Classifications

• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
  • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
  • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
  • A01N43/22—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom rings with more than six members
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
  • A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides

Definitions

• the present invention relates to new active substance combinations which consist of the known spinosad and a further known, insecticidally active substance and a further known, fungicidally active substance and are very well suited for controlling animal pests and fungi.
• Metominostrobin (IIj), Capropamid (Ilk) and Diclocymet (III), Tricyclazol (Um), Oryzemate (Iln) and
• insecticidal and fungicidal activity of the combinations of three active compounds according to the invention is considerably higher than the effects of the individual components. So there is an unforeseeable, real synergistic effect and not just an addition.
• Spinosad is essentially a mixture of Spinosyn A and Spinosyn D (see Pesticide Manual, British Crop Protection Council, 11 * Ed., 1997, page 1272 and Dow Elanco trade magazine Down to Earth, Vol. 52, No . 1, 1997 and the literature cited therein).
• Furametpyr (Ile) has the following structure
• Diclocymet (III) has the following structure and is known from JP 07206608.
• Tricyclazole (Um) has the following structure
• Oryzemate (Iln) has the following structure
• the active ingredient of the formula (purple) is the l - [(6-chloro-3-pyridinyl) methyl] -N-nitro-2-imidazolidinimine, which is known as an insecticide under the name imidacloprid (cf. pesticide Manual, 11 * Ed. (1997, page 706).
• the active ingredient of the formula (Illb) is known from EP-A-0 428 941.
• the active ingredient of the formula (IIIc) is known from US Pat. 4,849,432.
• the active ingredient of the formula (IIld) is known from EP-A 0 580 553.
• the active ingredient of the formula (IIle) is known from WO 91/4965.
• the active ingredient of the formula (Ulf) is known from EP-A 0 649 845.
• the active ingredient of the formula (Illg) is known from the Pesticide Manual cited above, page 880.
• 1 to 10 parts by weight of active compound of the formula (I) comprises 0.1 to 10 parts by weight, preferably 0.2 to 5 parts by weight, of an active compound of the formulas (Ila) to (IIj) and 0.1 to 1.5 parts by weight preferably 0.1 to 1.0 parts by weight of active ingredient of the formula (purple), (Illb) or (IIIc).
• the active substance combinations are suitable for good plant tolerance and favorable warm-blood toxicity for combating animal pests, in particular insects, arachnids and nematodes, which occur in agriculture, in forests, in the protection of stocks and materials and in the hygiene sector. They can preferably be used as pesticides. They are effective against normally sensitive and resistant species as well as against all or individual stages of development.
• the pests mentioned above include:
• Isopoda for example, Oniscus asellus, Armadillidium vulgare, Porcellio scaber.
• Diplopoda for example, Blaniulus guttulatus.
• Thysanura e.g. Lepisma saccharina.
• Orthoptera e.g. Acheta domesticus, Gryllotalpa spp., Locusta migratoria migratorioides, Melanoplus spp., Schistocerca gregaria.
• Phthiraptera e.g. Pediculus humanus corporis, Haematopinus spp., Linognathus spp., Trichodectes spp., Damalinia spp ..
• Thysanoptera e.g. Hercinothrips femoralis, Thrips tabaci, Thrips palmi, Frankliniella accidentalis.
• Trialeurodes vaporariorum Aphis gossypii, Brevicoryne brassicae, Cryptomyzus ribis, aphis fabae, aphis pomi, eriosoma lanigerum, hyalopterus arundi is, phylloxera vastatrix, pemphigus spp., macrosiphum avenae, myzus spp., phorodon humuli, rhopalosiphum padi, empoasca spp , Laodelphax striatellus, Nilaparvata lugens, Aonidiella aurantii, Aspidiotus hederae, Pseudococcus spp., Psylla spp.
• Conoderus spp. Melolontha melolontha, Amphimallon solstitialis, Costelytra zealan- dica, Lissorhoptrus oryzophilus.
• Hymenoptera From the order of the Hymenoptera, for example Diprion spp., Hoplocampa spp., Lasius spp., Monomorium pharaonis, Vespa spp. From the order of the Diptera, for example Aedes spp., Anopheles spp., Culex spp., Drosophila melanogaster, Musca spp., Fannia spp., Calliphora erythrocephala, Lucilia spp., Chrysomyia spp., Cuterebra spp., Gastrophilus spp., Hyppobosca spp., Stomoxys spp., Oestrus spp., Hypoderma spp., Tabanus spp., Tannia spp., Bibio hortulanus, Os- cinella frit, Phorbia spp., Pegomyia hyoscyami, Ceratiti
• Plant-parasitic nematodes include e.g. Pratylenchus spp., Radopholus similis, Ditylenchus dipsaci, Tylenchulus semipenetrans, Heterodera spp., Globodera spp., Meloidogyne spp., Aphelenchoides spp., Longidorus spp., Xiphinema spp., Trichodorus spp ..
• the active compound combinations according to the invention also have very good fungicidal properties and can be used to control phytopathogenic fungi, such as Plasmodiophoromycetes, Oomycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes, Deuteromycetes, etc.
• the active compound combinations according to the invention are particularly suitable for combating Pyricularia, Pellicularia, Cochliobolus, Gibberella, Rhizoctonia and Fusarium spp.
• the active compound combinations according to the invention are particularly notable for very good activity against pests and fungi in rice cultivation.
• the good plant tolerance of the active ingredient combinations in the concentrations necessary to combat plant diseases allows treatment of above-ground parts of plants, of propagation stock and seeds and of the soil.
• the active substance combinations according to the invention can be used for leaf application or as a mordant.
• the active ingredients can be converted into the customary formulations, such as solutions, emulsions, wettable powders, suspensions, powders, dusts, pastes, soluble powders, granules, suspension emulsion concentrates, impregnated with active ingredients
• formulations are made in a known manner, e.g. by mixing the active ingredients with extenders, that is to say liquid solvents and / or solid carriers, if appropriate using surface-active agents, that is to say
• Emulsifiers and / or dispersants and / or foaming agents Emulsifiers and / or dispersants and / or foaming agents.
• organic solvents can also be used as auxiliary solvents.
• auxiliary solvents e.g. organic solvents
• aromatics such as xylene, toluene, or alkylnaphthalenes
• chlorinated aromatics and chlorinated aliphatic hydrocarbons such as chlorobenzenes, chlorethylenes or methylene chloride
• aliphatic hydrocarbons such as cyclohexane or paraffins, e.g.
• Petroleum fractions mineral and vegetable oils, alcohols such as butanol or glycol and their ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethylformamide and dimethyl sulfoxide, and water.
• alcohols such as butanol or glycol and their ethers and esters
• ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone
• strongly polar solvents such as dimethylformamide and dimethyl sulfoxide, and water.
• Possible solid carriers are: for example ammonium salts and natural rock powders such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth and synthetic rock powders such as highly disperse silica, aluminum oxide and silicates
• Solid carrier materials for granules are: for example broken and fractionated natural rocks such as calcite, marble, pumice, sepiolite, dolomite as well as synthetic granules from inorganic and organic flours as well as granules from organic material such as sawdust, coconut shells, corn cobs and tobacco stalks;
• Possible emulsifying and or foam-generating agents are: for example nonionic and anionic emulsifiers, such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, for example alkylaryl polyglycol ethers, alkyl sulfonates, alkyl sulfates, aryl sul
• Adhesives such as carboxymethyl cellulose, natural and synthetic powdery, granular or latex-shaped polymers, such as gum arabic, polyvinyl alcohol, polyvinyl acetate, and natural phospholipids such as cephalins and lecithins and synthetic phospholipids can be used in the formulations.
• Mineral and vegetable oils can also be used as additives.
• Dyes such as inorganic pigments, e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc can be used.
• the formulations generally contain between 0.1 and 95% by weight of active ingredients, preferably between 0.5 and 90%.
• the active substance combinations can be used as such, in the form of their formulations or the use forms prepared therefrom, such as ready-to-use solutions, emulsifiable concentrates, emulsions, suspensions, wettable powders, soluble powders and granules. They are used in the customary manner, for example by pouring, spraying, atomizing, scattering, spreading, dry pickling, wet pickling, wet pickling, slurry pickling or incrusting. According to the invention, all plants and parts of plants can be treated. Plants are understood here to mean all plants and plant populations, such as desired and unwanted wild plants or crop plants (including naturally occurring crop plants).
• Crop plants can be plants which can be obtained by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or combinations of these methods, including the transgenic plants and including the plant cultivars which can or cannot be protected by plant breeders' rights.
• Plant parts are to be understood to mean all above-ground and underground parts and organs of the plants, such as sprout, leaf, flower and root, examples being leaves, needles, stems, stems, flowers, fruiting bodies, fruits and seeds as well as roots, tubers and rhizomes.
• the plant parts also include crops and vegetative and generative propagation material, for example cuttings, tubers, rhizomes, offshoots and seeds.
• the treatment of the plants and parts of plants according to the invention with the active substances takes place directly or by acting on their surroundings, living space or storage space according to the usual treatment methods, e.g. by dipping, spraying, vaporizing, atomizing, scattering, spreading and, in the case of propagation material, in particular seeds, furthermore by single- or multilayer coating.
• the active compound concentrations in the use forms can be varied within a substantial range. They are generally between 1 and 0.0001% by weight, preferably between 0.5 and 0.001%.
• active compound 0.001 to 50 g per kilogram of seed, preferably 0.01 to 10 g, are generally required.
• active ingredient concentrations of 0.00001 to 0.1% by weight, preferably 0.0001 to 0.02% by weight, are required at the site of action.
• the good insecticidal activity of the active compound combinations according to the invention can be seen from the examples below. While the individual active ingredients and also the combination of two active ingredients each have weaknesses in the insecticidal action, the combination of three active ingredients shows an action that goes beyond a simple combination of actions with a synergistic effect.
• Insecticides always have a synergistic effect if the insecticidal effect of the active ingredient combinations is greater than the sum of the effects of the individually applied active ingredients.
• Fungicides always have a synergistic effect if the fungicidal activity of the active ingredient combinations is greater than the sum of the effects of the individually applied active ingredients.
• Test insect Diabrotica balteata - larvae in the soil
• Emulsifier 1 part by weight of alkylaryl polyglycol ether
• Amount of emulsifier and dilute the concentrate with water to the desired concentration is practically irrelevant, the only decisive factor is the amount of active ingredient per unit volume of soil, which is given in ppm (mg / 1).
• the bottom is filled into 0.5 liter pots and these are left to stand at 20 ° C.

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• Life Sciences & Earth Sciences (AREA)
• Agronomy & Crop Science (AREA)
• Pest Control & Pesticides (AREA)
• Plant Pathology (AREA)
• Health & Medical Sciences (AREA)
• Engineering & Computer Science (AREA)
• Dentistry (AREA)
• General Health & Medical Sciences (AREA)
• Wood Science & Technology (AREA)
• Zoology (AREA)
• Environmental Sciences (AREA)
• Agricultural Chemicals And Associated Chemicals (AREA)

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• 1998
  • 1998-12-16 DE DE19857967A patent/DE19857967A1/de not_active Withdrawn
• 1999
  • 1999-12-03 JP JP2000587610A patent/JP4677101B2/ja not_active Expired - Lifetime
  • 1999-12-03 WO PCT/EP1999/009449 patent/WO2000035282A1/de active IP Right Grant
  • 1999-12-03 KR KR1020017006428A patent/KR100612137B1/ko not_active Expired - Lifetime
  • 1999-12-03 AU AU19698/00A patent/AU1969800A/en not_active Abandoned

Patent Citations (6)

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