WO1998003686A1 - Formage de metaux semi-solides - Google Patents

Formage de metaux semi-solides Download PDF

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Publication number
WO1998003686A1
WO1998003686A1 PCT/AU1997/000458 AU9700458W WO9803686A1 WO 1998003686 A1 WO1998003686 A1 WO 1998003686A1 AU 9700458 W AU9700458 W AU 9700458W WO 9803686 A1 WO9803686 A1 WO 9803686A1
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WO
WIPO (PCT)
Prior art keywords
temperature
metal
molten metal
forming
casting
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Application number
PCT/AU1997/000458
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English (en)
Inventor
Gabriela Tausig
Kenong Xia
Original Assignee
The University Of Melbourne
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The University Of Melbourne filed Critical The University Of Melbourne
Priority to AU34301/97A priority Critical patent/AU729897B2/en
Priority to EP97930263A priority patent/EP0958387A4/fr
Priority to JP10506382A priority patent/JP2000514717A/ja
Priority to US09/214,643 priority patent/US6311759B1/en
Publication of WO1998003686A1 publication Critical patent/WO1998003686A1/fr

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21J—FORGING; HAMMERING; PRESSING METAL; RIVETING; FORGE FURNACES
    • B21J5/00—Methods for forging, hammering, or pressing; Special equipment or accessories therefor
    • B21J5/004—Thixotropic process, i.e. forging at semi-solid state
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D7/00—Modifying the physical properties of iron or steel by deformation
    • C21D7/13—Modifying the physical properties of iron or steel by deformation by hot working
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C1/00—Making non-ferrous alloys
    • C22C1/12—Making non-ferrous alloys by processing in a semi-solid state, e.g. holding the alloy in the solid-liquid phase
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S164/00—Metal founding
    • Y10S164/90—Rheo-casting

Definitions

  • the present invention relates to a process for producing metal articles using thixoforming.
  • Semisolid metal processing is generally used to refer to any processing of a metal alloy at temperatures between the solidus and liquidus temperatures of that alloy.
  • Semisolid metal processing involves producing a thixotropic material that comprises a mixture or slurry of solid metal particles and molten (or liquid) metal and subsequently forming or shaping the thixotropic material.
  • the term "semi-solid metal processing" conventionally encompasses both the methods of producing the thixotropic material and the subsequent forming or shaping of the thixotropic material.
  • rheoprocessing in which an alloy is fully melted by heating to a temperature above the liquidus temperature and the melt is then cooled to a temperature between the solidus and liquidus temperature to thereby produce the thixotropic material, and subsequently forming or shaping the thixotropic material.
  • An example of rheoprocessing is rheocasting; and b) thixoforming, in which a semisolid metal processing feedstock is produced by cooling a semisolid slurry to fully solidify the metal. The feedstock is then reheated to a temperature between the solidus and liquidus temperatures to produce a thixotropic material just prior to being shaped.
  • Thixoforming processes are further subdivided, if rather arbitrarily, into categories according to the conventional metal shaping technologies with which they are comparable in terms of general processing and especially in terms of the actual machinery used for metal shaping.
  • thixocasting is based on liquid metal die casting technology, where as thixoforging is more akin to solid metal forging, for example, in the use of vertical forging presses in shaping of the articles. While there seems to be some difficulty in literature and the industry in drawing a clear line between thixocasting and thixoforging processes, there is a clear distinction between thixoforming and conventional metal processing (e.g. casting and forging).
  • Thixoforming is a new development in metal shaping processes in that the metal is being shaped in its partially solid, partially liquid (i.e. semisolid) state, rather than in the fully liquid (casting) or fully solid (forging) state.
  • a basic requirement for an alloy to be satisfactorily used in a thixoforming process is that the alloy has a globular, non- dendritic microstructure which when reheated to the partially solid/partially liquid state forms a slurry of solid globular particles of primary phase suspended in a lower melting point constituent which is the liquid component of the slurry. It is such a slurry which is subsequently thixoformed.
  • Thixoforming has many advantages over conventional forging operations. Most of these are directly related to the excellent flow characteristics of semisolid thixotropic materials. The forming stresses are up to four orders of magnitude lower in the semisolid state for thixotropic materials.
  • Brinegar et al in U.S. Patent No. 4,832,1 12 describe a method of forming a fine grained equiaxed castings from molten metals to produce ingots, forging preforms and investment castings.
  • the method described in this patent relates mainly to superalloys used in the aerospace industry and is directed towards producing a chemically homogeneous, fine grained and sound product.
  • the method involves melting a metal with the temperature of the molten metal being reduced to remove almost all of the superheat in the molten metal.
  • the molten metal is placed in a mould and solidified by extracting heat from the mixture at a rate to solidify the molten metal to form the solid article and to obtain a substantially equiaxed cellular microstructure uniformly throughout the article.
  • turbulence is induced in the molten metal prior to its introduction to the mould or while it is in the mould.
  • U.S. 4,832,1 12 suggests that the temperature of the molten metal have, at the time of casting, a temperature that is within 20°F (11.1°C) above the measured melting point of the metal.
  • U.S. 4,832,112 is used to make investment castings, ingots or forging preforms.
  • the patent makes no mention of thixoforming and indeed the emphasis in this patent on the fine grain size for improved forgeability and improved properties in an investment casting would teach the skilled person away from post treatment of the product of U.S. 4,832, 1 12 by thixoforming as the partial remelting required in thixoforming potentially would cause coarsening of the grain size.
  • the present invention provides a process for producing a solid article including the steps of melting a metal alloy to produce a molten metal, reducing the temperature of the molten metal to a temperature of from substantially the liquidus temperature to about 10°C above the liquidus temperature, casting said molten metal at said temperature, solidifying the cast metal to produce a solidified metal, partially remelting the solidified metal by heating the solidified metal to a temperature between the solidus temperature and the liquidus temperature to produce a thixotropic material and forming the thixotropic material to a desired shape.
  • the present inventors have discovered that by very carefully controlling the temperature of the molten metal at casting to a temperature of from substantially the liquidus temperature to about 10°C above the liquidus temperature, the solidified metal thus obtained is especially suitable for use in thixoforming and indeed significant and surprising advantages accrue in the subsequent thixoforming process.
  • the present inventors have also discovered that very beneficial results are obtained if the temperature of the molten metal at casting is within the range of from the liquidus temperature to about 5°C above the liquidus temperature and this temperature range represents a preferred embodiment of the present invention. Even more preferably, the temperature of the molten melt at casting is within the range of from the liquidus temperature to about 2°C above the liquidus temperature. Most preferably, the molten metal is cast at the liquidus temperature.
  • control of temperature in molten metal casting requires that the temperature of the molten metal be measured and that the temperature of the molten metal be controlled. Both temperature measurement and temperature control will have a degree of uncertainty associated therewith.
  • temperature control it is desired to control the temperature of a pool of molten metal, which is typically held in a furnace, ladle or holding vessel.
  • accurate temperature control depends on several factors including the volume of metal, the furnace type and configuration, casting method and the temperature control system used.
  • Good temperature control can be achieved with the right temperature control and monitoring system, but would become progressively more difficult as the volume of melt to be held at precisely or within a couple of degrees of the target temperature, increases.
  • the spatial temperature distribution (temperature uniformity) within a volume of melt is best measured by a number of probes distributed throughout the volume. The number and placement of probes would depend on the desired accuracy.
  • the probe output should be linked to furnace control which can then adjust input power to keep the melt within a specified temperature range.
  • furnace control which can then adjust input power to keep the melt within a specified temperature range.
  • the ease and speed of achieving this of course depends on the furnace itself and the sensitivity and programming of its control systems. Again, the degree of accuracy achievable should be specified by equipment manufacturers, and give acceptable confidence interval.
  • High volume continuous type casting production tends to have quite sophisticated temperature control systems as the casting temperature is an important and sensitive variable irrespective of the actual casting temperature. It is not unusual to achieve temperature uniformity to well within and better than 5°C if so required, in large volumes of metal.
  • the casting procedure will also play an important role in temperature control.
  • the molten metal cannot be simply held in a ladle from which it is scooped out and put into moulds.
  • the holding vessel will most likely need to be a well controlled furnace with preferably bottom pouring type arrangement, or a tilting furnace. This would ensure that the remaining metal pool is kept at the right temperature while casting proceeds.
  • current temperature control techniques allow the temperature of the molten metal to be controlled to the accuracy required by the present invention.
  • current techniques will allow the temperature to be set at the liquidus temperature and controlled to within 5°C above that temperature.
  • the present inventors have achieved temperature control to within 2°C of the desired temperature in the experimental work conducted in relation to the present invention.
  • the lower limit of temperature range for casting is the liquidus temperature or no more than 2°C below the liquidus temperature. It will be appreciated that it is preferred that the temperature of the molten metal is kept at or above the liquidus temperature (within the upper limits prescribed above) prior to casting to minimise or avoid solidification in the vessel containing the molten metal.
  • the solidified metal can be partially remelted and thixoformed and that significant benefits accrue in the thixoforming process.
  • the processing windows for the thixoforming process are larger.
  • Tests conducted by the present inventor have shown that thixoforming can be easily conducted using high solids fraction, low die temperature and low forming speed whereas other materials would require lower solids fraction and higher forming speeds to obtain similar results.
  • Lower forming speeds and die temperatures would ease wear and maintenance on the thixoforming equipment whilst allowing the specification of lower cost materials of construction in the thixoforming apparatus.
  • High solids fraction may be desirable because the flow pattern formed into the final article under conditions of thixoforming at high solids content has the potential to enhance the strength of the final article.
  • the molten metal is cast at precisely its liquidus temperature.
  • the solidified metal produced from casting of the molten metal and subsequent solidification is preferably in the form of a billet or ingot.
  • the solidified metal has been found to have an as-cast microstructure that contains independent globules separated by a phase of lower melting point material (normally eutectic phase).
  • a phase of lower melting point material normally eutectic phase.
  • Upon heating the solidified metal to a temperature between the solidus and liquidus temperatures a semi-solid material or slurry comprising solid particles and molten metal alloy is obtained. Due to the morphology of the solidified metal, in having a globular primary grain structure, it is not necessary to hold the semi-solid material at the thixoforming temperature for any length of time before thixoforming the material.
  • H13 tool 0.32-0.45 C, 0.20-0.50 Mn, 0.80-1.2 Si, 4.75-5.50 Cr, 1.10-1.75 Mo, 0.80-1.75 V
  • the step of casting the molten metal at a temperature of from substantially the liquidus temperature to about 10°C above the liquidus temperature may comprise casting the molten metal into a mould, preferably a steel mould, with the mould being at ambient temperature or at an elevated temperature.
  • the casting step may include continuously or semi-continuously casting the molten metal, for example, to form billet or ingot.
  • the casting apparatus may be supplied with molten metal from a source of molten metal held at substantially the liquidus temperature.
  • a holding furnace or other source of molten metal may hold the molten metal at a temperature above the liquidus temperature and the molten metal may be cooled to substantially the liquidus temperature when or after the molten metal is transferred to the casting apparatus.
  • the thixotropic material is preferably self supporting in that it will hold its shape in the absence of applied external forces.
  • the semi-solid or thixotropic material formed by partially remelting the solidified metal preferably contains a solids fraction of from 0.6 to 0.8, by volume.
  • the forming speed used during thixoforming may be relatively low and the die temperature during thixoforming may also be relatively low. For example, the forming speed may fall within the range of about O.lm/s to about 0.2m/s.
  • the die temperature may fall within the range of about 150°C to about 300°C
  • the process of the present invention allows a combination of thixoforming operating parameters to be used that had conventionally been believed to be unsuitable for producing articles other than simple test components.
  • the combination of thixoforming operating parameters that can be used in the present invention include high solid content in the semi-solid material, low forming speed and low die temperature.
  • Figure 1 shows a photomicrograph of the microstructure obtained by casting aluminium alloy 2618 from its liquidus temperature
  • Figure 2 shows a photomicrograph of the microstructure obtained by casting aluminium alloy 2618 from a temperature of 50-60°C above its liquidus temperature
  • Figure 3 shows a photomicrograph of the metal casting shown in Figure 1 after the casting has been heated to a temperature between the solidus and liquidus temperature;
  • Figure 4 shows a photomicrograph of an article formed by thixoforming the material shown in Figure 3;
  • Figure 5 shows a schematic diagram of the thixoforming process used in the present invention
  • Figure 6 shows a cross-sectional, side elevation of a clutch hub formed in accordance with the present invention
  • Figure 7 shows a sectional view of the clutch hub shown in Figure 6 showing regions of heavy flow and recrystallisation in a clutch hub formed from thixotropic material having a solid content of 75-80% by volume;
  • Figure 8 is a similar figure to Figure 7 but shows regions of heavy flow and recrystallisation in a clutch hub formed from thixotropic material having a solid content of 60-70% by volume;
  • Figure 9 is a photomicrograph of a sample taken from Region Al of Figure 7.
  • Figure 10 is a photomicrograph of a sample taken from Region A2 of Figure 7.
  • FIG. 1 shows a photomicrograph of the structure obtained for an aluminium alloy 2618. About 450g of this alloy was heated to above the liquidus temperature of 638°C and then cooled to precisely 638°C. The molten alloy was then cast into a cylindrical steel mould having an outer diameter of 120mm and an outer length of 140mm. The mould cavity of this mould had a diameter of 50mm and a length of 80mm. The mould was at ambient temperature when casting commenced.
  • Figure 1 shows a photomicrograph of the as cast structure obtained from this experiment. Misorientation measurements between the particles and three-dimensional imaging of the particles in Figure 1 indicate that they are independent globules separated by eutectic phase.
  • Figure 2 shows a photomicrograph of the as-cast structure obtained using similar apparatus but with casting conducted in the conventional manner in which the melt is cast at a temperature of about 50-60°C above the liquidus temperature.
  • a dendritic structure is obtained. This structure is not especially suitable for thixoforming.
  • the microstructure obtained in 2618 alloy has been reproduced in other wrought and casting alloys, such as 2011 (wrought alloy), 7075 (wrought alloy), and A356 (casting alloy) by casting those alloys from their liquidus temperature.
  • a total of over 54 experiments were carried out to produce materials of various compositions (i.e. commercial compositions of aluminium alloys 2618,2011,7075 and A356) and microstructures (i.e. as-liquidus-cast, as conventional-cast, as-reheated and as-formed).
  • the microstructure of the materials was examined by optical microscopy and image analysis to ascertain the non- dendritic structure.
  • the thixotropic structure was further confirmed by three dimensional modelling and by measuring the orientations of adjacent grains by using scanning electron microscopy and electron back scattered pattern.
  • the liquidus-cast 2618 slugs were reheated to semisolid temperature range to have about 60% solid and 40% liquid.
  • the slugs were then either cut through using a knife edge or compressed manually by a flat ceramic tool to show the ability of the material to deform easily. (It was impossible to do so with the conventionally cast material). This shows the suitability of the material for use in thixoforming.
  • the as-liquidus-cast alloy was subsequently reheated to the desired processing temperature in the solid-liquid region followed by thixoforming into near-net-shape.
  • the microstructure after reheating of a liquidus cast 2618 alloy is shown in Fig.3; the fine, non-dendritic structure is retained.
  • the microstructure after thixoforming is shown in Fig.4; the flow is homogeneous.
  • the billet of thixotropic material is introduced into open dies which subsequently close to form the article, and then open again for the ejection of the finished component.
  • This is opposed to and believed to be unique over known thixoforming processes that use forming processes that are akin to die casting in which a thixotropic material is injected into a set of closed dies through a shot sleeve.
  • the open die thixoforming process must not be confused with conventional open die solid forging.
  • the open die thixoforming process of the present practice is more akin to conventional closed die solid forging, in the same way in which thixocasting can be likened to liquid die casting, for example.
  • a typical thixoforming cycle as practiced in the present "open die” approach used in the following Examples and shown schematically in Figure 5 consists of the following steps: (a) billet reheating, in which billet 10 is supplied to induction heating means 12 and heated to a temperature between the solidus and liquidus temperature to produce a thixotropic material.
  • the thixotropic material is preferably self-supporting (b) billet transfer to open dies, 14, 16 (c) forging stroke initiation and forming, and (d) removal of thixoformed component (not shown).
  • the dies 14, 16 open and the billet 10 is removed from an induction heating coil case 12 and seated in the lower die 16.
  • the press operator initiates the forming cycle (defined by the pre-set forming speed, and final forming load) and the billet 10 is thixoformed upon the approach of the top die 14 and its closure onto the lower die 16.
  • the thixotropic billet 10 is forced to follow the contours of the dies. The dies stay closed for a predetermined time (dwell time).
  • a typical forming cycle defined by the time from semisolid billet removal from the heating coil, and including its placement in the press and forming by die closure, is less than 20 seconds.
  • the commercially available aluminium alloy 2618 was thixoformed under various forming conditions (to be discussed hereunder).
  • the billet of solidified metal was obtained by casting molten metal from the liquidus temperature.
  • the demonstration article thixoformed in the Examples is an automotive clutch hub component 20 as shown in Figure 6.
  • This component has previously been manufactured from steel by conventional forging methods. In conventional forging methods for producing this component, the component was made with the use of two die sets, blocker and finisher die and was subject to finishing/machining operations. When the article was produced by thixoforming in accordance with the present invention, only the finisher die was required to arrive at a near net shape compound in a single step.
  • the starting thixotropic material provided to die 14 is a self-supporting cylindrical billet having a ratio of height to diameter (H/D) of about 1.4.
  • the thixoforming step used to produce the clutch hub shown in Figure 6 reduces the height of the billet to about 40% of the original height in the central region of the hub and to about 11% of the original height in the peripheral flange portion of the hub.
  • the final diameter of the hub is approximately 2.4 times the diameter of the cylindrical billet of thixotropic material.
  • the clutch hub 20 was successfully thixoforged from alloy 2618 under a wide range of thixoforming conditions.
  • Process parameters investigated were (a) semisolid condition, ie. fraction of solid phase in the starting billet; (b) die temperature; and (c) forming speed. All of these are related to the ease (or lack thereof) with which an article can be thixoformed.
  • the lower the fraction of the solid phase and the higher the fraction of the liquid constituent the less viscous is the semisolid slurry charge and the easier it is to deform.
  • the resistance of a semisolid slurry system to applied force increases steeply with increasing fraction of solid in the material, for the range of fractions solid that can be practically applied in semisolid forging (ie. 0.8> fraction solid >0.5).
  • Die temperature is most often related to surface finish of thixoforgings, where higher die temperatures tend to produce better surface finish and also prevent premature freezing of the semisolid slurry charge on contact with the dies.
  • the forming speed is related to the rate of shearing (deformation) of the semisolid charge, and generally the higher the shearing rate, the lower the resistance of the semisolid slurry system to the applied load.
  • Another obviously important variable is the applied load necessary for the deforming (shaping) of the semisolid charge, and this may be several orders of magnitude less in thixoforming than is required in conventional forging.
  • clutch hubs were successfully thixoformed at solid fractions in the semi-solid material of 0.8>fraction solid >0.6, at die temperatures from 150-300°C, and forming speeds of 0.1-0.2m/s.
  • the forming load was 350 tons (well below the press capacity), and it was obvious that a much smaller forming load would suffice.
  • the full forming load was only applied as the final clamping load, which is produced only after the top and bottom dies come in contact and fully close.
  • the fraction solid of the semisolid charge was varied from low (60% solid) to medium (70% solid) to high (80% solid), and for each fraction solid the forming speed was varied from slow ( ⁇ 0.1 m/s) to medium (0.2 m/s).
  • Low (150°C) or high (300°C) die temperature did not at all affect the surface finish quality of the thixoforged clutch hubs. In all of the thixoforging trials fully dense, near net clutch hubs were produced to the shape dictated by the forging dies.
  • the solidified metal produced by casting a billet from molten metal at the liquidus temperature showed extremely favourable thixoforming characteristics.
  • a part (automotive clutch hub) which required a substantial change in dimensions from the starting billet to the final article, was easily thixoformed in a single step, to near net shape as dictated by the forging dies, under a wide range of thixoforming conditions.
  • the conditions included quite a high solid fraction of the semisolid charge (80% solid), quite cool forging dies (150°C), and only moderate forming speeds.
  • thixoforging a component can be thixoforged at fractions of solid of 40-80%, at forming velocities of 0.1 -0.5 m/s, and with dies at 150-300°C.
  • thixocasting lower fractions of solid (40-60%) and much higher forming speeds (>1 m/s) are necessary.
  • the size of the processing window, or the flexibility of the thixoforming process is in either case heavily dependent on the quality of the thixoforming feedstock, and also on the complexity of the article to be produced.
  • the primary globular grains remain largely unchanged from how they appear in the original reheated thixotropic billet just prior to forming (see Figure 9).
  • the extent of the flow regions is found to be dependent on the initial fraction of solid in the starting billet. At higher fraction of solid phase, these regions are found to increase (as shown in Figure 7), and at lower fraction solid they are reduced (as shown in Figure 8).
  • the location of the flow regions is the same irrespective of the fraction of solid phase in the starting billet, only their extent changes according to solid fraction, as mentioned previously. In the view of results presented in thixoforging literature 1 ' 2 ' 3 this is an unexpected result, as there is no mention of flow patterns in thixoforged components.
  • Microstructures presented in literature are akin to those in the unchanged regions without flow in the above example. It can also be postulated on the basis of the above results, that the flow patterns are likely to disappear if the fraction solid in the starting billet is substantially low. It would seem from the results obtained so far that negligible flow pattern or no flow pattern at all could be obtained at fractions solid of less than 60%.
  • the excellent tensile properties of the thixoformed clutch hubs can be related to the unique microstructure of the thixoformed parts. Samples were taken from regions of the components that contained the "flow patterns" and from those without. Regions with flow patterns showed the excellent tensile properties mentioned above, where as regions where flow of material was not observed showed somewhat lower (but still impressive) tensile strengths and elongations. It can therefore be concluded that the flow structure is a desirable outcome of the present thixoforming process, which has a positive bearing on the tensile properties of the thixoformed parts.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
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  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Forging (AREA)

Abstract

Le procédé de fabrication d'un article métallique façonné de la présente invention consiste à faire fondre un alliage de métaux, à réduire la température du métal fondu jusqu'à la température dite 'liquidus', à couler le métal fondu à cette température dite 'liquidus' dans un moule et à laisser solidifier le métal fondu de façon à obtenir une matière première d'alimentation. On chauffe ensuite cette matière première d'alimentation à une température comprise entre les températures dites 'liquidus' et 'solidus' de façon à produire un matériau thixotrope auto-portant que l'on façonne alors pour lui donner la forme souhaitée. Mouler la matière première d'alimentation à partir d'une matière fondue, sensiblement à la température 'liquidus', produit une microstructure qui convient particulièrement à un formage ultérieur du matériau thixotrope et cela rend possible un formage à des vitesses relativement faibles et sous des pressions relativement basses.
PCT/AU1997/000458 1996-07-18 1997-07-18 Formage de metaux semi-solides WO1998003686A1 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
AU34301/97A AU729897B2 (en) 1996-07-18 1997-07-18 Semi-solid forming
EP97930263A EP0958387A4 (fr) 1996-07-18 1997-07-18 Formage de metaux semi-solides
JP10506382A JP2000514717A (ja) 1996-07-18 1997-07-18 半固体成形加工
US09/214,643 US6311759B1 (en) 1996-07-18 1997-07-18 Semi-solid metal processing

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Application Number Priority Date Filing Date Title
AUPO1102A AUPO110296A0 (en) 1996-07-18 1996-07-18 Liquidus casting of alloys
AUPO1102 1996-07-18

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WO1998003686A1 true WO1998003686A1 (fr) 1998-01-29

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EP (1) EP0958387A4 (fr)
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WO (1) WO1998003686A1 (fr)

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EP0969111A1 (fr) * 1998-06-26 2000-01-05 Alusuisse Technology & Management AG Boulon métallique ayant des propriétés thixotropes et son procédé de fabrication
WO2000044944A2 (fr) * 1998-06-10 2000-08-03 Suraltech, Inc. Processus de production de compositions metalliques a grains fins et de formage d'articles de metaux semi-solides profiles
WO2001024215A1 (fr) * 1999-09-24 2001-04-05 General Electric Company Materiaux d'enveloppe de col de tube cathodique et fabrication
WO2002024381A1 (fr) * 2000-09-21 2002-03-28 Massachusetts Institute Of Technology Compositions d'alliage metallique et procede d'obtention
US6645323B2 (en) * 2000-09-21 2003-11-11 Massachusetts Institute Of Technology Metal alloy compositions and process
EP1426460A1 (fr) * 2002-12-05 2004-06-09 Ascometal Acier pour construction mécanique, procédé de mise en forme à chaud d'une pièce de cet acier, et pièce ainsi obtenue
EP1426459A1 (fr) * 2002-12-05 2004-06-09 Ascometal Acier pour construction mécanique, procédé de mise en forme à chaud d'une pièce de cet acier et piéce ainsi obtenue
US6918427B2 (en) 2003-03-04 2005-07-19 Idraprince, Inc. Process and apparatus for preparing a metal alloy
WO2009064234A1 (fr) * 2007-11-14 2009-05-22 Aktiebolaget Skf Procédé de fabrication d'acier
CN103212572A (zh) * 2013-04-17 2013-07-24 燕山大学 一种镁合金板材的轧制方法
EP3382047A1 (fr) * 2017-03-29 2018-10-03 The Boeing Company Alliage titane-cuivre-fer et procédé de thixoformage associé
EP3804878A1 (fr) * 2019-10-11 2021-04-14 Cie Automotive, S.A. Forgeage proche du solidus

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6742567B2 (en) * 2001-08-17 2004-06-01 Brunswick Corporation Apparatus for and method of producing slurry material without stirring for application in semi-solid forming
US6773666B2 (en) 2002-02-28 2004-08-10 Alcoa Inc. Al-Si-Mg-Mn casting alloy and method
US7513962B2 (en) * 2002-09-23 2009-04-07 Worcester Polytechnic Institute Alloy substantially free of dendrites and method of forming the same
FR2848129B1 (fr) * 2002-12-05 2006-01-27 Ascometal Sa Procede de fabrication d'un piston pour moteur a explosion, et piston ainsi obtenu
FR2858331B1 (fr) * 2003-08-01 2006-12-01 Aubert Et Duval Surface en contact avec le titane ou un alliage de titane
US7255151B2 (en) * 2004-11-10 2007-08-14 Husky Injection Molding Systems Ltd. Near liquidus injection molding process
US8083871B2 (en) 2005-10-28 2011-12-27 Automotive Casting Technology, Inc. High crashworthiness Al-Si-Mg alloy and methods for producing automotive casting
US20080295989A1 (en) * 2007-05-30 2008-12-04 Husky Injection Molding Systems Ltd. Near-Liquidus Rheomolding of Injectable Alloy
SE0701358L (sv) * 2007-06-01 2008-10-07 Skf Ab En lagerkomponent för ett rullningslager eller ett glidlager
JP2009262190A (ja) * 2008-04-24 2009-11-12 Toyota Central R&D Labs Inc ダイカスト鋳物
EP2383056B1 (fr) * 2010-04-28 2016-11-30 Nemak Dillingen GmbH Procédé et appareil pour dispositif de détection de métaux sans contact
CN102172771A (zh) * 2011-03-25 2011-09-07 天津福来明思铝业有限公司 铝合金半固态触变加工中的重熔加热工艺
US9555468B2 (en) * 2012-09-12 2017-01-31 Lucio Megolago Albani Process and plant for producing components made of an aluminium alloy for vehicles and white goods, and components obtained thereby
JP6342912B2 (ja) * 2012-11-08 2018-06-13 ディーディーエム システムズ， インコーポレイテッド 金属構成要素の加法的製造および修復
RU2573543C1 (ru) * 2014-09-04 2016-01-20 Федеральное государственное унитарное предприятие "Всероссийский научно-исследовательский институт авиционных материалов" (ФГУП "ВИАМ") Способ получения изделий из алюминиевых сплавов
GB201600645D0 (en) * 2016-01-13 2016-02-24 Rolls Royce Plc Improvements in additive layer manufacturing methods
US20180281055A1 (en) * 2017-03-29 2018-10-04 The Boeing Company Titanium-Cobalt Alloy And Associated Thixoforming Method
CN107983929A (zh) * 2018-01-05 2018-05-04 北京科技大学 一种加热炉用钴合金垫块半固态触变成形工艺方法
KR102091198B1 (ko) * 2018-04-13 2020-03-23 한국생산기술연구원 금속체 내부의 기공 제거 방법
CN112204239B (zh) * 2018-05-31 2022-06-21 日本制铁株式会社 钢活塞
CN114888216A (zh) * 2022-04-28 2022-08-12 重庆大学 一种微观组织及力学性能梯度分布的钢铁壳体构件及成形方法

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4524820A (en) * 1982-03-30 1985-06-25 International Telephone And Telegraph Corporation Apparatus for providing improved slurry cast structures by hot working
US4585494A (en) * 1984-04-11 1986-04-29 Olin Corporation Beta copper base alloy adapted to be formed as a semi-solid metal slurry and a process for making same
US4621676A (en) * 1983-02-23 1986-11-11 The Secretary Of State For Trade And Industry In Her Britanic Majesty's Government Of The United Kingdom Of Great Britain And Northern Ireland Casting of metallic materials
US4771818A (en) * 1979-12-14 1988-09-20 Alumax Inc. Process of shaping a metal alloy product
WO1992003582A1 (fr) * 1990-08-27 1992-03-05 Alcan International Limited Metal leger a pores separes et procede de production
EP0701002A1 (fr) * 1994-09-09 1996-03-13 Ube Industries, Ltd. Procédé de fabrication d'alliages d'aluminium ou de magnésium à l'état semi-solide
EP0733421A1 (fr) * 1995-03-22 1996-09-25 Hitachi Metals, Ltd. Procédé de coulage sous pression
US5571346A (en) * 1995-04-14 1996-11-05 Northwest Aluminum Company Casting, thermal transforming and semi-solid forming aluminum alloys

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4771818A (en) * 1979-12-14 1988-09-20 Alumax Inc. Process of shaping a metal alloy product
US4524820A (en) * 1982-03-30 1985-06-25 International Telephone And Telegraph Corporation Apparatus for providing improved slurry cast structures by hot working
US4621676A (en) * 1983-02-23 1986-11-11 The Secretary Of State For Trade And Industry In Her Britanic Majesty's Government Of The United Kingdom Of Great Britain And Northern Ireland Casting of metallic materials
US4585494A (en) * 1984-04-11 1986-04-29 Olin Corporation Beta copper base alloy adapted to be formed as a semi-solid metal slurry and a process for making same
WO1992003582A1 (fr) * 1990-08-27 1992-03-05 Alcan International Limited Metal leger a pores separes et procede de production
EP0701002A1 (fr) * 1994-09-09 1996-03-13 Ube Industries, Ltd. Procédé de fabrication d'alliages d'aluminium ou de magnésium à l'état semi-solide
EP0733421A1 (fr) * 1995-03-22 1996-09-25 Hitachi Metals, Ltd. Procédé de coulage sous pression
US5571346A (en) * 1995-04-14 1996-11-05 Northwest Aluminum Company Casting, thermal transforming and semi-solid forming aluminum alloys

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP0958387A4 *

Cited By (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000044944A2 (fr) * 1998-06-10 2000-08-03 Suraltech, Inc. Processus de production de compositions metalliques a grains fins et de formage d'articles de metaux semi-solides profiles
WO2000044944A3 (fr) * 1998-06-10 2000-11-16 Suraltech Inc Processus de production de compositions metalliques a grains fins et de formage d'articles de metaux semi-solides profiles
EP0969111A1 (fr) * 1998-06-26 2000-01-05 Alusuisse Technology & Management AG Boulon métallique ayant des propriétés thixotropes et son procédé de fabrication
WO2001024215A1 (fr) * 1999-09-24 2001-04-05 General Electric Company Materiaux d'enveloppe de col de tube cathodique et fabrication
US6465948B1 (en) 1999-09-24 2002-10-15 General Electric Company Cathode ray tube funnel envelope materials and construction
WO2002024381A1 (fr) * 2000-09-21 2002-03-28 Massachusetts Institute Of Technology Compositions d'alliage metallique et procede d'obtention
US6645323B2 (en) * 2000-09-21 2003-11-11 Massachusetts Institute Of Technology Metal alloy compositions and process
FR2848225A1 (fr) * 2002-12-05 2004-06-11 Ascometal Sa Acier pour construction mecanique, procede de mise en forme a chaud d'une piece de cet acier et piece ainsi obtenue
EP1426459A1 (fr) * 2002-12-05 2004-06-09 Ascometal Acier pour construction mécanique, procédé de mise en forme à chaud d'une pièce de cet acier et piéce ainsi obtenue
FR2848226A1 (fr) * 2002-12-05 2004-06-11 Ascometal Sa Acier pour construction mecanique, procede de mise en forme a chaud d'une piece de cet acier, et piece ainsi obtenue
EP1426460A1 (fr) * 2002-12-05 2004-06-09 Ascometal Acier pour construction mécanique, procédé de mise en forme à chaud d'une pièce de cet acier, et pièce ainsi obtenue
US6994758B2 (en) 2002-12-05 2006-02-07 Ascometal Steel for mechanical construction, method of hot-shaping of a part from this steel, and part thus obtained
US7005017B2 (en) 2002-12-05 2006-02-28 Ascometal Steel for mechanical construction, method of hot-shaping of a part from this steel, and part thus obtained
US6918427B2 (en) 2003-03-04 2005-07-19 Idraprince, Inc. Process and apparatus for preparing a metal alloy
WO2009064234A1 (fr) * 2007-11-14 2009-05-22 Aktiebolaget Skf Procédé de fabrication d'acier
US8377235B2 (en) 2007-11-14 2013-02-19 Aktiebolaget Skf Process for forming steel
CN103212572A (zh) * 2013-04-17 2013-07-24 燕山大学 一种镁合金板材的轧制方法
CN103212572B (zh) * 2013-04-17 2015-04-29 燕山大学 一种镁合金板材的轧制方法
EP3382047A1 (fr) * 2017-03-29 2018-10-03 The Boeing Company Alliage titane-cuivre-fer et procédé de thixoformage associé
US10357822B2 (en) 2017-03-29 2019-07-23 The Boeing Company Titanium-copper-iron alloy and associated thixoforming method
RU2760224C2 (ru) * 2017-03-29 2021-11-23 Зе Боинг Компани Титано-медно-железный сплав и соответствующий способ тиксоформинга
EP3804878A1 (fr) * 2019-10-11 2021-04-14 Cie Automotive, S.A. Forgeage proche du solidus

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US6311759B1 (en) 2001-11-06
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AUPO110296A0 (en) 1996-08-08
EP0958387A4 (fr) 2003-07-16

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