WO2000020478A1 - Liquid curable resin composition - Google Patents
Liquid curable resin composition Download PDFInfo
- Publication number
- WO2000020478A1 WO2000020478A1 PCT/NL1999/000609 NL9900609W WO0020478A1 WO 2000020478 A1 WO2000020478 A1 WO 2000020478A1 NL 9900609 W NL9900609 W NL 9900609W WO 0020478 A1 WO0020478 A1 WO 0020478A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- acrylate
- meth
- compound
- composition
- liquid curable
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
- C09D175/16—Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/104—Coating to obtain optical fibres
- C03C25/106—Single coatings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3203—Polyhydroxy compounds
- C08G18/3215—Polyhydroxy compounds containing aromatic groups or benzoquinone groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/67—Unsaturated compounds having active hydrogen
- C08G18/671—Unsaturated compounds having only one group containing active hydrogen
- C08G18/672—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
Definitions
- a polymerizable monofunctional or polyfunctional compound can be added to the liquid curable resin composition of the present invention.
- the mono-functional compound which can be used in the composition of the present invention are vinyl group-containing lactams such as N-vinyl pyrrolidone and N-vinyl caprolactam; (meth) acrylates containing an alicyclic structure such as isobornyl (meth) acrylate, bornyl (meth) acrylate, tricyclodecanyl (meth) acrylate, and dicyclopentanyl (meth) acrylate; benzyl (meth) acrylate, 4-butylcyclohexyl (meth) acrylate, acryloylmorpholine, vinyl imidazole, and vinylpyridine .
- R 6 and R 8 individually represent a hydrogen atoms or methyl group
- R 7 and R 9 individually represent an alkylene group having 2-8, preferably 2-5, carbon atoms
- R 10 to R 15 individually represent a hydrogen atom or methyl group
- p and q individually indicate an integer from 0 to 5 , preferably from 1 to 4,
- Lucirin TPO manufactured by BASF
- Ubecryl P36 manufactured by Ubecryl P36
- the photosensitizer triethylamine, diethylamine, N- methyldiethanoleamine, ethanolamine, 4- dimethylaminobenzoic acid, 4 -methyl dimethylaminobenzoate, 4 -ethyl dimethylaminobenzoate, 4-isoamyl dimethylaminobenzoate, and Ubecryl P102, 103, 104, 105 (manufactured by UCB) can be given.
- a reaction vessel equipped with a stirrer was charged with 16.98 g of 2,4-tolylene diisocyanate, 0.015 g of 2, 6-di-t-butyl-p-cresol, 0.05 g of dibutyltin dilaurate, and 0.005 g of phenothiazine.
- the mixture was cooled with ice to 10°C or below while stirring.
- 11.32 g of 2 -hydroxyethyl acrylate was added dropwise while controlling the temperature of the solution to 20°C or below, following which the mixture was reacted for one hour while stirring.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Optical Fibers, Optical Fiber Cores, And Optical Fiber Bundles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyurethanes Or Polyureas (AREA)
- Paints Or Removers (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP10/282407 | 1998-10-05 | ||
JP28240798A JP3991472B2 (ja) | 1998-10-05 | 1998-10-05 | 液状硬化性樹脂組成物 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2000020478A1 true WO2000020478A1 (en) | 2000-04-13 |
Family
ID=17652019
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/NL1999/000609 WO2000020478A1 (en) | 1998-10-05 | 1999-09-30 | Liquid curable resin composition |
Country Status (2)
Country | Link |
---|---|
JP (1) | JP3991472B2 (ja) |
WO (1) | WO2000020478A1 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20130284262A1 (en) * | 2010-12-02 | 2013-10-31 | Nissan Chemical Industries, Ltd. | Film-forming material |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4821175B2 (ja) * | 2005-05-26 | 2011-11-24 | Jsr株式会社 | ウレタン(メタ)アクリレート、放射線硬化性組成物、及びその硬化膜 |
JP5297030B2 (ja) * | 2006-12-25 | 2013-09-25 | 大阪瓦斯株式会社 | フルオレン骨格を有するウレタン(メタ)アクリレート |
JP2014062195A (ja) * | 2012-09-21 | 2014-04-10 | Ksm Kk | 光硬化性組成物、及び、光硬化性組成物の製造方法 |
JP6270513B2 (ja) * | 2013-02-13 | 2018-01-31 | 大阪ガスケミカル株式会社 | フルオレン骨格を有するポリウレタン樹脂 |
JP2017132859A (ja) * | 2016-01-26 | 2017-08-03 | アイカ工業株式会社 | プリズム形成用光硬化性樹脂組成物 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4663412A (en) * | 1984-10-31 | 1987-05-05 | Ecoplastics Limited | Fluorene containing compounds and negative photoresist compositions therefrom |
WO1992003483A1 (en) * | 1990-08-16 | 1992-03-05 | Minnesota Mining And Manufacturing Company | Polymeric mixtures and process therefor |
US5109097A (en) * | 1990-09-07 | 1992-04-28 | Minnesota Mining And Manufacturing Company | Radiation curable coating |
EP0598552A2 (en) * | 1992-11-16 | 1994-05-25 | Sola International Holdings, Ltd. | Cross-linkable polymeric composition |
JPH1017632A (ja) * | 1996-07-04 | 1998-01-20 | Nippon Kayaku Co Ltd | 樹脂組成物、注型用組成物及びその硬化物 |
JPH1067977A (ja) * | 1996-08-28 | 1998-03-10 | Nippon Steel Chem Co Ltd | 光ディスク用接着剤及び光ディスク |
-
1998
- 1998-10-05 JP JP28240798A patent/JP3991472B2/ja not_active Expired - Lifetime
-
1999
- 1999-09-30 WO PCT/NL1999/000609 patent/WO2000020478A1/en active Application Filing
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4663412A (en) * | 1984-10-31 | 1987-05-05 | Ecoplastics Limited | Fluorene containing compounds and negative photoresist compositions therefrom |
WO1992003483A1 (en) * | 1990-08-16 | 1992-03-05 | Minnesota Mining And Manufacturing Company | Polymeric mixtures and process therefor |
US5109097A (en) * | 1990-09-07 | 1992-04-28 | Minnesota Mining And Manufacturing Company | Radiation curable coating |
EP0598552A2 (en) * | 1992-11-16 | 1994-05-25 | Sola International Holdings, Ltd. | Cross-linkable polymeric composition |
JPH1017632A (ja) * | 1996-07-04 | 1998-01-20 | Nippon Kayaku Co Ltd | 樹脂組成物、注型用組成物及びその硬化物 |
JPH1067977A (ja) * | 1996-08-28 | 1998-03-10 | Nippon Steel Chem Co Ltd | 光ディスク用接着剤及び光ディスク |
Non-Patent Citations (2)
Title |
---|
CHEMICAL ABSTRACTS, vol. 128, no. 14, 6 April 1998, Columbus, Ohio, US; abstract no. 168179, "Urethane (meth)acrylate polymer casting composition" XP002122970 * |
CHEMICAL ABSTRACTS, vol. 128, no. 3, 19 January 1998, Columbus, Ohio, US; abstract no. 24966, "adhesives containing polyurethane acrylates with diphenylfluorene structures" XP002122971 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20130284262A1 (en) * | 2010-12-02 | 2013-10-31 | Nissan Chemical Industries, Ltd. | Film-forming material |
US9761741B2 (en) * | 2010-12-02 | 2017-09-12 | Nissan Chemical Industries, Ltd. | Film-forming material |
Also Published As
Publication number | Publication date |
---|---|
JP2000109528A (ja) | 2000-04-18 |
JP3991472B2 (ja) | 2007-10-17 |
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