WO2001032780A1 - Compose cire - Google Patents

Compose cire Download PDF

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Publication number
WO2001032780A1
WO2001032780A1 PCT/DE2000/003793 DE0003793W WO0132780A1 WO 2001032780 A1 WO2001032780 A1 WO 2001032780A1 DE 0003793 W DE0003793 W DE 0003793W WO 0132780 A1 WO0132780 A1 WO 0132780A1
Authority
WO
WIPO (PCT)
Prior art keywords
wax
montan
solidification point
compound
compound according
Prior art date
Application number
PCT/DE2000/003793
Other languages
German (de)
English (en)
Inventor
Jörg Abraham
Jutta Edel
Andreas Mieth
Original Assignee
Romonta Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Romonta Gmbh filed Critical Romonta Gmbh
Publication of WO2001032780A1 publication Critical patent/WO2001032780A1/fr

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
    • C08L91/06—Waxes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
    • C08L91/06—Waxes
    • C08L91/08—Mineral waxes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
    • D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers

Definitions

  • the invention relates to a wax compound which is provided as an additive during incorporation into a carrier system to make it hydrophobic.
  • Mainly mineral and building materials or fillers based on fibers or renewable raw materials as well as pigments are regarded as carrier substances.
  • aqueous, surfactant-based emulsions or dispersions e.g. on paraffin or paraffin / montan wax basis, and subsequent drying;
  • montan wax for waterproofing purposes has long been known. The effectiveness is significantly increased by combination with paraffins. Such systems were used directly as prills or as dispersions. Milling with mineral carriers and thus the production of a finely divided product is also described in the prior art. Through the use of dispersions or dry grinding products, the wax is more evenly distributed and in a much greater fineness than prilled wax in the mixture of application substances. This will make the continuous
  • Impregnation as a result of the effect of heat favors the fact that smaller particles firstly melt faster and more completely and secondly that the wax melt has to overcome shorter distances in order to penetrate the application material without defects.
  • the amount of work required and the temperature holding time decrease.
  • An essential aim of the invention is therefore the further development of the state of the art in the field in question with regard to the further reduction of the application material in the carrier system.
  • the melting point should be below the temperature that occurs during processing
  • the compound should be finely dispersible and have a high active ingredient content
  • the product should be easy to fix and also flowable carrier substances can be metered;
  • the invention relates to a compound of natural and / or synthetic waxes, montan wax ingredients, resin, preferably of natural origin, and paraffin waxes and / or fats or fatty acids.
  • the compound is also chemically modified.
  • it contains small amounts of hardening or elasticity-improving substances, surface-active and / or effectiveness-increasing substances, and grinding aids or substances which prevent reagglomeration.
  • the specific substance composition of the compound according to the invention depends on the substance matrix in which it should act. The properties of the wax compound are adjusted in such a way that it can be shredded using suitable grinding processes, e.g. Grinding in chilled high-speed
  • Mills with high impact loads can be processed into a dust-like product and in this form leads to a significantly improved mass-effectiveness ratio.
  • the subject matter of the invention is defined in detail by the features described below.
  • montan wax In addition to the montan wax component, up to 40% esterified wax fractions and up to 60% paraffins are contained.
  • Alkaline earth based on wax, provided.
  • the esterification is carried out with 10-40% longer-chain alcohols from C 8 or 3-10% or with polyhydric alcohols, for example glycols or polyvinyl alcohol, in each case based on wax.
  • montan wax ingredients mentioned are a fraction of aliphatic wax acids and esters concentrated or mainly non-straight chain components of montan wax, which can be pretreated by oxygen oxidation and then esterified.
  • the said montan wax fraction can be caused by other long-chain ester waxes
  • Natural basis such as carnauba, modified fats or synthetic esters, can be replaced in whole or in part and reinforced by up to 80% thermoplastic resins based on natural or hydrocarbon based on the wax fraction.
  • the paraffin parts are hardened by up to 30% additives, for example
  • PE wax or hard paraffin or by up to 30% elasticity improving
  • Elastomers each based on paraffin
  • the compound according to the invention contains small amounts of activity-increasing additives in the form of silicone oil.
  • the total compound contains a maximum of 15%.
  • the substances supporting the grinding and connecting substances are added and incorporated between the wax compound and the surfaces of the application substances. Both tasks are performed by up to 30% lignin products, especially lignin sulfonates, and up to 25% cellulose derivatives, such as their ethers and esters, based on the total compound.
  • the wax compound described is suitable with regard to its use for direct fine grinding, as well as for grinding with carriers of mineral and / or other nature, such as carbon products or fibers.
  • the product is also suitable for surfactant-based dispersion. It can therefore be used for many areas of application.
  • Example 4 30% carnauba wax or montan wax

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

L'invention concerne un composé cire servant de granulats lors de son intégration dans un système support aux fins d'imperméabilisation de ce dernier. On utilise comme supports principalement des matériaux de construction ou matières de charge minéraux et basés sur des fibres ou des matières brutes renouvelables, ainsi que des pigments. L'invention concerne un composé en cires naturelles et/ou synthétiques, des constituants de cire instantanée, de la résine, de préférence d'origine naturelle, et des paraffines et/ou des graisses ou acides gras. En outre, ce composé est chimiquement modifié. Il contient non seulement les constituants cités qui peuvent être présents ensemble ou individuellement, mais aussi de faibles quantités de substances durcissantes ou améliorant l'élasticité, des agents tensioactifs et/ou augmentant l'efficacité ainsi que des agents auxiliaires de broyage ou des substances empêchant la réagglomération. La composition concrète du composé selon l invention est déterminée par la matrice matière dans laquelle elle doit agir. Les propriétés du composé cire sont réglées de telle façon que des procédés de désintégration adéquats, par exemple, un broyage dans des broyeurs grande vitesse refroidis et à fortes sollicitations de percussions, permettent de le transformer en produit pulvérulent. Le composé permet alors, sous cette forme, d'obtenir un rapport masse/efficacité nettement amélioré.
PCT/DE2000/003793 1999-11-01 2000-10-27 Compose cire WO2001032780A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19952563.3 1999-11-01
DE1999152563 DE19952563A1 (de) 1999-11-01 1999-11-01 Wachscompound

Publications (1)

Publication Number Publication Date
WO2001032780A1 true WO2001032780A1 (fr) 2001-05-10

Family

ID=7927575

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/DE2000/003793 WO2001032780A1 (fr) 1999-11-01 2000-10-27 Compose cire

Country Status (2)

Country Link
DE (1) DE19952563A1 (fr)
WO (1) WO2001032780A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003104330A1 (fr) * 2002-06-05 2003-12-18 Clariant Gmbh Melanges de cires finement broyees
EP1426350A2 (fr) 2002-10-30 2004-06-09 Readymix AG Matériaux de construction, élément de construction en résultant et utilisation des cires montans

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004011391A1 (fr) * 2002-07-30 2004-02-05 Cooee Biosciences Limited Materiaux de construction impermeabilisants renfermant des esters a haut poids moleculare
CA2798256C (fr) 2009-05-28 2018-04-24 Lignol Innovations Ltd. Derives de lignine naturelle provenant de charges d'alimentation de bois de feuillus
CA2824446C (fr) 2010-02-15 2018-09-18 Lignol Innovations Ltd. Compositions de liant comprenant des derives de lignine
EP2536780A4 (fr) 2010-02-15 2013-11-13 Lignol Innovations Ltd Compositions en fibres de carbone contenant des dérivés de lignine
EP2688959A4 (fr) 2011-03-24 2014-09-10 Lignol Innovations Ltd Compositions comprenant une biomasse lignocellulosique et un solvant organique

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3616015A (en) * 1969-08-11 1971-10-26 Dennison Mfg Co Clear heat transfer and method of applying the same
GB2081242A (en) * 1980-08-06 1982-02-17 Dessau Zementkombinat Hydrophobic gypsum
DD210645A1 (de) * 1982-10-11 1984-06-20 Petrolchemisches Kombinat Formtrennmittel auf wachsemulsionsbasis
WO1987001654A1 (fr) * 1983-06-06 1987-03-26 Dennison Manufacturing Company Lamine thermotransferable

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3616015A (en) * 1969-08-11 1971-10-26 Dennison Mfg Co Clear heat transfer and method of applying the same
GB2081242A (en) * 1980-08-06 1982-02-17 Dessau Zementkombinat Hydrophobic gypsum
DD210645A1 (de) * 1982-10-11 1984-06-20 Petrolchemisches Kombinat Formtrennmittel auf wachsemulsionsbasis
WO1987001654A1 (fr) * 1983-06-06 1987-03-26 Dennison Manufacturing Company Lamine thermotransferable

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
H.RÖMPP: "Römpp-Lexicon Chemie", 1998, THIEME, STUTTGART, ISBN: 3-13-734910-9, XP002163364, 4 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003104330A1 (fr) * 2002-06-05 2003-12-18 Clariant Gmbh Melanges de cires finement broyees
EP1426350A2 (fr) 2002-10-30 2004-06-09 Readymix AG Matériaux de construction, élément de construction en résultant et utilisation des cires montans

Also Published As

Publication number Publication date
DE19952563A1 (de) 2001-05-03

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