WO2000061707A1 - Piles a combustible, procedes, et systemes - Google Patents

Piles a combustible, procedes, et systemes Download PDF

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Publication number
WO2000061707A1
WO2000061707A1 PCT/US2000/008299 US0008299W WO0061707A1 WO 2000061707 A1 WO2000061707 A1 WO 2000061707A1 US 0008299 W US0008299 W US 0008299W WO 0061707 A1 WO0061707 A1 WO 0061707A1
Authority
WO
WIPO (PCT)
Prior art keywords
fuel
less
fuel cell
fischer
tropsch
Prior art date
Application number
PCT/US2000/008299
Other languages
English (en)
Inventor
Harvard L. Tomlinson, Jr.
J. Branch Russell
Original Assignee
Syntroleum Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Syntroleum Corporation filed Critical Syntroleum Corporation
Priority to CA002364537A priority Critical patent/CA2364537A1/fr
Priority to AU63339/00A priority patent/AU6333900A/en
Priority to EP00950202A priority patent/EP1192238A1/fr
Publication of WO2000061707A1 publication Critical patent/WO2000061707A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
    • C10L1/08—Liquid carbonaceous fuels essentially based on blends of hydrocarbons for compression ignition
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/16—Hydrocarbons
    • C10L1/1616—Hydrocarbons fractions, e.g. lubricants, solvents, naphta, bitumen, tars, terpentine
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M8/1231—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte with both reactants being gaseous or vaporised
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M2008/1293—Fuel cells with solid oxide electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0065—Solid electrolytes
    • H01M2300/0068—Solid electrolytes inorganic
    • H01M2300/0071—Oxides
    • H01M2300/0074—Ion conductive at high temperature
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Definitions

  • the separated light Fischer-Tropsch liquid comprises a fuel additive; and said fuel additive is added to a petroleum fuel feedstock to provide a product with less than about 0.05 wt. % sulfur and less than about 10 wt. % aromatics, and wherein the resultant product comprises the fuel-cell fuel.
  • the fuel cell operating method comprises the steps of: providing a fuel cell fuel comprising a light Fischer-Tropsch liquid having at least 77 wt. % normal and iso-paraffins, less than 20 wt. % olefins, less than 9 wt. % alcohols, less than 0.001 wt. % sulfur, and less than 5 wt. % aromatics; and supplying the fuel-cell fuel to the fuel cell to produce electrical energy therefrom.
  • Certain embodiments of the fuel-cell fuel can readily be handled in the same fuel distribution systems used for distributing and dispensing internal combustion engine fuels such as gasoline and diesel fuel.
  • refueling would be no more complicated than fueling a car today, and would involve none of the toxicity concerns of methanol
  • a fuel cell fuel from the Fischer-Tropsch process as described herein that contains substantially no sulfur, no or minimal aromatics, and only small amounts of olefins and alcohol, many of the present complications of gasoline reforming for fuel cells are eliminated.
  • Fuel cell fuel processor systems no longer need to scrub sulfur, chorine, and metal from the processor gas stream. The task of removing sulfur from the hydrogen feed stream before it can damage the fuel cell is all but eliminated. Implications of a clean, substantially sulfur-free fuel cell fuel with no or minimal aromatics are interesting.
  • F-T (Fischer-Tropsch)-alcohol fuel cell fuel blends in which paraffins are replaced by alcohol(s) of equivalent or lesser carbon number have lower pour- point temperatures than those of F-T neat. This is due to the presence of the alcohol or alcohols in the blends. Thus, such blends may have lower start-up temperatures in the presence of some catalysts. These blends also have a hydrogen carrying capacity which is higher than that of pure alcohol or alcohol fuel cell fuel blends and proportional to the F-T component of the F-T-alcohol blend fuel cell fuel.
  • Another advantage is that the fuel-cell fuel can be made from feedstock natural gas generally available worldwide.
  • the light F-T liquid product delivered to conduit 130 may be further separated as necessary to produce a product in the range of from about C 4 or C5 to about C18 or to about C 20 or to about C 22 , or in the range of about C 10 to about C 2 o or preferably in the range of about C 5 to about C 9 , having the following characteristics: at least 77 wt. % normal and iso-paraffins, less than 20 wt. % olefins, less than 9 wt. % alcohols, less than 0.001 wt. % sulfur, and less than 10 wt. % aromatics (preferably less than 5 wt. % aromatics, and more preferably still less than 1 wt. % aromatics).
  • the product makes a good fuel-cell fuel.
  • Feed 414 includes F-T light oils that are preferably C 4 -C 2 ⁇ paraffins, olefins, and alcohols.
  • the gaseous remains, or tailgas, of cooling unit 408 are discharged as stream 416 which may be used elsewhere in system 400 or may be used in the synthesis gas system or a fuel cell system or other processes as a fuel.
  • Stream 416 includes diluent, H2, CO, CH 4 and some minor compounds.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Sustainable Energy (AREA)
  • Electrochemistry (AREA)
  • Sustainable Development (AREA)
  • Manufacturing & Machinery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

La présente invention concerne un combustible pour pile à combustible, un procédé de fabrication de combustible pour pile à combustible, un système de pile à combustible mettant en oeuvre une alimentation Fischer-Tropsch et un procédé de fonctionnement d'une pile à combustible. Le combustible pour pile à combustible est un liquide léger de Fischer-Tropsch présentant au moins 77 % en poids normal et d'isoparrafines, moins de 20 % en poids d'oléfines, moins de 9 % en poids d'alcools, moins de 0,001 % en poids de soufre et moins de 5 % en poids d'aromatiques. Le procédé de fabrication de combustible pour pile à combustible comprend la séparation d'une fraction lourde d'un liquide de Fischer-Tropsch, l'hydrocraquage de la fraction lourde et la séparation d'une fraction en C5-C18 du produit hydrocraqué.
PCT/US2000/008299 1999-03-31 2000-03-30 Piles a combustible, procedes, et systemes WO2000061707A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CA002364537A CA2364537A1 (fr) 1999-03-31 2000-03-30 Piles a combustible, procedes, et systemes
AU63339/00A AU6333900A (en) 1999-03-31 2000-03-30 Fuel-cell fuels, methods, and systems
EP00950202A EP1192238A1 (fr) 1999-03-31 2000-03-30 Piles a combustible, procedes, et systemes

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US12746599P 1999-03-31 1999-03-31
US60/127,465 1999-03-31
US16165999P 1999-10-21 1999-10-21
US60/161,659 1999-10-21
US49969000A 2000-02-08 2000-02-08
US09/499,690 2000-02-08

Publications (1)

Publication Number Publication Date
WO2000061707A1 true WO2000061707A1 (fr) 2000-10-19

Family

ID=27383583

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2000/008299 WO2000061707A1 (fr) 1999-03-31 2000-03-30 Piles a combustible, procedes, et systemes

Country Status (5)

Country Link
EP (1) EP1192238A1 (fr)
AU (1) AU6333900A (fr)
CA (1) CA2364537A1 (fr)
PE (1) PE20010080A1 (fr)
WO (1) WO2000061707A1 (fr)

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002050217A1 (fr) * 2000-12-21 2002-06-27 Bp Oil International Limited Composition de combustible hydrocarbone a double usage
EP1273650A1 (fr) * 2000-04-10 2003-01-08 Nippon Mitsubishi Oil Corporation Combustible a utiliser dans une pile a combustible
EP1273651A1 (fr) * 2000-04-10 2003-01-08 Nippon Mitsubishi Oil Corporation Combustible destine a un dispositif de pile a combustible
WO2004051060A1 (fr) * 2002-12-03 2004-06-17 Shell Internationale Research Maatschappij B.V. Procede et appareil de controle de la performance d'un moteur d'allumage par compression a melange homogene (hcci)
WO2005001976A1 (fr) * 2003-06-25 2005-01-06 Accentus Plc Traitement de dechets biologiques visant a produire de l'energie
WO2005021689A1 (fr) * 2003-09-03 2005-03-10 Shell Internationale Research Maatschappij B.V. Compositions de combustible
WO2007092734A1 (fr) * 2006-02-02 2007-08-16 Syntroleum Corporation hydrocarbure paraffinique pour une application A des piles A combustible
WO2008040789A2 (fr) * 2006-10-05 2008-04-10 Shell Internationale Research Maatschappij B.V. Compositions de carburant
US7393877B2 (en) 2003-12-31 2008-07-01 Total France Process for the conversion of a synthesis gas to hydrocarbons in the presence of beta-SiC and effluent from this process
EP2011183A2 (fr) * 2006-04-03 2009-01-07 Bloom Energy Corporation Systeme de pile a combustible et configuration de partie classique
EP2169033A1 (fr) * 2008-09-25 2010-03-31 Shell Internationale Research Maatschappij B.V. Huile de carburant d'hydrocarbures pour une utilisation dans un système de piles à combustible
US7883813B2 (en) 2006-04-03 2011-02-08 Bloom Energy Corporation Fuel cell system ventilation scheme
US20110130474A1 (en) * 2009-11-27 2011-06-02 Korea Institute Of Science And Technology Gtl-fpso system for conversion of associated gas in oil fields and stranded gas in stranded gas fields, and process for production of synthetic fuel using the same
CN102260485A (zh) * 2010-05-25 2011-11-30 M·阿伦博里 热交换介质
US8288041B2 (en) 2008-02-19 2012-10-16 Bloom Energy Corporation Fuel cell system containing anode tail gas oxidizer and hybrid heat exchanger/reformer
WO2013152903A1 (fr) * 2012-04-13 2013-10-17 Commissariat A L'energie Atomique Et Aux Energies Alternatives Production de dihydrogene par une transformation de gaz de tete issus d'une synthese
US8822094B2 (en) 2006-04-03 2014-09-02 Bloom Energy Corporation Fuel cell system operated on liquid fuels
US8920997B2 (en) 2007-07-26 2014-12-30 Bloom Energy Corporation Hybrid fuel heat exchanger—pre-reformer in SOFC systems
US9287572B2 (en) 2013-10-23 2016-03-15 Bloom Energy Corporation Pre-reformer for selective reformation of higher hydrocarbons
US9475995B2 (en) 2009-11-27 2016-10-25 Korea Institute Of Science And Technology GTL-FPSO system for conversion of stranded gas in stranded gas fields and associated gas in oil-gas fields, and process for production of synthetic fuel using the same
US11398634B2 (en) 2018-03-27 2022-07-26 Bloom Energy Corporation Solid oxide fuel cell system and method of operating the same using peak shaving gas

Families Citing this family (1)

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Publication number Priority date Publication date Assignee Title
BR0207894A (pt) * 2001-03-05 2004-06-22 Shell Int Research Processo para a preparação de um ou mais produtos combustìveis de hidrocarbonetos, e, produto hidrocarboneto

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US4125566A (en) * 1976-08-17 1978-11-14 Institut Francais Du Petrole Process for upgrading effluents from syntheses of the Fischer-Tropsch type
US4500417A (en) * 1982-12-28 1985-02-19 Mobil Oil Corporation Conversion of Fischer-Tropsch products
US4522894A (en) * 1982-09-30 1985-06-11 Engelhard Corporation Fuel cell electric power production
US5292983A (en) * 1991-05-07 1994-03-08 Shell Oil Company Process for the production of isoparaffins
US5362378A (en) * 1992-12-17 1994-11-08 Mobil Oil Corporation Conversion of Fischer-Tropsch heavy end products with platinum/boron-zeolite beta catalyst having a low alpha value
US5401589A (en) * 1990-11-23 1995-03-28 Vickers Shipbuilding And Engineering Limited Application of fuel cells to power generation systems
US5660940A (en) * 1993-12-20 1997-08-26 Sufucell Ab Method for producing electric energy in a biofuel-powered fuel cell
US5689031A (en) * 1995-10-17 1997-11-18 Exxon Research & Engineering Company Synthetic diesel fuel and process for its production
US5766274A (en) * 1997-02-07 1998-06-16 Exxon Research And Engineering Company Synthetic jet fuel and process for its production
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US3986349A (en) * 1975-09-15 1976-10-19 Chevron Research Company Method of power generation via coal gasification and liquid hydrocarbon synthesis
US4125566A (en) * 1976-08-17 1978-11-14 Institut Francais Du Petrole Process for upgrading effluents from syntheses of the Fischer-Tropsch type
US4522894A (en) * 1982-09-30 1985-06-11 Engelhard Corporation Fuel cell electric power production
US4500417A (en) * 1982-12-28 1985-02-19 Mobil Oil Corporation Conversion of Fischer-Tropsch products
US5401589A (en) * 1990-11-23 1995-03-28 Vickers Shipbuilding And Engineering Limited Application of fuel cells to power generation systems
US5292983A (en) * 1991-05-07 1994-03-08 Shell Oil Company Process for the production of isoparaffins
US5362378A (en) * 1992-12-17 1994-11-08 Mobil Oil Corporation Conversion of Fischer-Tropsch heavy end products with platinum/boron-zeolite beta catalyst having a low alpha value
US5660940A (en) * 1993-12-20 1997-08-26 Sufucell Ab Method for producing electric energy in a biofuel-powered fuel cell
US5689031A (en) * 1995-10-17 1997-11-18 Exxon Research & Engineering Company Synthetic diesel fuel and process for its production
US5766274A (en) * 1997-02-07 1998-06-16 Exxon Research And Engineering Company Synthetic jet fuel and process for its production
USH1849H (en) * 1998-11-20 2000-05-02 Sasol Technology (Proprietary) Limited Fischer-Tropsch products as fuel for fuel cells

Cited By (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1273650A4 (fr) * 2000-04-10 2004-10-06 Nippon Oil Corp Combustible a utiliser dans une pile a combustible
EP1273650A1 (fr) * 2000-04-10 2003-01-08 Nippon Mitsubishi Oil Corporation Combustible a utiliser dans une pile a combustible
EP1273651A1 (fr) * 2000-04-10 2003-01-08 Nippon Mitsubishi Oil Corporation Combustible destine a un dispositif de pile a combustible
EP1273651A4 (fr) * 2000-04-10 2004-10-13 Nippon Oil Corp Combustible destine a un dispositif de pile a combustible
WO2002050217A1 (fr) * 2000-12-21 2002-06-27 Bp Oil International Limited Composition de combustible hydrocarbone a double usage
US7213567B2 (en) 2002-12-03 2007-05-08 Shell Oil Company Process and apparatus for controlling the performance of a Homogeneous Charge Compression Ignition (HCCI) engine
WO2004051060A1 (fr) * 2002-12-03 2004-06-17 Shell Internationale Research Maatschappij B.V. Procede et appareil de controle de la performance d'un moteur d'allumage par compression a melange homogene (hcci)
WO2005001976A1 (fr) * 2003-06-25 2005-01-06 Accentus Plc Traitement de dechets biologiques visant a produire de l'energie
AU2004269170B2 (en) * 2003-09-03 2008-12-11 Shell Internationale Research Maatschappij B.V. Fuel compositions
WO2005021689A1 (fr) * 2003-09-03 2005-03-10 Shell Internationale Research Maatschappij B.V. Compositions de combustible
US7737311B2 (en) 2003-09-03 2010-06-15 Shell Oil Company Fuel compositions
AU2004269170C1 (en) * 2003-09-03 2009-05-21 Shell Internationale Research Maatschappij B.V. Fuel compositions
US7393877B2 (en) 2003-12-31 2008-07-01 Total France Process for the conversion of a synthesis gas to hydrocarbons in the presence of beta-SiC and effluent from this process
WO2007092734A1 (fr) * 2006-02-02 2007-08-16 Syntroleum Corporation hydrocarbure paraffinique pour une application A des piles A combustible
US8822094B2 (en) 2006-04-03 2014-09-02 Bloom Energy Corporation Fuel cell system operated on liquid fuels
EP2011183A2 (fr) * 2006-04-03 2009-01-07 Bloom Energy Corporation Systeme de pile a combustible et configuration de partie classique
US7883813B2 (en) 2006-04-03 2011-02-08 Bloom Energy Corporation Fuel cell system ventilation scheme
EP2011183A4 (fr) * 2006-04-03 2009-12-02 Bloom Energy Corp Systeme de pile a combustible et configuration de partie classique
US8057944B2 (en) 2006-04-03 2011-11-15 Bloom Energy Corporation Hybrid reformer for fuel flexibility
US7704617B2 (en) 2006-04-03 2010-04-27 Bloom Energy Corporation Hybrid reformer for fuel flexibility
WO2008040789A2 (fr) * 2006-10-05 2008-04-10 Shell Internationale Research Maatschappij B.V. Compositions de carburant
WO2008040789A3 (fr) * 2006-10-05 2008-07-03 Shell Int Research Compositions de carburant
US9166240B2 (en) 2007-07-26 2015-10-20 Bloom Energy Corporation Hot box design with a multi-stream heat exchanger and single air control
US8920997B2 (en) 2007-07-26 2014-12-30 Bloom Energy Corporation Hybrid fuel heat exchanger—pre-reformer in SOFC systems
US8535839B2 (en) 2008-02-19 2013-09-17 Bloom Energy Corporation Fuel cell system containing anode tail gas oxidizer and hybrid heat exchanger/reformer
US9105894B2 (en) 2008-02-19 2015-08-11 Bloom Energy Corporation Fuel cell system containing anode tail gas oxidizer and hybrid heat exchanger/reformer
US8288041B2 (en) 2008-02-19 2012-10-16 Bloom Energy Corporation Fuel cell system containing anode tail gas oxidizer and hybrid heat exchanger/reformer
US8419928B2 (en) 2008-09-25 2013-04-16 Shell Oil Company Hydrocarbon fuel oil for use in fuel cell system
EP2169033A1 (fr) * 2008-09-25 2010-03-31 Shell Internationale Research Maatschappij B.V. Huile de carburant d'hydrocarbures pour une utilisation dans un système de piles à combustible
US20110130474A1 (en) * 2009-11-27 2011-06-02 Korea Institute Of Science And Technology Gtl-fpso system for conversion of associated gas in oil fields and stranded gas in stranded gas fields, and process for production of synthetic fuel using the same
US9199890B2 (en) * 2009-11-27 2015-12-01 Korea Institute Of Science And Technology GTL-FPSO system for conversion of associated gas in oil fields and stranded gas in stranded gas fields, and process for production of synthetic fuel using the same
US9475995B2 (en) 2009-11-27 2016-10-25 Korea Institute Of Science And Technology GTL-FPSO system for conversion of stranded gas in stranded gas fields and associated gas in oil-gas fields, and process for production of synthetic fuel using the same
AU2010354129B2 (en) * 2010-05-25 2014-06-12 Avantherm Ab Heat exchange medium
JP2013532202A (ja) * 2010-05-25 2013-08-15 エーセー１ インベント アーベー 熱交換媒体
WO2011149400A1 (fr) * 2010-05-25 2011-12-01 Arrhenborg Mats Agent d'échange de chaleur
CN102260485A (zh) * 2010-05-25 2011-11-30 M·阿伦博里 热交换介质
WO2013152903A1 (fr) * 2012-04-13 2013-10-17 Commissariat A L'energie Atomique Et Aux Energies Alternatives Production de dihydrogene par une transformation de gaz de tete issus d'une synthese
US9982352B2 (en) 2012-04-13 2018-05-29 Commissariat A L'energie Atomique Et Aux Energies Alternatives Production of dihydrogen by conversion of overhead gases resulting from a synthesis
US9287572B2 (en) 2013-10-23 2016-03-15 Bloom Energy Corporation Pre-reformer for selective reformation of higher hydrocarbons
US9799902B2 (en) 2013-10-23 2017-10-24 Bloom Energy Corporation Pre-reformer for selective reformation of higher hydrocarbons
US11398634B2 (en) 2018-03-27 2022-07-26 Bloom Energy Corporation Solid oxide fuel cell system and method of operating the same using peak shaving gas
US11876257B2 (en) 2018-03-27 2024-01-16 Bloom Energy Corporation Solid oxide fuel cell system and method of operating the same using peak shaving gas

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PE20010080A1 (es) 2001-01-30
EP1192238A1 (fr) 2002-04-03
AU6333900A (en) 2000-11-14

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