WO2000061101A1 - Produit cosmetique aqueux contenant des esters d'acide tartrique ou d'acide citrique d'alkylpolyglucose et des polymeres cationiques ou amphoteres - Google Patents

Produit cosmetique aqueux contenant des esters d'acide tartrique ou d'acide citrique d'alkylpolyglucose et des polymeres cationiques ou amphoteres Download PDF

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Publication number
WO2000061101A1
WO2000061101A1 PCT/EP2000/002969 EP0002969W WO0061101A1 WO 2000061101 A1 WO2000061101 A1 WO 2000061101A1 EP 0002969 W EP0002969 W EP 0002969W WO 0061101 A1 WO0061101 A1 WO 0061101A1
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Prior art keywords
acid
composition according
group
hair
alkyl
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PCT/EP2000/002969
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German (de)
English (en)
Inventor
Jens Meyer
Dieter Goddinger
Winfried Seidel
Joachim-Kurt Foitzik
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Hans Schwarzkopf Gmbh & Co. Kg
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Priority to AU45424/00A priority Critical patent/AU4542400A/en
Publication of WO2000061101A1 publication Critical patent/WO2000061101A1/fr

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60—Sugars; Derivatives thereof
    • A61K8/604—Alkylpolyglycosides; Derivatives thereof, e.g. esters
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/731—Cellulose; Quaternized cellulose derivatives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
    • A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/54—Polymers characterized by specific structures/properties
    • A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
    • A61K2800/5426—Polymers characterized by specific structures/properties characterized by the charge cationic
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/54—Polymers characterized by specific structures/properties
    • A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
    • A61K2800/5428—Polymers characterized by specific structures/properties characterized by the charge amphoteric or zwitterionic

Definitions

  • the invention relates to aqueous cosmetic compositions for the treatment of hair or skin, which are formulated on a mild surfactant basis, and to the use of these compositions for cleaning hair and skin.
  • agents with certain mild surfactants in combination with cationic polymers are both extremely mild and have excellent product performance.
  • hair that is cleaned with appropriate shampoos has excellent properties in terms of volume, shine, combability, grip and "body”.
  • the invention therefore relates to aqueous cosmetic compositions for treating the hair or the skin on a mild surfactant base, which contain as surfactant at least one ester of a hydroxy-substituted bicarbonic acid or tricarboxylic acid (A) with the general formula (I),
  • YH or -OH is, provided that X is when X is -CH 2 COOR, R, R 1 and R 2 independently of one another are a hydrogen atom, an alkali metal or alkaline earth metal cation, an ammonium group, the cation of an ammonium organic Base or a radical Z which is derived from a polyhydroxylated organic compound which is selected from the group consisting of etherified (C 6 -C 18 ) alkyl polysaccharides with 1 to 6 monomeric saccharide units and etherified aliphatic (C 6 -C 16 ) hydroxyalkyl Polyols having 2 to 16 hydroxyl radicals, is selected, under the condition that at least one of the groups R, R 1 or R 2 is a Z radical and at least one polymer (B) selected from cationic polymers and amphopolymer.
  • R, R 1 and R 2 independently of one another are a hydrogen atom, an alkali metal or alkaline earth metal cation, an ammoni
  • the compounds of the formula (I) are, for example, from European patent EP-B1-0 258 814 and from the articles by N. Burns, Drag Cosmet. Ind. 160 (3), 42 (1997) and T. Verzotti et al., Cosmetic News XX-112, 29 (1997).
  • this prior art does not provide any indication of the agents according to the invention.
  • R, R 1 and R 2 preferably represent alkali metal cations, in particular the sodium ion, alkaline earth metal cations, in particular the magnesium ion, and the ammonium ion.
  • the group Z is preferably an etherified (C 6 -C 18 ) alkyl polysaccharide.
  • Group Z preferably contains glucose as the saccharide.
  • C 6 -C 6 alkyl groups in particular are used as alkyl groups, the choice of unbranched saturated groups being preferred.
  • the alkyl groups can, however, also be mixtures which are obtained when natural fats and oils are processed. Mixtures consisting essentially of
  • C 8 -C 16 alkyl groups can be preferred according to the invention.
  • a mixture of alkyl groups such as is obtained when coconut oil is processed, is very particularly preferred.
  • Group Z contains 1 to 6 monomeric saccharide units. According to a preferred embodiment, the group Z contains 2 to 6 glucose units. However, it may also be preferred to use groups Z with 1.2 to 3, in particular 1.3 to 2, glucose units. It should be noted that mixtures always arise in the synthesis, and these numerical values are derived from the stoichiometric ratio of the starting substances fatty alcohol and saccharide.
  • the compounds according to formula (I) are derivatives of citric acid, tartaric acid or malic acid. Such compounds which are derivatives of citric acid and in particular tartaric acid are preferred according to the invention.
  • the agents according to the invention can of course also contain more than one surfactant (A) of the formula (I).
  • the agents according to the invention preferably contain the compounds of formula (I) in amounts of 0.5 to 8.0% by weight, particularly preferably in amounts of 1 to 5% by weight and in particular in amounts of about 2 to 3% by weight. -%, each based on the total mean.
  • the agents according to the invention contain a polymer (B) as a second mandatory component.
  • the agents according to the invention contain a cationic polymer as polymer (B).
  • the permanent cationic polymers are preferred among the cationic polymers.
  • polymers which have a cationic group irrespective of the pH of the agent are referred to as “permanently cationic” usually polymers that have a quaternary nitrogen atom, for example in the form of a
  • Preferred cationic polymers are, for example, quaternized cellulose derivatives, such as are available under the names of Celquat ® and Polymer JR ® commercially.
  • the compounds Celquat ® H 100, Celquat ® L 200 and Polymer JR ® 400 are preferred quaternized cellulose derivatives.
  • Polysiloxanes with quaternary groups such as the commercially available products Q2-7224 (manufacturer: Dow Corning; a stabilized trimethylsilylamodimethicone), Dow Corning ® 929 Emulsion (containing a hydroxylamino-arnino- modified silicone, which is also referred to as amodimethicone), SM -2059 (manufacturer: General Electric), SLM-55067 (manufacturer: Wacker) and Abil ® -Quat 3270 and 3272 (manufacturer: Th. Goldschmidt; diquaternary polydimethylsiloxanes, Quaternium-80),
  • Cationic guar derivatives such as in particular the products sold under the trade names Cosmedia ® Guar and Jaguar ® ,
  • Polymeric dimethyldiallylammonium salts and their copolymers with esters and amides of acrylic acid and methacrylic acid Under the names Merquat ® 100 (Poly (dimethyldiallylammonium chloride)) and Merquat ® 550 (dimethyl diallylarnmoniumchlorid-acrylamide copolymer) commercially available products are examples of such cationic polymers.
  • Copolymers of vinyl pyrrolidone with quaternized derivatives of dialkylamino acrylate and methacrylate such as, for example, vinyl pyrrolidone-dimethylaminomethacrylate copolymers quaternized with diethyl sulfate.
  • vinyl pyrrolidone-dimethylaminomethacrylate copolymers quaternized with diethyl sulfate are commercially available under the names Gafquat ® 734 and Gafquat ® 755.
  • Vinylpyrrolidone methoimidazolinium chloride copolymers such as those sold under the name Luviquat ®, quaternized polyvinyl alcohol and under the designations Polyquaternium 2, Polyquaternium 17, Polyquaternium 18 and Polyquaternium 27 known polymers with quaternary nitrogen atoms in the main polymer chain.
  • Cationic polymers preferred according to the invention are quaternized cellulose derivatives and polymeric dimethyldiallylammonium salts and their copolymers.
  • Cationic cellulose derivatives, in particular the commercial product Polymer ® JR 400, are very particularly preferred cationic polymers.
  • ampho-polymers are also suitable as polymers (B).
  • amphopolymer refers to amphoteric polymers, i.e. Polymers that contain both free amino grappes and free -COOH or S ⁇ 3H groups in the molecule and to form internal ones
  • Salts are capable, zwitterionic polymers which contain quaternary ammonium groups and -COO " or -SO3 ' groups in the molecule, and those polymers which contain -COOH or S ⁇ 3H groups and quaternary ammonium groups.
  • amphopolymer suitable is that available under the name Amphomer ® acrylic resin, the methacrylate is a copolymer of tert.-butylamino, N- (1,1,3,3-tetramethylbutyl) -acrylamide and two or more monomers from the group Acrylic acid, methacrylic acid and their simple esters.
  • amphopolymers are composed of unsaturated carboxylic acids (for example acrylic and methacrylic acid), cationically derivatized unsaturated carboxylic acids (for example acrylamidopropyl-trimethyl-ammonium chloride) and optionally other ionic or nonionic monomers, as described, for example, in German Offenlegungsschrift 39 29 973 and can be found in the prior art cited there.
  • Terpolymers of acrylic acid, methyl acrylate and memacrylamidopropyltrimonium chloride, as are commercially available under the name Merquat ® 2001 N are particularly preferred amphopolymers according to the invention.
  • the polymers (B) are preferred in the preparations according to the invention in amounts of 0.05 to 5% by weight. based on the entire preparation. Amounts of 0.1 to 2% by weight are particularly preferred.
  • the agents according to the invention contain water as the third mandatory component.
  • the agents according to the invention usually have a pH in the range from 2 to 9. Agents with pH values in the range from 3 to 7, in particular in the range from 4 to 5.5, can be preferred in the context of the teaching according to the invention.
  • any acid or base that can be used for cosmetic purposes can be used to adjust this pH.
  • an acid it may be preferred to use an acid from the group of the edible acids such as, for example, acetic acid, lactic acid, tartaric acid, citric acid, malic acid, ascorbic acid and gluconic acid.
  • citric acid and lactic acid is particularly preferred.
  • the cosmetic agent is not subject to any restrictions.
  • the mildness of the preparations according to the invention is particularly effective in agents for treating the hair and skin, in particular for cleaning and maintaining the hair and skin.
  • the agent according to the invention is a hair cleanser (shampoo), a shower bath, a foam bath or a liquid soap.
  • shampoos and shower baths are preferred representatives of this embodiment.
  • the shampoos, shower baths, foam baths and liquid soaps according to the invention preferably contain at least one further cleaning component. This is selected in particular from the group of anionic, ampholytic, zwitterionic and nonionic surfactants; However, according to a further embodiment, it can also be cationic surfactants.
  • Suitable anionic surfactants in agents according to the invention are all anionic surface-active substances suitable for use on the human body. These are characterized by a water-solubilizing, anionic group such as. B. a carboxylate, sulfate, sulfonate or phosphate group and a lipophilic alkyl group with about 10 to 22 carbon atoms.
  • the molecule can contain glycol or polyglycol ether groups, ester, ether and amide groups and hydroxyl groups.
  • suitable anionic surfactants are, in each case in the form of the sodium, potassium, magnesium and ammonium as well as the mono-, di- and trialkanolammomium salts with 2 or 3 carbon atoms in the alkanol group,
  • Ether carboxylic acids of the formula RO- (CH2-CH2 ⁇ ) ⁇ -CH2-COOH, in which R is a linear
  • amide ether carboxylates of the formula [R-NH (-CH 2 -CH 2 -O) n -CH 2 -COO] m Z, in which R is for one linear or branched, saturated or unsaturated acyl radical with 2 to 29 C atoms, n for integers from 1 to 10, m for the numbers 1 or 2 and Z for a cation from the group of alkali or alkaline earth metals, acyl sarcosides with 10 up to 18 C atoms in the acyl group, acyl taurides with 10 to 18 C atoms in the acyl group, acyl isethionates with 10 to 18 C atoms in the acyl group,
  • Esters of tartaric acid and citric acid with alcohols the addition products of about 2-15 molecules of ethylene oxide and / or propylene oxide to fatty alcohols with 8 to 22 carbon atoms, coconut monoglyceride sulfates.
  • Preferred anionic surfactants are alkyl sulfates, alkyl polyglycol ether sulfates and ether carboxylic acids with 10 to 18 carbon atoms in the alkyl group and up to 12 glycol ether groups in the molecule, and sulfosuccinic acid and dialkyl esters with 8 to 18 carbon atoms in the alkyl group and sulfosuccinic acid mono- alkyl polyoxyethyl ester with 8 to 18 carbon atoms in the alkyl group and 1 to 6 oxyethyl groups.
  • Non-ionic surfactants contain z.
  • B a polyol group, a polyalkylene glycol ether group or a combination of polyol and polyglycol ether group.
  • Such connections are, for example
  • Preferred nonionic surfactants are alkyl polyglycosides of the general formula RO- (S) ⁇ . These connections are characterized by the following parameters.
  • the alkyl radical R contains 6 to 22 carbon atoms and can be either linear or branched. Primary linear and methyl-branched aliphatic radicals in the 2-position are preferred. Examples of such alkyl radicals are 1-octyl, 1-decyl, 1-lauryl, 1-myristyl, 1-cetyl and 1-stearyl. 1-Octyl, 1-decyl, 1-lauryl, 1-myristyl are particularly preferred. When using so-called "oxo alcohols" as starting materials, compounds with an odd number of carbon atoms in the alkyl chain predominate.
  • the alkyl polyglycosides which can be used according to the invention can contain, for example, only a certain alkyl radical R. Usually, however, these compounds are made from natural fats and oils or mineral oils. In this case, the alkyl radicals R are mixtures corresponding to the starting compounds or corresponding to the respective working up of these compounds.
  • Any mono- or oligosaccharides can be used as sugar building block S.
  • Sugar with 5 or 6 carbon atoms and the corresponding oligosaccharides are usually used.
  • sugars are glucose, fructose, galactose. Arabinose, ribose, xylose, lyxose, allose, old rose, marmose, gulose, idose, talose and sucrose.
  • Preferred sugar building blocks are glucose. Fructose, galactose, arabinose and sucrose; Glucose is particularly preferred.
  • alkyl polyglycosides which can be used according to the invention contain an average of 1.1 to 5 sugar units. Alkyl polyglycosides with x values from 1.1 to 1.6 are preferred. Alkyl glycosides in which x is 1.1 to 1.4 are very particularly preferred.
  • the alkyl glycosides can also serve to improve the fixation of the fragrance components on the hair.
  • the person skilled in the art will preferably resort to this substance class as a further ingredient of the preparations according to the invention.
  • alkoxylated homologs of the alkyl polyglycosides mentioned can also be used according to the invention. These homologues can contain an average of up to 10 ethylene oxide and / or propylene oxide units per alkyl glycoside unit.
  • the compounds with alkyl groups used as surfactants can each be uniform substances. However, it is generally preferred to start from natural vegetable or animal raw materials in the production of these substances, so that substance mixtures with different alkyl chain lengths depending on the respective raw material are obtained.
  • both products with a "normal” homolog distribution and those with a narrowed homolog distribution can be used.
  • “Normal” homolog distribution is understood to mean mixtures of homologues which are obtained as catalysts when converting fatty alcohol and alkylene oxide using alkali metals, alkali metal hydroxides or alkali metal alcoholates.
  • narrow homolog distributions are obtained if, for example, hydrotalcites, alkaline earth metal salts of ether carboxylic acids, alkaline earth metal oxides, hydroxides or alcoholates are used as catalysts become. The use of products with a narrow homolog distribution can be preferred.
  • zwitterionic surfactants can be used, in particular as co-surfactants.
  • Zwitterionic surfactants are surface-active compounds that contain at least one quaternary ammonium group and at least one in the molecule
  • Particularly suitable zwitterionic surfactants are the so-called betaines such as the N-alkyl-N, N-dimethylammonium glycinate, for example the cocoalkyl-dimethylammonium glycinate, N-acyl-aminopropyl-N, N-dimethyl-ammonium glycinate, for example the cocoacylaminopropyl-dimethylammonium glycinate.
  • a preferred zwitterionic surfactant is the fatty acid amide derivative known under the INCI name Cocamidopropyl Betaine.
  • Ampholytic surfactants are also particularly suitable as co-surfactants.
  • Ampholytic surfactants are surface-active compounds which, in addition to a C 8 -C 18 -alkyl or acyl group, contain at least one free amino group and at least one -COOH or -SO H group in the molecule and are capable of forming internal salts .
  • ampholytic surfactants are N-alkylglycines, N-alkylpropionic acids, N-alkylaminobutyric acids, N-alkyliminodipropionic acids, N-hydroxyethyl-N-alkylamidopropylglycines, N-alkyltaurines, N-alkyl sarcosines, 2-alkylamino propionic acids and alkylamino acetic acids, each with approximately 8 to 18 carbon atoms in the alkyl group.
  • Particularly preferred ampholytic surfactants are N-Kokosalkylamino- propionate, cocoacylaminoethyl aminopropionate and C] 2 . ⁇ 8 acyl sarcosine.
  • Examples of the cationic surfactants which can be used in the hair treatment compositions according to the invention are, in particular, quaternary ammonium compounds.
  • Ammonium halides in particular chlorides and bromides, such as alkyltrimethylammonium chlorides, dialkyldimethylammonium chlorides and trialkylmethylammonium chlorides, eg. B. cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, distearyl dimethylammonium chloride. Lauryldimethylammonium chloride, Lauryldimethylbenzylammoniumchlorid and Tricetylmethylammoniumchlorid.
  • the shampoos according to the invention preferably contain the further cleaning components in amounts of from 5.0 to 40% by weight, in particular from 5.0 to 20% by weight, based on the particular preparation.
  • Preparations of particularly great mildness are obtained if, in addition to the surfactants (A), a zwitterionic surfactant, in particular of the betaine type, is used. Anionic and / or nonionic surfactants can then be added as further surfactants.
  • Nonionic surfactants in particular of the alkylglycoside type, have proven to be outstandingly suitable according to the invention.
  • the agents according to the invention preferably also contain at least one organic thickener.
  • Such thickeners are, for example, thickeners such as agar, guar gum, alginates, cellulose ethers, gelatin, pectins and / or xanthan gum.
  • Ethoxylated fatty alcohols in particular those with limited homolog distribution as they are, for example, as a commercial product under the name Arlypon F ® (Henkel) on the market, alkoxylated methyl glucoside, such as the product Glucamate ® DOE 120 (Amerchol) and ethoxylated propylene glycol esters such as the commercial product Antü ® 141 (Goldschmidt) can be preferred organic thickeners.
  • Hair treatment agents can be, for example, shampoos, hair rinses, hair treatments, permanent waving agents (wave lotions, fixatives), hair colorants, hair tinting agents, hair setting agents, hair sprays, hair lotions or hair tip fluids.
  • the preparations can be formulated as solutions, emulsions, gels, creams, aerosols or lotions; they can remain on the hair or, after a short exposure time, which can be preferred, rinsed out again.
  • the agents according to the invention which also serve to treat hair, contain at least one additional conditioning active ingredient.
  • this improves the combability of the hair after the treatment. This is especially recommended for shampoos that are formulated for the "children" target group in order to correspond to the well-known sensitivity of children when combing, especially of wet hair.
  • Protein hydrolyzates in particular elastin, collagen, keratin, milk protein, soy protein, almond protein, pea protein, potato protein, oat protein, corn protein and wheat protein hydrolyzates, their condensation products with fatty acids and quaternized protein hydrolyzates are also suitable as conditioning agents .
  • Products based on plants can be preferred according to the invention.
  • Silicone oils and silicone gums suitable as conditioning agents are, in particular, dialkyl and alkylarylsiloxanes, such as, for example, dimethylpolysiloxane and methylphenylpolysiloxane, and their alkoxylated and quaternized analogs.
  • Examples of such silicones are the products sold by Dow Coming under the names DC 190, DC 200 and DC 1401 and the commercial product Fancorsil ® LIM-1.
  • a suitable anionic silicone oil is the product Dow Coming ® ! 784.
  • alkylamidoamines, especially fatty acid amidoamines such as the stearylamidopropyldimethylamine available under the name Tego Amid ® S 18, are notable for their good biodegradability.
  • estersquats such as the dialkylammonium methosulfates sold under the trademark Stepantex ® and the corresponding products of the Dehyquart ® series are also very readily biodegradable.
  • Preferred vegetable oils and waxes as conditioning agents are jojoba oil, sunflower oil. Orange oil, almond oil, wheat germ oil and peach seed oil. Jojoba oil and orange oil are particularly preferred.
  • the amount of dissolved inorganic salts is limited to less than 2% by weight, in particular less than 0.5% by weight. It should also be noted that such salts are not only e.g. to adjust the viscosity, but can also be introduced by other active ingredients, in particular surfactants.
  • nonionic polymers such as vinylpyrrolidone / vinyl acrylate copolymers, polyvinylpyrrolidone and vinylpyrrolidone / vinyl acetate copolymers, anionic polymers such as polyacrylic and polymethacrylic acids, their salts, their copolymers with acrylic and methacrylic acid esters and - amides and their derivatives, which are obtained by crosslinking with polyfunctional agents, polyoxycarboxylic acids, such as polyketo and polyaldehydocarboxylic acids and their salts, and polymers and copolymers of crotonic acid with esters and amides of acrylic and methacrylic acid, such as vinyl acetate-crotonic acid and vinyl acetate.
  • nonionic polymers such as vinylpyrrolidone / vinyl acrylate copolymers, polyvinylpyrrolidone and vinylpyrrolidone / vinyl acetate copolymers
  • anionic polymers such as polyacrylic and polymeth
  • Vinyl propionate-crotonic acid copolymers such as glucose and maleic acid, hair-conditioning compounds such as phospholipids, for example soy lecithin, egg lecithin and cephalins, other perfume oils, in particular those with the fragrance note of a cargo, such as apple, bime. Strawberry. Peach apricot. Pineapple, banana. Cherry. Kiwi, mango, coconut. Almond, grapefruit. Passion fruit, tangerine and melon, or the scent of a luxury, such as tobacco, cola. Chewing gum, guarana, chocolate. Cocoa, vanilla. Sarsaparilla, peppermint and rum. Dimethyl isosorbide and cyclodextrins,
  • Solubilizers such as ethanol, isopropanol, ethylene glycol, propylene glycol, glycerin, diethylene glycol and ethoxylated triglycerides, dyes,
  • Anti-dandruff agents such as climbazole, piroctone olamine and zinc omadine, active agents such as bisabolol, allantoin, panthenol, niacinmid, tocopherol and plant extracts,
  • Consistency enhancers such as sugar esters, polyol esters or polyol alkyl ethers, fats and waxes such as walrus, beeswax, montan wax, paraffins, esters, glycerides and fatty alcohols, fatty acid alkanolamides,
  • Complexing agents such as EDTA, NTA, ⁇ -alaninediacetic acid and phosphonic acids, swelling and penetration substances such as PCA, glycerol, propylene glycol monoethyl ether, carbonates, hydrogen carbonates, guanidines, ureas and primary, secondary and tertiary phosphates,
  • Opacifiers such as latex or styrene / acrylamide copolymers, pearlescent agents such as ethylene glycol mono- and distearate or PEG-3 distearate, direct dyes so-called coupler and developer components as oxidation dye precursors,
  • Reducing agents such as Thioglycolic acid and its derivatives, thiolactic acid, cytamine, thio malic acid and ⁇ -mercaptoethanesulfonic acid, oxidizing agents such as hydrogen peroxide, potassium bromate and sodium bromate, blowing agents such as propane-butane mixtures, N2O, dimethyl ether, CO2 and air and
  • Antioxidants Bitter substances such as Denatonium Benzoate, preservatives.
  • the invention also relates to the use of an agent according to one of claims 1 to 10 for cleaning skin and hair.
  • N, N-Dimethyl-N-coconut amidopropylammonium acetobetaine (approx. 30% active substance in water; INCI name: Cocamidopropyl betaine) (CLARIANT) N-coconut fatty acid amidoethyl-N-2-hydroxyethylglycine sodium salt (approx. 50% active substance in water; INCI name : Disodium Cocoamphodiacetate) (WITCO) neutralized ester of alkyl polyglucose with tartaric acid (approx. 30% active substance in water; ⁇ NCI name (provisional): Sodium Cocopolyglucose Tartrate) (CESALPINIA) neutralized ester of alkyl polyglucose with citric acid (approx. 30% active substance in water ; ⁇ NCI name (provisional): Sodium Cocopolyglucose Citrate) (CESALPINIA)
  • HOFFMANN LA-ROCHE quaternized hydroxyethyl cellulose (INCI name: Polyquaternium-10) (AMERCHOL)
  • Dimethyldiallylammonium chloride-acrylamide copolymer (approx. 9% active substance in water; INCI name: Polyquaternium-7) (MERCK)
  • Wheat protein hydrolyzate (approx. 18% active substance; INCI name: Hydrolyzed Wheat Protein) (DGF STOESS) Silicone emulsion (INCI name: Dimethiconol (and) TEA-Dodecylbenzenesulfonate) (CALGON)

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  • Cosmetics (AREA)

Abstract

L'invention concerne des produits cosmétiques aqueux pour le traitement des cheveux ou de la peau, à base d'un tensioactif doux, qui contiennent: comme tensioactif, au moins un ester d'un acide bicarboxylique ou tricarboxylique (A) à substitution hydroxy, correspondant à la formule générale (I), dans laquelle X représente H ou un groupe CH2COOR, Y représente H ou OH, à condition que Y représente H lorsque X représente CH2COOR, et R, R1 et R2 représentent, indépendamment l'un de l'autre, un atome d'hydrogène, un cation de métal alcalin ou alcalino-terreux, un groupe ammonium, le cation d'une base ammonium-organique ou un reste Z provenant d'un composé organique polyhydroxylé sélectionné dans le groupe comportant des alkyle (C¿6?-C18)-polysaccharides éthérifiés présentant 1 à 6 unités saccharides monomères et des hydroxyalkyle (C6-C16)-polyols aliphatiques, éthérifiés, comportant 2 à 16 restes hydroxyle, à condition qu'au moins un des groupes R, R?1 ou R2¿ soit un reste Z; et au moins un polymère (B) sélectionné parmi des polymères cationiques et des amphopolymères. Ces produits cosmétiques se caractérisent par une douceur exceptionnelle et des caractéristiques de soin remarquables.
PCT/EP2000/002969 1999-04-12 2000-04-04 Produit cosmetique aqueux contenant des esters d'acide tartrique ou d'acide citrique d'alkylpolyglucose et des polymeres cationiques ou amphoteres WO2000061101A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU45424/00A AU4542400A (en) 1999-04-12 2000-04-04 Aqueous cosmetic preparations containing tartaric-acid or citric-acid esters of alkyl polyglucose and cationic or amphoteric polymers

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19916334A DE19916334A1 (de) 1999-04-12 1999-04-12 Kosmetisches Mittel und Verwendung
DE19916334.0 1999-04-12

Publications (1)

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WO2000061101A1 true WO2000061101A1 (fr) 2000-10-19

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AU (1) AU4542400A (fr)
DE (1) DE19916334A1 (fr)
WO (1) WO2000061101A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003059297A2 (fr) * 2002-01-21 2003-07-24 Slovakofarma A.S. Compositions dermatologiques topiques et procede pour leur preparation
EP1762220A3 (fr) * 2005-09-09 2010-06-09 Henkel AG & Co. KGaA Composition de teinture des fibres keratiniques comprenant des polymères de poids moléculaire faible

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102007029061A1 (de) * 2007-06-21 2009-03-12 Henkel Ag & Co. Kgaa Haut- und Haarbehandlungsmittel mit einem Extrakt eines Süßgrases

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0510564A1 (fr) * 1991-04-24 1992-10-28 AUSCHEM S.P.A. in fallimento Procédé de préparation d'agents tensioactifs dérivés d'acides di- ou tri-carboxyliques
WO1994007458A1 (fr) * 1992-09-29 1994-04-14 Henkel Kommanditgesellschaft Auf Aktien Combinaison d'un shampoing/apres-shampoing
FR2785795A1 (fr) * 1998-11-12 2000-05-19 Oreal Compositions cosmetiques contenant un tensioactif ester d'alkylpolyglycoside anionique et un ceramide et leurs utilisations

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0510564A1 (fr) * 1991-04-24 1992-10-28 AUSCHEM S.P.A. in fallimento Procédé de préparation d'agents tensioactifs dérivés d'acides di- ou tri-carboxyliques
WO1994007458A1 (fr) * 1992-09-29 1994-04-14 Henkel Kommanditgesellschaft Auf Aktien Combinaison d'un shampoing/apres-shampoing
FR2785795A1 (fr) * 1998-11-12 2000-05-19 Oreal Compositions cosmetiques contenant un tensioactif ester d'alkylpolyglycoside anionique et un ceramide et leurs utilisations

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
VERZOTTI, T. ET AL.: "Alchilpoliglucosidi esteri: formulare con "delicatezza"", COSMETIC NEWS, vol. 112, January 1997 (1997-01-01) - February 1997 (1997-02-01), pages 29 - 31, XP000938713 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003059297A2 (fr) * 2002-01-21 2003-07-24 Slovakofarma A.S. Compositions dermatologiques topiques et procede pour leur preparation
WO2003059297A3 (fr) * 2002-01-21 2003-12-18 Slovakofarma As Compositions dermatologiques topiques et procede pour leur preparation
EP1762220A3 (fr) * 2005-09-09 2010-06-09 Henkel AG & Co. KGaA Composition de teinture des fibres keratiniques comprenant des polymères de poids moléculaire faible

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Publication number Publication date
AU4542400A (en) 2000-11-14
DE19916334A1 (de) 2000-10-19

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