WO2000035282A1 - Combination of active agents - Google Patents

Combination of active agents Download PDF

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Publication number
WO2000035282A1
WO2000035282A1 PCT/EP1999/009449 EP9909449W WO0035282A1 WO 2000035282 A1 WO2000035282 A1 WO 2000035282A1 EP 9909449 W EP9909449 W EP 9909449W WO 0035282 A1 WO0035282 A1 WO 0035282A1
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Prior art keywords
spp
active compound
active
combinations according
active ingredient
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PCT/EP1999/009449
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German (de)
French (fr)
Inventor
Wolfram Andersch
Ulrike Wachendorff-Neumann
Gerd Hänssler
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Bayer Aktiengesellschaft
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Priority to JP2000587610A priority Critical patent/JP4677101B2/en
Priority to AU19698/00A priority patent/AU1969800A/en
Publication of WO2000035282A1 publication Critical patent/WO2000035282A1/en

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/22—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom rings with more than six members
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides

Definitions

  • the present invention relates to new active substance combinations which consist of the known spinosad and a further known, insecticidally active substance and a further known, fungicidally active substance and are very well suited for controlling animal pests and fungi.
  • Metominostrobin (IIj), Capropamid (Ilk) and Diclocymet (III), Tricyclazol (Um), Oryzemate (Iln) and
  • insecticidal and fungicidal activity of the combinations of three active compounds according to the invention is considerably higher than the effects of the individual components. So there is an unforeseeable, real synergistic effect and not just an addition.
  • Spinosad is essentially a mixture of Spinosyn A and Spinosyn D (see Pesticide Manual, British Crop Protection Council, 11 * Ed., 1997, page 1272 and Dow Elanco trade magazine Down to Earth, Vol. 52, No . 1, 1997 and the literature cited therein).
  • Furametpyr (Ile) has the following structure
  • Diclocymet (III) has the following structure and is known from JP 07206608.
  • Tricyclazole (Um) has the following structure
  • Oryzemate (Iln) has the following structure
  • the active ingredient of the formula (purple) is the l - [(6-chloro-3-pyridinyl) methyl] -N-nitro-2-imidazolidinimine, which is known as an insecticide under the name imidacloprid (cf. pesticide Manual, 11 * Ed. (1997, page 706).
  • the active ingredient of the formula (Illb) is known from EP-A-0 428 941.
  • the active ingredient of the formula (IIIc) is known from US Pat. 4,849,432.
  • the active ingredient of the formula (IIld) is known from EP-A 0 580 553.
  • the active ingredient of the formula (IIle) is known from WO 91/4965.
  • the active ingredient of the formula (Ulf) is known from EP-A 0 649 845.
  • the active ingredient of the formula (Illg) is known from the Pesticide Manual cited above, page 880.
  • 1 to 10 parts by weight of active compound of the formula (I) comprises 0.1 to 10 parts by weight, preferably 0.2 to 5 parts by weight, of an active compound of the formulas (Ila) to (IIj) and 0.1 to 1.5 parts by weight preferably 0.1 to 1.0 parts by weight of active ingredient of the formula (purple), (Illb) or (IIIc).
  • the active substance combinations are suitable for good plant tolerance and favorable warm-blood toxicity for combating animal pests, in particular insects, arachnids and nematodes, which occur in agriculture, in forests, in the protection of stocks and materials and in the hygiene sector. They can preferably be used as pesticides. They are effective against normally sensitive and resistant species as well as against all or individual stages of development.
  • the pests mentioned above include:
  • Isopoda for example, Oniscus asellus, Armadillidium vulgare, Porcellio scaber.
  • Diplopoda for example, Blaniulus guttulatus.
  • Thysanura e.g. Lepisma saccharina.
  • Orthoptera e.g. Acheta domesticus, Gryllotalpa spp., Locusta migratoria migratorioides, Melanoplus spp., Schistocerca gregaria.
  • Phthiraptera e.g. Pediculus humanus corporis, Haematopinus spp., Linognathus spp., Trichodectes spp., Damalinia spp ..
  • Thysanoptera e.g. Hercinothrips femoralis, Thrips tabaci, Thrips palmi, Frankliniella accidentalis.
  • Trialeurodes vaporariorum Aphis gossypii, Brevicoryne brassicae, Cryptomyzus ribis, aphis fabae, aphis pomi, eriosoma lanigerum, hyalopterus arundi is, phylloxera vastatrix, pemphigus spp., macrosiphum avenae, myzus spp., phorodon humuli, rhopalosiphum padi, empoasca spp , Laodelphax striatellus, Nilaparvata lugens, Aonidiella aurantii, Aspidiotus hederae, Pseudococcus spp., Psylla spp.
  • Conoderus spp. Melolontha melolontha, Amphimallon solstitialis, Costelytra zealan- dica, Lissorhoptrus oryzophilus.
  • Hymenoptera From the order of the Hymenoptera, for example Diprion spp., Hoplocampa spp., Lasius spp., Monomorium pharaonis, Vespa spp. From the order of the Diptera, for example Aedes spp., Anopheles spp., Culex spp., Drosophila melanogaster, Musca spp., Fannia spp., Calliphora erythrocephala, Lucilia spp., Chrysomyia spp., Cuterebra spp., Gastrophilus spp., Hyppobosca spp., Stomoxys spp., Oestrus spp., Hypoderma spp., Tabanus spp., Tannia spp., Bibio hortulanus, Os- cinella frit, Phorbia spp., Pegomyia hyoscyami, Ceratiti
  • Plant-parasitic nematodes include e.g. Pratylenchus spp., Radopholus similis, Ditylenchus dipsaci, Tylenchulus semipenetrans, Heterodera spp., Globodera spp., Meloidogyne spp., Aphelenchoides spp., Longidorus spp., Xiphinema spp., Trichodorus spp ..
  • the active compound combinations according to the invention also have very good fungicidal properties and can be used to control phytopathogenic fungi, such as Plasmodiophoromycetes, Oomycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes, Deuteromycetes, etc.
  • the active compound combinations according to the invention are particularly suitable for combating Pyricularia, Pellicularia, Cochliobolus, Gibberella, Rhizoctonia and Fusarium spp.
  • the active compound combinations according to the invention are particularly notable for very good activity against pests and fungi in rice cultivation.
  • the good plant tolerance of the active ingredient combinations in the concentrations necessary to combat plant diseases allows treatment of above-ground parts of plants, of propagation stock and seeds and of the soil.
  • the active substance combinations according to the invention can be used for leaf application or as a mordant.
  • the active ingredients can be converted into the customary formulations, such as solutions, emulsions, wettable powders, suspensions, powders, dusts, pastes, soluble powders, granules, suspension emulsion concentrates, impregnated with active ingredients
  • formulations are made in a known manner, e.g. by mixing the active ingredients with extenders, that is to say liquid solvents and / or solid carriers, if appropriate using surface-active agents, that is to say
  • Emulsifiers and / or dispersants and / or foaming agents Emulsifiers and / or dispersants and / or foaming agents.
  • organic solvents can also be used as auxiliary solvents.
  • auxiliary solvents e.g. organic solvents
  • aromatics such as xylene, toluene, or alkylnaphthalenes
  • chlorinated aromatics and chlorinated aliphatic hydrocarbons such as chlorobenzenes, chlorethylenes or methylene chloride
  • aliphatic hydrocarbons such as cyclohexane or paraffins, e.g.
  • Petroleum fractions mineral and vegetable oils, alcohols such as butanol or glycol and their ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethylformamide and dimethyl sulfoxide, and water.
  • alcohols such as butanol or glycol and their ethers and esters
  • ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone
  • strongly polar solvents such as dimethylformamide and dimethyl sulfoxide, and water.
  • Possible solid carriers are: for example ammonium salts and natural rock powders such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth and synthetic rock powders such as highly disperse silica, aluminum oxide and silicates
  • Solid carrier materials for granules are: for example broken and fractionated natural rocks such as calcite, marble, pumice, sepiolite, dolomite as well as synthetic granules from inorganic and organic flours as well as granules from organic material such as sawdust, coconut shells, corn cobs and tobacco stalks;
  • Possible emulsifying and or foam-generating agents are: for example nonionic and anionic emulsifiers, such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, for example alkylaryl polyglycol ethers, alkyl sulfonates, alkyl sulfates, aryl sul
  • Adhesives such as carboxymethyl cellulose, natural and synthetic powdery, granular or latex-shaped polymers, such as gum arabic, polyvinyl alcohol, polyvinyl acetate, and natural phospholipids such as cephalins and lecithins and synthetic phospholipids can be used in the formulations.
  • Mineral and vegetable oils can also be used as additives.
  • Dyes such as inorganic pigments, e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc can be used.
  • the formulations generally contain between 0.1 and 95% by weight of active ingredients, preferably between 0.5 and 90%.
  • the active substance combinations can be used as such, in the form of their formulations or the use forms prepared therefrom, such as ready-to-use solutions, emulsifiable concentrates, emulsions, suspensions, wettable powders, soluble powders and granules. They are used in the customary manner, for example by pouring, spraying, atomizing, scattering, spreading, dry pickling, wet pickling, wet pickling, slurry pickling or incrusting. According to the invention, all plants and parts of plants can be treated. Plants are understood here to mean all plants and plant populations, such as desired and unwanted wild plants or crop plants (including naturally occurring crop plants).
  • Crop plants can be plants which can be obtained by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or combinations of these methods, including the transgenic plants and including the plant cultivars which can or cannot be protected by plant breeders' rights.
  • Plant parts are to be understood to mean all above-ground and underground parts and organs of the plants, such as sprout, leaf, flower and root, examples being leaves, needles, stems, stems, flowers, fruiting bodies, fruits and seeds as well as roots, tubers and rhizomes.
  • the plant parts also include crops and vegetative and generative propagation material, for example cuttings, tubers, rhizomes, offshoots and seeds.
  • the treatment of the plants and parts of plants according to the invention with the active substances takes place directly or by acting on their surroundings, living space or storage space according to the usual treatment methods, e.g. by dipping, spraying, vaporizing, atomizing, scattering, spreading and, in the case of propagation material, in particular seeds, furthermore by single- or multilayer coating.
  • the active compound concentrations in the use forms can be varied within a substantial range. They are generally between 1 and 0.0001% by weight, preferably between 0.5 and 0.001%.
  • active compound 0.001 to 50 g per kilogram of seed, preferably 0.01 to 10 g, are generally required.
  • active ingredient concentrations of 0.00001 to 0.1% by weight, preferably 0.0001 to 0.02% by weight, are required at the site of action.
  • the good insecticidal activity of the active compound combinations according to the invention can be seen from the examples below. While the individual active ingredients and also the combination of two active ingredients each have weaknesses in the insecticidal action, the combination of three active ingredients shows an action that goes beyond a simple combination of actions with a synergistic effect.
  • Insecticides always have a synergistic effect if the insecticidal effect of the active ingredient combinations is greater than the sum of the effects of the individually applied active ingredients.
  • Fungicides always have a synergistic effect if the fungicidal activity of the active ingredient combinations is greater than the sum of the effects of the individually applied active ingredients.
  • Test insect Diabrotica balteata - larvae in the soil
  • Emulsifier 1 part by weight of alkylaryl polyglycol ether
  • Amount of emulsifier and dilute the concentrate with water to the desired concentration is practically irrelevant, the only decisive factor is the amount of active ingredient per unit volume of soil, which is given in ppm (mg / 1).
  • the bottom is filled into 0.5 liter pots and these are left to stand at 20 ° C.

Abstract

The invention relates to novel combinations of active agents, consisting of spinosad, another compound which acts as an insecticide and another compound which acts as a fungicide. The inventive combinations of active agents have very good insecticide and fungicide properties.

Description

WirkstoffkombinationenActive ingredient combinations
Die vorliegende Erfindung betrifft neue Wirkstoffkombinationen, die aus dem be- kannten Spinosad und einem weiteren bekannten, insektizid wirksamen Stoff und einem weiteren bekannten, fungizid wirksamen Stoff bestehen und sehr gut zur Bekämpfung von tierischen Schädlingen und von Pilzen geeignet sind.The present invention relates to new active substance combinations which consist of the known spinosad and a further known, insecticidally active substance and a further known, fungicidally active substance and are very well suited for controlling animal pests and fungi.
Es ist bereits bekannt geworden, daß man Spinosyne bzw. Spinosad zur Bekämpfung von Insekten verwenden kann (WO 97/00 265, WO 93/09 126, WO 94/20 518, US-It has already become known that spinosyns or spinosad can be used to control insects (WO 97/00 265, WO 93/09 126, WO 94/20 518, US Pat.
5 362 634, US-5 202 242, US-5 670 364, US-5 227 295, DowElanco trade magazine Down to Earth, Vol. 52, No. 1, 1997; Pesticide Manual, 1 l,h Ed., 1997, Seite 1272).5,362,634, U.S. 5,202,242, U.S. 5,670,364, U.S. 5,227,295, DowElanco trade magazine Down to Earth, vol. 52, no. 1, 1997; Pesticide Manual, 1 l , ed., 1997, page 1272).
Es wurde nun gefunden, daß die neuen Wirkstoffkombinationen ausIt has now been found that the new combinations of active ingredients
A) Spinosad (I)A) Spinosad (I)
B) einer fungizid wirksamen Verbindung aus der Reihe Benomyl (Ha), Thio- phanate-methyl (Ilb), Acibenzolar (IIc), Flutolanil (Ild), Furametpyr (He), Fumoxadone (Ilf), Metalaxyl (Ilg), Mefluoxam (Ilh), Azoxystrobin (Ili) undB) a fungicidally active compound from the series benomyl (Ha), thiophanate-methyl (Ilb), acibenzolar (IIc), flutolanil (Ild), furametpyr (He), fumoxadone (Ilf), metalaxyl (Ilg), mefluoxam ( Ilh), Azoxystrobin (Ili) and
Metominostrobin (IIj), Capropamid (Ilk) und Diclocymet (III), Tricyclazol (Um), Oryzemate (Iln) undMetominostrobin (IIj), Capropamid (Ilk) and Diclocymet (III), Tricyclazol (Um), Oryzemate (Iln) and
C) einer insektizid wirksamen Verbindung aus der Reihe l-[(6-Chlor-3-pyri- dinyl)-methyl]-N-nitro-2-imidazolidinimin der FormelC) an insecticidally active compound from the series I - [(6-chloro-3-pyridinyl) methyl] -N-nitro-2-imidazolidinimine of the formula
Figure imgf000003_0001
Figure imgf000004_0001
Figure imgf000003_0001
Figure imgf000004_0001
Figure imgf000004_0002
Figure imgf000004_0002
Figure imgf000004_0003
Figure imgf000004_0003
Figure imgf000004_0004
Figure imgf000004_0004
Figure imgf000004_0005
Figure imgf000004_0005
und
Figure imgf000005_0001
and
Figure imgf000005_0001
sehr gute insektizide und fungizide Eigenschaften besitzen.have very good insecticidal and fungicidal properties.
Überraschenderweise ist die insektizide und fungizide Wirkung der erfindungsgemäßen Kombinationen aus drei Wirkstoffen wesentlich höher als die Wirkungen der einzelnen Komponenten. Es liegt also ein nicht vorhersehbarer, echter synergistischer Effekt vor und nicht nur eine Wirkungsergänzung.Surprisingly, the insecticidal and fungicidal activity of the combinations of three active compounds according to the invention is considerably higher than the effects of the individual components. So there is an unforeseeable, real synergistic effect and not just an addition.
Bei Spinosad handelt es sich im wesentlichen um ein Gemisch aus Spinosyn A und Spinosyn D (vgl. Pesticide Manual, British Crop Protection Council, 11* Ed., 1997, Seite 1272 und Dow Elanco trade magazine Down to Earth, Vol. 52, No. 1, 1997 und die darin zitierte Literatur).Spinosad is essentially a mixture of Spinosyn A and Spinosyn D (see Pesticide Manual, British Crop Protection Council, 11 * Ed., 1997, page 1272 and Dow Elanco trade magazine Down to Earth, Vol. 52, No . 1, 1997 and the literature cited therein).
Die fungizid wirksamen Verbindungen der Formeln (Ila) bis (Ild) und (Ilf) bis (IIj) sind bekannt aus dem Pesticide Manual, 11 Ed., 1997:The fungicidally active compounds of the formulas (Ila) to (Ild) and (Ilf) to (IIj) are known from the Pesticide Manual, 11 Ed., 1997:
Figure imgf000005_0002
Figure imgf000005_0002
Benomyl (Ila) Thiophanate-methyl (Ilb)Benomyl (Ila) Thiophanate-methyl (Ilb)
Figure imgf000005_0003
Figure imgf000005_0003
Acibenzolar (IIc) Flutolanil (Ild)
Figure imgf000006_0001
Acibenzolar (IIc) Flutolanil (Ild)
Figure imgf000006_0001
Fumoxadone (Ilf) Metalaxyl (Hg)Fumoxadone (Ilf) Metalaxyl (Hg)
Figure imgf000006_0002
Figure imgf000006_0002
Mefluoxam (Ilh) Azoxystrobin (Ili)Mefluoxam (Ilh) Azoxystrobin (Ili)
Figure imgf000006_0003
Figure imgf000006_0003
Metominostrobin (IIj)Metominostrobin (IIj)
Furametpyr (Ile) hat die folgende StrukturFurametpyr (Ile) has the following structure
Figure imgf000006_0004
und ist bekannt aus EP 315 502.
Figure imgf000006_0004
and is known from EP 315 502.
Capropamid (Ilk) hat die folgende Struktur
Figure imgf000007_0001
Capropamid (Ilk) has the following structure
Figure imgf000007_0001
N-(R)-[l-(4-Chlor-phenyl)-ethyl]-(lS)-2,2-dichlor-l-ethyl-3t-methyl-lr-cyclopro- pancarbonsäureamid der Formel (Ilka)N- (R) - [1- (4-chlorophenyl) ethyl] - (IS) -2,2-dichloro-l-ethyl-3t-methyl-lr-cyclopropanecarboxamide of the formula (Ilka)
Figure imgf000007_0002
Figure imgf000007_0002
undand
N-(R)-[ 1 -(4-Chlor-phenyl)-ethyl]-(l R)-2,2-dichlor- 1 -ethyl-3t-methyl- 1 r-cyclopro- pancarbonsäureamid der Formel (Ilkb)N- (R) - [1 - (4-chlorophenyl) ethyl] - (1 R) -2,2-dichloro-1-ethyl-3t-methyl-1 r-cyclopropanecarboxamide of the formula (Ilkb)
Figure imgf000007_0003
Figure imgf000007_0003
Die Verbindung der Formel (Ilk) und deren einzelne Isomere sind bekannt (vgl.The compound of the formula (IIk) and its individual isomers are known (cf.
EP-A 0 341 475).EP-A 0 341 475).
Diclocymet (III) hat die folgende Struktur
Figure imgf000008_0001
und ist bekannt aus JP 07206608.Diclocymet (III) has the following structure
Figure imgf000008_0001
and is known from JP 07206608.
Tricyclazol (Um) hat die folgende StrukturTricyclazole (Um) has the following structure
Figure imgf000008_0002
und ist bekannt aus Pesticide Manual, British Crop Protection Conucil, l lth Ed, 1997, Seite 999.
Figure imgf000008_0002
and is known from Pesticide Manual, British Crop Protection Conucil, lth Ed, 1997, page 999.
Oryzemate (Iln) hat die folgende StrukturOryzemate (Iln) has the following structure
Figure imgf000008_0003
und ist bekannt aus Pesticide Manual, British Crop Protection Conucil, l lth Ed, 1997, Seite 1239.
Figure imgf000008_0003
and is known from Pesticide Manual, British Crop Protection Conucil, lth Ed, 1997, page 1239.
Bei dem Wirkstoff der Formel (lila) handelt es sich um das l-[(6-Chlor-3-pyridinyl)- methyl]-N-nitro-2-imidazolidinimin, das unter der Bezeichnung Imidacloprid als Insektizid bekannt ist (vgl. Pesticide Manual, 11* Ed. (1997, Seite 706).The active ingredient of the formula (purple) is the l - [(6-chloro-3-pyridinyl) methyl] -N-nitro-2-imidazolidinimine, which is known as an insecticide under the name imidacloprid (cf. pesticide Manual, 11 * Ed. (1997, page 706).
Der Wirkstoff der Formel (Illb) ist bekannt aus EP- A-0 428 941. Der Wirkstoff der Formel (IIIc) ist bekannt aus U.S.-Patent No. 4,849,432.The active ingredient of the formula (Illb) is known from EP-A-0 428 941. The active ingredient of the formula (IIIc) is known from US Pat. 4,849,432.
Der Wirkstoff der Formel (Illd) ist bekannt aus EP-A 0 580 553.The active ingredient of the formula (IIld) is known from EP-A 0 580 553.
Der Wirkstoff der Formel (Ille) ist bekannt aus WO 91 /4965.The active ingredient of the formula (IIle) is known from WO 91/4965.
Der Wirkstoff der Formel (Ulf) ist bekannt aus EP-A 0 649 845.The active ingredient of the formula (Ulf) is known from EP-A 0 649 845.
Der Wirkstoff der Formel (Illg) ist bekannt aus dem oben zitierten Pesticide Manual, Seite 880.The active ingredient of the formula (Illg) is known from the Pesticide Manual cited above, page 880.
Wenn die Wirkstoffe in den erfindungsgemäßen Wirkstoffkombinationen in bestimmten Gewichtsverhältnissen vorhanden sind, zeigt sich der synergistische Effekt besonders deutlich. Jedoch können die Gewichtsverhältnisse der Wirkstoffe in den Wirkstoffkombinationen in einem relativ großen Bereich variiert werden. Im allgemeinen entfallen auf 1 Gewichtsteil an Wirkstoff der Formel (I) 0,1 bis 10 Gewichtsteile, vorzugsweise 0,2 bis 5 Gewichtsteile, an einem Wirkstoff der Formeln (Ila) bis (IIj) und 0,1 bis 1,5 Gewichtsteile, vorzugsweise 0,1 bis 1,0 Gewichtsteile an Wirkstoff der Formel (lila), (Illb) oder (IIIc).If the active compounds are present in the active compound combinations according to the invention in certain weight ratios, the synergistic effect is particularly evident. However, the weight ratios of the active ingredients in the active ingredient combinations can be varied within a relatively wide range. In general, 1 to 10 parts by weight of active compound of the formula (I) comprises 0.1 to 10 parts by weight, preferably 0.2 to 5 parts by weight, of an active compound of the formulas (Ila) to (IIj) and 0.1 to 1.5 parts by weight preferably 0.1 to 1.0 parts by weight of active ingredient of the formula (purple), (Illb) or (IIIc).
Die Wirkstoffkombinationen eignen sich bei guter Pflanzenverträglichkeit und günstiger Warmblütertoxizität zur Bekämpfung von tierischen Schädlingen, insbesondere Insekten, Spinnentieren und Nematoden, die in der Landwirtschaft, in Forsten, im Vorrats- und Materialschutz sowie auf dem Hygienesektor vorkommen. Sie können vorzugsweise als Pflanzenschutzmittel eingesetzt werden. Sie sind gegen normal sensible und resistente Arten sowie gegen alle oder einzelne Entwicklungsstadien wirksam. Zu den oben erwähnten Schädlingen gehören:The active substance combinations are suitable for good plant tolerance and favorable warm-blood toxicity for combating animal pests, in particular insects, arachnids and nematodes, which occur in agriculture, in forests, in the protection of stocks and materials and in the hygiene sector. They can preferably be used as pesticides. They are effective against normally sensitive and resistant species as well as against all or individual stages of development. The pests mentioned above include:
Aus der Ordnung der Isopoda z.B. Oniscus asellus, Armadillidium vulgäre, Porcellio scaber. Aus der Ordnung der Diplopoda z.B. Blaniulus guttulatus.From the order of the Isopoda, for example, Oniscus asellus, Armadillidium vulgare, Porcellio scaber. From the order of the Diplopoda, for example, Blaniulus guttulatus.
Aus der Ordnung der Chilopoda z.B. Geophilus carpophagus, Scutigera spp..From the order of the Chilopoda e.g. Geophilus carpophagus, Scutigera spp ..
Aus der Ordnung der Symphyla z.B. Scutigerella immaculata.From the order of the Symphyla e.g. Scutigerella immaculata.
Aus der Ordnung der Thysanura z.B. Lepisma saccharina.From the order of the Thysanura e.g. Lepisma saccharina.
Aus der Ordnung der Collembola z.B. Onychiurus armatus.From the order of the Collembola e.g. Onychiurus armatus.
Aus der Ordnung der Orthoptera z.B. Acheta domesticus, Gryllotalpa spp., Locusta migratoria migratorioides, Melanoplus spp., Schistocerca gregaria.From the order of the Orthoptera e.g. Acheta domesticus, Gryllotalpa spp., Locusta migratoria migratorioides, Melanoplus spp., Schistocerca gregaria.
Aus der Ordnung der Blattaria z.B. Blatta orientalis, Periplaneta americana, Leuco- phaea maderae, Blattella germanica.From the order of the Blattaria e.g. Blatta orientalis, Periplaneta americana, Leucophaea maderae, Blattella germanica.
Aus der Ordnung der Dermaptera z.B. Forficula auricularia.From the order of the Dermaptera e.g. Forficula auricularia.
Aus der Ordnung der Isoptera z.B. Reticulitermes spp..From the order of the Isoptera e.g. Reticulitermes spp ..
Aus der Ordnung der Phthiraptera z.B. Pediculus humanus corporis, Haematopinus spp., Linognathus spp., Trichodectes spp., Damalinia spp..From the order of the Phthiraptera e.g. Pediculus humanus corporis, Haematopinus spp., Linognathus spp., Trichodectes spp., Damalinia spp ..
Aus der Ordnung der Thysanoptera z.B. Hercinothrips femoralis, Thrips tabaci, Thrips palmi, Frankliniella accidentalis.From the order of the Thysanoptera e.g. Hercinothrips femoralis, Thrips tabaci, Thrips palmi, Frankliniella accidentalis.
Aus der Ordnung der Heteroptera z.B. Eurygaster spp., Dysdercus intermedius, Piesma quadrata, Cimex lectularius, Rhodnius prolixus, Triatoma spp.From the order of the Heteroptera e.g. Eurygaster spp., Dysdercus intermedius, Piesma quadrata, Cimex lectularius, Rhodnius prolixus, Triatoma spp.
Aus der Ordnung der Homoptera z.B. Aleurodes brassicae, Bemisia tabaci,From the order of the Homoptera e.g. Aleurodes brassicae, Bemisia tabaci,
Trialeurodes vaporariorum, Aphis gossypii, Brevicoryne brassicae, Cryptomyzus ribis, Aphis fabae, Aphis pomi, Eriosoma lanigerum, Hyalopterus arundi is, Phylloxera vastatrix, Pemphigus spp., Macrosiphum avenae, Myzus spp., Phorodon humuli, Rhopalosiphum padi, Empoasca spp., Euscelis bilobatus, Nephotettix cincticeps, Lecanium corni, Saissetia oleae, Laodelphax striatellus, Nilaparvata lugens, Aonidiella aurantii, Aspidiotus hederae, Pseudococcus spp., Psylla spp.Trialeurodes vaporariorum, Aphis gossypii, Brevicoryne brassicae, Cryptomyzus ribis, aphis fabae, aphis pomi, eriosoma lanigerum, hyalopterus arundi is, phylloxera vastatrix, pemphigus spp., macrosiphum avenae, myzus spp., phorodon humuli, rhopalosiphum padi, empoasca spp , Laodelphax striatellus, Nilaparvata lugens, Aonidiella aurantii, Aspidiotus hederae, Pseudococcus spp., Psylla spp.
Aus der Ordnung der Lepidoptera z.B. Pectinophora gossypiella, Bupalus piniarius, Cheimatobia brumata, Lithocolletis blancardella, Hyponomeuta padella, Plutella xylostella, Malacosoma neustria, Euproctis chrysorrhoea, Lymantria spp., Buccu- latrix thurberiella, Phyllocnistis citrella, Agrotis spp., Euxoa spp., Feltia spp., Earias insulana, Heliothis spp., Mamestra brassicae, Panolis flammea, Spodoptera spp., Trichoplusia ni, Carpocapsa pomonella, Pieris spp., Chilo spp., Pyrausta nubilalis, Ephestia kuehniella, Galleria mellonella, Tineola bisselliella, Tinea pellionella, Hofmannophila pseudospretella, Cacoecia podana, Capua reticulana, Choristoneura fumiferana, Clysia ambiguella, Homona magnanima, Tortrix viridana, Cnaphalocerus spp., Oulema oryzae.From the order of the Lepidoptera e.g. Pectinophora gossypiella, Bupalus piniarius, Cheimatobia brumata, Lithocolletis blancardella, Hyponomeuta padella, Plutella xylostella, Malacosoma neustria, Euproctis chrysorrhoea, Lymantria spp., Buccu- latrix thurberistiis sella , Heliothis spp., Mamestra brassicae, Panolis flammea, Spodoptera spp., Trichoplusia ni, Carpocapsa pomonella, Pieris spp., Chilo spp., Pyrausta nubilalis, Ephestia kuehniella, Galleria mellonella, Tineola bisselliella, Hofeamannodellailaella, Hofeamannellaellaella, Tinea pellionella Capua reticulana, Choristoneura fumiferana, Clysia ambiguella, Homona magnanima, Tortrix viridana, Cnaphalocerus spp., Oulema oryzae.
Aus der Ordnung der Coleoptera z.B. Anobium punctatum, Rhizopertha dominica, Bruchidius obtectus, Acanthoscelides obtectus, Hylotrupes bajulus, Agelastica alni, Leptinotarsa decemlineata, Phaedon cochleariae, Diabrotica spp., Psylliodes chryso- cephala, Epilachna varivestis, Atomaria spp., Oryzaephilus surinamensis, Antho- nomus spp., Sitophilus spp., Otiorrhynchus sulcatus, Cosmopolites sordidus, Ceuthorrhynchus assimilis, Hypera postica, Dermestes spp., Trogoderma spp., Anthrenus spp., Attagenus spp., Lyctus spp., Meligethes aeneus, Ptinus spp., Niptus hololeucus, Gibbium psylloides, Tribolium spp., Tenebrio molitor, Agriotes spp.,From the order of the Coleoptera e.g. Anobium punctatum, Rhizopertha dominica, Bruchidius obtectus, Acanthoscelides obtectus, Hylotrupes bajulus, Agelastica alni, Leptinotarsa decemlineata, Phaedon cochleariae, Diabrotica spp., Psylliodes chryso-cephala, syllable, Or spp., Otiorrhynchus sulcatus, Cosmopolites sordidus, Ceuthorrhynchus assimilis, Hypera postica, Dermestes spp., Trogoderma spp., Anthrenus spp., Attagenus spp., Lyctus spp., Meligethes aeneus, Ptinus sppium, sides., Nipt ., Tenebrio molitor, Agriotes spp.,
Conoderus spp., Melolontha melolontha, Amphimallon solstitialis, Costelytra zealan- dica, Lissorhoptrus oryzophilus.Conoderus spp., Melolontha melolontha, Amphimallon solstitialis, Costelytra zealan- dica, Lissorhoptrus oryzophilus.
Aus der Ordnung der Hymenoptera z.B. Diprion spp., Hoplocampa spp., Lasius spp., Monomorium pharaonis, Vespa spp. Aus der Ordnung der Diptera z.B. Aedes spp., Anopheles spp., Culex spp., Droso- phila melanogaster, Musca spp., Fannia spp., Calliphora erythrocephala, Lucilia spp., Chrysomyia spp., Cuterebra spp., Gastrophilus spp., Hyppobosca spp., Stomoxys spp., Oestrus spp., Hypoderma spp., Tabanus spp., Tannia spp., Bibio hortulanus, Os- cinella frit, Phorbia spp., Pegomyia hyoscyami, Ceratitis capitata, Dacus oleae,From the order of the Hymenoptera, for example Diprion spp., Hoplocampa spp., Lasius spp., Monomorium pharaonis, Vespa spp. From the order of the Diptera, for example Aedes spp., Anopheles spp., Culex spp., Drosophila melanogaster, Musca spp., Fannia spp., Calliphora erythrocephala, Lucilia spp., Chrysomyia spp., Cuterebra spp., Gastrophilus spp., Hyppobosca spp., Stomoxys spp., Oestrus spp., Hypoderma spp., Tabanus spp., Tannia spp., Bibio hortulanus, Os- cinella frit, Phorbia spp., Pegomyia hyoscyami, Ceratitis capitata, Dacus oleae,
Tipula paludosa, Hylemyia spp., Liriomyza spp..Tipula paludosa, Hylemyia spp., Liriomyza spp ..
Aus der Ordnung der Siphonaptera z.B. Xenopsylla cheopis, Ceratophyllus spp..From the order of the Siphonaptera e.g. Xenopsylla cheopis, Ceratophyllus spp ..
Aus der Klasse der Arachnida z.B. Scorpio maurus, Latrodectus mactans, Acarus siro, Argas spp., Ornithodoros spp., Dermanyssus gallinae, Eriophyes ribis, Phyllo- coptruta oleivora, Boophilus spp., Rhipicephalus spp., Amblyomma spp., Hyalomma spp., Ixodes spp., Psoroptes spp., Chorioptes spp., Sarcoptes spp., Tarsonemus spp., Bryobia praetiosa, Panonychus spp., Tetranychus spp..From the class of the Arachnida e.g. Scorpio maurus, Latrodectus mactans, Acarus siro, Argas spp., Ornithodoros spp., Dermanyssus gallinae, Eriophyes ribis, Phyllo- coptruta oleivora, Boophilus spp., Rhipicephalus spp., Amblyomma spp., Hyalommodes spp., I ., Chorioptes spp., Sarcoptes spp., Tarsonemus spp., Bryobia praetiosa, Panonychus spp., Tetranychus spp ..
Zu den pflanzenparasitären Nematoden gehören z.B. Pratylenchus spp., Radopholus similis, Ditylenchus dipsaci, Tylenchulus semipenetrans, Heterodera spp., Globodera spp., Meloidogyne spp., Aphelenchoides spp., Longidorus spp., Xiphinema spp., Trichodorus spp..Plant-parasitic nematodes include e.g. Pratylenchus spp., Radopholus similis, Ditylenchus dipsaci, Tylenchulus semipenetrans, Heterodera spp., Globodera spp., Meloidogyne spp., Aphelenchoides spp., Longidorus spp., Xiphinema spp., Trichodorus spp ..
Die erfindungsgemäßen Wirkstoffkombinationen besitzen weiterhin sehr gute fungizide Eigenschaften und lassen sich zur Bekämpfung von phytopathogenen Pilzen, wie Plasmodiophoromycetes, Oomycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes, Deuteromycetes usw. einsetzen.The active compound combinations according to the invention also have very good fungicidal properties and can be used to control phytopathogenic fungi, such as Plasmodiophoromycetes, Oomycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes, Deuteromycetes, etc.
Die erfindungsgemäßen Wirkstoffkombinationen eignen sich besonders gut zur Bekämpfung von Pyricularia, Pellicularia, Cochliobolus, Gibberella, Rhizoctonia und Fusarium spp.The active compound combinations according to the invention are particularly suitable for combating Pyricularia, Pellicularia, Cochliobolus, Gibberella, Rhizoctonia and Fusarium spp.
Die erfindungsgemäßen Wirkstoffkombinationen zeichnen sich insbesondere durch eine sehr gute Wirksamkeit gegenüber Schädlingen und Pilzen im Reisanbau aus. Die gute Pflanzenverträglichkeit der Wirkstoffkombinationen in den zur Bekämpfung von Pflanzenkrankheiten notwendigen Konzentrationen erlaubt eine Behandlung von oberirdischen Pflanzenteilen, von Pflanz- und Saatgut und des Bodens. Die erfϊndungsgemäßen Wirkstoffkombinationen können zur Blattapplikation oder auch als Beizmittel eingesetzt werden.The active compound combinations according to the invention are particularly notable for very good activity against pests and fungi in rice cultivation. The good plant tolerance of the active ingredient combinations in the concentrations necessary to combat plant diseases allows treatment of above-ground parts of plants, of propagation stock and seeds and of the soil. The active substance combinations according to the invention can be used for leaf application or as a mordant.
Die Wirkstoffe können in die üblichen Formulierungen überfuhrt werden, wie Lösungen, Emulsionen, Spritzpulver, Suspensionen, Pulver, Stäubemittel, Pasten, lösli- ehe Pulver, Granulate, Suspensions-Emulsions-Konzentrate, Wirkstoff-imprägnierteThe active ingredients can be converted into the customary formulations, such as solutions, emulsions, wettable powders, suspensions, powders, dusts, pastes, soluble powders, granules, suspension emulsion concentrates, impregnated with active ingredients
Natur- und synthetische Stoffe sowie Feinstverkapselungen in polymeren Stoffen.Natural and synthetic substances as well as very fine encapsulation in polymeric substances.
Diese Formulierungen werden in bekannter Weise hergestellt, z.B. durch Vermischen der Wirkstoffe mit Streckmitteln, also flüssigen Lösungsmitteln und/oder festen Trä- gerstoffen, gegebenenfalls unter Verwendung von oberflächenaktiven Mitteln, alsoThese formulations are made in a known manner, e.g. by mixing the active ingredients with extenders, that is to say liquid solvents and / or solid carriers, if appropriate using surface-active agents, that is to say
Emulgiermitteln und/oder Dispergiermitteln und/oder schaumerzeugenden Mitteln.Emulsifiers and / or dispersants and / or foaming agents.
Im Falle der Benutzung von Wasser als Streckmittel können z.B. auch organische Lösungsmittel als Hilfslösungsmittel verwendet werden. Als flüssige Lösungsmittel kommen im wesentlichen in Frage: Aromaten, wie Xylol, Toluol, oder Alkylnaph- thaline, chlorierte Aromaten und chlorierte aliphatische Kohlenwasserstoffe, wie Chlorbenzole, Chlorethylene oder Methylenchlorid, aliphatische Kohlenwasserstoffe, wie Cyclohexan oder Paraffine, z.B. Erdölfraktionen, mineralische und pflanzliche Öle, Alkohole, wie Butanol oder Glykol sowie deren Ether und Ester, Ketone wie Aceton, Methylethylketon, Methylisobutylketon oder Cyclohexanon, stark polare Lösungsmittel, wie Dimethylformamid und Dimethylsulfoxid, sowie Wasser.If water is used as an extender, e.g. organic solvents can also be used as auxiliary solvents. The following are essentially suitable as liquid solvents: aromatics, such as xylene, toluene, or alkylnaphthalenes, chlorinated aromatics and chlorinated aliphatic hydrocarbons, such as chlorobenzenes, chlorethylenes or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffins, e.g. Petroleum fractions, mineral and vegetable oils, alcohols such as butanol or glycol and their ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethylformamide and dimethyl sulfoxide, and water.
Als feste Trägerstoffe kommen in Frage: z.B. Ammoniumsalze und natürliche Gesteinsmehle, wie Kaoline, Tonerden, Tal- kum, Kreide, Quarz, Attapulgit, Montmorillonit oder Diatomeenerde und synthetische Gesteinsmehle, wie hochdisperse Kieselsäure, Aluminiumoxid und Silikate, als feste Trägerstoffe für Granulate kommen in Frage: z.B. gebrochene und fraktionierte natürliche Gesteine wie Calcit, Marmor, Bims, Sepiolith, Dolomit sowie synthetische Granulate aus anorganischen und organischen Mehlen sowie Granulate aus organischem Material wie Sägemehl, Kokosnußschalen, Maiskolben und Tabakstengeln; als Emulgier- und oder schaumerzeugende Mittel kommen in Frage: z.B. nichtionogene und anionische Emulgatoren, wie Polyoxyethylen-Fettsäure- Ester, Polyoxyethylen-Fettalkohol-Ether, z.B. Alkylaryl-polyglykolether, Alkylsulfo- nate, Alkylsulfate, Arylsulfonate sowie Einweißhydrolysate; als Dispergiermittel kommen in Frage: z.B. Lignin-Sulfitablaugen und Methylcellulose.Possible solid carriers are: for example ammonium salts and natural rock powders such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth and synthetic rock powders such as highly disperse silica, aluminum oxide and silicates, Solid carrier materials for granules are: for example broken and fractionated natural rocks such as calcite, marble, pumice, sepiolite, dolomite as well as synthetic granules from inorganic and organic flours as well as granules from organic material such as sawdust, coconut shells, corn cobs and tobacco stalks; Possible emulsifying and or foam-generating agents are: for example nonionic and anionic emulsifiers, such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, for example alkylaryl polyglycol ethers, alkyl sulfonates, alkyl sulfates, aryl sulfonates and protein hydrolyzates; Possible dispersing agents are, for example, lignin sulfite waste liquor and methyl cellulose.
Es können in den Formulierungen Haftmittel wie Carboxymethylcellulose, natürliche und synthetische pulvrige, körnige oder latexformige Polymere verwendet werden, wie Gummiarabicum, Polyvinylalkohol, Polyvinylacetat, sowie natürliche Phospho- lipide, wie Kephaline und Lecithine und synthetische Phospholipide. Weitere Addi- tive können mineralische und vegetabile Öle sein.Adhesives such as carboxymethyl cellulose, natural and synthetic powdery, granular or latex-shaped polymers, such as gum arabic, polyvinyl alcohol, polyvinyl acetate, and natural phospholipids such as cephalins and lecithins and synthetic phospholipids can be used in the formulations. Mineral and vegetable oils can also be used as additives.
Es können Farbstoffe wie anorganische Pigmente, z.B. Eisenoxid, Titanoxid, Ferro- cyanblau und organische Farbstoffe, wie Alizarin-, Azo- und Metallphthalocyanin- farbstoffe und Spurennährstoffe wie Salze von Eisen, Mangan, Bor, Kupfer, Kobalt, Molybdän und Zink verwendet werden.Dyes such as inorganic pigments, e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc can be used.
Die Formulierungen enthalten im allgemeinen zwischen 0,1 und 95 Gew.-% Wirkstoffe, vorzugsweise zwischen 0,5 und 90 %.The formulations generally contain between 0.1 and 95% by weight of active ingredients, preferably between 0.5 and 90%.
Die Wirkstoffkombinationen können als solche, in Form ihrer Formulierungen oder den daraus bereiteten Anwendungsformen, wie gebrauchsfertige Lösungen, emul- gierbare Konzentrate, Emulsionen, Suspensionen, Spritzpulver, lösliche Pulver und Granulate, angewendet werden. Die Anwendung geschieht in üblicher Weise, z.B. durch Gießen, Verspritzen, Versprühen, Verstreuen, Verstreichen, Trockenbeizen, Feuchtbeizen, Naßbeizen, Schlämmbeizen oder Inkrustieren. Erfindungsgemäß können alle Pflanzen und Pflanzenteile behandelt werden. Unter Pflanzen werden hierbei alle Pflanzen und Pflanzenpopulationen verstanden, wie erwünschte und unerwünschte Wildpflanzen oder Kulturpflanzen (einschließlich natürlich vorkommender Kulturpflanzen). Kulturpflanzen können Pflanzen sein, die durch konventionelle Züchtungs- und Optimierungsmethoden oder durch bio- technologische und gentechnologische Methoden oder Kombinationen dieser Methoden erhalten werden können, einschließlich der transgenen Pflanzen und einschließlich der durch Sortenschutzrechte schützbaren oder nicht schützbaren Pflanzensorten. Unter Pflanzenteilen sollen alle oberirdischen und unterirdischen Teile und Organe der Pflanzen, wie Sproß, Blatt, Blüte und Wurzel verstanden werden, wobei beispielhaft Blätter, Nadeln, Stengel, Stämme, Blüten, Fruchtkörper, Früchte und Samen sowie Wurzeln, Knollen und Rhizome aufgeführt werden. Zu den Pflanzenteilen gehört auch Erntegut sowie vegetatives und generatives Vermehrungsmaterial, beispielsweise Stecklinge, Knollen, Rhizome, Ableger und Samen.The active substance combinations can be used as such, in the form of their formulations or the use forms prepared therefrom, such as ready-to-use solutions, emulsifiable concentrates, emulsions, suspensions, wettable powders, soluble powders and granules. They are used in the customary manner, for example by pouring, spraying, atomizing, scattering, spreading, dry pickling, wet pickling, wet pickling, slurry pickling or incrusting. According to the invention, all plants and parts of plants can be treated. Plants are understood here to mean all plants and plant populations, such as desired and unwanted wild plants or crop plants (including naturally occurring crop plants). Crop plants can be plants which can be obtained by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or combinations of these methods, including the transgenic plants and including the plant cultivars which can or cannot be protected by plant breeders' rights. Plant parts are to be understood to mean all above-ground and underground parts and organs of the plants, such as sprout, leaf, flower and root, examples being leaves, needles, stems, stems, flowers, fruiting bodies, fruits and seeds as well as roots, tubers and rhizomes. The plant parts also include crops and vegetative and generative propagation material, for example cuttings, tubers, rhizomes, offshoots and seeds.
Die erfϊndungsgemäße Behandlung der Pflanzen und Pflanzenteile mit den Wirkstoffen erfolgt direkt oder durch Einwirkung auf deren Umgebung, Lebensraum oder Lagerraum nach den üblichen Behandlungsmethoden, z.B. durch Tauchen, Sprühen, Verdampfen, Vernebeln, Streuen, Aufstreichen und bei Vermehrungsmaterial, insbesondere bei Samen, weiterhin durch ein- oder mehrschichtiges Umhüllen.The treatment of the plants and parts of plants according to the invention with the active substances takes place directly or by acting on their surroundings, living space or storage space according to the usual treatment methods, e.g. by dipping, spraying, vaporizing, atomizing, scattering, spreading and, in the case of propagation material, in particular seeds, furthermore by single- or multilayer coating.
Bei der Behandlung von Pflanzenteilen können die Wirkstoffkonzentrationen in den Anwendungsformen in einem größeren Bereich variiert werden. Sie liegen im allgemeinen zwischen 1 und 0,0001 Gew.-%, vorzugweise zwischen 0,5 und 0,001 %.When treating parts of plants, the active compound concentrations in the use forms can be varied within a substantial range. They are generally between 1 and 0.0001% by weight, preferably between 0.5 and 0.001%.
Bei der Saatgutbehandlung werden im allgemeinen Wirkstoffmengen von 0,001 bis 50 g je Kilogramm Saatgut, vorzugsweise 0,01 bis 10 g, benötigt.In the case of seed treatment, amounts of active compound of 0.001 to 50 g per kilogram of seed, preferably 0.01 to 10 g, are generally required.
Bei Behandlung des Bodens sind Wirkstoffkonzentrationen von 0,00001 bis 0,1 Gew.-%, vorzugsweise von 0,0001 bis 0,02 Gew.-%, am Wirkungsort erforderlich. Die gute insektizide Wirkung der erfindungsgemäßen Wirkstoffkombinationen geht aus den nachfolgenden Beispielen hervor. Während die einzelnen Wirkstoffe und auch die Kombination aus jeweils zwei Wirkstoffen in der insektiziden Wirkung Schwächen aufweisen, zeigt die Kombination aus drei Wirkstoffen eine Wirkung, die über eine einfache Wirkungssummierung mit synergistischem Effekt hinausgeht.When treating the soil, active ingredient concentrations of 0.00001 to 0.1% by weight, preferably 0.0001 to 0.02% by weight, are required at the site of action. The good insecticidal activity of the active compound combinations according to the invention can be seen from the examples below. While the individual active ingredients and also the combination of two active ingredients each have weaknesses in the insecticidal action, the combination of three active ingredients shows an action that goes beyond a simple combination of actions with a synergistic effect.
Ein synergistischer Effekt liegt bei Insektiziden immer dann vor, wenn die insektizide Wirkung der Wirkstoffkombinationen größer ist als die Summe der Wirkungen der einzeln applizierten Wirkstoffe.Insecticides always have a synergistic effect if the insecticidal effect of the active ingredient combinations is greater than the sum of the effects of the individually applied active ingredients.
Ein synergistischer Effekt liegt bei Fungiziden immer dann vor, wenn die fungizide Wirkung der Wirkstoffkombinationen größer ist als die Summe der Wirkungen der einzeln applizierten Wirkstoffe. Fungicides always have a synergistic effect if the fungicidal activity of the active ingredient combinations is greater than the sum of the effects of the individually applied active ingredients.
AnwendungsbeispielApplication example
Grenzkonzentrationstest /BodeninsektenLimit concentration test / soil insects
Testinsekt: Diabrotica balteata - Larven im BodenTest insect: Diabrotica balteata - larvae in the soil
Lösungsmittel: 4 Gewichtsteile AcetonSolvent: 4 parts by weight of acetone
Emulgator: 1 Gewichtsteil AlkylarylpolyglykoletherEmulsifier: 1 part by weight of alkylaryl polyglycol ether
Zur Herstellung einer zweckmäßigen Wirkstoffzubereitung vermischt man 1 Ge- wichtsteil Wirkstoff mit der angegebenen Menge Lösungsmittel, gibt die angegebeneTo produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amount of solvent, the specified amount is given
Menge Emulgator zu und verdünnt das Konzentrat mit Wasser auf die gewünschte Konzentration. Dabei spielt die Konzentration des Wirkstoffes in der Zubereitung praktisch keine Rolle, entscheidend ist allein die Wirkstoffgewichtsmenge pro Volumeneinheit Boden, welche in ppm (mg/1) angegeben wird. Man füllt den Boden in 0,5 1 Töpfe und läßt diese bei 20°C stehen.Amount of emulsifier and dilute the concentrate with water to the desired concentration. The concentration of the active ingredient in the preparation is practically irrelevant, the only decisive factor is the amount of active ingredient per unit volume of soil, which is given in ppm (mg / 1). The bottom is filled into 0.5 liter pots and these are left to stand at 20 ° C.
Sofort nach dem Ansatz werden je Topf 5 Maiskörner ausgelegt. Nach 3 Tagen werden die Testinsekten in den behandelten Boden gesetzt. Nach weiteren 7 Tagen wird der Wirkungsgrad ermittelt. Der Wirkungsgrad berechnet sich aus der Anzahl der aufgelaufenden Maispflanzen.Immediately after the preparation, 5 corn kernels are laid out per pot. After 3 days, the test insects are placed in the treated soil. The efficiency is determined after a further 7 days. The efficiency is calculated from the number of maize plants that emerge.
Wirkstoffe, Aufwandmengen und Resultate gehen aus der nachfolgenden Tabelle hervor: Active ingredients, application rates and results are shown in the table below:
Tabelletable
BodeninsektizideSoil insecticides
Diabrotica balteata - Larven im BodenDiabrotica balteata - larvae in the soil
Figure imgf000018_0001
Tabelle
Figure imgf000018_0001
table
BodeninsektizideSoil insecticides
Diabrotica balteata - Larven im BodenDiabrotica balteata - larvae in the soil
Figure imgf000019_0001
Figure imgf000019_0001

Claims

Patentansprüche claims
1. Mittel, gekennzeichnet durch einen Gehalt an einer Wirkstoffkombination enthaltend1. Agent, characterized by containing an active ingredient combination
A) Spinosad (I)A) Spinosad (I)
B) eine fungizid wirksame Verbindung aus der Reihe Benomyl (Ila), Thiophanate-methyl (Ilb), Acibenzolar (IIc), Flutolanil (Ild), Fura- metpyr (Ile), Fumoxadone (Ilf), Metalaxyl (Hg), Mefluoxam (Ilh),B) a fungicidally active compound from the series benomyl (Ila), thiophanate-methyl (Ilb), acibenzolar (IIc), flutolanil (Ild), furametyr (Ile), fumoxadone (Ilf), metalaxyl (Hg), mefluoxam ( Ilh),
Azoxystrobin (Ili) und Metominostrobin (IIj), Capropamid (Ilk) und Diclocymet (III), Tricyclazol (Um), Oryzemate (Iln) undAzoxystrobin (Ili) and Metominostrobin (IIj), Capropamid (Ilk) and Diclocymet (III), Tricyclazol (Um), Oryzemate (Iln) and
C) eine insektizid wirksame Verbindung aus der Reihe l-[(6-Chlor-3- pyridinyl)-methyl]-N-nitro-2-imidazolidinimin der FormelC) an insecticidally active compound from the series I - [(6-chloro-3-pyridinyl) methyl] -N-nitro-2-imidazolidinimine of the formula
Figure imgf000020_0001
Figure imgf000020_0001
Figure imgf000020_0002
Figure imgf000020_0002
Figure imgf000020_0003
Figure imgf000021_0001
Figure imgf000020_0003
Figure imgf000021_0001
Figure imgf000021_0002
Figure imgf000021_0002
Figure imgf000021_0003
Figure imgf000021_0003
Figure imgf000021_0004
Figure imgf000021_0004
undand
Figure imgf000021_0005
Figure imgf000021_0005
2. Verfahren zur Bekämpfung von tierischen Schädlingen, dadurch gekennzeichnet, daß man Wirkstoffkombinationen gemäß Anspruch 1 auf die Schädlinge und/oder deren Lebensraum einwirken läßt.2. A method for controlling animal pests, characterized in that active compound combinations according to claim 1 are allowed to act on the pests and / or their habitat.
3. Verwendung von Wirkstoffkombinationen gemäß Anspruch 1 zur Bekämpfung von tierischen Schädlingen.3. Use of active ingredient combinations according to claim 1 for combating animal pests.
4. Verfahren zur Herstellung von Schädlingsbekämpfungsmitteln, dadurch gekennzeichnet, daß man Wirkstoffkombinationen gemäß Anspruch 1 mit Streckmitteln und/oder oberflächenaktiven Stoffen vermischt.4. A process for the preparation of pesticides, characterized in that active compound combinations according to claim 1 are mixed with extenders and / or surface-active substances.
5. Verfahren zur Bekämpfung von Pilzen, dadurch gekennzeichnet, daß man Wirkstoffkombinationen gemäß Anspruch 1 auf Pilze und/oder deren Lebensraum einwirken läßt.5. A method of combating fungi, characterized in that active compound combinations according to claim 1 are allowed to act on fungi and / or their habitat.
6. Verwendung von Wirkstofϊkombinationen gemäß Anspruch 1 zur Bekämpfung von Pilzen. 6. Use of drug combinations according to claim 1 for combating fungi.
PCT/EP1999/009449 1998-12-16 1999-12-03 Combination of active agents WO2000035282A1 (en)

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WO2010092028A3 (en) * 2009-02-11 2011-07-14 Basf Se Pesticidal mixtures
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WO2010092028A3 (en) * 2009-02-11 2011-07-14 Basf Se Pesticidal mixtures
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