WO2000078543A1 - New fabric coating compositions providing excellent resistance to seam combing, particularly for use on automotive airbag fabrics - Google Patents

New fabric coating compositions providing excellent resistance to seam combing, particularly for use on automotive airbag fabrics Download PDF

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Publication number
WO2000078543A1
WO2000078543A1 PCT/US2000/016511 US0016511W WO0078543A1 WO 2000078543 A1 WO2000078543 A1 WO 2000078543A1 US 0016511 W US0016511 W US 0016511W WO 0078543 A1 WO0078543 A1 WO 0078543A1
Authority
WO
WIPO (PCT)
Prior art keywords
ethylene
fabric
fabric substrate
coating composition
polysiloxane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2000/016511
Other languages
English (en)
French (fr)
Inventor
Richard Henry Parker
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Milliken and Co
Original Assignee
Milliken and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Milliken and Co filed Critical Milliken and Co
Priority to AT00942846T priority Critical patent/ATE262563T1/de
Priority to DE60009251T priority patent/DE60009251T2/de
Priority to JP2001504572A priority patent/JP2003502483A/ja
Priority to AU57416/00A priority patent/AU5741600A/en
Priority to EP00942846A priority patent/EP1113927B1/en
Publication of WO2000078543A1 publication Critical patent/WO2000078543A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/128Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with silicon polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04Polysiloxanes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31652Of asbestos
    • Y10T428/31663As siloxane, silicone or silane
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2369Coating or impregnation improves elasticity, bendability, resiliency, flexibility, or shape retention of the fabric
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2861Coated or impregnated synthetic organic fiber fabric

Definitions

  • This invention relates to a new adhesive coating composition, particularly
  • This coating provides excellent adhesive properties to the coated
  • an automotive airbag in that, it may result in the loss of inflating air, and under
  • Airbags for motor vehicles are known and have been used for a substantial
  • Polychloroprene was the polymer of choice in the early development of this
  • coating levels of polymer have dropped from around 2.5 ounces per square yard of
  • one-layer coating which provides low permeability, resistance to yarn shifting and
  • composition for fabric substrates which provides substantial reduction of the
  • Yet another object of the invention is to provide
  • the inventive coating (which may be utilized on any fabric substrate)
  • This coating is comprised of a polysiloxane
  • inventive material is comprised of a polyalkyl- or
  • polyphenylsiloxane blended with a copolymer of ethylene and, as one non- limiting
  • non-limiting preferred substituent vinyl acetate, and cured with a peroxide. It has been found that the ethylene-methyl acrylate copolymer provides the most desired
  • the coating is produced by combining, in solution, 50-95 parts
  • the siloxane component may be any organic peroxide curing agent.
  • the siloxane component may be any organic peroxide curing agent.
  • the siloxane component may be any organic peroxide curing agent.
  • the preferred polyalkylsiloxane is a vinyl-containing
  • polydimethylsiloxane and the preferred polyarylsiloxane is a vinyl-containing
  • polyphenylsiloxane either of these materials may contain nondisclosed materials
  • ethylene-containing copolymer may be a copolymer comprised of 60-85 weight
  • ethylene containing copolymer may also be an ethylene containing copolymer comprised of 20-60 weight percent
  • ethylene and 40-80 weight percent vinyl acetate preferably from about 25-50 weight percent ethylene and from about 50-75 weight percent vinyl acetate
  • the preferred curing agent is an acyl peroxide, typically, but not limited to, benzoyl
  • a solvent is preferably present to effectuate proper and thorough mixing of the components of
  • the preferred coating composition More preferably such solvent is organic and
  • volatile i.e., evaporates easily at a relatively low temperature
  • such a solvent is toluene or similar type volatile liquid.
  • the coating may contain silane coupling agents of the type well known to
  • trimethoxysilanes as merely a broad example. It may also contain pigments or
  • colorants for identification or aesthetic reasons
  • inert ingredients such as
  • composition and make it suitable for use as an airbag coating.
  • This inventive coating composition may be applied to any type of fabric
  • fibers such as polyester, polyamide, regenerated cellulose and the like.
  • inorganic fibers such as glass, boron derivative fibers and the like. Furthermore,
  • the target fabrics may be woven, knitted, non-woven and the like.
  • the target fabrics may be woven, knitted, non-woven and the like.
  • target fabric substrate comprises synthetic fibers, preferably, polyesters and
  • polyamides and is preferably an airbag fabric.
  • any standard low permeability airbag fabric is desired.
  • target airbag fabric with the inventive composition.
  • target airbag fabric within this invention is a
  • plain woven fabric formed from yarns comprising polyamide or polyester fibers.
  • Such yarn preferably has a linear density of about 210 denier to about 630 denier.
  • Such yarns are preferably formed from multiple filaments, wherein the filaments
  • Such substrate fabrics are preferably woven
  • an airbag base fabric referred to as an airbag base fabric.
  • a toluene dispersion comprised of from 20-30 percent non- volatile
  • preferred dispersion comprises 65 phr of the vinyl functional polysiloxane
  • the formulation is preferably scrape coated
  • the solvent toluene, for example
  • Scrape coating in this sense includes, and is not
  • knife coating in particular, knife over roll, knife over gap, knife over
  • the coating composition exhibits excellent adhesive properties
  • the final dry weight of the coating is preferably about 2 ounces per square
  • fabric is also substantially impermeable to air, when measured according to ASTM
  • the substrate fabric is preferably a woven nylon
  • such substrate fabric will be formed
  • a coating dispersion was prepared using the following constituents,
  • This material was coated onto a 420 denier, nylon 6,6 fabric substrate,
  • Example 2 A coating dispersion was prepared using the following constituents,
  • This material was coated onto a 420 denier, nylon 6,6 fabric substrate,
  • Levapren 400O is a copolymer, understood
  • a typical silicone coating dispersion was prepared using the following
  • Calcium Oxide filler 5 parts This material was coated onto a 420 denier, nylon 6,6 fabric substrate,

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Organic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Air Bags (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Paints Or Removers (AREA)
  • Reinforced Plastic Materials (AREA)
  • Graft Or Block Polymers (AREA)
PCT/US2000/016511 1999-06-17 2000-06-15 New fabric coating compositions providing excellent resistance to seam combing, particularly for use on automotive airbag fabrics Ceased WO2000078543A1 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
AT00942846T ATE262563T1 (de) 1999-06-17 2000-06-15 Gewebebeschichtungszusammensetzungen mit ausgezeichneter ausfaserungsfestigkeit, insbesondere für airbags in kraftfahrzeugen
DE60009251T DE60009251T2 (de) 1999-06-17 2000-06-15 Gewebebeschichtungszusammensetzungen mit ausgezeichneter ausfaserungsfestigkeit, insbesondere für airbags in kraftfahrzeugen
JP2001504572A JP2003502483A (ja) 1999-06-17 2000-06-15 特に自動車用エアバッグファブリックに使用するための、優れたシームコーミング耐性を提供する新規なファブリックコーティング組成物
AU57416/00A AU5741600A (en) 1999-06-17 2000-06-15 New fabric coating compositions providing excellent resistance to seam combing, particularly for use on automotive airbag fabrics
EP00942846A EP1113927B1 (en) 1999-06-17 2000-06-15 New fabric coating compositions providing excellent resistance to seam combing, particularly for use on automotive airbag fabrics

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/335,202 US6348543B1 (en) 1999-06-17 1999-06-17 Fabric coating compositions providing excellent resistance to seam combing, particularly for use on automotive airbag fabrics
US09/335,202 1999-06-17

Publications (1)

Publication Number Publication Date
WO2000078543A1 true WO2000078543A1 (en) 2000-12-28

Family

ID=23310713

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2000/016511 Ceased WO2000078543A1 (en) 1999-06-17 2000-06-15 New fabric coating compositions providing excellent resistance to seam combing, particularly for use on automotive airbag fabrics

Country Status (7)

Country Link
US (3) US6348543B1 (https=)
EP (1) EP1113927B1 (https=)
JP (1) JP2003502483A (https=)
AT (1) ATE262563T1 (https=)
AU (1) AU5741600A (https=)
DE (1) DE60009251T2 (https=)
WO (1) WO2000078543A1 (https=)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003043817A1 (en) * 2001-11-16 2003-05-30 Dow Corning Corporation Silane-crosslinked polyolefin coated fabrics for airbags
JP2005048165A (ja) * 2003-07-29 2005-02-24 Milliken & Co ポリマー塗料ブレンド
EP1529823A1 (en) * 2003-11-06 2005-05-11 Milliken & Company Textile products and silicone-based copolymeric coating compositions for textile products
WO2006104769A3 (en) * 2005-03-28 2007-06-21 Milliken & Co Liquid polymeric coating compositions and air bags coated therewith

Families Citing this family (24)

* Cited by examiner, † Cited by third party
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US6740607B2 (en) * 1999-06-07 2004-05-25 Bradford Industries, Inc. Substrate with stretch and heat sealing properties to make a multidirectional restraint module design
US6753275B2 (en) * 1999-06-07 2004-06-22 Bradford Industries, Inc. Laminated multi-layered woven textile fabrics for use in air holding vehicle restraint systems
US6734123B2 (en) 1999-06-07 2004-05-11 Bradford Industries, Inc. Polyurethane coated fabrics for use in air-holding vehicle restraint systems
US6734125B2 (en) 1999-06-07 2004-05-11 Bradford Industries, Inc. Laminated multi-denier mixed fabrics for use in inflatable vehicle restraint systems
US6239046B1 (en) 1999-06-07 2001-05-29 Bradford Industries, Inc. Polysiloxane coated fabrics for use in air bags
US6770578B2 (en) 1999-06-07 2004-08-03 Bradford Industries, Inc. Laminated textile fabrics for use in air holding vehicle restraint systems
US6294487B1 (en) * 1999-09-24 2001-09-25 Milliken & Company Airbag fabric processing very low cover factor
US6605327B1 (en) * 2000-10-16 2003-08-12 Dana Corporation Vinyl acetate copolymers in hoses
US6846004B2 (en) * 2002-09-24 2005-01-25 Milliken & Company Silicone-based low permeability airbag fabric coatings
DE10326757A1 (de) * 2003-06-13 2005-01-13 Bst Berger Safety Textiles Gmbh & Co. Kg Verfahren zur Herstellung eines Luftsacks
US7687413B2 (en) * 2004-08-20 2010-03-30 Invista North America S.A.R.L. Edgecomb resistance polyester
US20060084743A1 (en) * 2004-10-20 2006-04-20 Chen John C Composition comprising polymer and silicone rubber
US7543843B2 (en) * 2006-08-10 2009-06-09 Milliken & Company Airbag coatings made with hybrid resin compositions
US8117966B1 (en) 2007-12-06 2012-02-21 Graber Curtis E Stun grenade
US7737058B2 (en) * 2008-01-23 2010-06-15 Milliken & Company Airbag with flame retardant monolithic coating layer
US7651118B1 (en) 2008-08-30 2010-01-26 Bradford Industries, Inc. Polyvinyl chloride coated fabrics for use in air bags
US20100129575A1 (en) * 2008-08-30 2010-05-27 Veiga Manuel J Polyvinyl chloride coated fabrics for use in air bags
US9079558B2 (en) * 2009-01-16 2015-07-14 Global Safety Textiles, Llc Coated airbag
US7737059B1 (en) 2009-02-19 2010-06-15 Milliken & Company Airbag coating
US8109534B2 (en) * 2009-07-22 2012-02-07 Highland Industries, Inc. Highly thermal resistant material for a vehicle safety device
US8887639B2 (en) 2012-06-21 2014-11-18 Curtis E. Graber Inflatable bag with burst control envelope and gas generator
US9574858B2 (en) 2012-06-21 2017-02-21 Curtis E. Graber Inflatable bag with burst control envelope and gas generator
US10301504B2 (en) 2015-12-17 2019-05-28 Milliken & Company Textile substrate with a continuous coating of a mixture of polyester polyurethane and polycarbonate polyurethane
US12227141B2 (en) 2018-10-17 2025-02-18 Dow Global Technologies Llc Coating composition, a coated fabric, a method of making a coated fabric, and an article made from the coated fabric

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US5399402A (en) * 1992-01-23 1995-03-21 Shin-Etsu Chemical Co., Ltd. Air bag coating composition and air bag
US5529837A (en) * 1994-02-28 1996-06-25 Shin-Etsu Chemical Co., Ltd. Silicone coated base material and air bag base material

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Publication number Priority date Publication date Assignee Title
US5208097A (en) * 1991-10-31 1993-05-04 Dow Corning Toray Silicone Co., Ltd. Base fabric for air bag
US5399402A (en) * 1992-01-23 1995-03-21 Shin-Etsu Chemical Co., Ltd. Air bag coating composition and air bag
US5529837A (en) * 1994-02-28 1996-06-25 Shin-Etsu Chemical Co., Ltd. Silicone coated base material and air bag base material

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003043817A1 (en) * 2001-11-16 2003-05-30 Dow Corning Corporation Silane-crosslinked polyolefin coated fabrics for airbags
JP2005048165A (ja) * 2003-07-29 2005-02-24 Milliken & Co ポリマー塗料ブレンド
EP1505132A3 (en) * 2003-07-29 2006-02-01 Milliken & Company Polymer coating blends
EP1529823A1 (en) * 2003-11-06 2005-05-11 Milliken & Company Textile products and silicone-based copolymeric coating compositions for textile products
WO2006104769A3 (en) * 2005-03-28 2007-06-21 Milliken & Co Liquid polymeric coating compositions and air bags coated therewith
US7407898B2 (en) 2005-03-28 2008-08-05 Milliken & Company Liquid polymeric coating compositions and air bags coated therewith

Also Published As

Publication number Publication date
ATE262563T1 (de) 2004-04-15
US6545092B2 (en) 2003-04-08
DE60009251T2 (de) 2005-02-24
EP1113927A4 (en) 2002-01-30
DE60009251D1 (de) 2004-04-29
US20020065367A1 (en) 2002-05-30
EP1113927A1 (en) 2001-07-11
US20020111097A1 (en) 2002-08-15
US6348543B1 (en) 2002-02-19
US6468929B2 (en) 2002-10-22
AU5741600A (en) 2001-01-09
EP1113927B1 (en) 2004-03-24
JP2003502483A (ja) 2003-01-21

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