WO1998059082A1 - Method for treating molten lead with calcium - Google Patents
Method for treating molten lead with calcium Download PDFInfo
- Publication number
- WO1998059082A1 WO1998059082A1 PCT/FR1998/001304 FR9801304W WO9859082A1 WO 1998059082 A1 WO1998059082 A1 WO 1998059082A1 FR 9801304 W FR9801304 W FR 9801304W WO 9859082 A1 WO9859082 A1 WO 9859082A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- calcium
- lead
- sheath
- alloy
- alloys
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B13/00—Obtaining lead
- C22B13/06—Refining
Definitions
- the invention relates to a method for treating lead in the molten state using calcium or calcium alloys, in particular the refining of lead and the preparation of lead-calcium alloys.
- Patent FR 2514786 from the company Extramet proposes using an Mg-Ca alloy containing 25 to 45% Ca in the form of granules injected into the molten lead bath using a carrier gas for the debismuthage of the lead. inert. The manufacture of such granules is described in patent EP 0048713 from the same company. The injection technique effectively improves the yield of treatment, but it requires investment in expensive injection equipment. Subject of the invention
- the object of the present invention is to allow an efficient, simple and economical treatment of lead with calcium while avoiding loss of calcium by oxidation.
- the subject of the invention is a process for treating molten lead with calcium or calcium alloys in which the calcium or its alloys are introduced into the bath continuously and regularly using a cored wire consisting of a charge of calcium or calcium alloys surrounded by a sheath of fusible or decomposable material at a temperature below 700 ° C.
- the invention is based on the idea of using, to avoid premature oxidation of calcium and its alloys on the surface of the lead bath, the cored wire technique commonly used in the steel industry with the aim of obtaining more penetration. depth of the product in liquid iron.
- steel sheathed wires filled with calcium powder are used, often mixed with other powdered products such as iron, lime aluminate or fluxes.
- Pfizer patent EP 0137618 describes an example of the use of this cored wire technique.
- the wires to steel sheath used in the steel industry is not suitable for the treatment of lead, because they lead to an undesirable supply of iron in the lead and the dissolution of the wire is too slow taking into account the temperature of the bath to be treated.
- the cored wire technique can be used effectively and safely provided that the sheath can disappear quickly enough in contact with liquid lead from its melting temperature (327 ° C ), while remaining for some time in the molten bath to allow reaching a sufficient injection depth.
- Good results have been obtained with polymer sheaths, for example polyethylene or polypropylene, or with metallic sheaths with melting point below 700 ° C, for example lead, aluminum or zinc.
- the plastic sheathed wires can be produced either by forming a polymer sheet, or by using a preformed tube, or by a co-extrusion technique, such as that described in patent EP 0559589 in the name of the applicant.
- the metallic sheathed wires can be manufactured according to the usual technique for the sheathed steel sheathed wires, that is to say by roller profiling of a tube with contiguous edges not welded from a metallic strip.
- the charge of calcium or of a calcium alloy can consist of powder or of a mixture of powders of pure metals or their alloys. It can also consist of a solid calcium or calcium alloy wire obtained by extrusion.
- a cored wire according to the invention makes it possible to improve the efficiency of addition of calcium, magnesium and / or aluminum both in the refining of lead and in the development of Pb- alloys. It.
- the calcium and magnesium contents are respectively 420 and 830 ppm, ie an addition yield of 80.5% in Ca and 82% in Mg.
- Example 2 An operation identical to that of Example 1 was carried out with a piece of Mg-Ca alloy at 34%> by weight of calcium. Analysis of the lead after treatment leads to a content of 450 ppm of Ca and 870 ppm of Mg, i.e. an addition yield of 86.5% in Ca and 86.1% in Mg
- Example 2 An operation identical to that of Example 1 was repeated with a cored wire with lead sheath loaded with 34%> by weight of calcium in grains of size between 0.4 and 2 mm, and 66%> of magnesium in grains of size between 0.3 and 0.8 mm
- Analysis of the lead at the end of the treatment indicates a content of 470 ppm of Ca and 900 ppm of Mg, ie an addition yield of 90.3%> in Ca and 89, 1% in Mg, which represents a significant increase compared to the mixture of Example 1 or of the alloy of Example 2
- Example 3 The test of Example 3 was repeated with a composite wire consisting of a solid wire of Mg-Ca alloy with 34% Ca, extruded to a diameter of 12 mm and sheathed with a lead strip of thickness 0.5 mm Analysis of the lead after treatment gives a content of 485 ppm of Ca and 930 ppm of Mg, i.e. an addition yield of 93.2%) of Ca and 92% of Mg
- Example 4 The test of Example 4 is repeated with an extruded wire sheathed with lead of an Mg-Ca alloy containing 20.6% o of Ca Analysis of the lead after treatment gives a content of 295 ppm of Ca and 1,120 ppm of Mg, ie an addition yield of 93% in Ca and 91.7% in Mg It is found that the decrease in the Ca content of the Mg-Ca alloy does not cause any significant difference in the addition yields, or in the dissolution rates.
- This example and the following ones relate to the addition of calcium and aluminum in the molten lead to produce an alloy containing 0.1% Ca and 0.05% Al.
- a charge of 65 kg of lead was melted which was maintained at a temperature of 550 ° C.
- it was necessary to introduce 122 g of Ca and 65 g of Al in pieces ie an addition yield of 53.3% in Ca and 50%> in Al. If we replace the pieces with shot, only 89 g of Ca and 48 g of Al are needed, ie an addition yield of 73% in Ca and 67.7% in Al.
- Example 6 To obtain the same lead alloy as in Example 6, a cored wire with a diameter of 13 mm was used, consisting of an aluminum sheath of 0.7 mm thickness and a load of calcium pellets with particle size ⁇ 2 mm, or 148 g of Ca and 77 g of Al per meter of wire. 0.46 m of wire was required to reach the desired composition of the lead alloy, ie an addition yield of 95% o in Ca and 91% in Al.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Treatment Of Steel In Its Molten State (AREA)
Abstract
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP98932251A EP0991787A1 (en) | 1997-06-23 | 1998-06-23 | Method for treating molten lead with calcium |
AU82211/98A AU8221198A (en) | 1997-06-23 | 1998-06-23 | Method for treating molten lead with calcium |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9708071A FR2764905B1 (en) | 1997-06-23 | 1997-06-23 | PROCESS FOR TREATING MOLTEN LEAD WITH CALCIUM AND CALCIUM-BASED WIRE FOR SUCH TREATMENT |
FR97/08071 | 1997-06-23 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1998059082A1 true WO1998059082A1 (en) | 1998-12-30 |
Family
ID=9508520
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/FR1998/001304 WO1998059082A1 (en) | 1997-06-23 | 1998-06-23 | Method for treating molten lead with calcium |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP0991787A1 (en) |
AU (1) | AU8221198A (en) |
FR (1) | FR2764905B1 (en) |
WO (1) | WO1998059082A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2692358C1 (en) * | 2018-04-06 | 2019-06-24 | Акционерное общество "АКОМ" | Method of crude lead from bismuth refinement |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2807768B1 (en) * | 2000-04-13 | 2002-10-31 | Pechiney Electrometallurgie | PROCESS FOR THE DEBISMUTHAGE OF MOLTEN LEAD WITH CALCIUM AND MAGNESIUM |
US6933468B2 (en) | 2000-10-10 | 2005-08-23 | Hobart Brothers Company | Aluminum metal-core weld wire and method for forming the same |
EP1197288B1 (en) * | 2000-10-10 | 2006-03-29 | Illinois Tool Works Inc. | Aluminum metal-core weld wire |
DE102011080405A1 (en) | 2011-08-04 | 2013-02-07 | Bayer Pharma AG | New substituted 3-biphenyl-3-yl-8,8-difluoro-4-hydroxy-1-azaspiro(4.5)dec-3-en-2-one derivatives useful for prophylaxis or therapy of tumor diseases comprising breast cancer, prostate cancer, colorectal cancer or non-small cell lung cancer |
DE102011080406A1 (en) | 2011-08-04 | 2013-02-07 | Bayer Pharma AG | Substituted 3- (biphenyl-3-yl) -4-hydroxy-8-methoxy-1-azaspiro8 [4.5] dec-3-ene-2-ones |
Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1428041A (en) * | 1920-09-21 | 1922-09-05 | Kroll Guillaume Justine | Process for the separation and recovery of metals from metal alloys |
JPS5472708A (en) * | 1977-11-21 | 1979-06-11 | Hitachi Cable Ltd | Manufacture of linear additive for steel |
JPS5472710A (en) * | 1977-11-21 | 1979-06-11 | Hitachi Cable Ltd | Manufacture of linear additive for steel |
JPS5472750A (en) * | 1977-11-21 | 1979-06-11 | Hitachi Cable Ltd | Manufacture of wire additive for steel |
FR2514786A1 (en) * | 1981-10-20 | 1983-04-22 | Extramet Sa | Bismuth removal from molten lead - using mixt. of calcium-magnesium alloy granules, pref. of eutectic compsn. |
EP0048713B1 (en) * | 1979-12-21 | 1983-12-28 | Extramet | Process for manufacturing metal pellets, product obtained thereby and device for implementing such process |
CH665852A5 (en) * | 1986-05-29 | 1988-06-15 | Fischer Ag Georg | Adding material to metal melt - using non-metallic cover tubing surrounding the material |
EP0137618B1 (en) * | 1983-08-12 | 1988-06-22 | Pfizer Inc. | Process and apparatus for adding calcium to a bath of molten ferrous material |
RU2011685C1 (en) * | 1993-02-09 | 1994-04-30 | Александр Алексеевич Неретин | Method of producing refining calcium additive wire |
EP0559589B1 (en) * | 1992-03-05 | 1995-01-18 | Pechiney Electrometallurgie | Cored wire with a plastic sheath for additions to metal baths |
FR2711376A1 (en) * | 1993-10-19 | 1995-04-28 | Pechiney Electrometallurgie | Composite wire for introducing magnesium into a liquid metal |
-
1997
- 1997-06-23 FR FR9708071A patent/FR2764905B1/en not_active Expired - Fee Related
-
1998
- 1998-06-23 WO PCT/FR1998/001304 patent/WO1998059082A1/en not_active Application Discontinuation
- 1998-06-23 EP EP98932251A patent/EP0991787A1/en not_active Withdrawn
- 1998-06-23 AU AU82211/98A patent/AU8221198A/en not_active Abandoned
Patent Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1428041A (en) * | 1920-09-21 | 1922-09-05 | Kroll Guillaume Justine | Process for the separation and recovery of metals from metal alloys |
JPS5472708A (en) * | 1977-11-21 | 1979-06-11 | Hitachi Cable Ltd | Manufacture of linear additive for steel |
JPS5472710A (en) * | 1977-11-21 | 1979-06-11 | Hitachi Cable Ltd | Manufacture of linear additive for steel |
JPS5472750A (en) * | 1977-11-21 | 1979-06-11 | Hitachi Cable Ltd | Manufacture of wire additive for steel |
EP0048713B1 (en) * | 1979-12-21 | 1983-12-28 | Extramet | Process for manufacturing metal pellets, product obtained thereby and device for implementing such process |
FR2514786A1 (en) * | 1981-10-20 | 1983-04-22 | Extramet Sa | Bismuth removal from molten lead - using mixt. of calcium-magnesium alloy granules, pref. of eutectic compsn. |
EP0137618B1 (en) * | 1983-08-12 | 1988-06-22 | Pfizer Inc. | Process and apparatus for adding calcium to a bath of molten ferrous material |
CH665852A5 (en) * | 1986-05-29 | 1988-06-15 | Fischer Ag Georg | Adding material to metal melt - using non-metallic cover tubing surrounding the material |
EP0559589B1 (en) * | 1992-03-05 | 1995-01-18 | Pechiney Electrometallurgie | Cored wire with a plastic sheath for additions to metal baths |
RU2011685C1 (en) * | 1993-02-09 | 1994-04-30 | Александр Алексеевич Неретин | Method of producing refining calcium additive wire |
FR2711376A1 (en) * | 1993-10-19 | 1995-04-28 | Pechiney Electrometallurgie | Composite wire for introducing magnesium into a liquid metal |
Non-Patent Citations (2)
Title |
---|
DATABASE WPI Section Ch Week 9504, Derwent World Patents Index; Class M21, AN 95-029224 * |
PATENT ABSTRACTS OF JAPAN vol. 003, no. 095 (C - 055) 11 August 1979 (1979-08-11) * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2692358C1 (en) * | 2018-04-06 | 2019-06-24 | Акционерное общество "АКОМ" | Method of crude lead from bismuth refinement |
Also Published As
Publication number | Publication date |
---|---|
FR2764905A1 (en) | 1998-12-24 |
EP0991787A1 (en) | 2000-04-12 |
AU8221198A (en) | 1999-01-04 |
FR2764905B1 (en) | 1999-07-23 |
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