WO1997020083A1 - Coated cutting insert and method of making it - Google Patents

Coated cutting insert and method of making it Download PDF

Info

Publication number
WO1997020083A1
WO1997020083A1 PCT/SE1996/001579 SE9601579W WO9720083A1 WO 1997020083 A1 WO1997020083 A1 WO 1997020083A1 SE 9601579 W SE9601579 W SE 9601579W WO 9720083 A1 WO9720083 A1 WO 9720083A1
Authority
WO
WIPO (PCT)
Prior art keywords
layer
tic
cemented carbide
nyo
thickness
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/SE1996/001579
Other languages
English (en)
French (fr)
Inventor
Annika Sandman
Camilla Oden
Jeanette Persson
Åke ÖSTLUND
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sandvik AB
Original Assignee
Sandvik AB
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from SE9504304A external-priority patent/SE9504304D0/xx
Priority claimed from SE9603662A external-priority patent/SE514284C2/sv
Priority to IL12447696A priority Critical patent/IL124476A/xx
Application filed by Sandvik AB filed Critical Sandvik AB
Priority to EP96941283A priority patent/EP0870073B1/en
Priority to US09/077,370 priority patent/US6062776A/en
Priority to JP09520426A priority patent/JP2000515433A/ja
Priority to AT96941283T priority patent/ATE213282T1/de
Priority to BR9611788A priority patent/BR9611788A/pt
Priority to DE69619272T priority patent/DE69619272T2/de
Publication of WO1997020083A1 publication Critical patent/WO1997020083A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C30/00Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
    • C23C30/005Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process on hard metal substrates
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C29/00Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
    • C22C29/02Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
    • C22C29/06Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds
    • C22C29/08Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds based on tungsten carbide
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/22Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
    • C23C16/30Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/22Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
    • C23C16/30Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
    • C23C16/40Oxides
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T407/00Cutters, for shaping
    • Y10T407/26Cutters, for shaping comprising cutting edge bonded to tool shank
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T407/00Cutters, for shaping
    • Y10T407/27Cutters, for shaping comprising tool of specific chemical composition
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24942Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
    • Y10T428/2495Thickness [relative or absolute]
    • Y10T428/24967Absolute thicknesses specified
    • Y10T428/24975No layer or component greater than 5 mils thick

Definitions

  • the present invention relates to a coated cutting tool (cemented carbide insert) particularly useful for toughness demanding wet and dry machining, preferably milling, of low and medium alloyed steels and stainless steels, with raw surfaces such as cast skin, forged skin, hot or cold rolled skin or pre-machined surfaces under unstable conditions.
  • a coated cutting tool cemented carbide insert
  • the cutting edge is worn according to different wear mechanisms, such as chemical wear, abrasive wear, adhesive wear and by edge chipping caused by cracks formed along the cutting edge, the so called comb cracks. In bad conditions problems with bulk and edge line breakages occur commonly.
  • a coated cemented carbide insert When cutting in steels with raw surface zones or cutting under difficult conditions a coated cemented carbide insert must consist of a tough carbide and have very good coating adhesion.
  • the adhesive wear When machining in low alloyed steels and stainless steels the adhesive wear is generally the dominating wear type. Here generally 1-3 ⁇ m CVD- or PVD-coatings have to be used.
  • Measures can be taken to improve the cutting performance with respect to a specific wear type. However, very often such action will have a negative effect on other wear properties.
  • Comb crack formation can be reduced by lowering the binder phase content. However, such action will lower the toughness properties of the cutting inserts which is not desirable.
  • Swedish patent application 9504304-8 discloses a coated cutting insert particularly useful for milling in low and medium alloyed steel with or without raw surface zones during wet or dry conditions.
  • the insert is characterized by WC-Co cemented carbide with a low content of cubic carbides and a highly W-alloyed binder phase and a coating including an innermost layer of
  • TiC x NyO z with columnar grains and a top layer of TiN and an inner layer of K-AI2O3.
  • Swedish patent application 9501286-0 discloses a coated cutting insert particularly useful for dry milling of grey cast iron.
  • the insert is characterized by a straight WC-Co cemented carbide grade and a coating including a layer of TiC x NyO z with columnar grains and a top layer of fine grained textured OC-AI2O3.
  • Swedish patent application 9502640-7 discloses a coated turning insert particularly useful for intermittent turning in low alloyed steel .
  • the insert is characterized by a WC-Co cemented carbide body having a highly W-alloyed Co-binder phase and a coating including a layer of TiC x NyO z with columnar grains and a top layer of a fine grained, textured OC-AI2O3.
  • Swedish patent application 9503056-5 discloses a coated turning cutting tool particularly useful for cutting in hot and cold forged low alloyed steel.
  • the insert is characterized by a WC-Co cemented carbide body having a highly W-alloyed Co-binder phase and a coating including a layer of TiC x NyO z with columnar grains and a top layer of a fine-grained, OC-AI2O3.
  • Swedish patent application 9602413-8 discloses a coated turning insert particularly useful for turning in stainless steel.
  • the insert is characterised by WC-Co- based cemented carbide substrate having a highly W- alloyed Co-binder phase and a coating including an innermost layer of TiC x NyO z with columnar grains and a top layer of TiN and an inner layer of fine grained K- I2O3.
  • a cutting tool preferably for milling, can be obtained with excellent cutting performance in low and medium alloyed steel, with or without raw surface zones preferably under unstable conditions such as vibrations, long overhang, chip- hammering or recutting of chips or in generally toughness demanding operations both in wet and dry conditions. It has also been found that this specific cutting tool also works in stainless steel .
  • the cutting tool according to the invention shows improved properties with respect to many of the wear types earlier mentioned.
  • the cutting tool insert according to the invention consists of: a cemented carbide body with a rather low W-alloyed binder phase and with a well balanced chemical composition and grain size of the WC, a columnar TiC x N y O z -layer, a -AI2O3-layer, a TiN-layer and optionally followed by smoothening the cutting edges by brushing the edges with e.g. a SiC based brush.
  • a coated cutting tool insert consisting of a cemented carbide body with a composition of 10.9-13 wt% Co, preferably 11.0-12.0 wt% Co, most preferably 11.1-11.7 wt% Co, 0.2- 1.8 wt% cubic carbides, preferably 0.4-1.8 wt% cubic carbides, most preferably 0.5-1.7 wt% cubic carbides of the metals Ta, Nb and Ti and balance WC.
  • the cemented carbide may also contain other carbides from elements from group IVb, Vb or VIb of the periodic table.
  • the content of Ti is preferably on a level corresponding to a technical impurity.
  • the average grain size of the WC is in the range of about 1.5-2.5 u , preferably about 1.7 ⁇ m.
  • the cobalt binder phase is rather low alloyed with W.
  • the CW-value is a function of the W content in the Co binder phase. A high CW-value corresponds to a low W-content in the binder phase.
  • the cemented carbide body has a CW-ratio of 0.87- 0.99, preferably 0.88-0.97, and most preferably 0.90- 0.95.
  • the cemented carbide may contain small amounts, ⁇ 1 volume %, of ⁇ -phase (MgC) , without any detrimental effect. From the CW-value it follows that no free graphite is allowed in the cemented carbide body according to the present invention.
  • the coating comprises
  • a first (innermost) layer of TiC x NyO z with x+y+z-1, preferably y>x and z ⁇ 0.2, most preferably y>0.8 and z 0, with equiaxed grains with size ⁇ 0.5 ⁇ m and a total thickness ⁇ 1.5 ⁇ m preferably >0.1 ⁇ m.
  • the AI2O3-layer has a thickness of 0.5-5 ⁇ m, preferably 0.5-2 ⁇ , and most preferably 0.5-1.5 ⁇ m.
  • This outermost layer, AI2O3 or TiC x NyO z has a surface roughness Rmax ⁇ . 0.4 ⁇ m over a length of 10 ⁇ m.
  • the TiC x NyO z -layer if present, is preferably removed along the cutting edge.
  • the TiC x NyO z layer is removed and the underlying alumina layer is partly or completely removed along the cutting edge.
  • the present invention also relates to a method of making a coated cutting tool insert consisting of a cemented carbide body with a composition of 10.9-13 wt% Co, preferably 11.0-12.0 wt% Co, most preferably 11.1- 11.7 wt% Co, 0.2-1.8 wt% cubic carbides, preferably 0.4- 1.8 wt% cubic carbides, most preferably 0.5-1.7 wt% cubic carbides of the metals Ta, Nb and Ti and balance WC.
  • the cemented carbide may also contain other carbides from elements from group IVb, Vb or VIb of the periodic table.
  • the content of Ti is preferably on a level corre ⁇ sponding to a technical impurity.
  • the average grain size of the WC is in the range of about 1.5-2.5 ⁇ m, preferably about 1.7 ⁇ .
  • Onto the cemented carbide body is deposited
  • the exact conditions depend to a certain extent on the design of the equipment used.
  • a smooth AI2O3-layer essentially consisting of K- AI2O3 is deposited under conditions disclosed in e.g. EP-A-523 021.
  • the AI2O3 layer has a thickness of 0.5-5 ⁇ m, preferably 0.5-2 ⁇ m, and most preferably 0.5-1.5 ⁇ m.
  • a further layer ( ⁇ 1 ⁇ m, preferably 0.1-0.5 ⁇ m thick) of TiC x N y O z is deposited, but the Al2 ⁇ 3-layer can be the outermost layer.
  • This outermost layer, AI2O3 or TiC x NyO z has a surface roughness R max ⁇ .0.4 ⁇ m over a length of 10 ⁇ m.
  • the smooth coating surface can be obtained by a gentle wet-blasting the coating surface with fine grained (400-150 mesh) alumina powder or by brushing (preferably used when TiC x NyO z top coating is present) the edges with brushes based on e.g. SiC as disclosed e.g. in Swedish patent application 9402543-4.
  • the TiC x NyO z -layer, if present, is preferably removed along the cutting edge. Alternatively, the TiC x NyO z layer is removed and the underlying alumina layer is partly or completely removed along the cutting edge.
  • a cemented carbide milling tool in accordance with the invention with the composition 11.5 wt-% Co, 1.25 wt-% TaC, 0.30 wt-% NbC and balance WC, with a binder phase alloyed with W corresponding to a CW-ratio of 0.93 were coated with a 0.5 ⁇ m equiaxed TiCrj _ 05 N 0. 5" layer (with a high nitrogen content corresponding to an estimated C/N-ratio of 0.05) followed by a 4 ⁇ m thick TiCr j .54N0.46-layer, with columnar grains by using MTCVD- technique (temperature 885-850 °C and CH3CN as the carbon/nitrogen source) .
  • a 1.0 ⁇ thick layer of AI2O3 was deposited using a temperature 970 °C and a concentration of H2S dopant of 0.4 % as disclosed in EP-A-523 021.
  • a thin (0.3 ⁇ m) layer of TiN was deposited on top according to known CVD-technique. XRD-measurement showed that the Al2 ⁇ 3 ⁇ layer consisted of 100 % K-phase.
  • the cemented carbide body had a WC grain size in average of 1.7 ⁇ m.
  • the coated inserts were brushed by a nylon straw brush containing SiC grains.
  • a cemented carbide milling tool in accordance with the invention with the composition 11.1 wt-% Co, 1.25 wt-% TaC, 0.30 wt-% NbC and balance WC, with a binder phase alloyed with W corresponding to a CW-ratio of 0.93 were coated with a 0.5 ⁇ m equiaxed TiCg 05 N 0 95" layer followed by a 4 ⁇ m thick TiC ⁇ .54N0.46"l yer, with columnar grains by using MTCVD-technique (temperature 885-850 °C and CH3CN as the carbon/nitrogen source) .
  • a 1.0 ⁇ m thick layer of AI2O3 was deposited using a temperature 970 °C and a concentration of H2S dopant of 0.4 % as disclosed in EP-A-523 021.
  • a thin (0.3 ⁇ ) layer of TiN was deposited on top according to known CVD-technique. XRD-measurement showed that the AI2O3-layer consisted of 100 % K-phase.
  • the cemented carbide body had a WC grain size in average of 1.8 ⁇ .
  • the coated inserts were brushed by a nylon straw brush containing SiC grains.
  • a strongly competitive cemented carbide grade from an external leading carbide producer was selected for comparison in a milling test.
  • the carbide had a composition of 11.4 wt-% Co, 0.1 wt-% TiC, 1.9 wt-% TaC, 0.4 wt% NbC balance WC and a CW-ratio of 0.90.
  • the WC- grain size was 1.4 ⁇ m.
  • the insert had a PVD-coating consisting of total 5 ⁇ m of TiN/TiC/TiC,N/TiC layers.
  • a strongly competitive cemented carbide grade from an external leading carbide producer was selected for comparison in a milling test.
  • the carbide had a composition of 11.5 wt-% Co, 0.2 wt-% TiC, 1.4 wt-% TaC, balance WC and a CW-ratio of 0.97.
  • the WC-grain size was 1.5 ⁇ m.
  • the insert had a conventional CVD-coating consisting of total 4.8 ⁇ m of TiN/TiC, /TiC layers.
  • Feed rate/tooth 0.15 mm/rev.
  • Competitor C (prior art): 1.3 Competitor D (prior art): 13
  • the WC-grain size was 3.2 ⁇ m.
  • the insert had a conventional CVD-coating consisting of total 2.5 ⁇ m TiC/TiC,N/TiN.
  • Inserts from A, B, C and E were tested in a face milling operation. Operation: Face milling, R260.22-250 Work-piece: Bar, 200x250 mm with holes Material: SS2541 Cutting speed: 100 m/min Feed rate/tooth: 0,4 mm/rev. Depth of cut: 2 mm Insert-style: SEKN 1204
  • a strongly competitive cemented carbide grade from an external leading carbide producer was selected for comparison in a milling test.
  • the carbide had a composition of 9.5 wt-% Co, 6.6 wt-% TiC, 12.7 wt-% TaC, 1.4 wt-% NbC, balance WC and a CW-ratio of 0.83.
  • the insert was uncoated.
  • Feed rate/tooth 0,19 mm/rev.
  • Tool-life criterion was chipping of the edge.
  • the WC-grain size was 1.7 ⁇ m.
  • the insert had the same coating as mentioned in example A. Inserts from A, B, E and G were tested in a square- shoulder test. Operation: Full slot , widening, 0 exit angle ,
  • Competitor I (prior art): 5
  • Tool-life criterion was chipping in the edge line due to plastic deformation.
  • Example 5 A cemented cutting tool identical to the one mentioned in example A, but the brushing was different. Examination of the brushed inserts in a light microscope showed that the thin TiN-layer and the AI2O3-layer had been brushed away only along the cutting edge leaving there a smooth TiCg .54 0.46 ⁇ surface. Coating thickness measurements on cross sectioned brushed samples showed no reduction of the TiCg .5 N0.4 ⁇ -layer, but the outer TiN-layer and the AI2O3-layer were removed along the edge line. Inserts from C, D, E, I and J were tested in a face milling operation. Two parallel bars each of a thickness of 35 mm were central positioned relatively the cutter body, and the bars were placed with an airgap of 10 mm in between. Operation: Face milling,
  • Competitor C (prior art) : 18
  • Competitor D (prior art) : 22
  • Competitor E (prior art): 15 Competitor I (prior art) : 22
  • Tool-life criterion was chipping due to comb crack formation.
  • Example 6 Inserts from A and E were tested in a turning test.
  • Facing Work-piece Cylinder, 180 mm Material : SS2541, 300 HB Cutting speed: 220 m/min Feed rate: 0, 3 mm/rev. Depth of cut: 2 mm Insert-style: CNMG 120408-PM Note: dry
  • Competitor E (prior art): 4
  • Competitor E (prior art): 3
  • Tool-life criterion was flank wear due to plastic deformation.
  • Competitor E (prior art) : 21

Landscapes

  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Organic Chemistry (AREA)
  • Metallurgy (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Vapour Deposition (AREA)
  • Cutting Tools, Boring Holders, And Turrets (AREA)
  • Prostheses (AREA)
  • Absorbent Articles And Supports Therefor (AREA)
  • Turning (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)
PCT/SE1996/001579 1995-11-30 1996-11-29 Coated cutting insert and method of making it Ceased WO1997020083A1 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
DE69619272T DE69619272T2 (de) 1995-11-30 1996-11-29 Beschichteter schneideinsatz und verfahren zu dessen herstellung
BR9611788A BR9611788A (pt) 1995-11-30 1996-11-29 Inserção de corte revestida e método para fabricação da mesma
IL12447696A IL124476A (en) 1995-11-30 1996-11-29 Coated cutting insert and method of making it
EP96941283A EP0870073B1 (en) 1995-11-30 1996-11-29 Coated cutting insert and method of making it
US09/077,370 US6062776A (en) 1995-11-30 1996-11-29 Coated cutting insert and method of making it
JP09520426A JP2000515433A (ja) 1995-11-30 1996-11-29 被覆された切削植刃及びその製造方法
AT96941283T ATE213282T1 (de) 1995-11-30 1996-11-29 Beschichteter schneideinsatz und verfahren zu dessen herstellung

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
SE9504304-8 1995-11-30
SE9504304A SE9504304D0 (sv) 1995-11-30 1995-11-30 Coated milling insert
SE9603662-9 1996-10-04
SE9603662A SE514284C2 (sv) 1996-10-04 1996-10-04 Belagt hårdmetallskär för fräsning av låg- och mediumlegerat stål och rostfritt stål

Publications (1)

Publication Number Publication Date
WO1997020083A1 true WO1997020083A1 (en) 1997-06-05

Family

ID=26662440

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/SE1996/001579 Ceased WO1997020083A1 (en) 1995-11-30 1996-11-29 Coated cutting insert and method of making it

Country Status (10)

Country Link
US (1) US6062776A (enExample)
EP (1) EP0870073B1 (enExample)
JP (1) JP2000515433A (enExample)
KR (1) KR100430360B1 (enExample)
CN (1) CN1203636A (enExample)
AT (1) ATE213282T1 (enExample)
BR (1) BR9611788A (enExample)
DE (1) DE69619272T2 (enExample)
IL (1) IL124476A (enExample)
WO (1) WO1997020083A1 (enExample)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000003062A1 (en) * 1998-07-09 2000-01-20 Sandvik Ab (Publ) Coated grooving or parting insert
WO2001016388A1 (en) * 1999-09-01 2001-03-08 Sandvik Ab (Publ) Coated grooving or parting insert
US6632514B1 (en) 1999-11-25 2003-10-14 Seco Tools Ab Coated cutting insert for milling and turning applications
US6689450B2 (en) * 2001-03-27 2004-02-10 Seco Tools Ab Enhanced Al2O3-Ti(C,N) multi-coating deposited at low temperature
EP2039447A1 (en) 2007-09-13 2009-03-25 Seco Tools Ab Coated cutting insert for milling applications
US8012611B2 (en) 2004-10-29 2011-09-06 Sumitomo Electric Hardmetal Corp. Surface-coated cutting tool
US8084148B2 (en) 2007-09-13 2011-12-27 Seco Tools Ab Insert for milling of cast iron

Families Citing this family (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6293739B1 (en) * 1998-04-14 2001-09-25 Sumitomo Electric Industries, Ltd. Coated cemented carbide cutting tool
SE9903090D0 (sv) 1999-09-01 1999-09-01 Sandvik Ab Coated milling insert
JP4437353B2 (ja) * 2000-03-30 2010-03-24 株式会社タンガロイ 被覆切削工具およびその製造方法
SE519250C2 (sv) * 2000-11-08 2003-02-04 Sandvik Ab Belagt hårdmetallskär och användning av detsamma för våtfräsning
US6805944B2 (en) * 2001-03-26 2004-10-19 Mitsubishi Materials Corporation Coated cemented carbide cutting tool
US8562664B2 (en) * 2001-10-25 2013-10-22 Advanced Cardiovascular Systems, Inc. Manufacture of fine-grained material for use in medical devices
SE523826C2 (sv) * 2002-03-20 2004-05-25 Seco Tools Ab Skär belagt med TiAIN för bearbetning med hög hastighet av legerade stål, sätt att framställa ett skär och användning av skäret
SE523827C2 (sv) * 2002-03-20 2004-05-25 Seco Tools Ab Belagt skär för bearbetning med hög hastighet av låg-och medelhögt legerade stål, sätt att framställa ett skär och använding av skäret
SE526599C2 (sv) * 2003-06-16 2005-10-18 Seco Tools Ab CVD-belagt hårdmetallskär
DE10332101B4 (de) * 2003-07-15 2016-02-04 Kennametal Inc. Schneidwerkzeug und Verfahren zu dessen Herstellung
SE527679C2 (sv) * 2004-01-26 2006-05-09 Sandvik Intellectual Property Hårdmetallkropp, särskilt spiralborr, och användning av denna för verktyg för roterande metallbearbetning
SE527724C2 (sv) * 2004-02-17 2006-05-23 Sandvik Intellectual Property Belagt skärverktyg för bearbetning av bimetall samt sätt och användning
US7455918B2 (en) * 2004-03-12 2008-11-25 Kennametal Inc. Alumina coating, coated product and method of making the same
SE528012C2 (sv) * 2004-07-05 2006-08-08 Sandvik Intellectual Property Belagt hårdmetallskär med skarp skäregg avsett för metallbearbetning samt sätt för dess framställning
SE528108C2 (sv) * 2004-07-13 2006-09-05 Sandvik Intellectual Property Belagt hårdmetallskär, speciellt för svarvning av stål, samt sätt att tillverka detsamma
CN101151115B (zh) * 2005-03-29 2012-10-31 住友电工硬质合金株式会社 被覆切削刀头及其制造方法
ATE541068T1 (de) * 2005-09-09 2012-01-15 Sandvik Intellectual Property Pvd-beschichtetes schneidwerkzeug
SE529015C2 (sv) * 2005-09-09 2007-04-10 Sandvik Intellectual Property PVD-belagt skärverktygsskär tillverkat av hårdmetall
SE529856C2 (sv) * 2005-12-16 2007-12-11 Sandvik Intellectual Property Belagt hårdmetallskär, sätt att tillverka detta samt dess användning för fräsning
SE529857C2 (sv) * 2005-12-30 2007-12-11 Sandvik Intellectual Property Belagt hårdmetallskär, sätt att tillverka detta samt dess användning för djuphålsborrning
SE530516C2 (sv) * 2006-06-15 2008-06-24 Sandvik Intellectual Property Belagt hårdmetallskär, metod att tillverka detta samt dess användning vid fräsning av gjutjärn
SE530634C2 (sv) * 2006-06-15 2008-07-22 Sandvik Intellectual Property Belagt hårdmetallskär, metod att tillverka detta samt dess användning vid torr fräsning av gjutjärn
SE0701321L (sv) * 2007-06-01 2008-12-02 Sandvik Intellectual Property Belagt skär
SE531933C2 (sv) 2007-12-14 2009-09-08 Seco Tools Ab Belagt hårdmetallskär för bearbetning av stål och rostfria stål
SE532044C2 (sv) * 2007-12-27 2009-10-06 Seco Tools Ab Användning av ett CVD belagt skär vid fräsning
CN101879611B (zh) * 2010-06-28 2012-01-18 株洲钻石切削刀具股份有限公司 用于不锈钢车削的硬质合金涂层刀片
CN103157815B (zh) * 2011-12-08 2016-10-19 三菱综合材料株式会社 在高速重切削中发挥优异的耐磨性的表面包覆切削工具
CN105828992B (zh) * 2013-12-26 2018-10-09 京瓷株式会社 切削工具
KR101537718B1 (ko) * 2014-04-23 2015-07-20 한국야금 주식회사 부분적으로 제거된 피막이 형성된 절삭공구
CN105482623A (zh) * 2015-12-22 2016-04-13 常熟市复林造纸机械有限公司 一种复卷机用耐腐蚀切割刀具
CN107557755B (zh) * 2016-07-01 2020-05-01 山特维克知识产权股份有限公司 具有{0 0 1}织构化κ-Al2O3层的CVD涂层切削工具
KR20180065117A (ko) 2016-12-07 2018-06-18 주식회사 세진티앤에스 탄소섬유가 코팅된 고강도 커팅 툴
EP3778084A4 (en) * 2019-06-13 2022-02-09 Sumitomo Electric Hardmetal Corp. CUTTING TOOL
CN113403516A (zh) * 2020-03-17 2021-09-17 杭州巨星科技股份有限公司 刃口材料、耐磨钳及其制造方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4643620A (en) * 1983-05-27 1987-02-17 Sumitomo Electric Industries, Ltd. Coated hard metal tool
EP0653499A1 (en) * 1993-05-31 1995-05-17 Sumitomo Electric Industries, Ltd. Coated cutting tool and method for producing the same
EP0685572A2 (en) * 1994-05-31 1995-12-06 Mitsubishi Materials Corporation Coated hard-alloy blade member
EP0686707A1 (en) * 1992-12-22 1995-12-13 Mitsubishi Materials Corporation Surface coated cutting tool
EP0693574A1 (en) * 1994-07-20 1996-01-24 Sandvik Aktiebolag Aluminium oxide coated tool
EP0709484A1 (en) * 1994-10-20 1996-05-01 Mitsubishi Materials Corporation Coated tungsten carbide-based cemented carbide blade member

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69007885T2 (de) * 1989-07-13 1994-07-28 Seco Tools Ab Mit mehreren Oxiden beschichteter Karbidkörper und Verfahren zu seiner Herstellung.
US5436071A (en) * 1990-01-31 1995-07-25 Mitsubishi Materials Corporation Cermet cutting tool and process for producing the same
JP2867803B2 (ja) * 1992-06-25 1999-03-10 三菱マテリアル株式会社 耐チッピング性にすぐれた表面被覆炭化タングステン基超硬合金製切削工具
GB9214851D0 (en) * 1992-07-13 1992-08-26 Europ Economic Community Communities desulphurisation of waste gases
JP3161088B2 (ja) * 1992-09-28 2001-04-25 三菱マテリアル株式会社 表面被覆wc基超硬合金製切削工具
US5576093A (en) * 1992-10-22 1996-11-19 Mitsubishi Materials Corporation Multilayer coated hard alloy cutting tool
US5372873A (en) * 1992-10-22 1994-12-13 Mitsubishi Materials Corporation Multilayer coated hard alloy cutting tool
SE514695C2 (sv) * 1995-07-14 2001-04-02 Sandvik Ab Skärverktyg belagt med aluminiumoxid och sätt för dess framställning
SE514177C2 (sv) * 1995-07-14 2001-01-15 Sandvik Ab Belagt hårdmetallskär för intermittent bearbetning i låglegerat stål
US5786069A (en) * 1995-09-01 1998-07-28 Sandvik Ab Coated turning insert
EP0784103B1 (en) * 1996-01-10 2003-04-09 Mitsubishi Materials Corporation Method of manufacturing coated cutting tools

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4643620A (en) * 1983-05-27 1987-02-17 Sumitomo Electric Industries, Ltd. Coated hard metal tool
EP0686707A1 (en) * 1992-12-22 1995-12-13 Mitsubishi Materials Corporation Surface coated cutting tool
EP0653499A1 (en) * 1993-05-31 1995-05-17 Sumitomo Electric Industries, Ltd. Coated cutting tool and method for producing the same
EP0685572A2 (en) * 1994-05-31 1995-12-06 Mitsubishi Materials Corporation Coated hard-alloy blade member
EP0693574A1 (en) * 1994-07-20 1996-01-24 Sandvik Aktiebolag Aluminium oxide coated tool
EP0709484A1 (en) * 1994-10-20 1996-05-01 Mitsubishi Materials Corporation Coated tungsten carbide-based cemented carbide blade member

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
USRE39986E1 (en) 1998-07-09 2008-01-01 Sandvik Intellectual Property Ab Coated grooving or parting insert
WO2000003062A1 (en) * 1998-07-09 2000-01-20 Sandvik Ab (Publ) Coated grooving or parting insert
US6261673B1 (en) 1998-07-09 2001-07-17 Sandvik Ab Coated grooving or parting insert
USRE40025E1 (en) 1999-09-01 2008-01-22 Sandvik Intellectual Property Ab Coated grooving or parting insert and method of making same
US6627049B2 (en) 1999-09-01 2003-09-30 Sandvik Ab Method of making grooving or parting insert
US6342291B1 (en) 1999-09-01 2002-01-29 Sandvik Ab Coated grooving or parting insert and method of making same
WO2001016388A1 (en) * 1999-09-01 2001-03-08 Sandvik Ab (Publ) Coated grooving or parting insert
USRE40873E1 (en) * 1999-09-01 2009-08-18 Sandvik Intellectual Property Aktiebolag Method of making grooving or parting insert
US6632514B1 (en) 1999-11-25 2003-10-14 Seco Tools Ab Coated cutting insert for milling and turning applications
US6689450B2 (en) * 2001-03-27 2004-02-10 Seco Tools Ab Enhanced Al2O3-Ti(C,N) multi-coating deposited at low temperature
US8012611B2 (en) 2004-10-29 2011-09-06 Sumitomo Electric Hardmetal Corp. Surface-coated cutting tool
EP2039447A1 (en) 2007-09-13 2009-03-25 Seco Tools Ab Coated cutting insert for milling applications
US8053063B2 (en) 2007-09-13 2011-11-08 Seco Tools Ab Coated cutting insert for milling applications
US8084148B2 (en) 2007-09-13 2011-12-27 Seco Tools Ab Insert for milling of cast iron
US8142621B2 (en) 2007-09-13 2012-03-27 Seco Tools Ab Insert for milling of cast iron
US8192793B2 (en) 2007-09-13 2012-06-05 Seco Tools Ab Coated cutting insert for milling applications

Also Published As

Publication number Publication date
DE69619272D1 (de) 2002-03-21
JP2000515433A (ja) 2000-11-21
US6062776A (en) 2000-05-16
ATE213282T1 (de) 2002-02-15
BR9611788A (pt) 1999-07-13
IL124476A0 (en) 1998-12-06
DE69619272T2 (de) 2002-10-31
KR100430360B1 (ko) 2004-07-16
EP0870073B1 (en) 2002-02-13
KR19990071774A (ko) 1999-09-27
CN1203636A (zh) 1998-12-30
EP0870073A1 (en) 1998-10-14
IL124476A (en) 2001-08-26

Similar Documents

Publication Publication Date Title
EP0870073B1 (en) Coated cutting insert and method of making it
EP0871796B1 (en) Coated milling insert and method of making it
US6221479B1 (en) Cemented carbide insert for turning, milling and drilling
US5786069A (en) Coated turning insert
US5945207A (en) Coated cutting insert
EP0874919B1 (en) Coated turning insert and method of making it
EP1218557B1 (en) Coated grooving or parting insert
EP1953258A1 (en) Texture-hardened alpha-alumina coated tool
EP1348779A1 (en) Coated cutting tool for turning of steel
US8043729B2 (en) Coated cutting tool insert
WO2009011648A1 (en) Textured alpha- alumina coated cutting tool insert for turning of steel
EP1100979B1 (en) Coated grooving or parting insert
EP1997938A2 (en) Coated cutting tool insert
WO2001016389A1 (en) Coated milling insert
US8192793B2 (en) Coated cutting insert for milling applications
EP1676939A1 (en) Coated cutting insert
US7429151B2 (en) Coated inserts for wet milling

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 96198660.3

Country of ref document: CN

AK Designated states

Kind code of ref document: A1

Designated state(s): BR CN IL JP KR US

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): AT BE CH DE DK ES FI FR GB GR IE IT LU MC NL PT SE

DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
121 Ep: the epo has been informed by wipo that ep was designated in this application
WWE Wipo information: entry into national phase

Ref document number: 1996941283

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 1019980704052

Country of ref document: KR

WWE Wipo information: entry into national phase

Ref document number: 09077370

Country of ref document: US

WWP Wipo information: published in national office

Ref document number: 1996941283

Country of ref document: EP

WWP Wipo information: published in national office

Ref document number: 1019980704052

Country of ref document: KR

WWG Wipo information: grant in national office

Ref document number: 1996941283

Country of ref document: EP

WWG Wipo information: grant in national office

Ref document number: 1019980704052

Country of ref document: KR