WO2000044246A1 - Dry ascidian powder, utilization thereof, process for producing the same, method for relieving ascidian smell and dry ascidian - Google Patents

Dry ascidian powder, utilization thereof, process for producing the same, method for relieving ascidian smell and dry ascidian Download PDF

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Publication number
WO2000044246A1
WO2000044246A1 PCT/JP2000/000403 JP0000403W WO0044246A1 WO 2000044246 A1 WO2000044246 A1 WO 2000044246A1 JP 0000403 W JP0000403 W JP 0000403W WO 0044246 A1 WO0044246 A1 WO 0044246A1
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Prior art keywords
powder
squirt
dried
sea squirt
sea
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PCT/JP2000/000403
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French (fr)
Japanese (ja)
Inventor
Haruhisa Shionoya
Kunio Yamazaki
Josuke Shimizu
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Haruhisa Shionoya
Kunio Yamazaki
Josuke Shimizu
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Application filed by Haruhisa Shionoya, Kunio Yamazaki, Josuke Shimizu filed Critical Haruhisa Shionoya
Priority to JP2000595558A priority Critical patent/JP4402839B2/en
Publication of WO2000044246A1 publication Critical patent/WO2000044246A1/en

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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L17/00Food-from-the-sea products; Fish products; Fish meal; Fish-egg substitutes; Preparation or treatment thereof
    • A23L17/20Fish extracts
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L17/00Food-from-the-sea products; Fish products; Fish meal; Fish-egg substitutes; Preparation or treatment thereof
    • A23L17/10Fish meal or powder; Granules, agglomerates or flakes

Definitions

  • the present invention relates to a novel food form of sea squirt which is easy to be taken by anyone with reduced sea scent, its use, its production method, method of reducing sea scent, and dried sea squirt.
  • the sea squirt (sea sheath) is a kind of protozoa that settle on rocks on the sea floor.
  • the soft body muscle and internal organs
  • husk capsule
  • the edible part has been used for food since ancient times.
  • sea squirts are rich in ingredients with high nutritional value and useful ingredients for the human body.
  • ascidian muscle is included in glycogen content and is a valuable source of animal carbohydrates that are easily digested and quickly absorbed.
  • Ascidian extract contains amino acids such as insulin, which has a cell activating effect, leucine, which has an intellectual enhancing effect, glycine, alanine, nocline, serine, threonine, tyrosine, methionine, and aspartic acid. , Gnore, acid, histidine, arginine, lysine, etc.
  • betaine-choline and the like are included.
  • Purine bases include adenine and xanthine.
  • Minerals include sodium, potassium, potassium, iron, and zinc.
  • Trace elements include selenium, which has the effect of preventing aging and improving sexual performance, as well as a large amount such as sodium, germanium, and the like. It also contains unsaturated fatty acids such as eicosapentaenoic acid and docosahexaenoic acid, and various vitamins such as vitamin B, vitamin II, and vitamin E. Of these, glycine, alanine, glutamic acid, and betaine are components that are closely related to taste.
  • sea squirts are a very valuable ingredient in food.
  • sea squirts have a peculiar smell (smell of sea squirt). It is.
  • raw sea squirts are foods that are easily damaged and easily discolored and have extremely poor storage stability. For these reasons, sea squirts are eaten as raw delicacies and savory foods in a limited area, as well as being processed into salted foods.
  • the present invention has been made in view of the above background art, and provides a novel food form of sea squirt whose sea scent is reduced and which is easy for anyone to ingest, its use, its manufacturing method, method of reducing sea scent, and dried sea squirt. Aim. Disclosure of the invention
  • the present inventors found that the soft body from which the outer skin (capsule) of the sea squirt was removed was powdered through a specific process, so that it could be used as a food material. Surprisingly, this dry powder has an antibacterial effect, as well as an elasticity-enhancing effect on food and a shape-preventing effect.
  • the present invention has been made based on such knowledge, and the dry powder of the sea squirt of the present invention is manufactured using a soft body from which the outer skin (capsule) of the sea squirt has been removed as described in claim 1. It is characterized by having.
  • the food material of the present invention is characterized in that, as described in Claim 2, a dried powder of sea squirt is a main component.
  • the processed food of the present invention is characterized in that it contains dried sea squirt powder as described in claim 3.
  • the processed food according to claim 4 is the processed food according to claim 3, characterized in that the processed food is a kind.
  • the processed food according to claim 5 is the processed food according to claim 3, wherein the processed food is rice cake.
  • seasoning of the present invention is characterized in that it contains dried sea squirt powder as described in claim 6.
  • the elasticity enhancer for food additives of the present invention comprises a squirt as described in claim 7. Characterized by using a dry powder as an active ingredient.
  • the food additive type collapse preventive agent of the present invention is characterized in that dry powder of sea squirt is used as an active ingredient.
  • the antibacterial agent of the present invention is characterized by using dried powder of sea squirt as an active ingredient.
  • the superoxide dismutase-like activator of the present invention is characterized in that, as described in claim 10, a dry powder of sea squirt is used as an active ingredient.
  • the method for producing a dried squirt powder of the squirt according to the present invention is characterized in that, as described in claim 11, the soft body from which the outer skin (capsule) of the squirt is removed is freeze-dried in vacuum and then pulverized.
  • the method for producing a dried squirt powder of the squirt according to the present invention comprises forming a soft body from which the outer skin (capsule) of the squirt is removed into a slurry and spray-drying the slurry.
  • the soft body portion from which the outer skin (capsule) of the sea squirt is removed is made into a paste, which is dried under reduced pressure. It is characterized by crushing.
  • the method for reducing the smell of sea squirt of the present invention is characterized in that the soft body part from which the outer skin (capsule) of the sea squirt has been removed is subjected to vacuum freeze-drying.
  • the method for reducing squirt odor according to the present invention is characterized in that, as described in claim 15, the soft body portion from which the outer skin (capsule) of the squirt is removed is made into a slurry-like material, and this is spray-dried. I do.
  • the dried squirt according to the present invention is obtained by vacuum freeze-drying a soft part from which the outer skin (capsule) of the squirt is removed, as described in claim 16.
  • the dried squirt of the present invention is obtained by drying a soft body from which the outer skin (capsule) of the squirt has been removed as a paste-like material and drying it under reduced pressure, as described in claim 17.
  • FIG. 1 shows the S D 0 extract of the dried powder of sea squirt of the present invention and the S 0 D of the PBS extract.
  • FIG. 3 is a diagram showing a similar activity.
  • the sea squirt used in the present invention is not particularly limited, and any sea squirt, such as a sea squirt, a red sea squirt, a white sea squirt, may be used without particular limitation.
  • the method for producing a dried sea squirt powder in the present invention is roughly classified into three methods as described in detail below.
  • the sea squirt is separated into an outer skin and a soft body part, and the separated soft body part is washed with water or the like (peeling step).
  • the soft part is frozen as it is, or cut or crushed into an appropriate size or shape (freezing step).
  • freezing conditions There are no particular restrictions on the freezing conditions.
  • the freezing may be performed at 120 ° C. to 150 ° C. using a freezer or the like.
  • Vacuum freeze-drying may be performed according to a conventional method.However, in consideration of the quality of the obtained dried squirt, a vacuum of 1 Pa to 50 Pa and a drying temperature of 30 ° C to 70 ° C is used. It is desirable to do this.
  • the drying time cannot be specified unconditionally because it depends on the treatment amount, but in order to suppress the growth of bacteria, it is desirable to dry the water so that the water activity becomes 0.5 or less.
  • the dried sea squirt obtained is orange and has the original taste and aroma of sea squirt, but the sea scent is significantly reduced.
  • the dried squirt is pulverized by a pulverizer (pulverizing step). Grinding conditions may be in accordance with ordinary methods.
  • the particle size is desirably in the range of 10 to 100 microns using a pulverizer of 0.1 to 1 millimesh in consideration of the quality such as fluidity of the obtained powder.
  • the dried powder of sea squirt produced through the above-mentioned stripping, freezing, drying, and crushing processes is an orange fluid powder, and although the sea scent is significantly reduced, Has a taste and aroma. Also, the dried powder of this sea squirt is always It does not deteriorate in taste or aroma even when left at room temperature, and can be stored for a long time.
  • a stripping step similar to the manufacturing method through the vacuum freeze-drying step is performed.
  • the soft part obtained in the first step is converted into a slurry (a slurry-like substance forming step).
  • a method of forming the soft body into a slurry-like material include a method using a mass colloid, a ball mill, or the like singly or in combination according to a conventional method. Since the soft part of sea squirt is fibrous, it is necessary to sufficiently pulverize the fibrous material to obtain a spray-dryable slurry. Therefore, in consideration of this point, it is desirable to make the soft body a paste-like material by using a masco nozzle, and to make the slurry into a slurry-like material by using a ball mill.
  • the second step may be performed immediately after the first step.However, the soft body obtained in the first step is temporarily frozen for a purpose such as temporary storage, and then the thawed product is thawed. May be used to perform the second step.
  • the slurry obtained in the second step is dried by spray drying (drying step).
  • Spray drying may be performed according to a conventional method. Taking into account the quality of the spray dryer, such as the force, the power, and the fluidity of the powder obtained, the operating conditions of the spray dryer are: inlet hot air temperature 130 ° C to 200 ° C, outlet exhaust air temperature 5 0 ° C ⁇ 1 2 0 ° C, it is desirable that the air volume 3 m 3 Zm in ⁇ 7 m 3 / min.
  • the dried powder of the sea squirt having the same characteristics as the dried powder of the sea squirt obtained by the manufacturing method of passing through the vacuum freeze-drying process without passing through the crushing process Can be obtained.
  • the slurry is exposed to hot air during spray drying, and the powder during drying has a residence time of several seconds, and the latent heat of evaporation suppresses the rise in powder temperature, so there is no quality deterioration Excellent dry powder can be obtained.
  • a stripping step similar to the manufacturing method through the vacuum freeze-drying step is performed.
  • the soft body obtained in the first step is used as a paste ( ⁇ —Strand-like molding process).
  • Strand-like molding process
  • the second step may be performed immediately after the first step.However, the soft body obtained in the first step is temporarily frozen for a purpose such as temporary storage, and then the thawed product is thawed. And the second step may be performed.
  • the paste-like substance obtained in the second step is dried under reduced pressure (drying step).
  • the drying under reduced pressure is performed, for example, by spreading the paste-like material thinly on a plate.
  • the drying conditions pressure 5 xl 0 4 P a ⁇ : L xl 0 5 P a, the drying temperature 3 0 ° C ⁇ 5 0 ° C and the like.
  • a pulverization step similar to the production method through a vacuum freeze-drying step is performed.
  • the dried powder of sea squirt produced through the above-mentioned stripping process, pasty material forming process, drying process, and crushing process is dark orange, has excellent fluidity, and has a high flavor but no odor.
  • This powder is different from the powder obtained by the manufacturing method passing through the vacuum freeze-drying process and the powder obtained by the spray drying process from the viewpoint of sight, taste, and smell, and is left at room temperature.
  • the taste and aroma do not change, and they are common in that they can be stored for a long time.
  • the dried sea squirt powder obtained by the above manufacturing method is extremely versatile and can be used as a food material with high nutritional value.
  • Examples of application as food materials include, but are not limited to, udon (buckwheat noodles, buckwheat, Chinese noodles, Chinese food, staples, etc.), rice cakes, various instant foods, and kneaded products (kamaboko, chikuwa, soy sage, hamburg, etc.) ), Confectionery (snack confectionery, baked confectionery, rice crackers, Japanese confectionery, Western confectionery, etc.), breads, donuts, powdered soups, cheese, tofu and other processed foods.
  • the addition of dried sea squirt powder to a type I mochi has the advantage of enhancing the elastic chewy texture as described below.
  • cheese is produced by adding this powder, a mellow cheese can be obtained.
  • this powder When this powder is added to the batter, the batter fries clearly, and when it is added to the pickles, you can enjoy the texture of L, even pickled fresh pickles.
  • This Mixing the powder with milk or juice can give it a rich taste.
  • this powder When this powder is applied to, for example, a kind of rice cake, it is desirable to add 0.1 to 5 wt% to the flour and rice cake.
  • dried sea squirt powder contains natural umami ingredients such as glycine, alanine, gnoremic acid, betaine, etc.
  • it can be used as a seasoning itself, as well as miso, sauces, dressings, It can be added to various seasonings such as mayonnaise and can be applied to all kinds of dishes such as Japanese, Western and Chinese.
  • seasonings such as mayonnaise and can be applied to all kinds of dishes such as Japanese, Western and Chinese.
  • the dried sea squirt powder appears to have surfactant and emulsifying effects and does not cause phase separation when added to the dressing. Also, it does not solidify fats and oils contained in stew and other stew. Therefore, the broth to which the dried sea squirt powder is added has an advantage that it can be used as a sauce.
  • dried sea squirt powder can be taken as a nutritional food or nutrient that is convenient for carrying. .
  • the dried sea squirt powder has high utility value as an elasticity enhancer for food additives and a shape collapse preventive agent.
  • One of the factors of this effect is that the structure of the dough (texture) is firmly mixed with actin and myosin, which are proteins contained in muscle fibers that make up most of the edible portion of ascidian. The power to make it possible is considered.
  • the effect of the dried sea squirt powder can be exerted by adding 0.1 wt% or more to food.
  • dried sea squirt powder is highly useful as an antibacterial agent. This effect can be exerted by adding 0.1 lwt% or more to food.
  • One of the factors is considered to be the contribution of strong antioxidant action such as selenium and glycine contained in sea squirt.
  • the dried sea squirt powder has an SOD-like activity. Therefore, dried squirt powder As a SOD-like activator, it eliminates active oxygen, which is a causative agent of living body aging, allergy and inflammation, damage to smooth muscle during myocardial infarction, liver damage, cancer, etc. The utility value is high in that it has a preventive effect.
  • the dried squirt as the raw material of the dried powder can be used as it is or returned to water for health foods and natural foods. It can also be used as a meal or to enhance the flavor of sake.
  • the dried squirt obtained by the manufacturing method through the reduced pressure drying step has no odor but has a high flavor. Therefore, the flaked dried squirt obtained by coarsely pulverizing the flakes can also be used as a material for sprinkling.
  • the slurry-like material obtained by the spraying process of the dried sea squirt powder and the paste-like material obtained by the manufacturing method passing through the reduced-pressure drying process may be used as a direct addition to a class I product.
  • the slurry-like material obtained by the spraying process of the dried sea squirt powder and the paste-like material obtained by the manufacturing method passing through the reduced-pressure drying process may be used as a direct addition to a class I product.
  • Example 1 Manufacture of dried squirt powder (method via vacuum freeze-drying process)
  • the red sea squirt from the Sea of Okhotsk was separated into the outer hull and the soft body immediately after being caught, and the separated soft body was washed with water, placed in a freezer at 135 ° C, and frozen.
  • Example 2 Production of dried squirt powder (method via spray drying step) The frozen material of the soft part obtained in the same manner as in Example 1 was put into a plastic bag, thawed with running water, and then crushed using a massco mouth whatsoever (three passes: clearance of 0.02 mm x 3 times). A paste was obtained. This paste was refined with a ball mill to obtain a slurry. In the case of fine particles, zirconia with a particle size of 0.65 mm was used as the media, the gap was 0.2 mm, the number of revolutions was 250 rpm, the residence time was about 2 minutes, and the outlet liquid temperature was 40 ° C or less. Performed twice under the conditions.
  • This slurry was spray-dried to obtain a dried squirt powder.
  • the spray dryer has a chamber diameter of 1.0m, conical section at 50 °, chamber volume of about 0.8m2 Fluid nozzle atomizer, air nozzle PA120, liquid nozzle PF600, Air pressure 0.75 kg / cm ⁇
  • the liquid supply method used was a tube pump.
  • a dried powder of sea squirt was obtained (evaluation by laser diffraction method).
  • the operating conditions were set to the inlet hot air temperature of 150. C, outlet exhaust temperature 70.
  • the air flow rate was 5.OmVmin
  • the dry powder strength of the sea squirt with a particle size of 28.0 microns and a water content of 9.0 wt% was obtained (evaluation by laser diffraction method). All of the powders were orange fluid powders with the original taste and aroma of sea squirt, although the smelt odor was significantly reduced.
  • the water activity of the dried sea squirt powder was 0.30.
  • Example 3 Manufacture of dried squirt powder (method through reduced pressure drying step)
  • the frozen product of the soft part obtained in the same manner as in Example 1 was put into a binnino bag, thawed with running water, and then crushed using a Masco mouth Ida (7 passes: clearance 3 mm x 2 times, l mm x 2 times, 0.02 mm x 3 times) to obtain a paste.
  • the water content of the obtained paste was 85.2%.
  • the paste was spread as thinly as possible on an alumite plate. Put it in vacuum dryer, the pressure 8. 0 xl 0 4 P a ⁇ 9. 3 x 1 0 4 P a, for 1 9 hrs dried at a drying temperature 4 0 ° C, to obtain a dried Hoya .
  • the obtained dried sea squirt was a deep orange with a water content of 22.1%, had a high flavor, but had no odor.
  • This dried squirt was pulverized with a 0.5 mm mesh pulverizer to obtain a dry powder of about 30 microns.
  • the resulting powder is dark, orange with a water activity of 0.24, excellent in fluidity, It had a high flavor but no odor.
  • Example 2 After 7 kg of the soft flour was put into the mixer, 70 g of the dried squirt powder of the sea squirt obtained in Example 1 was added, and the mixture was stirred and uniformly mixed. Next, a salt solution having a salt concentration of 10 ° C prepared by adding salt to 2.1 kg of water was gradually added into the mixer, and the mixture was stirred for about 20 minutes. After aging for 2 hours, the mixture was molded, cut with a brush having a width of 16 mm, and cut into a length of 30 cm to obtain a udon noodles containing dried squirt powder.
  • the sea urchin without dried squirt powder showed a sticky feeling over time, and the quality retention was limited to 10 days after production, but the noodles containing dried squirt powder after 10 days had passed. There was no difference between immediately after production.
  • Example 1 After soaking 2.8 kg of rice cake in water for 6 hours, the rice was drained for about 30 minutes. With electric mochi After putting 600 cc of water into the machine, add the rice cake described above, further add 20 g of the dried sea squirt powder obtained in Example 1, mix gently, and dry the sea squirt powder according to the manual of the electric rice cake maker. A rice cake was prepared.
  • the obtained mochi had a chewy texture rich in elasticity as in the udon of Example 2.
  • the mochi made by the same method except that the dried sea squirt powder and the sea squirt powder were not cut, cut into 3 cm squares and placed in boiling water for 5 minutes. However, each piece expands and loses its shape so that it cannot be lifted with chopsticks, and the boiling water becomes considerably cloudy. Hot water was slightly cloudy o
  • the mochi produced by the same method except that the dried squirt powder was not used was left indoors, and 10 days after the production, blue mold was generated.
  • Example 6 S0D-like activity test of dried powdered extract of sea squirt (part 1)
  • Example 2 500 mg of the dried sea squirt powder obtained in Example 1 was dissolved in 10 ml of dimethyl sulfoxide (DMSO) and stirred for one day. Thereafter, the mixture was centrifuged at 300 rpm for 10 minutes to remove insoluble portions, and a sample having the composition shown in Table 2 was prepared using the supernatant as a sample.
  • DMSO dimethyl sulfoxide
  • DMPO 5,5 dimethyl-1-pyrroline-1-oxide
  • PBS phosphate buffered saline
  • the DMSO extract of the dried sea squirt powder had a S0D-like activity higher than that of vitamin A (retino-monophosphate: RA) 20 ⁇ g / m1.
  • Example 7 SOD-like activity test of dried powdered extract of sea squirt (part 2)
  • the SOD-like activity of the PBS extract of the dried sea squirt powder was evaluated in the same manner as in Example 6 except that PBS was used in place of DM S0 used in Example 6. Had excellent activity.
  • Example 2 The soft body portion washed with water in the same manner as in Example 1 was dried under normal temperature and normal humidity conditions, but it took a long time to dry, and the smell of sea squirt became considerably strong. Also, as time passed, dirt could no longer be ignored. Drying under low temperature conditions (2 ° C to 8 ° C) and drying using salted soft parts were also attempted, but the results were the same, it took a long time to dry, and the smell of sea squirt became quite strong. . Therefore, it was not possible to produce a dried powder of ascidian by these methods. Industrial applicability
  • the dried sea squirt powder of the present invention has the original taste and scent of the sea squirt, despite the reduced squirt odor which has been a cause of dislike of the sea squirt, and has good storage stability. Therefore, it can be added to various processed foods as a food material with excellent versatility and high nutritional value, or used as a seasoning. It is also highly useful as an elasticity enhancer for food additives, an anti-deformation agent, an antibacterial agent, and an SOD-like activator.

Abstract

A dry ascidian powder produced by starting with the mollusc part of ascidian remaining after eliminating the integument (tunica). This powder is an ascidian food product of a novel with a high storage stability wherein the ascidian smell, which causes a like or dislike for ascidian, has been relieved but the characteristic taste and flavor of ascidian are sustained. This powder is usable in various purposes over a wide range, for example, as a highly nutritious food additive to be blended into various processed foods or as a seasoning as such. Moreover, it is highly useful as food additives such as an elasticity improving agent, a shape-retention agent, an antibacterial agent, an agent with an SOD-like activity, etc.

Description

明細書 ホヤの乾燥粉末、 その用途、 その製造方法、 ホヤ臭の軽減方法および乾燥ホヤ 技術分野  Description Dry powder of sea squirt, its use, its manufacturing method, method of reducing sea squirt, and dried sea squirt
本発明は、 ホヤ臭が軽減された誰にでも摂取しやすいホヤの新規な食品形態、 その用途、 その製造方法、 ホヤ臭の軽減方法および乾燥ホヤに関する。 背景技術  TECHNICAL FIELD The present invention relates to a novel food form of sea squirt which is easy to be taken by anyone with reduced sea scent, its use, its production method, method of reducing sea scent, and dried sea squirt. Background art
ホヤ (海鞘) は、 海底の岩石などに着生する原索動物の一種で、 我が国では、 東北地方から北海道地方にかけて漁獲され、 外皮 (被嚢) を除去した軟体部 (筋 肉および内蔵) は、 可食部として古くから食用に供せられている。  The sea squirt (sea sheath) is a kind of protozoa that settle on rocks on the sea floor. In Japan, the soft body (muscle and internal organs) whose husk (capsule) is removed from the Tohoku region to the Hokkaido region is caught. The edible part has been used for food since ancient times.
ところで、 ホヤには、 栄養価値カ高い成分や人体にとって有用な成分が豊富に 含まれていることが知られている。 例えば、 ホヤの筋肉には、 グリコーゲンカ哆 量に含まれており、 消化されやすく吸収の早い動物性炭水化物の供給源として貴 重である。 ホヤのエキス分には、 アミノ酸として、 細胞活性化作用などがある夕 ゥリン、 知的能力向上作用などがあるロイシンをはじめ、 グリシン、 ァラニン、 ノくリン、 セリン、 スレオニン、 チロシン、 メチォニン、 ァスパラギン酸、 グノレ夕 ミン酸、 ヒスチジン、 アルギニン、 リジンなどが含まれている。 また、 塩基とし ては、 ベタインゃコリンなど力含まれている。 プリン塩基としては、 アデニンや キサンチンなどが含まれている。 ミネラルとしては、 ナトリウム、 カリウム、 力 ルシゥム、 鉄、 亜鉛などが含まれている。 微量元素としては、 老化防止や性能力 向上作用があるセレンをはじめ、 ノくナジゥム、 ゲルマニウムなど力多量に含まれ ている。 更に、 エイコサペンタエン酸ゃドコサへキサェン酸などの不飽和脂肪酸 や、ビタミ B、ビタミン〇、ビタミン Eなどの各種ビタミン類も含まれている。 これらのうち、 グリシン、 ァラニン、 グルタミン酸、 ベタインは、 味覚に密接に 関係している成分である。  By the way, it is known that sea squirts are rich in ingredients with high nutritional value and useful ingredients for the human body. For example, ascidian muscle is included in glycogen content and is a valuable source of animal carbohydrates that are easily digested and quickly absorbed. Ascidian extract contains amino acids such as insulin, which has a cell activating effect, leucine, which has an intellectual enhancing effect, glycine, alanine, nocline, serine, threonine, tyrosine, methionine, and aspartic acid. , Gnore, acid, histidine, arginine, lysine, etc. In addition, as a base, betaine-choline and the like are included. Purine bases include adenine and xanthine. Minerals include sodium, potassium, potassium, iron, and zinc. Trace elements include selenium, which has the effect of preventing aging and improving sexual performance, as well as a large amount such as sodium, germanium, and the like. It also contains unsaturated fatty acids such as eicosapentaenoic acid and docosahexaenoic acid, and various vitamins such as vitamin B, vitamin II, and vitamin E. Of these, glycine, alanine, glutamic acid, and betaine are components that are closely related to taste.
このように、 ホヤは、 成分的に非常に貴重な食品である。 しかしながら、 ホヤ は、 特有の臭味 (ホヤ臭) を有しているので、 人によって好き嫌いが激しい食品 である。 また、 生のホヤは、 傷みやすく、 変色しやすい保存安定性の極めて悪い 食品である。 これらの理由のため、 ホヤは、 限られた地域で生のホヤが食されて いるほか、 塩辛などに加工されて珍味や酒肴品として食されているにすぎないの カ現状である。 As such, sea squirts are a very valuable ingredient in food. However, sea squirts have a peculiar smell (smell of sea squirt). It is. In addition, raw sea squirts are foods that are easily damaged and easily discolored and have extremely poor storage stability. For these reasons, sea squirts are eaten as raw delicacies and savory foods in a limited area, as well as being processed into salted foods.
本発明は、 上記の背景技術に鑑み、 ホヤ臭力軽減された誰にでも摂取しやすい ホヤの新規な食品形態、 その用途、 その製造方法、 ホヤ臭の軽減方法および乾燥 ホヤを提供することを目的とする。 発明の開示  The present invention has been made in view of the above background art, and provides a novel food form of sea squirt whose sea scent is reduced and which is easy for anyone to ingest, its use, its manufacturing method, method of reducing sea scent, and dried sea squirt. Aim. Disclosure of the invention
本発明者らは、 種々の検討を行った結果、 ホヤの外皮 (被嚢) を除去した軟体 部を特定の工程を経て粉末化することによって、 食品素材として用いることがで きる非常に汎用性の高い乾燥粉末力得られること、 まったく意外なことに、 この 乾燥粉末は、 食品に対する弾力増強作用や型くずれ防止作用の他、 抗菌作用、 ス As a result of various studies, the present inventors found that the soft body from which the outer skin (capsule) of the sea squirt was removed was powdered through a specific process, so that it could be used as a food material. Surprisingly, this dry powder has an antibacterial effect, as well as an elasticity-enhancing effect on food and a shape-preventing effect.
—パ一ォキシドジスムターゼ (S O D ) 様活性作用などの機能性を有すること、 また、 好き嫌 、の原因となるホヤ臭を効果的に軽減できることを知見した。 本発明は、 かかる知見に基づきなされたもので、 本発明のホヤの乾燥粉末は、 請求の範囲第 1項記載の通り、 ホヤの外皮 (被嚢) を除去した軟体部を原料にし て製造されたことを特徴とする。 —We have found that it has functionalities such as a peroxide dismutase (SOD) -like activity and that it can effectively reduce ascidian odor, which causes liking and dislike. The present invention has been made based on such knowledge, and the dry powder of the sea squirt of the present invention is manufactured using a soft body from which the outer skin (capsule) of the sea squirt has been removed as described in claim 1. It is characterized by having.
また、 本発明の食品素材は、 請求の範囲第 2項記載の通り、 ホヤの乾燥粉末を 主成分とすることを特徴とする。  Further, the food material of the present invention is characterized in that, as described in Claim 2, a dried powder of sea squirt is a main component.
また、 本発明の加工食品は、 請求の範囲第 3項記載の通り、 ホヤの乾燥粉末を 含むことを特徴とする。  Further, the processed food of the present invention is characterized in that it contains dried sea squirt powder as described in claim 3.
また、 請求の範囲第 4項記載の加工食品は、 請求の範囲第 3項記載の加工食品 において、 加工食品が麵類であることを特徴とする。  Further, the processed food according to claim 4 is the processed food according to claim 3, characterized in that the processed food is a kind.
また、 請求の範囲第 5項記載の加工食品は、 請求の範囲第 3項記載の加工食品 において、 加工食品が餅であることを特徴とする。  The processed food according to claim 5 is the processed food according to claim 3, wherein the processed food is rice cake.
また、 本発明の調味料は、 請求の範囲第 6項記載の通り、 ホヤの乾燥粉末を含 むことを特徴とする。  Further, the seasoning of the present invention is characterized in that it contains dried sea squirt powder as described in claim 6.
また、 本発明の食品添加用弾力増強剤は、 請求の範囲第 7項記載の通り、 ホヤ の乾燥粉末を有効成分とすることを特徴とする。 Further, the elasticity enhancer for food additives of the present invention comprises a squirt as described in claim 7. Characterized by using a dry powder as an active ingredient.
また、 本発明の食品添加用型くずれ防止剤は、 請求の範囲第 8項記載の通り、 ホャの乾燥粉末を有効成分とすることを特徴とする。  In addition, as set forth in claim 8, the food additive type collapse preventive agent of the present invention is characterized in that dry powder of sea squirt is used as an active ingredient.
また、 本発明の抗菌剤は、 請求の範囲第 9項記載の通り、 ホヤの乾燥粉末を有 効成分とすることを特徴とする。  Further, as described in claim 9, the antibacterial agent of the present invention is characterized by using dried powder of sea squirt as an active ingredient.
また、 本発明のスーパ一ォキシドジスムタ一ゼ様活性剤は、 請求の範囲第 1 0 項記載の通り、 ホヤの乾燥粉末を有効成分とすることを特徴とする。  Further, the superoxide dismutase-like activator of the present invention is characterized in that, as described in claim 10, a dry powder of sea squirt is used as an active ingredient.
また、本発明のホヤの乾燥粉末の製造方法は、請求の範囲第 1 1項記載の通り、 ホヤの外皮 (被嚢) を除去した軟体部を真空凍結乾燥した後、 粉砕することを特 徴とする。  Further, the method for producing a dried squirt powder of the squirt according to the present invention is characterized in that, as described in claim 11, the soft body from which the outer skin (capsule) of the squirt is removed is freeze-dried in vacuum and then pulverized. And
また、本発明のホヤの乾燥粉末の製造方法は、請求の範囲第 1 2項記載の通り、 ホヤの外皮 (被嚢) を除去した軟体部をスラリー状物とし、 これを噴霧乾燥する ことを特徴とする。  Further, the method for producing a dried squirt powder of the squirt according to the present invention, as described in claim 12, comprises forming a soft body from which the outer skin (capsule) of the squirt is removed into a slurry and spray-drying the slurry. Features.
また、本発明のホヤの乾燥粉末の製造方法は、請求の範囲第 1 3項記載の通り、 ホヤの外皮 (被嚢) を除去した軟体部をペースト状物とし、 これを減圧乾燥した 後、 粉砕することを特徴とする。  Further, according to the method for producing a dried sea squirt powder of the present invention, as described in Claim 13, the soft body portion from which the outer skin (capsule) of the sea squirt is removed is made into a paste, which is dried under reduced pressure. It is characterized by crushing.
また、 本発明のホヤ臭の軽減方法は、 請求の範囲第 1 4項記載の通り、 ホヤの 外皮 (被嚢) を除去した軟体部を真空凍結乾燥することを特徴とする。  Further, as described in claim 14, the method for reducing the smell of sea squirt of the present invention is characterized in that the soft body part from which the outer skin (capsule) of the sea squirt has been removed is subjected to vacuum freeze-drying.
また、 本発明のホヤ臭の軽減方法は、 請求の範囲第 1 5項記載の通り、 ホヤの 外皮 (被嚢) を除去した軟体部をスラリー状物とし、 これを噴霧乾燥することを 特徴とする。  Further, the method for reducing squirt odor according to the present invention is characterized in that, as described in claim 15, the soft body portion from which the outer skin (capsule) of the squirt is removed is made into a slurry-like material, and this is spray-dried. I do.
また、 本発明の乾燥ホヤは、 請求の範囲第 1 6項記載の通り、 ホヤの外皮 (被 嚢) を除去した軟体部を真空凍結乾燥して得られたことを特徴とする。  Further, the dried squirt according to the present invention is obtained by vacuum freeze-drying a soft part from which the outer skin (capsule) of the squirt is removed, as described in claim 16.
また、 本発明の乾燥ホヤは、 請求の範囲第 1 7項記載の通り、 ホヤの外皮 (被 嚢) を除去した軟体部をペースト状物とし、 これを減圧乾燥して得られたことを 特徴とする。 図面の簡単な説明  Further, the dried squirt of the present invention is obtained by drying a soft body from which the outer skin (capsule) of the squirt has been removed as a paste-like material and drying it under reduced pressure, as described in claim 17. And BRIEF DESCRIPTION OF THE FIGURES
第 1図は、 本発明のホヤの乾燥粉末の DM S 0抽出物と P B S抽出物の S 0 D 様活性を示す線図である。 発明を実施するための最良の形態 FIG. 1 shows the S D 0 extract of the dried powder of sea squirt of the present invention and the S 0 D of the PBS extract. FIG. 3 is a diagram showing a similar activity. BEST MODE FOR CARRYING OUT THE INVENTION
本発明に用いられるホヤとしては、 マボャ、 赤ホヤ、 白ホヤなど、 食用に供せ られているホヤならば特段の制限はなく、 いずれのホヤも用いることができる。 本発明におけるホヤの乾燥粉末の製造方法は、 以下に詳述するように大きく分 けて 3つの方法がある。  The sea squirt used in the present invention is not particularly limited, and any sea squirt, such as a sea squirt, a red sea squirt, a white sea squirt, may be used without particular limitation. The method for producing a dried sea squirt powder in the present invention is roughly classified into three methods as described in detail below.
1 . 真空凍結乾燥工程を経る製造方法  1. Manufacturing method through vacuum freeze-drying process
まず、 第一工程として、 ホヤを外皮と軟体部に分離し、 分離した軟体部を水な どで洗浄する (剥き身工程)。  First, as a first step, the sea squirt is separated into an outer skin and a soft body part, and the separated soft body part is washed with water or the like (peeling step).
次に、 第二工程として、 前記軟体部を剥き身のまま、 あるいは適当な大きさや 形状に切断や破砕などして凍結させる(凍結工程)。凍結条件に特段の制限はなく、 例えば、 フリーザーなどを用いて、 一 2 0 °C〜一 5 0 °Cで凍結させればよい。 尚、 第二工程まではホヤの鮮度を考慮して、 漁獲後速やかに処理することが望 ましい。  Next, as a second step, the soft part is frozen as it is, or cut or crushed into an appropriate size or shape (freezing step). There are no particular restrictions on the freezing conditions. For example, the freezing may be performed at 120 ° C. to 150 ° C. using a freezer or the like. Up to the second step, it is desirable to treat the sea squirts as soon as possible after catching in consideration of the freshness of the sea squirt.
更に、 第三工程として、 ?東結させた軟体部を真空凍結乾燥にて乾燥させる (乾 燥工程)。真空凍結乾燥は、常法に従って行えばよいが、得られる乾燥ホヤの品質 を考慮すれば、 真空度 1 P a〜 5 0 P a、 乾燥温度 3 0 °C〜 7 0 °Cの条件にて行 うことが望ましい。 乾燥時間は、 処理量にも依存するので一概に特定することは できないが、 菌の増殖を抑制するためには、 水分活性が 0 . 5以下になるように 乾燥すること力望ましい。 得られる乾燥ホヤは橙色で、 ホヤ本来の味と香りを有 するものの、 ホヤ臭は著しく軽減されている。  Furthermore, as a third step,? Dry the dried soft parts by vacuum freeze-drying (drying process). Vacuum freeze-drying may be performed according to a conventional method.However, in consideration of the quality of the obtained dried squirt, a vacuum of 1 Pa to 50 Pa and a drying temperature of 30 ° C to 70 ° C is used. It is desirable to do this. The drying time cannot be specified unconditionally because it depends on the treatment amount, but in order to suppress the growth of bacteria, it is desirable to dry the water so that the water activity becomes 0.5 or less. The dried sea squirt obtained is orange and has the original taste and aroma of sea squirt, but the sea scent is significantly reduced.
最後に、第四工程として、乾燥ホヤを粉砕機にて粉砕する (粉砕工程)。粉砕条 件は、 常法に従えばよい。 粒度は、 得られる粉末の流動性などの品質を考慮すれ ば、 0 . 1ミリメッシュ〜 1 ミリメッシュの粉砕機を用いて、 1 0ミクロン〜 1 0 0ミクロンとすることが望ましい。  Finally, as a fourth step, the dried squirt is pulverized by a pulverizer (pulverizing step). Grinding conditions may be in accordance with ordinary methods. The particle size is desirably in the range of 10 to 100 microns using a pulverizer of 0.1 to 1 millimesh in consideration of the quality such as fluidity of the obtained powder.
上記の、 剥き身工程、 凍結工程、 乾燥工程、 粉砕工程を経て製造されるホヤの 乾燥粉末は、 橙色の流動性のある粉末で、 ホヤ臭が著しく軽減されているにもか かわらず、 ホヤ本来の味と香りを有している。 また、 このホヤの乾燥粉末は、 常 温で放置しても味や香り力変質することはなく、 長期保存が可能である。 The dried powder of sea squirt produced through the above-mentioned stripping, freezing, drying, and crushing processes is an orange fluid powder, and although the sea scent is significantly reduced, Has a taste and aroma. Also, the dried powder of this sea squirt is always It does not deteriorate in taste or aroma even when left at room temperature, and can be stored for a long time.
2 . 噴霧乾燥 (スプレードライ) 工程を経る製造方法  2. Manufacturing method through spray drying process
まず、 第一工程として、 真空凍結乾燥工程を経る製造方法と同様の剥き身工程 を行う。 First, as the first step, a stripping step similar to the manufacturing method through the vacuum freeze-drying step is performed.
:ヽ 第二工程として、 第一工程で得られた軟体部をスラリー状物とする (ス ラリ一状物成形工程)。軟体部をスラリ一状物とする方法としては、例えば、マス コロイダ一やボールミルなどを常法に従って単独で、 または組み合わせて用いる 方法が挙げられる。 ホヤの軟体部は繊維質であるため、 噴霧乾燥可能なスラリー 状物とするためには、 繊維質を十分に微砕する必要がある。 従って、 この点を考 慮すれば、 マスコ口イダ一を用いて軟体部をべ一スト状物とし、 これをボ一ルミ ルを用いて微細してスラリ一状物とすることが望ましい。  : ヽ In the second step, the soft part obtained in the first step is converted into a slurry (a slurry-like substance forming step). Examples of a method of forming the soft body into a slurry-like material include a method using a mass colloid, a ball mill, or the like singly or in combination according to a conventional method. Since the soft part of sea squirt is fibrous, it is necessary to sufficiently pulverize the fibrous material to obtain a spray-dryable slurry. Therefore, in consideration of this point, it is desirable to make the soft body a paste-like material by using a masco nozzle, and to make the slurry into a slurry-like material by using a ball mill.
尚、 第一工程に引き続き第二工程を即座に行ってもよいが、 第一工程で得られ た軟体部を一時保存などの目的のためにいつたん凍結させ、 その後、 これを解凍 したものを用いて第二工程を行ってもよい。  The second step may be performed immediately after the first step.However, the soft body obtained in the first step is temporarily frozen for a purpose such as temporary storage, and then the thawed product is thawed. May be used to perform the second step.
最後に、 第三工程として、 第二工程で得られたスラリー状物を噴霧乾燥にて乾 燥させる (乾燥工程)。噴霧乾燥は、常法に従って行えばよい。 し力、しなカら、得 られる粉末の流動性などの品質を考慮すれば、 噴霧乾燥機の運転条件は、 入口熱 風温度 1 3 0 °C〜 2 0 0 °C、 出口排風温度 5 0 °C〜 1 2 0 °C、 風量 3 m 3 Zm i n〜7 m 3 /m i nとすることが望ましい。 Finally, as a third step, the slurry obtained in the second step is dried by spray drying (drying step). Spray drying may be performed according to a conventional method. Taking into account the quality of the spray dryer, such as the force, the power, and the fluidity of the powder obtained, the operating conditions of the spray dryer are: inlet hot air temperature 130 ° C to 200 ° C, outlet exhaust air temperature 5 0 ° C~ 1 2 0 ° C, it is desirable that the air volume 3 m 3 Zm in~7 m 3 / min.
上記の、 剥き身工程、 スラリー状物成形工程、 乾燥工程によれば、 粉砕工程を 経ることなく、真空凍結乾燥工程を経る製造方法で得られるホヤの乾燥粉末と同 じ特性を有するホヤの乾燥粉末を得ることができる。 スラリ一状物は噴霧乾燥時 に熱風中にさらされるカ、 乾燥中の粉末は滞留時間が数秒間であり、 蒸発潜熱に よつて粉末温度の上昇が抑制されるので、 品質の劣化などがない優れた乾燥粉末 を得ることができる。  According to the stripping process, the slurry forming process, and the drying process, the dried powder of the sea squirt having the same characteristics as the dried powder of the sea squirt obtained by the manufacturing method of passing through the vacuum freeze-drying process without passing through the crushing process Can be obtained. The slurry is exposed to hot air during spray drying, and the powder during drying has a residence time of several seconds, and the latent heat of evaporation suppresses the rise in powder temperature, so there is no quality deterioration Excellent dry powder can be obtained.
3 . 減圧乾燥工程を経る製造方法 3. Manufacturing method through vacuum drying process
まず、 第一工程として、 真空凍結乾燥工程を経る製造方法と同様の剥き身工程 を行う。  First, as the first step, a stripping step similar to the manufacturing method through the vacuum freeze-drying step is performed.
次に、 第二工程として、 第一工程で得られた軟体部をべ一スト状物とする (ぺ —スト状物成形工程)。 軟体部をペースト状物とする方法には特段の制限はなく、 例えば、 マスコ口イダ一を常法に従って用いて行えばよい。 Next, as a second step, the soft body obtained in the first step is used as a paste (物 —Strand-like molding process). There is no particular limitation on the method of converting the soft part into a paste-like material.
尚、 第一工程に引き続き第二工程を即座に行ってもよいが、 第一工程で得られ た軟体部を一時保存などの目的のためにいつたん凍結させ、 その後、 これを解凍 したものを用し、て第二工程を行つてもよい。  The second step may be performed immediately after the first step.However, the soft body obtained in the first step is temporarily frozen for a purpose such as temporary storage, and then the thawed product is thawed. And the second step may be performed.
更に、 第三工程として、 第二工程で得られたペース卜状物を減圧乾燥にて乾燥 させる (乾燥工程)。減圧乾燥は、例えば、ペースト状物をプレート上に薄く延ば して行う。乾燥条件としては、圧力 5 x l 0 4 P a〜: L x l 0 5 P a、乾燥温度 3 0 °C〜5 0 °Cが挙げられる。 この条件によってペースト状物を乾燥させると、 高 い風味を有する (但し、 臭みはない) 乾燥ホヤを得ることができる。 Further, as a third step, the paste-like substance obtained in the second step is dried under reduced pressure (drying step). The drying under reduced pressure is performed, for example, by spreading the paste-like material thinly on a plate. The drying conditions, pressure 5 xl 0 4 P a~: L xl 0 5 P a, the drying temperature 3 0 ° C~5 0 ° C and the like. When the paste is dried under these conditions, a dried sea squirt having a high flavor (but no odor) can be obtained.
最後に、 第四工程として、 真空凍結乾燥工程を経る製造方法と同様の粉砕工程 を行う。  Finally, as a fourth step, a pulverization step similar to the production method through a vacuum freeze-drying step is performed.
上記の、 剥き身工程、 ペース卜状物成形工程、 乾燥工程、 粉砕工程を経て製造 されるホヤの乾燥粉末は、 濃い橙色で、 流動性に優れ、 高い風味を有するが臭み はない。 この粉末は、 真空凍結乾燥工程を経る製造方法で得られる粉末や、 噴霧 乾燥工程を経る製造方法で得られる粉末とは、 視覚上や味覚上や嗅覚上において 異なるものである力、 常温で放置しても味や香りが変質することはなく、 長期保 存が可能な点では共通している。  The dried powder of sea squirt produced through the above-mentioned stripping process, pasty material forming process, drying process, and crushing process is dark orange, has excellent fluidity, and has a high flavor but no odor. This powder is different from the powder obtained by the manufacturing method passing through the vacuum freeze-drying process and the powder obtained by the spray drying process from the viewpoint of sight, taste, and smell, and is left at room temperature. However, the taste and aroma do not change, and they are common in that they can be stored for a long time.
以上のような製造方法によつて得られるホヤの乾燥粉末は、 非常に汎用性に優 れ、 栄養価値の高い食品素材として用いることができる。  The dried sea squirt powder obtained by the above manufacturing method is extremely versatile and can be used as a food material with high nutritional value.
食品素材としての応用例としては、 例えば、 麵類 (うどん、 そば、 素麵、 中華 麵、ノ、。スタなど)、餅、各種インスタント食品、練製品 (かまぼこ、 ちくわ、 ソ一 セージ、ハンバーグなど)、菓子(スナック菓子、焼菓子、せんべい、和菓子、洋 菓子など)、パン類、 ドーナツ類、粉末スープ類、 チーズ、豆腐などの加工食品へ の添加を挙げることができる。 ホヤの乾燥粉末を麵類ゃ餅に添加すると、 後述す るように、 弾力性に富む歯ごたえを増強することができるなどの利点がある。 ま た、 この粉末を添加してチーズを製造すると、 まろやかなチーズに仕上げること ができる。また、この粉末を天ぶらの衣に加えると天ぶらがシャッキリと揚がり、 漬物に入れると L、つまでも新漬けのような歯ざわりを楽しむことができる。 この 粉末を牛乳やジュースに混ぜるとコクのある味に仕上げることができる。 この粉 末を、 例えば、 麵類ゃ餅に応用する場合、 薄力粉や餅米に対して 0 . l w t %〜 5 w t %添加することが望ましい。 Examples of application as food materials include, but are not limited to, udon (buckwheat noodles, buckwheat, Chinese noodles, Chinese food, staples, etc.), rice cakes, various instant foods, and kneaded products (kamaboko, chikuwa, soy sage, hamburg, etc.) ), Confectionery (snack confectionery, baked confectionery, rice crackers, Japanese confectionery, Western confectionery, etc.), breads, donuts, powdered soups, cheese, tofu and other processed foods. The addition of dried sea squirt powder to a type I mochi has the advantage of enhancing the elastic chewy texture as described below. In addition, if cheese is produced by adding this powder, a mellow cheese can be obtained. When this powder is added to the batter, the batter fries clearly, and when it is added to the pickles, you can enjoy the texture of L, even pickled fresh pickles. this Mixing the powder with milk or juice can give it a rich taste. When this powder is applied to, for example, a kind of rice cake, it is desirable to add 0.1 to 5 wt% to the flour and rice cake.
また、 ホヤの乾燥粉末は、 グリシン、 ァラニン、 グノレ夕ミン酸、 ベタインなど の天然のうま味成分を含んでいるので、 それ自体を調味料として利用することが できる他、 みそ、 たれ類、 ドレッシング、 マヨネーズなどの各種調味料に添加す ることもでき、 和食、 洋食、 中華などあらゆる料理に適用することができる。 お でんや煮物のだし代わりに用いると味覚が向上し、 その上、 日持ちがよくなる。 ホヤの乾燥粉末には界面活性作用と乳化作用があるようであり、 ドレッシングに 添加すると相分離を起させない。 また、 ステーキなどの煮汁に含まれる油脂を固 化させない。 従って、 ホヤの乾燥粉末を添加した煮汁は、 ソースとして利用でき るなどの利点がある。  In addition, as dried sea squirt powder contains natural umami ingredients such as glycine, alanine, gnoremic acid, betaine, etc., it can be used as a seasoning itself, as well as miso, sauces, dressings, It can be added to various seasonings such as mayonnaise and can be applied to all kinds of dishes such as Japanese, Western and Chinese. When used instead of a soup stock, the taste is improved and the shelf life is improved. The dried sea squirt powder appears to have surfactant and emulsifying effects and does not cause phase separation when added to the dressing. Also, it does not solidify fats and oils contained in stew and other stew. Therefore, the broth to which the dried sea squirt powder is added has an advantage that it can be used as a sauce.
また、 ホヤの乾燥粉末は、 乳糖や結晶セルロースなどの賦形剤を添加して錠剤 や丸薬にしたり、 カプセルに充填することによって、 携帯にも便利な栄養食品や 栄養剤として服用することもできる。  By adding excipients such as lactose and microcrystalline cellulose to tablets and pills or filling capsules, dried sea squirt powder can be taken as a nutritional food or nutrient that is convenient for carrying. .
ホヤの乾燥粉末を麵類ゃ餅などに添加すれば、 弾力性に富む歯ごたえを増強す ることができるとともに、 鍋物に入れた場合でも、 型くずれ (煮くずれ) を効果 的に防止することができる。 よって、 ホヤの乾燥粉末は、 食品添加用の弾力増強 剤や型くずれ防止剤としても利用価値が高い。 この作用の一要因としては、 ホヤ の可食部の大部分を構成する筋繊維に含まれる蛋白質であるァクチンやミオシン 力麵生地などに混合されることによって、 生地の構造 (テクスチャ一) を堅固な ものにすること力考えられる。 ホヤの乾燥粉末の当該作用は、 食品に対して 0 . 1 w t %以上添加することで発揮させることができる。  Addition of dried sea squirt powder to rice cakes, etc. can enhance the elasticity of the chewy texture and effectively prevent the shape loss (boil loss) even when placed in a pot. . Therefore, the dried sea squirt powder has high utility value as an elasticity enhancer for food additives and a shape collapse preventive agent. One of the factors of this effect is that the structure of the dough (texture) is firmly mixed with actin and myosin, which are proteins contained in muscle fibers that make up most of the edible portion of ascidian. The power to make it possible is considered. The effect of the dried sea squirt powder can be exerted by adding 0.1 wt% or more to food.
また、 ホヤの乾燥粉末を餅などに添加すれば、 カビの発生を効果的に抑制する ことができる。 従って、 ホヤの乾燥粉末は、 抗菌剤としても利用価値が高い。 こ の作用は、 食品に対して 0 . l w t %以上添加することで発揮させることができ る。 作用の一要因としては、 ホヤに含まれるセレンやグリシンなど力有する抗酸 化作用力寄与していること力考えられる。  In addition, the addition of dried sea squirt powder to rice cakes and the like can effectively suppress the generation of mold. Therefore, dried sea squirt powder is highly useful as an antibacterial agent. This effect can be exerted by adding 0.1 lwt% or more to food. One of the factors is considered to be the contribution of strong antioxidant action such as selenium and glycine contained in sea squirt.
更に、 ホヤの乾燥粉末は S O D様活性作用を有する。 従って、 ホヤの乾燥粉末 は S O D様活性剤として、 生体の老化、 アレルギーや炎症の惹起、 心筋梗塞に於 ける平滑筋の損傷、 肝臓障害、 癌などの原因物質とされる活性酸素を消去し、 こ れらの疾患の予防効果を有する点において利用価値が高い。 In addition, the dried sea squirt powder has an SOD-like activity. Therefore, dried squirt powder As a SOD-like activator, it eliminates active oxygen, which is a causative agent of living body aging, allergy and inflammation, damage to smooth muscle during myocardial infarction, liver damage, cancer, etc. The utility value is high in that it has a preventive effect.
尚、 ホヤの乾燥粉末の真空凍結乾燥工程を経る製造方法と減圧乾燥を経る製造 方法において、 乾燥粉末の原料となる乾燥ホヤは、 そのままで、 あるいは水にも どして、 健康食品や自然食品として食することや、 日本酒の風味向上のために利 用することもできる。 また、 減圧乾燥工程を経る製造方法において得られる乾燥 ホヤは、 臭みはないが高い風味を有している。 従って、 これを粗粉砕することに よって得られるフレーク状の乾燥ホヤは、 振りかけ用の素材としても利用するこ とができる。 さらに、 ホヤの乾燥粉末の噴霧乾燥工程を経る製造方法において得 られるスラリー状物や減圧乾燥工程を経る製造方法において得られるペース卜状 物につ 、ては、 直接麵類に添加するといつた利用方法もある。  In addition, in the manufacturing method of the dried sea squirt powder through the vacuum freeze-drying process and the manufacturing method through the reduced pressure drying, the dried squirt as the raw material of the dried powder can be used as it is or returned to water for health foods and natural foods. It can also be used as a meal or to enhance the flavor of sake. Further, the dried squirt obtained by the manufacturing method through the reduced pressure drying step has no odor but has a high flavor. Therefore, the flaked dried squirt obtained by coarsely pulverizing the flakes can also be used as a material for sprinkling. In addition, the slurry-like material obtained by the spraying process of the dried sea squirt powder and the paste-like material obtained by the manufacturing method passing through the reduced-pressure drying process may be used as a direct addition to a class I product. There are ways.
以下、 実施例によって本発明を更に具体的に説明する。 ただし、 本発明はこれ ら実施例に限定されるものではない。 実施例  Hereinafter, the present invention will be described more specifically with reference to examples. However, the present invention is not limited to these examples. Example
実施例 1 :ホヤの乾燥粉末の製造 (真空凍結乾燥工程を経る方法) Example 1: Manufacture of dried squirt powder (method via vacuum freeze-drying process)
オホーツク海産の赤ホヤを漁獲後速やかに外皮と軟体部に分離し、 分離した軟 体部を水洗いした後、 一 3 5 °Cの冷凍庫に入れ、 凍結させた。  The red sea squirt from the Sea of Okhotsk was separated into the outer hull and the soft body immediately after being caught, and the separated soft body was washed with water, placed in a freezer at 135 ° C, and frozen.
得られた軟体部の凍結物 4 0 k gを卜レイに並べ、 これを真空凍結乾燥機に入 れ、真空度 2 5 P a以下の条件で、棚温度を一 3 5 °Cから 4 0 °Cまで上昇させて、 2 4時間乾燥を行い、 5. 1 k gの乾燥ホヤを得た。 得られた乾燥ホヤは、 橙色 で、 ホヤ本来の味と香りを有するものの、 ホヤ臭は著しく軽減されていた。 この乾燥ホヤを 0. 5ミリメッシュの粉砕機で粉砕し、 約 3 0ミクロンの乾燥 粉末を得た。 得られた粉末は、 水分活性が 0. 0 7で (水分活性測定器としてシ ィベル機械株式会社製の T H 2 /R T D— 3 3 / B Sを使用:以下同じ)、ホヤ臭 力著しく軽減されているにもかかわらず、 ホヤ本来の味と香りを有する橙色の流 動性のある粉末であった。  40 kg of the obtained frozen soft body was placed in a tray, placed in a vacuum freeze dryer, and the shelf temperature was reduced from 135 ° C to 40 ° C under a vacuum of 25 Pa or less. C, and dried for 24 hours to obtain 5.1 kg of dried squirt. The obtained dried sea squirt was orange and had the original taste and aroma of the sea squirt, but the smell of sea squirt was significantly reduced. This dried squirt was pulverized with a 0.5 mm mesh pulverizer to obtain a dry powder of about 30 microns. The powder obtained had a water activity of 0.07 (using TH2 / RTD-33 / BS manufactured by Shibel Machine Co., Ltd. as a water activity measuring instrument: the same applies hereinafter), and the sea odor was significantly reduced. Despite this, it was an orange fluid powder with the original taste and aroma of sea squirt.
実施例 2 :ホヤの乾燥粉末の製造 (噴霧乾燥工程を経る方法) 実施例 1と同様にして得られた軟体部の凍結物をビニール袋に入れ、 流水にて 解凍した後、 マスコ口イダーを用いて破砕し (3回通し:クリアランスは 0. 0 2mmx 3回)、 ペースト状物を得た。 このペースト状物をボールミルで微細し てスラリ一状物を得た。 尚、 微細は、 メディアとして粒径が 0. 6 5 mmのジル コニァを用い、 ギャップ 0. 2mm, 回転数 2 5 0 0 r pm、 滞留時間約 2分、 出口液温 4 0°C以下の条件で 2回行った。 Example 2: Production of dried squirt powder (method via spray drying step) The frozen material of the soft part obtained in the same manner as in Example 1 was put into a plastic bag, thawed with running water, and then crushed using a massco mouth lider (three passes: clearance of 0.02 mm x 3 times). A paste was obtained. This paste was refined with a ball mill to obtain a slurry. In the case of fine particles, zirconia with a particle size of 0.65 mm was used as the media, the gap was 0.2 mm, the number of revolutions was 250 rpm, the residence time was about 2 minutes, and the outlet liquid temperature was 40 ° C or less. Performed twice under the conditions.
このスラリ一状物を噴霧乾燥することによってホヤの乾燥粉末を得た。 噴霧乾 燥機は、 チャンバ一直径 1. 0m、 コニカル部 5 0° 、 チャンバ一容積約 0. 8 m 2流体ノズルアトマイザ一、 エア一ノズル PA 1 2 0、 液体ノズル P F 6 0 1 0 0、 エア一圧力 0. 7 5 k g/cm\ 液体供給方法はチューブポンプ使 用のものを用いた。 運転条件を入口熱風温度 1 7 0°C、 出口排風温度 8 2°C、 風 量 5. 0m3Zm i nで行ったところ、 粒度が 2 7. 6ミクロン、 水分率が 4. 3 w t %のホヤの乾燥粉末が得られた(レーザ一回折法による評価)。また、運転 条件を入口熱風温度 1 5 0。C、 出口排風温度 7 0。Cヽ 風量 5. OmVm i nで 行ったところ、 粒度が 2 8. 0ミクロン、 水分率が 9. 0 w t %のホヤの乾燥粉 末力、'得られた(レーザ一回折法による評価)。いずれの粉末もホヤ臭力著しく軽減 されているにもかかわらず、 ホヤ本来の味と香りを有する橙色の流動性のある粉 末であつた。 前者のホヤの乾燥粉末の水分活性は 0. 3 0であつた。 This slurry was spray-dried to obtain a dried squirt powder. The spray dryer has a chamber diameter of 1.0m, conical section at 50 °, chamber volume of about 0.8m2 Fluid nozzle atomizer, air nozzle PA120, liquid nozzle PF600, Air pressure 0.75 kg / cm \ The liquid supply method used was a tube pump. The operating conditions inlet hot air temperature of 1 7 0 ° C, the outlet air discharge temperature 8 2 ° C, was performed by the air volume 5. 0m 3 Zm in, particle size 2 7.6 microns, the water content is 4. 3 wt% As a result, a dried powder of sea squirt was obtained (evaluation by laser diffraction method). In addition, the operating conditions were set to the inlet hot air temperature of 150. C, outlet exhaust temperature 70. When the air flow rate was 5.OmVmin, the dry powder strength of the sea squirt with a particle size of 28.0 microns and a water content of 9.0 wt% was obtained (evaluation by laser diffraction method). All of the powders were orange fluid powders with the original taste and aroma of sea squirt, although the smelt odor was significantly reduced. The water activity of the dried sea squirt powder was 0.30.
実施例 3 :ホヤの乾燥粉末の製造 (減圧乾燥工程を経る方法) Example 3: Manufacture of dried squirt powder (method through reduced pressure drying step)
実施例 1と同様にして得られた軟体部の凍結物をビニーノレ袋に入れ、 流水にて 解凍した後、 マスコ口イダ一を用いて破砕し (7回通し:クリアランスは 3mm x 2回、 l mmx 2回、 0. 0 2 mm x 3回)、 ペースト状物を得た。 得られた ペースト状物の水分は 8 5. 2 %であった。  The frozen product of the soft part obtained in the same manner as in Example 1 was put into a binnino bag, thawed with running water, and then crushed using a Masco mouth Ida (7 passes: clearance 3 mm x 2 times, l mm x 2 times, 0.02 mm x 3 times) to obtain a paste. The water content of the obtained paste was 85.2%.
このペースト状物をアルマイト製プレートにできるだけ薄く延ばした。 これを 減圧乾燥機に入れて、圧力 8. 0 x l 04P a〜9. 3 x 1 04 P a、乾燥温度 4 0°Cの条件で 1 9時間乾燥を行い、 乾燥ホヤを得た。 得られた乾燥ホヤは、 水分 が 2 2. 1 %の濃い橙色で、 高い風味を有していたが臭みはなかった。 The paste was spread as thinly as possible on an alumite plate. Put it in vacuum dryer, the pressure 8. 0 xl 0 4 P a~9. 3 x 1 0 4 P a, for 1 9 hrs dried at a drying temperature 4 0 ° C, to obtain a dried Hoya . The obtained dried sea squirt was a deep orange with a water content of 22.1%, had a high flavor, but had no odor.
この乾燥ホヤを 0. 5ミリメッシュの粉砕機で粉砕し、 約 3 0ミクロンの乾燥 粉末を得た。得られた粉末は、水分活性が 0. 24の濃 、橙色で、流動性に優れ、 高い風味を有していたが臭みはなかった。 This dried squirt was pulverized with a 0.5 mm mesh pulverizer to obtain a dry powder of about 30 microns. The resulting powder is dark, orange with a water activity of 0.24, excellent in fluidity, It had a high flavor but no odor.
実施例 4 :ホヤの乾燥粉末入りうどんの製造  Example 4: Production of udon with dried powder of sea squirt
薄力粉 7 k gをミキサ一に入れた後、 実施例 1で得られたホヤの乾燥粉末 7 0 gを加え、 攪拌して均一混合した。 次に、 水 2 . 1 k gに食塩を加えて調製した 塩分濃度 1 0度の食塩水をミキサー内に徐々に添加した後、 約 2 0分攪拌した。 熟成を 2時間行った後、 成形し、 幅 1 6 mmの力ッ夕一で切断して 3 0 c mの 長さに切りそろえてホヤの乾燥粉末入りうどんを得た。  After 7 kg of the soft flour was put into the mixer, 70 g of the dried squirt powder of the sea squirt obtained in Example 1 was added, and the mixture was stirred and uniformly mixed. Next, a salt solution having a salt concentration of 10 ° C prepared by adding salt to 2.1 kg of water was gradually added into the mixer, and the mixture was stirred for about 20 minutes. After aging for 2 hours, the mixture was molded, cut with a brush having a width of 16 mm, and cut into a length of 30 cm to obtain a udon noodles containing dried squirt powder.
上記の方法にて得たホヤの乾燥粉末入りうどんとホヤの乾燥粉末を入れない以 外は同じ方法で製造したうどんの官能検査を 1 0人のパネラーで行った。 結果を 表 1に示す。 表 1  Sensory tests were carried out by 10 panelists on the udon noodles produced by the same method except that the dried sea squirt noodles obtained by the above method and the dried sea squirt powder were not added. Table 1 shows the results. table 1
Figure imgf000012_0001
Figure imgf000012_0001
A:ホヤの乾燥粉末入りうどん B :ホヤの乾燥粉末なしうどん パネル評価: うどん以外の臭気を強く感じる · · · 3点  A: Udon with dried sea squirt powder B: Udon without dried squirt powder Panel evaluation: Strong odor other than udon · · · 3 points
うどん以外の臭気をわずかに感じる · · · 2点  Slightly smells other than udon · · · 2 points
うどん以外の臭気を感じない · · · 1点 表 1から明らかなように、 ホヤの乾燥粉末入りうどんについて 1人がうどん以 外の臭気をわずかに感じたカ^臭気の原因をホヤと断定することはできなかった。 得られたうどんを茹でてつけ麵として食したところ、 弾力性に富む歯ごたえが あった。 また、 麵つゆのからまりがよく、 非常に美味であった。  No smell other than udon 1 point As is clear from Table 1, as for the udon noodles containing dried squirt powder, one person felt a slight odor other than noodles. I couldn't do that. When the resulting udon was boiled and eaten as a soup, it had a very chewy texture. Also, the pork soup was very tasty and very delicious.
更に、 ホヤの乾燥粉末なしうどんは、 時間とともにべ夕ベタ感を呈し、 製造後 1 0日が品質保持の限界であつたが、 ホヤの乾燥粉末入りうどんは、 1 0日を経 過しても製造直後と何ら変わるところはなかった。  In addition, the sea urchin without dried squirt powder showed a sticky feeling over time, and the quality retention was limited to 10 days after production, but the noodles containing dried squirt powder after 10 days had passed. There was no difference between immediately after production.
実施例 5 :ホヤの乾燥粉末入り餅の製造 Example 5: Production of mochi with dried sea squirt powder
餅米 2 . 8 k gを 6時間水に浸した後、 3 0分程度水切りをした。 電気餅つき 機に水 600 c cを入れた後、 上記の餅米を入れ、 更に実施例 1で得られたホヤ の乾燥粉末 20 gを加え、 軽く混ぜてから電気餅つき機のマニュアルに従ってホ ャの乾燥粉末入り餅を製造した。 After soaking 2.8 kg of rice cake in water for 6 hours, the rice was drained for about 30 minutes. With electric mochi After putting 600 cc of water into the machine, add the rice cake described above, further add 20 g of the dried sea squirt powder obtained in Example 1, mix gently, and dry the sea squirt powder according to the manual of the electric rice cake maker. A rice cake was prepared.
得られた餅は実施例 2のうどんと同様、 弾力性に富む歯ごたえがあった。 ホヤの乾燥粉末入り餅と、 ホヤの乾燥粉末を入れな 、以外は同じ方法で製造し た餅を 3 cm角に切り、 熱湯に 5分間入れたところ、 ホヤの乾燥粉末を入れてい ない餅は、 各片とも膨張するとともに、 箸で持ち上げることができない程の型く ずれを起こし、 熱湯もかなりの程度白濁したが、 ホヤの乾燥粉末入り餅は、 膨張 の程度はわずかで、 箸で持ち上げることもでき、 熱湯はわずかに白濁した程度で あつた o  The obtained mochi had a chewy texture rich in elasticity as in the udon of Example 2. The mochi made by the same method except that the dried sea squirt powder and the sea squirt powder were not cut, cut into 3 cm squares and placed in boiling water for 5 minutes. However, each piece expands and loses its shape so that it cannot be lifted with chopsticks, and the boiling water becomes considerably cloudy. Hot water was slightly cloudy o
ホヤの乾燥粉末を入れない以外は同じ方法で製造した餅を屋内に放置しておい たところ、製造 10日後に青かび力発生したのに対し、ホヤの乾燥粉末入り餅は、 The mochi produced by the same method except that the dried squirt powder was not used was left indoors, and 10 days after the production, blue mold was generated.
20日を経過しても青かびの発生はなかった。 No blue mold had developed after 20 days.
実施例 6 :ホヤの乾燥粉末抽出物の S 0 D様活性試験 (その 1 ) Example 6: S0D-like activity test of dried powdered extract of sea squirt (part 1)
実施例 1で得られたホヤの乾燥粉末 500mgを 10m lのジメチルスルホキ シド (DMSO) に溶解し、 1昼夜攪拌した。 その後、 300 r pm、 10分間 遠心分離して不溶性部分を除去し、 上清をサンプルとして、 表 2に示す組成の試 料を作成した。 表 2  500 mg of the dried sea squirt powder obtained in Example 1 was dissolved in 10 ml of dimethyl sulfoxide (DMSO) and stirred for one day. Thereafter, the mixture was centrifuged at 300 rpm for 10 minutes to remove insoluble portions, and a sample having the composition shown in Table 2 was prepared using the supernatant as a sample. Table 2
ImM ヒポキサンチン溶液 50 β \ ImM hypoxanthine solution 50 β \
0. 4M 5, 5 ジメチル— 1 -ピロリンー 1 ォキシド (DMPO) 50 β 1 リン酸緩衝化生理食塩水 ( P B S ) 80 β \ サンプル 20 μ. \0.4M 5,5 dimethyl-1-pyrroline-1-oxide (DMPO) 50 β 1 phosphate buffered saline (PBS) 80 β \ sample 20 μ. \
0. 1 U/m 1 キサンチンォキシダーゼ 20 β I 上記の試料を用い、 稲波らの文献 ( Inanami, 0. etal. ; AMERICAN JOURNAL OF VETERINARY RESEARCH, Vol 60, No.4, April 1999, 452-457 ) に記載の方法に従 つて、電子スピン共鳴装置(ESR)によるサンプルの SOD様活性評価試験(活 性酸素消去能評価試験) を行った。 この方法は、 キサンチンォキシダ一ゼの働き で生成する活性酸素(スーパ一ォキシド) を DMPO (ラジカル捕捉剤) で捕捉 し、 これを ESRで定量する方法であり、 競合反応によるサンプノレの活性酸素消 去能を評価するものである。 サンプノレの代わりに DMSOを 20〃 1用いて作成 した試料をコントロールとし、 コントロールの S 0 D様活性との相対値としてサ ンプルの S 0 D様活性を求めた。 0.1 U / m 1 Xanthine oxidase 20 β I Using the above sample, Inana et al. (Inanami, 0. etal .; AMERICAN JOURNAL OF VETERINARY RESEARCH, Vol. According to the method described in), the sample was subjected to an SOD-like activity evaluation test (active oxygen scavenging ability evaluation test) using an electron spin resonance apparatus (ESR). This is how xanthine oxide works. In this method, DMPO (radical scavenger) is used to capture the active oxygen (superoxide) generated in the above process, and this is quantified by ESR. This is to evaluate the ability of Sampnole to eliminate active oxygen by a competitive reaction. A sample prepared using 20〃1 of DMSO instead of Sampnole was used as a control, and the S0D-like activity of the sample was determined as a relative value to the S0D-like activity of the control.
試験の結果、第 1図から明らかなように、ホヤの乾燥粉末の DM SO抽出物は、 ビタミン A (レチノ一ノレ: RA) 2 0 μ g/m 1よりも高い S 0 D様活性を有し ていた。  As a result of the test, as is clear from FIG. 1, the DMSO extract of the dried sea squirt powder had a S0D-like activity higher than that of vitamin A (retino-monophosphate: RA) 20 μg / m1. Was.
実施例 7 :ホヤの乾燥粉末抽出物の SOD様活性試験 (その 2) Example 7: SOD-like activity test of dried powdered extract of sea squirt (part 2)
実施例 6において用いた DM S 0の代わりに P B Sを用いた以外は実施例 6と 同様にしてホヤの乾燥粉末の P B S抽出物の SOD様活性を評価したところ、 第 1図から明らかなように、 優れた活性を有していた。  The SOD-like activity of the PBS extract of the dried sea squirt powder was evaluated in the same manner as in Example 6 except that PBS was used in place of DM S0 used in Example 6. Had excellent activity.
比較例 1 : Comparative Example 1:
実施例 1と同様にして水洗いした軟体部を、常温常湿条件下で乾燥してみたが、 乾燥に長時間を要し、 ホヤ臭がかなり強くなつた。 また、 時間が経過するにつれ て、 汚れが無視できなくなった。 低温 (2°C〜8°C) 条件下での乾燥や塩蔵した 軟体部を用いての乾燥も試みたが、 結果は同じで、 乾燥に長時間を要し、 ホヤ臭 がかなり強くなつた。 よって、 これらの方法ではホヤの乾燥粉末を製造すること はできなかった。 産業上の利用可能性  The soft body portion washed with water in the same manner as in Example 1 was dried under normal temperature and normal humidity conditions, but it took a long time to dry, and the smell of sea squirt became considerably strong. Also, as time passed, dirt could no longer be ignored. Drying under low temperature conditions (2 ° C to 8 ° C) and drying using salted soft parts were also attempted, but the results were the same, it took a long time to dry, and the smell of sea squirt became quite strong. . Therefore, it was not possible to produce a dried powder of ascidian by these methods. Industrial applicability
本発明のホヤの乾燥粉末は、 これまでホヤの好き嫌いの原因であったホヤ臭が 軽減されているにもかかわらず、 ホヤ本来の味と香りを有しており、 しかも保存 安定性がよい。 よって、 非常に汎用性に優れ、 栄養価値の高い食品素材として各 種加工食品に添加混入したり、 それ自体を調味料として用いたりすることができ る。 また、 食品添加用の弾力増強剤や型くずれ防止剤、 抗菌剤、 SOD様活性剤 などとしても利用価値が高い。  The dried sea squirt powder of the present invention has the original taste and scent of the sea squirt, despite the reduced squirt odor which has been a cause of dislike of the sea squirt, and has good storage stability. Therefore, it can be added to various processed foods as a food material with excellent versatility and high nutritional value, or used as a seasoning. It is also highly useful as an elasticity enhancer for food additives, an anti-deformation agent, an antibacterial agent, and an SOD-like activator.

Claims

請求の範囲 The scope of the claims
1 . ホヤの外皮 (被嚢) を除去した軟体部を原料にして製造されたホヤの乾燥粉 末。 1. A dried powder of sea squirt manufactured from the soft body from which the outer skin (capsule) of the sea squirt has been removed.
2 . ホヤの乾燥粉末を主成分とする食品素材。  2. Food material mainly composed of dried squirt powder.
3 . ホヤの乾燥粉末を含む加工食品。  3. Processed food containing dried sea squirt powder.
4 . 麵類である請求の範囲第 3項記載の加工食品。  4. The processed food according to claim 3, which is a class.
5 . 餅である請求の範囲第 3項記載の加工食品。  5. The processed food according to claim 3, which is a mochi.
6 . ホヤの乾燥粉末を含む調味料。  6. Seasoning containing dried sea squirt powder.
7 . ホヤの乾燥粉末を有効成分とする食品添加用弾力増強剤。  7. An elasticity enhancer for food additives containing dried sea squirt powder as an active ingredient.
8 . ホヤの乾燥粉末を有効成分とする食品添加用型くずれ防止剤。  8. An anti-collapse agent for food additives containing dried sea squirt powder as an active ingredient.
9 . ホヤの乾燥粉末を有効成分とする抗菌剤。  9. An antibacterial agent containing dried squirt powder as an active ingredient.
1 0 .ホヤの乾燥粉末を有効成分とするスーパ一ォキシドジスムタ一ゼ様活性剤。 10. Superoxide dismutase-like activator containing dried squirt powder as an active ingredient.
1 1 . ホヤの外皮 (被嚢) を除去した軟体部を真空凍結乾燥した後、 粉砕するこ とを特徴とするホヤの乾燥粉末の製造方法。 1 1. A method for producing dried sea squirt powder, comprising vacuum-freeze-drying the soft body from which the outer skin (capsule) of the sea squirt has been removed and then pulverizing it.
1 2 . ホヤの外皮 (被嚢) を除去した軟体部をスラリー状物とし、 これを噴霧乾 燥することを特徴とするホヤの乾燥粉末の製造方法。  1 2. A method for producing a dried sea squirt powder, comprising forming a soft body from which the outer skin (capsule) of the sea squirt has been removed into a slurry, and spray-drying the slurry.
1 3 . ホヤの外皮 (被嚢) を除去した軟体部をべ一スト状物とし、 これを減圧乾 燥した後、 粉砕することを特徴とするホヤの乾燥粉末の製造方法。  13 3. A method for producing a dried sea squirt powder, comprising: forming a soft body from which the outer skin (capsule) of the sea squirt has been removed, drying it under reduced pressure, and crushing it.
1 4 . ホヤの外皮 (被嚢) を除去した軟体部を真空凍結乾燥することを特徴とす るホヤ臭の軽減方法。  1 4. A method for reducing the odor of sea squirts, characterized by vacuum-freeze-drying the soft part from which the outer skin (capsule) of the squirt is removed.
1 5 . ホヤの外皮 (被嚢) を除去した軟体部をスラリー状物とし、 これを噴霧乾 燥することを特徴とするホャ臭の軽減方法。  15 5. A method for reducing the smell of sea squirt, characterized by removing the outer skin (capsule) of the sea squirt into a slurry and spray-drying the slurry.
1 6 . ホヤの外皮 (被嚢) を除去した軟体部を真空凍結乾燥して得られた乾燥ホ ャ。  1 6. A dry squirt obtained by vacuum freeze-drying the soft body from which the outer skin (capsule) of the squirt has been removed.
1 7 . ホヤの外皮 (被囊) を除去した軟体部をペースト状物とし、 これを減圧乾 燥して得られた乾燥ホヤ。  17 7. A dried sea squirt obtained by removing the outer skin (coating) of the sea squirt into a paste and drying it under reduced pressure.
PCT/JP2000/000403 1999-01-27 2000-01-27 Dry ascidian powder, utilization thereof, process for producing the same, method for relieving ascidian smell and dry ascidian WO2000044246A1 (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005120526A1 (en) * 2004-06-11 2005-12-22 Combi Corporation Composition for inhibiting the progress of muscular dystrophy
WO2006008890A1 (en) * 2004-06-11 2006-01-26 Combi Corporation Muscle strengthening composition
KR100684498B1 (en) 2005-01-13 2007-02-22 마산시 Method for preservation of Styela spp.
JP2008142071A (en) * 2006-12-11 2008-06-26 Shizuko Niwa Sea squirt processed goods and producing method therefor
JP2009544331A (en) * 2006-07-26 2009-12-17 ボヤヴァ・リパブリック・エルエルシー Cold impregnation method for strengthening corn and / or soybean
JP2012005425A (en) * 2010-06-25 2012-01-12 Kansai Univ Method for producing sake
JP2016005450A (en) * 2014-05-30 2016-01-14 株式会社石渡商店 Manufacturing method of seasoning sauce of shellfish or sea squirt and seasoning sauce of shellfish or sea squirt manufactured by the method

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5886061A (en) * 1981-11-17 1983-05-23 Katsuo Suzuki Preparation for food of delicate flavor from ascidian

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5886061A (en) * 1981-11-17 1983-05-23 Katsuo Suzuki Preparation for food of delicate flavor from ascidian

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005120526A1 (en) * 2004-06-11 2005-12-22 Combi Corporation Composition for inhibiting the progress of muscular dystrophy
WO2006008890A1 (en) * 2004-06-11 2006-01-26 Combi Corporation Muscle strengthening composition
JPWO2005120526A1 (en) * 2004-06-11 2008-04-03 コンビ株式会社 Muscular dystrophy progression inhibitory composition
JPWO2006008890A1 (en) * 2004-06-11 2008-05-01 コンビ株式会社 Muscle building composition
KR100684498B1 (en) 2005-01-13 2007-02-22 마산시 Method for preservation of Styela spp.
JP2009544331A (en) * 2006-07-26 2009-12-17 ボヤヴァ・リパブリック・エルエルシー Cold impregnation method for strengthening corn and / or soybean
JP2008142071A (en) * 2006-12-11 2008-06-26 Shizuko Niwa Sea squirt processed goods and producing method therefor
JP2012005425A (en) * 2010-06-25 2012-01-12 Kansai Univ Method for producing sake
JP2016005450A (en) * 2014-05-30 2016-01-14 株式会社石渡商店 Manufacturing method of seasoning sauce of shellfish or sea squirt and seasoning sauce of shellfish or sea squirt manufactured by the method

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