WO1999003753A1 - Closed flexible sachet - Google Patents

Closed flexible sachet Download PDF

Info

Publication number
WO1999003753A1
WO1999003753A1 PCT/EP1998/003826 EP9803826W WO9903753A1 WO 1999003753 A1 WO1999003753 A1 WO 1999003753A1 EP 9803826 W EP9803826 W EP 9803826W WO 9903753 A1 WO9903753 A1 WO 9903753A1
Authority
WO
WIPO (PCT)
Prior art keywords
sachet
sheets
channel
flexible
faces
Prior art date
Application number
PCT/EP1998/003826
Other languages
English (en)
French (fr)
Inventor
Alfred Yoakim
Alain Mariller
Original Assignee
Societe Des Produits Nestle S.A.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to JP50626099A priority Critical patent/JP4049402B2/ja
Priority to AU87282/98A priority patent/AU731750B2/en
Priority to EP98938628A priority patent/EP0996578B1/en
Priority to AT98938628T priority patent/ATE208732T1/de
Application filed by Societe Des Produits Nestle S.A. filed Critical Societe Des Produits Nestle S.A.
Priority to BR9811695-9A priority patent/BR9811695A/pt
Priority to SI9830078T priority patent/SI0996578T1/xx
Priority to APAP/P/2000/001729A priority patent/AP1268A/en
Priority to IL13309498A priority patent/IL133094A/xx
Priority to DK98938628T priority patent/DK0996578T3/da
Priority to DE69802537T priority patent/DE69802537T2/de
Priority to EA200000126A priority patent/EA001241B1/ru
Priority to CA002291234A priority patent/CA2291234A1/en
Publication of WO1999003753A1 publication Critical patent/WO1999003753A1/en
Priority to NO20000173A priority patent/NO318045B1/no
Priority to US09/482,274 priority patent/US6347725B1/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D85/00Containers, packaging elements or packages, specially adapted for particular articles or materials
    • B65D85/70Containers, packaging elements or packages, specially adapted for particular articles or materials for materials not otherwise provided for
    • B65D85/804Disposable containers or packages with contents which are mixed, infused or dissolved in situ, i.e. without having been previously removed from the package
    • B65D85/808Disposable containers or packages with contents which are mixed, infused or dissolved in situ, i.e. without having been previously removed from the package for immersion in the liquid to release part or all of their contents, e.g. tea bags

Definitions

  • the invention relates to a closed flexible sachet in the form of an individual portion provided for extraction under pressure, containing at least one pulverulent substance for the preparation of a beverage chosen from ground roast coffee, tea, instant coffee, a mixture of instant coffee and ground coffee, a chocolate-type product or any other dehydrated edible substance, consisting of two identical flexible sheets or of a single folded flexible sheet of circular, oval or polygonal shape, creating a space for the pulverulent substance between the two sheets or between the two faces of the folded sheet, and the two sheets or the two faces of _ the folded sheet are welded over their periphery so that the said sachet is substantially symmetrical with respect to its welding plane, the material used for the flexible sheets is impermeable to oxygen and to water vapour in order to preserve it, and the sachet is opened through the effect only of the rise in pressure which takes place upon injection of the extraction fluid.
  • Patent WO 94/01344 already relates to a closed flexible sachet provided for extraction under pressure. With this sachet, at the time of extraction, one of the flexible sheets is perforated so as to allow the arrival of the extraction water.
  • the drawback of perforating the sheet is that firstly it is necessary to guarantee the seal over the entire periphery of the sachet and, secondly, if the coffee in the sachet is not compacted, it is not always guaranteed that the said sachet will be perforated.
  • the object of the present invention is to develop a closed sachet provided for extraction under pressure, in which it is unnecessary to guarantee the seal over the entire periphery of the sachet at the time of extraction and which makes it possible to avoid perforating one of the two flexible sheets.
  • the present invention relates to a closed flexible sachet in the form of an individual portion provided for extraction under pressure, according to the preamble of Claim 1, and in which the two flexible sheets or the two faces of the folded sheet extend over one side of the said sachet beyond their welding line so as to provide, between the said sheets or between the two faces of the folded sheet, a channel which allows the arrival of the extraction fluid, the said channel being substantially perpendicular to the welding line on which it emerges.
  • the presence of the channel between the two flexible sheets or between the two faces of the folded sheet makes it possible to insert therein a needle or any other sharp element allowing the extraction water to be supplied without perforating or tearing one of the flexible sheets.
  • the needle or the sharp element it is also possible to envisage the arrival of the extraction water precisely at the entry of the said channel.
  • the important thing is that, in the sachet according to the invention, the said sachet is not opened by inserting the needle or the sharp element to the extent of breaking the weld which closes the said sachet, but it is the pressurized water which initiates and completely opens the said weld of the sachet in order to allow the extraction liquid to enter.
  • the water pressure is normally between 1 and 7 bar, i.e., in order to break the weld, a minimum pressure of water is required which allows the said weld to be opened up.
  • the method and the device which are used for the extraction of sachets according to the invention may advantageously be of the type which partially forms the subject of EP Patent Application Nos . 92107548 and 92112364. "Partially” is understood to mean that the device is used not for the arrival of the water but for the exit of the coffee.
  • the lower face of the sachet is opened by localized ruptures after its deformation against the non-perforating and non-cutting raised and hollowed-out elements present on the lower face of the device through the effect only of the rise in pressure which takes place upon injection of the extraction fluid.
  • the sachet according to the invention may be of square, rectangular, oval and other shapes. If the sachet is of rectangular shape, it has a width of approximately 2 to 15 cm, preferably of the order of 4-
  • the sachet has a thickness, at its centre, which is preferably between 5 and 20 mm.
  • the measured amount of pulverulent substance contained may vary between 5 and 50 g, according to its use.
  • the coffee is normally in the sachet in non- compacted form, which makes the said sachet relatively soft. It is, however, also possible to package compacted coffee.
  • the depth of the arrival channel for the extraction fluid is normally from 3 to 10 mm and the diameter of this channel is also between 3 and 10 mm.
  • the weld which closes the sachet normally has a depth of the order of 1 to 3 mm.
  • the sheets are moulded either by means of compression in a die/piston assembly, or by means of pressurization of the inner faces by a gas and/or suction of the outer faces. In both cases, the mould has the desired relief.
  • the sheets or the folded sheet may be made from flexible material such as aluminium with a thickness of from 5 to 40 microns or from plastic such as PET.
  • the sheets will consist of a flexible, multi-layer material which is suitable for welding using customary methods whilst at the same time forming sufficient protection for the product against oxygen and water vapour.
  • outer layer PET (normal, woven or non-woven) , PE, PP, PA, PS or paper
  • high-grade barrier central layer aluminium with a thickness of between 5 and 20 microns, EVOH, PVDC, PET or PVA
  • inner layer plastic, preferably PE or PP or OPP with welding lacquer.
  • the seal is normally achieved at a temperature of between 180 and 250°C.
  • PET-EVOH-PE or PET-aluminium-PE PET-EVOH-PE or PET-aluminium-PE .
  • biodegradable or water-soluble material is also possible as a single layer or in combination with other material.
  • the sachet according to the invention is manufactured in the conventional manner by means of deformation by moulding or by drawing of the two flexible sheets or of the folded flexible sheet which are impermeable to oxygen and to water vapour, by measuring the amount of pulverulent substance onto one of the flexible sheets and by welding the two sheets or the two faces of the folded sheet over their periphery.
  • the manufacturing operations are carried out under the protection of a stream of oxygen-free inert gas, for example under nitrogen or under C0 2 .
  • the major advantage of the sachet according to the invention is that it allows the arrival of the extraction water via a small opening in the weld between the two flexible sheets or between the two faces of the folded sheet.
  • the channel between the two flexible sheets or between the two faces of the folded sheet may, in one version, emerge directly on the welding line and the extraction fluid then has a single path via which to arrive at the sachet.
  • an arrival channel which is subdivided, after the welding line of the two flexible sheets or of the two faces of the folded sheet, into at least two channels emerging at different points in the sachet: for example, in the case of a sachet for a single cup, two arrival channels are envisaged, and, in the case of a sachet for two cups, four arrival channels are envisaged.
  • the sachet-extraction device it is a sharp element which is engaged into the water-arrival channel. So as to guarantee satisfactory insertion of the said sharp element into the channel, provision is made on each flexible sheet or on each face of the folded sheet for a break at the location of the said channel, allowing separation of the said flexible sheets or of the said faces of the folded sheet at the moment the extraction device is pricked. In another embodiment, it is also possible to envisage offsetting the two faces of the folded sheet at the location of the channel. As already mentioned above, it is not obligatory for the sharp element to engage in the channel .
  • a tube which is either adhesively bonded, or crimped or laid in position is placed in the extension of the channel.
  • the advantage of this tube is that it facilitates the insertion of the sharp element.
  • the sachet according to the invention needs a satisfactory seal viz a viz the extraction fluid only at the location of the arrival channel .
  • the consequence of this is that it facilitates the design of the extraction machine and therefore the latter' s cost.
  • Fig. 1 is a plan view of a blank for manufacturing a sachet according to the invention
  • Fig. 2 is a plan view of a blank in a second embodiment
  • Fig. 3 is a diagrammatic plan view of the sachet during extraction
  • Fig. 4 is a plan view of the sachet in a third embodiment
  • Fig. 5 is a plan view of the sachet in a fourth embodiment
  • Fig. 6 is a plan view of the sachet in a fifth embodiment ;
  • Fig. 7 is a plan view of the sachet in a sixth embodiment .
  • Fig. 8 is a plan view of the sachet in a seventh embodiment .
  • the blank (1) is a multi-layer flexible sheet based on aluminium, polyethylene and polypropylene, having a thickness of the order of 40 microns and which is foldable along the line (4) .
  • This sheet is thermoformed so as to create in it two cavities (2, 3) which make it possible to receive the ground roast coffee (40) therein.
  • the flexible sheet is then folded along the line (4) and the two faces of the sheet are welded along the hatched lines (5, 42) .
  • This welding provides a channel (6) between the two faces, allowing the insertion of the sharp element for sachet extraction.
  • FIG. 2 there is a sheet (11) based on the same composite as for Figure 1, the said sheet being foldable along the line (12) . It includes cavities (13, 14) for the ground roast coffee (41) .
  • the sheet is then folded over and welded along the hatched zones (20, 44) and a channel (15) is made in it which is subdivided into two channels (18, 19), allowing the water for extraction to arrive at two different points in the bed of coffee.
  • the water arrives it breaks the weld in the zone (46) and thus allows sachet extraction.
  • the breaks (16, 17) permit satisfactory opening of the channel (15) at the moment of extraction.
  • the border (43) which goes beyond the weld (44) has a width of from 2 to 4 cm.
  • Figure 3 shows a sachet (20) of more oval shape, with its measured amount of coffee (21) .
  • the weld also appears in the form of hatched zones (22) .
  • the welding zone (23) forms the separation between the channel (24) and the bed of coffee (21) .
  • the sharp element (25) is displaced between its guides (26) from a set-back position to a position of engagement in the channel (24) . It is from this moment onwards that the extraction fluid arrives at a pressure of between 1 and 3 bar and breaks the weld (23) .
  • FIG. 4 shows a sachet (30) which has a measured amount of coffee (31) with a weld (32) , the weld (33) forming the separation between the measured amount of coffee and the channel (31) for the arrival of the extraction fluid.
  • a tube (34) In this channel, provision is made for a tube (34) , allowing satisfactory insertion of the sharp element.
  • Figure 5 shows a sachet (47) obtained from a folded-over sheet, which gives two faces (56, 57) .
  • This sachet is provided for a single cup of coffee with one measured amount of coffee (49) .
  • the weld appears in the form of hatched zones (50, 51) .
  • the welding zone (52) forms the separation between the channel (53) and the bed of coffee (49) .
  • the channel (53) is subdivided into two channels (54, 55), so that the water satisfactorily moistens the coffee at two different locations.
  • the offset of the two sheets (56, 57) allows satisfactory opening-up of the channel (53) to permit satisfactory positioning of the water-arrival channel on the said channel (53) .
  • the extraction fluid arrives at a pressure of between 1 and 4 bar and breaks the weld (52) .
  • the water then flows into the sachet and the pressure in the sachet increases, and the lower face of the said sachet presses against raised and hollowed-out elements represented diagrammatically at
  • Figure 6 shows a sachet (48) which makes it possible to prepare two cups of coffee with a measured amount of coffee (69) and a measured amount (70) .
  • the weld appears in the form of hatched zones (61, 62, 63) .
  • the welding zone (72) forms the separation between the channel (71) and the bed of coffee (69) .
  • the channel (71) is subdivided into three channels: the two channels (64, 65) firstly allowing the extraction water to progress onto the bed of coffee (69) and, secondly, a third channel (66) allowing the water to progress towards the second bed of coffee
  • This channel (66) is then itself subdivided into two channels (67, 68) .
  • the extraction fluid arrives via the channel (71) at a pressure of between 1 and 4 bar and breaks the weld (72) .
  • the pressure in the sachet increases and the lower face of the said sachet presses against the raised and hollowed-out elements represented diagrammatically at (59, 60) until the said face tears at the locations of the said raised and hollowed-out elements so as to allow the coffee to flow into the two cups placed beneath the extraction device.
  • Figure 7 shows a sachet (73) obtained from a folded-over sheet giving two faces (74, 75) .
  • This sachet is provided for two cups of coffee with measured amounts of coffee (99, 100).
  • the weld appears in the form of hatched zones (76, 77, 78) .
  • the welding zone (81) forms the separation between the channel (86) and the beds of coffee (99, 100).
  • the channel (86) subdivides into four channels: two channels (82, 83) for the bed of coffee (99) and two channels (84, 85) for the bed of coffee (100) .
  • the offset of the two sheets (74, 75) allows satisfactory opening-up of the channel (86) to allow satisfactory positioning of the water-arrival channel on the said channel (86) .
  • the extraction fluid arrives at a pressure of between 1 and 4 bar and breaks the weld (81) .
  • the water then flows into the sachet and the pressure in the sachet increases and the lower face of the said sachet presses against the raised and hollowed-out elements represented diagrammatically at (79, 80) until the said face tears at the locations of the said raised and hollowed-out elements so as to allow the coffee to flow into the two cups placed beneath the extraction device.
  • FIG 8 shows a sachet (87) which makes it possible to prepare two cups of coffee with one measured amount of coffee (101) .
  • the weld appears in the form of hatched zones (88, 89, 90, 91).
  • the welding zone (92) forms the separation between the channel (93) and the bed of coffee (101) .
  • the channel (93) subdivides into three channels: the first two (94, 95) lead directly to the bed of coffee (101), and the third (96) conveys the water towards the bottom of the sachet.
  • the water arrives at four points on the bed of coffee, which allows satisfactory moistening of the said coffee and satisfactory extraction from the sachet .
  • the sachet according to the invention may be manufactured either from two flexible sheets or from a single folded flexible sheet.
  • the advantage of this second solution is that it dispenses with one welding zone and thus reduces the risks of a defective seal in the sachet according to the invention.
  • PVDC polyvinylidene chloride
  • PE polyethylene
  • PA polyamide
  • PVA polyvinylacetate

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Packages (AREA)
  • Apparatus For Making Beverages (AREA)
  • Bag Frames (AREA)
  • Materials For Medical Uses (AREA)
  • Orthopedics, Nursing, And Contraception (AREA)
PCT/EP1998/003826 1997-07-15 1998-06-23 Closed flexible sachet WO1999003753A1 (en)

Priority Applications (14)

Application Number Priority Date Filing Date Title
SI9830078T SI0996578T1 (en) 1997-07-15 1998-06-23 Closed flexible sachet
EP98938628A EP0996578B1 (en) 1997-07-15 1998-06-23 Closed flexible sachet
AT98938628T ATE208732T1 (de) 1997-07-15 1998-06-23 Versiegelter flexibler beutel
IL13309498A IL133094A (en) 1997-07-15 1998-06-23 Closed flexible sachet
BR9811695-9A BR9811695A (pt) 1997-07-15 1998-06-23 Sachê flexìvel fechado
AU87282/98A AU731750B2 (en) 1997-07-15 1998-06-23 Closed flexible sachet
APAP/P/2000/001729A AP1268A (en) 1997-07-15 1998-06-23 Closed flexible sachet.
JP50626099A JP4049402B2 (ja) 1997-07-15 1998-06-23 密閉した可撓性袋
DK98938628T DK0996578T3 (da) 1997-07-15 1998-06-23 Lukket, fleksibel pose
DE69802537T DE69802537T2 (de) 1997-07-15 1998-06-23 Versiegelter flexibler beutel
EA200000126A EA001241B1 (ru) 1997-07-15 1998-06-23 Закрытый гибкий пакетик
CA002291234A CA2291234A1 (en) 1997-07-15 1998-06-23 Closed flexible sachet
NO20000173A NO318045B1 (no) 1997-07-15 2000-01-13 Lukket, fleksibel pose
US09/482,274 US6347725B1 (en) 1997-07-15 2000-01-13 Closed flexible sachet

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP97202190.1 1997-07-15
EP97202190 1997-07-15

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US09/482,274 Continuation-In-Part US6347725B1 (en) 1997-07-15 2000-01-13 Closed flexible sachet

Publications (1)

Publication Number Publication Date
WO1999003753A1 true WO1999003753A1 (en) 1999-01-28

Family

ID=8228557

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1998/003826 WO1999003753A1 (en) 1997-07-15 1998-06-23 Closed flexible sachet

Country Status (22)

Country Link
EP (1) EP0996578B1 (pt)
JP (1) JP4049402B2 (pt)
AP (1) AP1268A (pt)
AR (1) AR015403A1 (pt)
AT (1) ATE208732T1 (pt)
AU (1) AU731750B2 (pt)
BR (1) BR9811695A (pt)
CA (1) CA2291234A1 (pt)
CO (1) CO4840527A1 (pt)
DE (1) DE69802537T2 (pt)
DK (1) DK0996578T3 (pt)
EA (1) EA001241B1 (pt)
EG (1) EG22403A (pt)
ES (1) ES2166181T3 (pt)
IL (1) IL133094A (pt)
NO (1) NO318045B1 (pt)
OA (1) OA11357A (pt)
PT (1) PT996578E (pt)
SI (1) SI0996578T1 (pt)
TW (1) TW412407B (pt)
WO (1) WO1999003753A1 (pt)
ZA (1) ZA986214B (pt)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000028868A1 (en) 1998-11-16 2000-05-25 Societe Des Produits Nestle S.A. Method and device for extracting the contents of a capsule
US7018428B2 (en) 2002-07-26 2006-03-28 L'oreal Process for the preparation of a dyeing composition for the dyeing of keratinous fibers from pressurized steam
WO2006043098A1 (en) * 2004-10-22 2006-04-27 Kraft Foods R & D, Inc. Flexible pad for preparing a beverage
US7658542B2 (en) 2003-04-01 2010-02-09 Pakerman S.A. Flexible liquid container
US20210086986A1 (en) 2010-07-22 2021-03-25 K-Fee System Gmbh Portion capsule having an identifier

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10215601B4 (de) * 2002-04-10 2005-08-04 Henkel Kgaa Wasserlöslicher Behälter sowie Verfahren zu seiner Herstellung und Verwendung desselben
FR2865646B1 (fr) * 2004-01-29 2009-02-13 Oreal Procede de preparation d'une composition pour le traitement cosmetique des matieres keratiniques a partir de fluide sous pression et d'agents protecteurs
CN104176356A (zh) * 2014-09-03 2014-12-03 陈家山 双层调料包
JP6386681B1 (ja) * 2018-01-10 2018-09-05 日本紙工株式会社 フィルター成型品の製造方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2228374A5 (en) * 1973-05-04 1974-11-29 Tchakirian Auguste Simple, cheap appts. for instant coffee prepn - ensuring full retention of aroma
US4220259A (en) * 1977-12-30 1980-09-02 Societe Generale Pour L'emballage Process and apparatus for at site preparation of beverages
GB2215189A (en) * 1988-03-02 1989-09-20 Mars G B Ltd Beverage brewing using microwave heating
WO1994001344A1 (fr) 1992-07-06 1994-01-20 Societe Des Produits Nestle S.A. Sachet souple ferme et son procede de fabrication

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2228374A5 (en) * 1973-05-04 1974-11-29 Tchakirian Auguste Simple, cheap appts. for instant coffee prepn - ensuring full retention of aroma
US4220259A (en) * 1977-12-30 1980-09-02 Societe Generale Pour L'emballage Process and apparatus for at site preparation of beverages
GB2215189A (en) * 1988-03-02 1989-09-20 Mars G B Ltd Beverage brewing using microwave heating
WO1994001344A1 (fr) 1992-07-06 1994-01-20 Societe Des Produits Nestle S.A. Sachet souple ferme et son procede de fabrication

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000028868A1 (en) 1998-11-16 2000-05-25 Societe Des Produits Nestle S.A. Method and device for extracting the contents of a capsule
US7018428B2 (en) 2002-07-26 2006-03-28 L'oreal Process for the preparation of a dyeing composition for the dyeing of keratinous fibers from pressurized steam
US7658542B2 (en) 2003-04-01 2010-02-09 Pakerman S.A. Flexible liquid container
WO2006043098A1 (en) * 2004-10-22 2006-04-27 Kraft Foods R & D, Inc. Flexible pad for preparing a beverage
US11465829B2 (en) 2010-07-22 2022-10-11 K-Fee System Gmbh Portion capsule having an identifier
US11254491B2 (en) 2010-07-22 2022-02-22 K-Fee System Gmbh Portion capsule having an identifier
US20210086986A1 (en) 2010-07-22 2021-03-25 K-Fee System Gmbh Portion capsule having an identifier
US11465830B2 (en) 2010-07-22 2022-10-11 K-Fee System Gmbh Portion capsule having an identifier
US11542094B2 (en) 2010-07-22 2023-01-03 K-Fee System Gmbh Portion capsule having an identifier
US11548722B2 (en) 2010-07-22 2023-01-10 K-Fee System Gmbh Portion capsule having an identifier
US11554910B2 (en) 2010-07-22 2023-01-17 K-Fee System Gmbh Portion capsule having an identifier
US11667465B2 (en) 2010-07-22 2023-06-06 K-Fee System Gmbh Portion capsule having an identifier
US11820586B2 (en) 2010-07-22 2023-11-21 K-Fee System Gmbh Portion capsule having an identifier
US11919703B2 (en) 2010-07-22 2024-03-05 K-Fee System Gmbh Portion capsule having an identifier

Also Published As

Publication number Publication date
CO4840527A1 (es) 1999-09-27
AR015403A1 (es) 2001-05-02
NO318045B1 (no) 2005-01-24
EA200000126A1 (ru) 2000-06-26
IL133094A0 (en) 2001-03-19
JP2002507953A (ja) 2002-03-12
EP0996578A1 (en) 2000-05-03
AU8728298A (en) 1999-02-10
SI0996578T1 (en) 2002-04-30
DE69802537D1 (de) 2001-12-20
BR9811695A (pt) 2000-09-26
OA11357A (en) 2003-12-17
IL133094A (en) 2003-11-23
JP4049402B2 (ja) 2008-02-20
AP1268A (en) 2004-04-02
ES2166181T3 (es) 2002-04-01
PT996578E (pt) 2002-03-28
EA001241B1 (ru) 2000-12-25
TW412407B (en) 2000-11-21
DE69802537T2 (de) 2002-05-23
ZA986214B (en) 2000-01-13
AP2000001729A0 (en) 2000-03-31
NO20000173L (no) 2000-03-14
AU731750B2 (en) 2001-04-05
EG22403A (en) 2003-01-29
ATE208732T1 (de) 2001-11-15
EP0996578B1 (en) 2001-11-14
NO20000173D0 (no) 2000-01-13
CA2291234A1 (en) 1999-01-28
DK0996578T3 (da) 2002-02-11

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