WO1998050510A1 - Composition de nettoyage pour surfaces dures - Google Patents

Composition de nettoyage pour surfaces dures Download PDF

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Publication number
WO1998050510A1
WO1998050510A1 PCT/EP1998/002575 EP9802575W WO9850510A1 WO 1998050510 A1 WO1998050510 A1 WO 1998050510A1 EP 9802575 W EP9802575 W EP 9802575W WO 9850510 A1 WO9850510 A1 WO 9850510A1
Authority
WO
WIPO (PCT)
Prior art keywords
composition according
group
anionic
apg
surfactant
Prior art date
Application number
PCT/EP1998/002575
Other languages
English (en)
Inventor
Giles James Crowley
George Hunter Cullen
Alexander Martin
Original Assignee
Unilever Plc
Unilever N.V.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Unilever Plc, Unilever N.V. filed Critical Unilever Plc
Priority to BR9809320-7A priority Critical patent/BR9809320A/pt
Priority to AU76516/98A priority patent/AU722809B2/en
Priority to PL98336659A priority patent/PL336659A1/xx
Priority to CA002288303A priority patent/CA2288303A1/fr
Priority to JP54771098A priority patent/JP2001523292A/ja
Priority to EP98924259A priority patent/EP0980419A1/fr
Publication of WO1998050510A1 publication Critical patent/WO1998050510A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/43—Solvents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2006—Monohydric alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/33—Amino carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives

Definitions

  • the present invention relates to a composition for hard surface cleaning.
  • Limescale mainly comprises calcium and magnesium carbonates, and can contain lesser amounts of soap scum, protein, particulates and other soils. Limescale is formed on evaporation of water containing said soils. While the deposit formed by evaporation is initially paste-like, it hardens with time to form a recalcitrant deposit.
  • Conventional cleaning compositions are generally buffered at alkaline pH so as to attack fatty soils. Limescale is resistant to the action of alkali and specialist cleaning compositions, of acid pH, are generally used to remove it.
  • 'Soap-scum' is a deposit formed by the reaction of soaps with metal ions. Soap-scum differs from limescale in that it is removed better under alkaline conditions and acid cleaners are generally poor at removing soap-scum.
  • the present invention provides a hard surface cleaning composition of pH 7-13 comprising:
  • a surfactant selected from the group comprising anionic sulphate, anionic sulphonate, alkyl poly glycoside and mixtures thereof,
  • a solvent selected from the group comprising hexanol, methyl digol, methanol and mixtures thereof.
  • compositions of the present invention are believed to be less damaging but have high contact angles and consequently wet soils and surfaces poorly.
  • wetting is improved by the addition of, for example, hexanol as solvent or that overall desorption of the soil particles is effected by the addition of, for example, methanol.
  • compositions of the invention comprise total surfactant levels of 2-8% on product, preferably around 4% on product.
  • total surfactant levels of 2-8% on product, preferably around 4% on product.
  • all levels of components are given as %wt on product unless stated as otherwise.
  • Suitable anionic surfactants for use in the compositions of the invention include: secondary alkane sulphonates, fatty acid ester sulphonates, dialkyl sulphosuccininates , alpha- olefin sulphonates, primary alkyl sulphates, alkylbenzene sulphonates and alkyl ether sulphates .
  • the most preferred anionic is primary alkyl sulphate (PAS) and this preferably comprises the major part (i.e. 50% or more) of the surfactant present.
  • PAS primary alkyl sulphate
  • the PAS comprises a mixture of materials of the general formulation:
  • R is a C 8 to C ⁇ ⁇ primary alkyl group and M is an equivalent cation.
  • M is preferably an alkali metal or ammonium or substituted ammonium. Sodium is preferred as cation.
  • Preferred alkyl polyglycosides have an alkyl chain comprising C 6 -i6 and it is preferred that more than 50%wt of the APG present in the compositions of the invention comprises a C 6 - ⁇ o alkyl APG. It is particularly preferred that the APG as a chain length of around C8.
  • the preferred degree of polymerisation is 1.1-1.6, more preferably 1.3- 1.5.
  • Suitable materials include GLUCOPON 225 and GLUCOPON 600 (both RTM ex HENKEL) . It was noted that compositions which comprise both the APG surfactant and hexanol spread over surfaces with particular ease to give very thin surface films.
  • the weight ratio of APG to anionic lies in the range 1:10-10:1 as anionic :APG.
  • compositions of the invention are free of ethoxylated alcohol nonionic surfactants.
  • the sequestering agents present in the composition of the invention are preferably organic and include the di and tricarboxylic acids such as adipate, glutarate, succinate, maleate and citrate.
  • Suitable sequestering materials include nitrillo triacetic acid (NTA) , methylglycine diacetic acid (MGDA) and ethylene diamine tetraacetic acid (EDTA) .
  • Preferred sequesterants are of the general formula:
  • R CH3 , CH2COOH or CH20H.
  • Typical levels of the sequestering agent in the compositions of the invention are l-10%wt, more preferably 2-7%wt, most preferably 2.5-6 or around 4%wt on product.
  • Hexanol is the preferred solvent at levels of 0.5-2%, more preferably 0.5-1%. At levels of hexanol above 2% surface damage can occur and usage at this level should be avoided for surfaces which are sensitive to this solvent.
  • compositions of the invention are free of solvents selected from the group comprising propylene glycol n-butyl ether and 2-butoxy ethanol .
  • Preferred final product viscosities are in the range 6-15 centipoise with viscosities of 8-10 centipoise being particularly preferred.
  • Preferred thickeners are polymers giving the required viscosity provided that they are compatible with the ionic strength of the composition.
  • the thickeners are non-charged polymers or nonionic/anionic saccharide polymers. These are preferably polysaccharrides and particularly xanthan gums and/or nonionic guar gums. Materials sold under the tradename KELZAN are especially suitable, as are materials sold under the tradename TYLOSE, such as TYLOSE H4000P. Charged thickener species are less preferred as these can salt out of solution, however it is envisaged that charged polymers, for example polyacrylates could be used when low levels of MGDA are present.
  • Typical levels of polymer are 0.05-0.5%, preferably around 0.1%. Polymer was found to be particularly effective in maintaining a stiff foam in the products of the invention which also contained APG. Minors :
  • Hydrotrope can be present in the compositions as required to improve the low temperature stability of the composition.
  • Suitable hydrotropes include the aromatic sulphonates, particularly benzene, toluene and cumene sulphonates at preferred levels of 0-6%wt, more preferably 1-2%.
  • pH regulants can be present to bring the compositions to the preferred pH of 9-12, more preferably to around pH 10. This can however be achieved without buffering systems in the presence of a sequesteran .
  • the alkaline pH is particularly preferred in the presence of the sequestering agents with a pK a >5 as these are believed to be most effective in a fully ionised form and generally ionise at markedly alkaline pH.
  • compositions of the invention is in the form of a clinging foam or other slow- draining product form, preferably delivered to the surface being cleaned in the form of a spray.
  • compositions comprise:
  • a surfactant selected from the group comprising anionic sulphate, anionic sulphonate, alkyl poly glycoside and mixtures thereof,
  • compositions were made up by simple mixing of the components in the levels indicated in Tables 1A, IB, 1C and 2A & 2B below, in water.
  • Tables 1A, IB & 1C show comparative examples while Tables 2A & B show compositions according to the present invention.
  • Tables 1A, IB, 1C and 2A & B ' Al ' is the level of surfactant present and 'A2' the level of any further main surfactant species.
  • the type and level of sequesterant is identified in the column headed 'Seq' and the solvent type and level is given for each formulation.
  • 'C is a cleaning score further described below;
  • 'V the viscosity of the product and 'Per' and 'Ena' the contact angles on perspex and enamel respectively as described below.
  • the tables also provide observations which include the time to soil deflocculation or break-up as seen under the microscope.
  • Tetracosane 24g 1. .19%
  • the Perspex substrates used are 10 x 10 cm black Perspex [TM] (ex. ICI) tiles and are prepared in the following way:
  • the protective backing film is first removed from the tiles .
  • the tiles are then placed on the WIRA (Wool Industries Research Abrasion Tester) machine for uniform scratching.
  • the total pressure applied is 252.5g.cm 2 on a 3.8cm 2 head (this equates to a total assembly mass of 959.6g applied to an area of 3.8cm 2 ) .
  • a piece of P600 grade wet and dry abrasive paper is fitted to the head and the tiles are scratched for 34 cycles on each side of the tiles.
  • the tiles are then cleaned with either 10% nonionic or hand dishwash liquid to remove perspex residues and grease.
  • the tiles are then rinsed and finally cleaned in methylated spirits to ensure that they are absolutely clean.
  • Tiles can be cleaned and reused. To do this the tiles must be washed in washing up liquid and then soaked in ethanolic potassium hydroxide for one hour or more. The tiles are then rinsed and washed in methylated spirits before being allowed to dry.
  • Soil is applied to the Perspex tiles as follows: for each set of ten tiles:
  • coco soap commercial 'Shield' (TM) soap was used
  • 0.75g 'Artificial Sebum' and 70-80g normally 75g distilled water are all placed in a 250cm 3 beaker.
  • the prepared soil is then added to 7.5 litres of tap water (approximately 10°FH see note below) and quickly stirred in until large amounts of foam have subsided and a scum is produced.
  • the tiles are then dipped in the soil whilst being suspended from a rack.
  • the soiled tiles are then left in racks overnight (approx 15 hours) at room temperature to dry and age.
  • Formulations can be delivered to both vertical surfaces or horizontal surfaces, as differences are seen due to drainage rates and viscosity effects.
  • Each of the formulations is applied by a manually operated spray pack, in this case a finger pump type spray with about 3 to 8 sprays given per soiled surface (back and front) .
  • the typical amount of formulation delivered is 0.12-0.15g per spray.
  • the formulation is left in contact with the tiles for either 30 seconds or 1 minute.
  • the tile is rinsed under the tap until it is as clean as possible, in all cases the same flow rate of water is used and the rinsing process is carried out at the same distance from the tap.
  • the performance of the cleaners can then be assessed by means of subjective visual examination. This is done by assigning a cleaning score to each tile on a scale of 1 to 6 as follows:
  • Tiles are washed and scrubbed with Jif LAC [TM] (a liquid abrasive cleaner) and hot water. They are then rinsed.
  • TM a liquid abrasive cleaner
  • a heaped spatula (approximately 5g) of fine calcite powder is placed on the tiles and they are then scrubbed with a damp cloth. 4. The tiles are then rinsed with de ineralised water. The tiles are deemed to be clean if the surface is completely hydrophillic (ie: the water forms a constant film and does not bead) .
  • the tiles are dried and then wiped with a paper tissue before use.
  • Grade Reagent made up to 100% with isopropyl alcohol. This mixture is mixed using a Silverson stirrer/homogeniser at full speed for 5 minutes. The soil is sprayed on to the tiles to give a nominal coverage of 2.28mg/cm2 (without solvent ). This gives a coverage of 0.0176g/cm2 when spraying the tile ( i.e. with solvent present ). The coated tiles are placed in an oven at 180 degrees Celsius for 35 minutes. The tiles are then allowed to cool to room temperature before use.
  • Viscosity was measured so as to give only a guide and a relative measure of viscosity.
  • a U-tube Viscometer was employed and used in accordance with International Standards ISO 3104-1976 and 3105-1976. All measurements were made at 25°C.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Abstract

L'invention concerne une composition de nettoyage pour surfaces dures. Cette composition présente un pH compris entre 7 et 13, et comporte: (a) un tensio-actif sélectionné dans le groupe comprenant du sulfate anionique, du sulfonate anionique, de l'alkyl poly-glycoside et des mélanges de ces derniers; (b) un agent chélateur pour les métaux du groupe II et (c) un solvant sélectionné dans le groupe comprenant de l'héxanol et du méthyle digol.
PCT/EP1998/002575 1997-05-02 1998-04-23 Composition de nettoyage pour surfaces dures WO1998050510A1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
BR9809320-7A BR9809320A (pt) 1997-05-02 1998-04-23 Composição de limpeza de superfìcies duras
AU76516/98A AU722809B2 (en) 1997-05-02 1998-04-23 Hard surface cleaning composition
PL98336659A PL336659A1 (en) 1997-05-02 1998-04-23 Compositions fro cleaning hard surfaces
CA002288303A CA2288303A1 (fr) 1997-05-02 1998-04-23 Composition de nettoyage pour surfaces dures
JP54771098A JP2001523292A (ja) 1997-05-02 1998-04-23 硬質表面洗浄用組成物
EP98924259A EP0980419A1 (fr) 1997-05-02 1998-04-23 Composition de nettoyage pour surfaces dures

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB9709065.8A GB9709065D0 (en) 1997-05-02 1997-05-02 Improvements relating to hard surface cleaning
GB9709065.8 1997-05-02

Publications (1)

Publication Number Publication Date
WO1998050510A1 true WO1998050510A1 (fr) 1998-11-12

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ID=10811800

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1998/002575 WO1998050510A1 (fr) 1997-05-02 1998-04-23 Composition de nettoyage pour surfaces dures

Country Status (11)

Country Link
EP (1) EP0980419A1 (fr)
JP (1) JP2001523292A (fr)
AR (1) AR012507A1 (fr)
AU (1) AU722809B2 (fr)
BR (1) BR9809320A (fr)
CA (1) CA2288303A1 (fr)
GB (1) GB9709065D0 (fr)
HU (1) HUP0002976A2 (fr)
PL (1) PL336659A1 (fr)
WO (1) WO1998050510A1 (fr)
ZA (1) ZA983667B (fr)

Cited By (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0864638A2 (fr) * 1997-03-12 1998-09-16 Showa Denko Kabushiki Kaisha Composition détergente
EP0893490A2 (fr) * 1997-07-25 1999-01-27 Henkel Kommanditgesellschaft auf Aktien Composition adoucissante pour tissus sans azote
WO2000071661A1 (fr) * 1999-05-21 2000-11-30 Reckitt Benckiser Inc. Compositions aqueuses de nettoyage de surfaces dures a faible residu particulierement adaptees pour le nettoyage de surfaces dures en verre brillantes
WO2001037658A2 (fr) * 1999-11-23 2001-05-31 Cognis Deutschland Gmbh & Co.Kg Tensioactifs concentres a faible pouvoir moussant a utiliser dans le domaine de la stimulation de croissance vegetale
WO2002066590A1 (fr) * 2000-12-12 2002-08-29 Colgate-Palmolive Company Detergent liquide degraissant pour lavages delicats
EP1411113A1 (fr) * 2001-07-24 2004-04-21 Kao Corporation Composition de pretraitement de blanchissage pour vetements
FR2847164A1 (fr) * 2002-11-19 2004-05-21 Oreal Sebum artificiel
EP1803801A1 (fr) * 2006-01-03 2007-07-04 Basf Aktiengesellschaft Poudre ou granule basés sur acide glutamique-N,N-diacetique et leurs sels
WO2008155160A1 (fr) * 2007-06-18 2008-12-24 Henkel Ag & Co. Kgaa Lessives ou détergents liquides hautement moussants, présentant une viscosité stable
WO2011100344A1 (fr) * 2010-02-09 2011-08-18 Basf Se Composition de détergent
US8262805B2 (en) 2010-08-23 2012-09-11 Ecolab Usa Inc. Poly sulfonate functionalized alkyl polyglucosides for enhanced food soil removal
US8283302B2 (en) 2010-06-21 2012-10-09 Ecolab Usa Inc. Alkyl polypentosides and alkyl polyglucosides (C8-C11) used for enhanced food soil removal
US8287659B2 (en) 2010-08-23 2012-10-16 Ecolab Usa Inc. Poly phosphate functionalized alkyl polyglucosides for enhanced food soil removal
US8299009B2 (en) 2010-06-21 2012-10-30 Ecolab Usa Inc. Betaine functionalized alkyl polyglucosides for enhanced food soil removal
US8329633B2 (en) 2010-09-22 2012-12-11 Ecolab Usa Inc. Poly quaternary functionalized alkyl polyglucosides for enhanced food soil removal
US8389457B2 (en) 2010-09-22 2013-03-05 Ecolab Usa Inc. Quaternary functionalized alkyl polyglucosides for enhanced food soil removal
US8460477B2 (en) 2010-08-23 2013-06-11 Ecolab Usa Inc. Ethoxylated alcohol and monoethoxylated quaternary amines for enhanced food soil removal
US8658584B2 (en) 2010-06-21 2014-02-25 Ecolab Usa Inc. Sulfosuccinate functionalized alkyl polyglucosides for enhanced food and oily soil removal
US8877703B2 (en) 2010-09-22 2014-11-04 Ecolab Usa Inc. Stearyl and lauryl dimoniumhydroxy alkyl polyglucosides for enhanced food soil removal
US9089251B2 (en) 2011-10-14 2015-07-28 Ecolab Usa Inc. Method of removing and preventing redeposition of protein soils using sugar esters
FR3022783A1 (fr) * 2014-06-30 2016-01-01 Oreal Sebum artificiel
US11834624B2 (en) 2014-03-07 2023-12-05 Ecolab Usa Inc. Alkyl amides for enhanced food soil removal and asphalt dissolution
US11834629B2 (en) 2019-12-17 2023-12-05 The Procter & Gamble Company Cleaning product
US11834627B2 (en) 2019-12-17 2023-12-05 The Procter & Gamble Company Cleaning product

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9926516B2 (en) * 2014-06-05 2018-03-27 The Procter & Gamble Company Mono alcohols for low temperature stability of isotropic liquid detergent compositions
JP6768282B2 (ja) * 2015-10-21 2020-10-14 ライオン株式会社 浴室用液体洗浄剤
KR102468091B1 (ko) * 2014-12-26 2022-11-18 라이온 가부시키가이샤 욕실용 액체 세정제
JP6770797B2 (ja) * 2015-10-21 2020-10-21 ライオン株式会社 浴室用液体洗浄剤

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2338052A1 (fr) * 1976-01-13 1977-08-12 United States Borax Chem Composition antimicrobienne de nettoyage
EP0151517A2 (fr) * 1984-01-17 1985-08-14 Unilever N.V. Composition détergente liquide
JPH0741799A (ja) * 1993-08-02 1995-02-10 Chichibu Onoda Cement Corp コンクリート製品用洗浄剤

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2338052A1 (fr) * 1976-01-13 1977-08-12 United States Borax Chem Composition antimicrobienne de nettoyage
EP0151517A2 (fr) * 1984-01-17 1985-08-14 Unilever N.V. Composition détergente liquide
JPH0741799A (ja) * 1993-08-02 1995-02-10 Chichibu Onoda Cement Corp コンクリート製品用洗浄剤

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Week 9516, Derwent World Patents Index; AN 95-118958, XP002074642 *

Cited By (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0864638A2 (fr) * 1997-03-12 1998-09-16 Showa Denko Kabushiki Kaisha Composition détergente
EP0864638A3 (fr) * 1997-03-12 1999-04-28 Showa Denko Kabushiki Kaisha Composition détergente
EP0893490A2 (fr) * 1997-07-25 1999-01-27 Henkel Kommanditgesellschaft auf Aktien Composition adoucissante pour tissus sans azote
EP0893490A3 (fr) * 1997-07-25 2002-10-02 Henkel Kommanditgesellschaft auf Aktien Composition adoucissante pour tissus sans azote
WO2000071661A1 (fr) * 1999-05-21 2000-11-30 Reckitt Benckiser Inc. Compositions aqueuses de nettoyage de surfaces dures a faible residu particulierement adaptees pour le nettoyage de surfaces dures en verre brillantes
WO2001037658A2 (fr) * 1999-11-23 2001-05-31 Cognis Deutschland Gmbh & Co.Kg Tensioactifs concentres a faible pouvoir moussant a utiliser dans le domaine de la stimulation de croissance vegetale
WO2001037658A3 (fr) * 1999-11-23 2001-12-27 Cognis Deutschland Gmbh Tensioactifs concentres a faible pouvoir moussant a utiliser dans le domaine de la stimulation de croissance vegetale
WO2002066590A1 (fr) * 2000-12-12 2002-08-29 Colgate-Palmolive Company Detergent liquide degraissant pour lavages delicats
EP1411113A4 (fr) * 2001-07-24 2005-04-20 Kao Corp Composition de pretraitement de blanchissage pour vetements
EP1411113A1 (fr) * 2001-07-24 2004-04-21 Kao Corporation Composition de pretraitement de blanchissage pour vetements
FR2847164A1 (fr) * 2002-11-19 2004-05-21 Oreal Sebum artificiel
CN101351539B (zh) * 2006-01-03 2012-12-05 巴斯夫欧洲公司 基于谷氨酸-n,n-二乙酸及其盐的混合粉末或混合颗粒
EP1803801A1 (fr) * 2006-01-03 2007-07-04 Basf Aktiengesellschaft Poudre ou granule basés sur acide glutamique-N,N-diacetique et leurs sels
WO2007077143A1 (fr) * 2006-01-03 2007-07-12 Basf Se Melange de poudres ou melange de granules a base d’acide glutaminique-n,n-acide diacetique et leurs sels
US7867966B2 (en) 2006-01-03 2011-01-11 Basf Aktiengesellschaft Mixed powder or mixed granule based on glutamic acid-N, N-diacetic acid and salts thereof
WO2008155160A1 (fr) * 2007-06-18 2008-12-24 Henkel Ag & Co. Kgaa Lessives ou détergents liquides hautement moussants, présentant une viscosité stable
WO2011100344A1 (fr) * 2010-02-09 2011-08-18 Basf Se Composition de détergent
US8283302B2 (en) 2010-06-21 2012-10-09 Ecolab Usa Inc. Alkyl polypentosides and alkyl polyglucosides (C8-C11) used for enhanced food soil removal
US8658584B2 (en) 2010-06-21 2014-02-25 Ecolab Usa Inc. Sulfosuccinate functionalized alkyl polyglucosides for enhanced food and oily soil removal
US8299009B2 (en) 2010-06-21 2012-10-30 Ecolab Usa Inc. Betaine functionalized alkyl polyglucosides for enhanced food soil removal
US8262805B2 (en) 2010-08-23 2012-09-11 Ecolab Usa Inc. Poly sulfonate functionalized alkyl polyglucosides for enhanced food soil removal
US8460477B2 (en) 2010-08-23 2013-06-11 Ecolab Usa Inc. Ethoxylated alcohol and monoethoxylated quaternary amines for enhanced food soil removal
US8287659B2 (en) 2010-08-23 2012-10-16 Ecolab Usa Inc. Poly phosphate functionalized alkyl polyglucosides for enhanced food soil removal
US10655085B2 (en) 2010-09-22 2020-05-19 Ecolab Usa Inc. Stearyl and lauryl dimoniumhydroxy alkyl polyglucosides for enhanced food soil removal
US8557760B2 (en) 2010-09-22 2013-10-15 Ecolab Usa Inc. Quaternary functionalized alkyl polyglucosides for enhanced food soil removal
US8389457B2 (en) 2010-09-22 2013-03-05 Ecolab Usa Inc. Quaternary functionalized alkyl polyglucosides for enhanced food soil removal
US8877703B2 (en) 2010-09-22 2014-11-04 Ecolab Usa Inc. Stearyl and lauryl dimoniumhydroxy alkyl polyglucosides for enhanced food soil removal
US10035975B2 (en) 2010-09-22 2018-07-31 Ecolab Usa Inc. Stearyl and lauryl dimoniumhydroxy alkyl polyglucosides for enhanced food soil removal
US8329633B2 (en) 2010-09-22 2012-12-11 Ecolab Usa Inc. Poly quaternary functionalized alkyl polyglucosides for enhanced food soil removal
US9089251B2 (en) 2011-10-14 2015-07-28 Ecolab Usa Inc. Method of removing and preventing redeposition of protein soils using sugar esters
US11834624B2 (en) 2014-03-07 2023-12-05 Ecolab Usa Inc. Alkyl amides for enhanced food soil removal and asphalt dissolution
FR3022783A1 (fr) * 2014-06-30 2016-01-01 Oreal Sebum artificiel
US11834629B2 (en) 2019-12-17 2023-12-05 The Procter & Gamble Company Cleaning product
US11834627B2 (en) 2019-12-17 2023-12-05 The Procter & Gamble Company Cleaning product

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HUP0002976A2 (hu) 2000-12-28
AU7651698A (en) 1998-11-27
PL336659A1 (en) 2000-07-03
CA2288303A1 (fr) 1998-11-12
JP2001523292A (ja) 2001-11-20
AU722809B2 (en) 2000-08-10
AR012507A1 (es) 2000-10-18
ZA983667B (en) 1999-11-01
EP0980419A1 (fr) 2000-02-23
GB9709065D0 (en) 1997-06-25
BR9809320A (pt) 2000-07-04

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