling af syntesegas til methanolfremstilling
CA2859678C (fr) 2011-12-19 2019-07-30 Stamicarbon B.V. Acting Under The Name Of Mt Innovation Center Procede de production d'ammoniac et d'uree
KR101437072B1 (ko) * 2011-12-26 2014-09-03 한국화학연구원 효율적인 이산화탄소 전환 촉매 및 이의 제조 방법
US9616414B2 (en) 2013-05-09 2017-04-11 Sabic Global Technologies B.V. Alkaline earth metal/metal oxide supported catalysts
US9499403B2 (en) 2013-07-10 2016-11-22 Saudi Arabian Oil Company Catalyst and process for thermo-neutral reforming of liquid hydrocarbons
US9486785B2 (en) 2013-07-31 2016-11-08 Saudi Basic Industries Corporation Catalyst and process for the production of olefins from syngas
CN103464164B (zh) * 2013-08-27 2015-11-18 中国华能集团清洁能源技术研究院有限公司 酒石酸络合法制备甲烷化催化剂的方法
CN103586028B (zh) * 2013-10-25 2015-05-20 中国华能集团清洁能源技术研究院有限公司 葡萄糖络合法制备甲烷化催化剂的方法
CA2942587A1 (fr) * 2014-03-14 2015-09-17 Basf Se Catalyseur renfermant de l'yttrium destine a l'hydratation de dioxyde de carbone haute temperature, l'hydratation de dioxyde de carbone haute temperature combinee et le reformage et/ou le reformage, et une methode d'hydratation de dioxyde de carbone haute temperature, d'hydratation de dioxyde de carbone haute temperature et de reformage et/ou de reformage
WO2016010416A1 (fr) 2014-07-15 2016-01-21 Stamicarbon B.V. Acting Under The Name Of Mt Innovation Center Procédé de restructuration d'un complexe de production d'urée
WO2017065613A1 (fr) 2015-10-15 2017-04-20 Stamicarbon B.V. Acting Under The Name Of Mt Innovation Center Procédé pour la production de méthanol
CN109678551B (zh) * 2019-01-21 2021-04-20 河北工业大学 一种多孔烧绿石陶瓷复合材料及其制备方法
CN112675863B (zh) * 2019-10-17 2023-04-28 中国石油化工股份有限公司 一种甲烷燃烧的催化剂及其制备方法和应用
CN111185165B (zh) * 2020-03-20 2022-09-20 北京工业大学 一种以水滑石和碳前体制备的铝镁钬复合氧化物负载钐铂催化剂的制备方法和应用
CN111889101B (zh) * 2020-08-13 2021-10-12 清华大学 用于VOCs和NO协同净化的改性复合氧化物催化剂及其制备方法
CN114984959A (zh) * 2022-06-07 2022-09-02 福州大学 一种甲烷催化燃烧铜钴尖晶石催化剂及其制备方法

Family Cites Families (4)

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US3385670A (en) * 1964-12-29 1968-05-28 Pullman Inc Steam reforming of hydrocarbons and catalyst therefor containing a cobalt component on a zirconia support
JPS58207946A (ja) * 1982-05-29 1983-12-03 Toyota Central Res & Dev Lab Inc 炭化水素の部分酸化用触媒およびその製造方法
US5756421A (en) * 1992-09-10 1998-05-26 Council Of Scientific & Industrial Research Composite catalysts containing transitional and alkaline earth metal oxides useful for oxidative conversion of methane (or natural gas) to carbon monoxide and hydrogen (or synthesis gas)
CO4370053A1 (es) * 1993-11-29 1996-10-07 Shell Int Research Proceso para la oxidacion parcial catalitica de hidrocarbu- ros

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10046309B2 (en) 2016-06-28 2018-08-14 Yasin Khani Supported nanocatalyst for catalytic reforming reactions

Also Published As

Publication number Publication date
WO2001036323A2 (fr) 2001-05-25
WO2001036323A3 (fr) 2002-02-14
EP1230146A2 (fr) 2002-08-14
AU1767901A (en) 2001-05-30

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