WO2001004061A1 - A biofuel cell using wastewater and active sludge for wastewater treatment - Google Patents
A biofuel cell using wastewater and active sludge for wastewater treatment Download PDFInfo
- Publication number
- WO2001004061A1 WO2001004061A1 PCT/KR2000/000228 KR0000228W WO0104061A1 WO 2001004061 A1 WO2001004061 A1 WO 2001004061A1 KR 0000228 W KR0000228 W KR 0000228W WO 0104061 A1 WO0104061 A1 WO 0104061A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- wastewater
- biofuel cell
- compartment
- anodic
- cathodic
- Prior art date
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- 239000002351 wastewater Substances 0.000 title claims abstract description 78
- 239000002551 biofuel Substances 0.000 title claims abstract description 61
- 239000010802 sludge Substances 0.000 title claims abstract description 37
- 238000004065 wastewater treatment Methods 0.000 title description 7
- 244000005700 microbiome Species 0.000 claims abstract description 36
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Classifications
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/30—Aerobic and anaerobic processes
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/16—Biochemical fuel cells, i.e. cells in which microorganisms function as catalysts
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/32—Nature of the water, waste water, sewage or sludge to be treated from the food or foodstuff industry, e.g. brewery waste waters
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/46—Apparatus for electrochemical processes
- C02F2201/461—Electrolysis apparatus
- C02F2201/46105—Details relating to the electrolytic devices
- C02F2201/46115—Electrolytic cell with membranes or diaphragms
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/005—Combined electrochemical biological processes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/10—Biological treatment of water, waste water, or sewage
Definitions
- the present invention relates to a biofuel cell using wastewater as a fuel.
- the present invention relates to a biofuel cell using organic substances contained in wastewater as a fuel, which biofuel cell can treat organism- containing wastewater while producing electricity.
- the biofuel cell according to the present invention allows reducing power generated from the catabolism of organic substances contained in wastewater by a microorganism to be converted directly into electrical energy.
- a biofuel cell is a device in which an organism or its part is used and by which reducing power generated from the energy metabolism of the organism can be converted into electrical energy.
- a microbial fuel cell in order to convert reducing power generated from the oxidation of a substrate by a microorganism serving as a catalyst into electrical energy, electrons generated from the energy metabolism of the microorganism should be transferred from the microorganism to an electrode.
- most of organisms including microorganisms are surrounded by a lipid membrane, a non-conductive material, at their cells. For this reason, direct electron exchange between the microorganism and the electrode cannot be effected.
- a suitable electron transfer mediator should be used to facilitate electron exchange between the microorganism and the electrode.
- the electron transfer mediator an electron carrier has been used that shows a strong lipophilic property in both the oxidized form and the reduced form, and is thus capable of passing through the membrane.
- roller et al. have proposed the use of Proteus vulgaris, Escherichia coli, Atcaligenes eutrophus, Azotobacter chroococum, or Bacillus subtilis, etc. as a catalyst, and thionine, methylene blue, brilliant cresyl blue, or benzyl viologen. etc. as an electron transfer mediator, in the biofuel cell (see. Roller et al.. 1984. Journal of Chemical Technology and Biotechnology 34B: 3-12). According to Roller et al.. an efficiency of the biofuel cell is significantly varied depending on the kind of the bacteria and the kind of the electron transfer mediator when being compared in view of the oxygen consumption amount. Moreover. Bennetto et al.
- anaerobic bacteria employing ferric ion, tetravalent manganese, hexavalent uranium, or hexavalent molybdenum, etc.. as an electron receptor.
- Substances, that can be used as a substrate for such metal salt- reducing bacteria include aliphatic compounds, such as lactic acid, pyruvic acid, acetic acid, propionic acid, valeric acid, and alcohol, etc.. and aromatic compounds, such as toluene, phenol, cresol, benzoic acid, benzyl alchol, and benzaldehyde, etc. (see, Lovley and Klug, 1990, Applied and Enviromental Microbiology 556: 1858-
- Anaerobic bacteria are classified into fermentative bacteria and respiratory bacteria depending on their energy metabolism property. Fermentative bacteria decompose sugar and protein, etc. into organic acid, whereas respiratory bacteria completely oxidize fermentative products by the reduction of a suitable electron receptor.
- Electron receptors that can be used in the oxidation of organic substances by anaerobic respiratory bacteria include ferric oxide [Fe(III)], nitrate, manganese dioxide, sulfate. carbonate and the like. The reduction of ferric oxide among these electron receptors is known to generate the largest energy by a reducing power generated from the oxidation of a given electron donor, with the energy level being low in order of nitrate, sulfate and carbonate(see.
- a biofuel cell comprising cathodic and anodic compartments defined in the interior of the biofuel cell and contained with conductive medium, respectively; an anode arranged in the anodic compartment ; a cathode arranged in the cathodic compartment ; and an ion exchange membrane interposed between the cathodic and anodic compartments and serving to divide the anodic compartment from the cathodic compartment .
- the anodic compartment contains wastewater and active sludge.
- the biofuel according to the present invention is operated using the densely cultured microorganisms, as a catalyst, and organic substances present in wastewater. as a fuel.
- Fig. 1 is a schematical view showing a biofuel cell of the present invention comprising a cathode, an anode, and a cation exchange membrane serving to divide the electrodes from each other, in which graphite felts are used as the respective electrodes.
- Fig. 2 is a graph showing a reduction in electric current, electricity quantity (coulomb), and COD. which results from the use of a starch wastewater and an aerobic sludge in a biofuel cell of the present invention
- Fig. 3 is a graph showing a reduction in electric current, electricity quantity (coulomb), and COD, which results from the use of a starch wastewater and an anaerobic sludge in a biofuel cell of the present invention.
- Fig. 4 is a graph showing a reduction in electric current, electricity quantity
- Fig. 5 is a graph showing a reduction in electric current, electricity quantity (coulomb), and COD, which results from the use of a wastewater from septic tank and an anaerobic sludge in a biofuel cell of the present invention.
- Fig. 6a is a photograph taken with a scanning electron microscope for the surface of an electrode which is in a state before being used in a biofuel of the present invention.
- Fig. 6b is a photograph taken with a scanning electron microscope for electrochemically active microorganisms attached onto the surface of an electrode which is in a state after being used in a biofuel cell.
- Fig. 1 is a schematical view showing the structure of a biofuel cell according to the present invention.
- the biofuel cell includes a cathodic compartment 12 and an anodic compartment 14.
- the cathodic and anodic compartments 12 and 14 have an oxygen introducing port 16 and a nitrogen introducing port 18, respectively.
- a cathode 22 and an anode 24 there can be used for the cathode 22 and the anode 24 of the biofuel cell.
- a graphite felt for the cathode 22 and the anode 24 of the biofuel cell, there can be used a graphite felt, a kind of graphite electrode.
- a cation exchange membrane 26 is interposed between the cathodic and anodic compartments 12 and 14.
- conductive media for the respective electrodes 22 and 24 are included.
- a buffer solution is used, with the preferred buffer solution being 50 mM of phosphate buffer solution adjusted to pH 7.
- the cathode compartment 12 is maintained at a saturated condition by being continuously introduced with air, while the anode is maintained at an anaerobic condition by being introduced with nitrogen from which oxygen was completely removed by a passage of nitrogen through a gas oven.
- reference numerals 32 and 34 represent an electrometer and a resistance terminal, respectively.
- the electrochemically active bacteria can be selectively densely cultured.
- the densely cultured microorganism species are used as a microorganism catalyst in the biofuel cell, such that they catabolize a variety of organic substances present in wastewater. Reducing power generated from the catabolism of the organic substances is used in the reaction with the electrode, thereby allowing electric power to be generated. Additionally, as the organic substances present in wastewater are catabolized with the densely cultured microorganisms, a concentration of the organic substances in wastewater are reduced, thereby allowing a wastewater treatment effect to be achieved.
- a starch wastewater and an anaerobic sludge in the anodic compartment 14 of the biofuel cell according to the present invention while using a starch wastewater and an aerobic sludge in the cathodic compartment 12.
- the densely cultured, electrochemically active bacteria produce electric current while using the organic substances in wastewater as a fuel.
- a cation generated from the anodic compartment 14 is passed through the cation exchange membrane 26 by which the anodic compartment 14 is divided from the cathodic compartment 12. After passing through the cation exchange membrane 26. the cation is sent to the cathodic compartment 12 saturated with oxygen, and is converted into water in the cathodic compartment 12.
- Example 1 is for further illustration purposes only and in no way limit the scope of this invention.
- microorganisms using iron as an electron receptor among microorganisms present in wastewater contained in the biofuel cell of the present invention were measured for a change in their colony number.
- a phosphate buffer solution-based medium (PBBM) was used as a medium.
- the following components were added to the medium to prepare a plate medium: lg/L of an yeast extract. lg/L of ammonium chloride. 25 ml/L of Macro- mineral (II) (including, per I L. 6 g of KH 2 P0 4 . 12 g of NaCl. 2.4 g of MgSO 4 -7H 2 O. and 1.6g of CaCl 2 -2H 2 0).
- II Macro- mineral
- microelements including 12.8 g of nitroacetic acid.
- a vitamin solution including 0.002 g of biotin. 0.002 g of folacin, 0.010 g of B6(pyridoxin)HCl. 0.005 g of B 1 (thiamin)HCl, 0.005 g of B2(riboflavin), 0.005 g of nicotinic acid(niacin), 0.005 g of panthothenic acid, O.OOOlg of B12 (cyanocobalamine) crystal, 0.005 g of PABA. and 0.005 g of lipoic acid (thioctic acid)), lml/L of resazurin (0.2%). and 1.8% of agar.
- a vitamin solution including 0.002 g of biotin. 0.002 g of folacin, 0.010 g of B6(pyridoxin)HCl. 0.005 g of B 1 (thiamin)HCl, 0.005 g of B2(riboflavin), 0.005
- Example 2 This example is to examine characteristics of a biofuel cell using a starch wastewater (collected from Samyang Genex. Co., Inchon, Korea) and an aerobic sludge (collected from Samyang Genex. Co., Inchon. Korea).
- a graphite felt was used for the respective electrodes of cathode and anode.
- As a conductive medium for the cathode 50 mM of phosphate buffer solution was used, and the cathodic compartment and the anodic compartment were connected through a cation exchange membrane.
- the conductive medium for the cathodic compartment was continuously introduced with air such that it was maintained in a condition where it was saturated with oxygen.
- the anodic compartment was introduced with nitrogen from which oxygen has been completely removed by a passage of nitrogen through a gas-purifying oven. Thus, the anodic compartment was removed in dissolved oxygen such that it was maintained in an anaerobic environment. All buffer solutions used in the test were adjusted to pH 7.0. Resistance of the fuel cell was set to infinity at the early stage of the reaction. When electric pressure reached a maximum, electric current produced at a resistance of 1 k ⁇ was measured. A biofuel cell was used in which the aerobic sludge and the starch wastewater were mixed in the volume ratio of 1 :4. The volume of the aerobic sludge and the starch wastewater contained in the biofuel cell was 25 ml in total. As electric current generated by the organic substances present in the starch wastewater was decreased. 5 ml of wastewater was replaced with fresh wastewater.
- the generated electric pressure was measured at an interval of 120 seconds with Potential Start Meter (2000 multimeter, keithley Instrument. Inc.. USA). The measured electric pressure was divided by resistance (lk ⁇ ) to be converted into electric current. Chemical oxygen demand (COD) of wastewater was analyzed using a standard method (see. Standard Method for the Examination of Water and
- a biofuel cell using starch wastewater and anaerobic sludge (collected from Samyang Genex, Co., Ltd., Inchon, Korea) was tested for a electric current productivity and a wastewater treatment ability.
- the condition and analysis method for the biofuel cell was the same as described in Example 1.
- a biofuel cell was used in which an anaerobic sludge and a starch wastewater were mixed in the volume ratio of 1 :4.
- the volume of the anaerobic sludge and the starch wastewater contained in the biofuel cell was 25 ml in total.
- a biofuel cell was tested for an electric productivity and a wastewater treatment ability according to the same method as described in Example 2. except that a livestock wastewater (collected from Ansan Livestock. Ansan, Korea) was used instead of the starch wastewater. Also, the condition and the analysis method for the biofuel cell were the same as described in Example 1. As can seen in Fig. 4, electric current was generated up to 0.21 mA. quantity of electricity was increased up to 12 Coulombs, and COD was reduced from 1030 ppm to 350 ppm. From this experiment, it was therefore confirmed that reducing power generated from the oxidation of a substrate present in the livestock wastewater was consumed directly by an electrode to generate electric current, and also to purify the livestock wastewater.
- Example 5 a biofuel cell using a wastewater from a septic tank
- Example 1 (collected from Apt. in Korea Institute of Science and Technology, Seoul, Korea) was tested for an electric productivity and a wastewater treatment ability.
- the operating condition and the analysis method for the biofuel cell were equal to those in Example 1.
- electric current was generated up to 0.05 mA.
- quantity of electricity was increased up to 2.3 Coulombs, and COD was reduced from 680 ppm to 250 ppm. From this experiment, it was therefore confirmed that reducing power generated from the oxidation of a substrate in the wastewater from a septic tank was transferred directly to the electrode to generate electric current, and also to purify the wastewater from a septic tank.
- the present invention provides the biofuel cell utilizing wastewater and sludge.
- a portion of reducing power generated when the electrochemically active microorganisms contained in the sludge are subjected to the energy metabolism with the substrate present in wastewater. is utilized for the production of a biomass.
- the remaining portion of the reducing power is utilized to produce electric current while purifying wastewater.
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Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
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AU33335/00A AU3333500A (en) | 1999-07-07 | 2000-03-17 | A biofuel cell using wastewater and active sludge for wastewater treatment |
JP2001509681A JP2004517437A (en) | 1999-07-07 | 2000-03-17 | Biofuel cells using activated sludge for wastewater and wastewater treatment |
CA 2378558 CA2378558A1 (en) | 1999-07-07 | 2000-03-17 | A biofuel cell using wastewater and active sludge for wastewater treatment |
EP20000911467 EP1232123A1 (en) | 1999-07-07 | 2000-03-17 | A biofuel cell using wastewater and active sludge for wastewater treatment |
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KR1999/27168 | 1999-07-07 | ||
KR1019990027168A KR100332932B1 (en) | 1999-07-07 | 1999-07-07 | A Biofuel Cell Using Wastewater and Activated Sludge for Wastewater Treatment |
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EP (1) | EP1232123A1 (en) |
JP (1) | JP2004517437A (en) |
KR (1) | KR100332932B1 (en) |
CN (1) | CN1164509C (en) |
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- 2000-03-17 CA CA 2378558 patent/CA2378558A1/en not_active Abandoned
- 2000-03-17 JP JP2001509681A patent/JP2004517437A/en active Pending
- 2000-03-17 EP EP20000911467 patent/EP1232123A1/en not_active Withdrawn
- 2000-03-17 WO PCT/KR2000/000228 patent/WO2001004061A1/en active Search and Examination
- 2000-03-17 CN CNB008108056A patent/CN1164509C/en not_active Expired - Fee Related
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Also Published As
Publication number | Publication date |
---|---|
AU3333500A (en) | 2001-01-30 |
KR20010009031A (en) | 2001-02-05 |
EP1232123A1 (en) | 2002-08-21 |
CA2378558A1 (en) | 2001-01-18 |
CN1364146A (en) | 2002-08-14 |
JP2004517437A (en) | 2004-06-10 |
KR100332932B1 (en) | 2002-04-20 |
CN1164509C (en) | 2004-09-01 |
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