WO1997001322A1 - Produits de soins capillaires contenant au moins une substance de soins capillaires - Google Patents

Produits de soins capillaires contenant au moins une substance de soins capillaires Download PDF

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Publication number
WO1997001322A1
WO1997001322A1 PCT/EP1996/002481 EP9602481W WO9701322A1 WO 1997001322 A1 WO1997001322 A1 WO 1997001322A1 EP 9602481 W EP9602481 W EP 9602481W WO 9701322 A1 WO9701322 A1 WO 9701322A1
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WO
WIPO (PCT)
Prior art keywords
hair
hair treatment
composition according
treatment composition
general formula
Prior art date
Application number
PCT/EP1996/002481
Other languages
German (de)
English (en)
Inventor
Mustafa Akram
Herbert Deutz
Astrid Kleen
Original Assignee
Hans Schwarzkopf Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE1996117569 external-priority patent/DE19617569A1/de
Application filed by Hans Schwarzkopf Gmbh filed Critical Hans Schwarzkopf Gmbh
Priority to AU63013/96A priority Critical patent/AU6301396A/en
Publication of WO1997001322A1 publication Critical patent/WO1997001322A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/55—Phosphorus compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/42—Amides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners

Definitions

  • the invention relates to preparations for hair treatment with constituents customary in cosmetics with at least one care substance
  • the hair treatment agents according to the invention include all hair cleansing agents (shampoos), hair shaping agents (permanent wave preparations), hair setting agents (hair waxes, gels, varnishes, liquid strengthening agents, sprays, foams) and hair care agents (hair lotions, pomades, rinses, and cures) ), as described for example in the book “Cosmetics” by Wilfried Umbach, Georg Thieme Verlag Stuttgart, New York, 1988 on pages 223 to 280
  • the scales are available from and break partially out The light falling on it is no longer reflected rt, the hair looks dull and lackluster Hair treatments alleviate worse problems, but often make the hair "heavy” and often hide the image of "too much of a good thing" due to their valuable ingredients. They also only work on the surface of the hair and can therefore do so do not regenerate completely
  • the object of the invention is achieved by the hair treatment agents mentioned in claims 1 to 25.
  • the care substances of the general formula (I) according to the invention are intended to penetrate the hair to be treated and to be stable in the pH range from 2 to 12 Combability and improved grip, above all a clearly measurable and permanent structural stabilization of the hair, in particular in damaged areas, can be achieved
  • the hair treatment compositions of the invention can, in addition to at least one compound of the general formula (I) in amounts of 0.01 to 10% by weight, additionally tiyptophan or another amino acid from the series glycine, alanine, leucine, isoleucine, norleucine, phenylalanine, arginine, histidine, proline , Hydroxyproline, cystine, cysteine, methionine, aspartic acid, glutamic acid and cysteic acid and / or mixtures thereof in amounts of 0.01 to 5% by weight.
  • tiyptophan or another amino acid from the series glycine, alanine, leucine, isoleucine, norleucine, phenylalanine, arginine, histidine, proline , Hydroxyproline, cystine, cysteine, methionine, aspartic acid, glutamic acid and cysteic acid and / or mixtures thereof in amounts of 0.01 to 5% by weight.
  • typhophane can additionally be present up to the same amount by weight of the compounds of the general formula (I) contained.
  • the hair treatment compositions of the invention can additionally contain one or more care substances, such as panthenol, tocopherol, wheat proteins, lecithins, keratin and silk hydrolyzates, Contain phospholipids, ceramides, pseudoceramides, phytosterols.
  • care substances such as panthenol, tocopherol, wheat proteins, lecithins, keratin and silk hydrolyzates, Contain phospholipids, ceramides, pseudoceramides, phytosterols.
  • Proteins and especially wheat proteins include in the Rompp Chemie Lexikon, 9th edition, vol. 5 on pages 3650 to 3657 and vol. 6 on pages 5029 to 5030. in the Rompp Chemie Lexikon, 9 edition, vol. 6 on pages 4637 to 4639. Structure and properties of phyto-sterols are described, for example, in perfumeerie & Kosmetik, 75th year (1994) on pages 755 to 758, and lecithins and their properties are for example from SA Riethmayer in SOFW, 121 volume (1995) discussed on pages 367 to 72. Ceramides and pseudoceramides are dealt with in the Rompp Chemie Lexikon, 9th edition, vol. 1 on page 623 with references
  • Hair cleaners with care substances are described in the documents DE 33 36 609, US 38 16 616 and US 42 920 212. These are care substances that accumulate in the cuticle area and consequently can only influence the hair from the outside. The active substances can do this Do not restructure hair from the inside
  • the hair cleansing agents according to the invention with one or more compound (s) of the general formula (I) as a care substance restructure the hair from the inside.
  • Thermoanalytical measurements on treated hair prove that the structure of the damaged hair is improved by treating a hair cleansing agent according to the invention
  • the hair cleansing agents according to the invention can, as water-soluble anionic, washing-active substances, preferably alkali metal, magnesium, ammonium and / or C 2 - to C 3 - to alkanolammonium salts of alkyl sulfuric acid hemiesters with 8 to 18 and preferably 12 to 16 carbon atoms in the Alkyl group or of alkyl polyglycol ether sulfuric acid hemiesters with 8 to 18 and preferably 12 to 16 carbon atoms in the alkyl group and 1 to 6 glycol ether groups in the molecule.
  • anionic detergent substances are primary and secondary linear alkanesulfonates with 10 to 18 carbon atoms, alkenesulfonates and hydroxyalkanesulfonates Cg - to Cjg- fatty acid alkylolamide polyglycol ether sulfates, Cg to C ⁇ g fatty acid monoglyceride sulfates, sulfosuccinic acid monoalkyl esters with 8 to 18 carbon atoms in the alkyl group or - dialkyl esters with 6 to 10 carbon atoms in the alkyl groups, alkylpolyglycol 18 carbons with men in the alkyl group and 2 to 6 polyglycol ether groups in the molecule as well as acyl sarcosines, acyl taurides and acyl isethionates with 8 to 18 carbon atoms in the acyl group
  • concentration of the anionic surface-active substances in the shampoo can be about 5 to about 50% by weight and
  • the hair cleansing agents according to the invention can contain standard additives and build-up substances, for example thickeners from the type Cg to C j g-fatty realkylolamide, opacifying agents, for example of the type of ethylene glycol distearate, pH-stability catalysts such as alkali or ammonium phosphates or -zitrate, preservatives, such as p-
  • the hair cleaners according to the invention with contents of 0.1 to 5% by weight of care substance (s) of the general formula (I) are distinguished by an unexpectedly intensive improvement in the properties of the hair washed with them.
  • the inner structure of the hair is significantly improved compared to shampoos with previously used care substances. This is very surprising because the other recipe ingredients themselves have no effects on the inner hair structure.
  • Example 1 or Example 2 Shampoo produced according to Example 1 or Example 2 was used to wash the hair on the head of women with hair damaged by permanent wave treatment. Comparative shampoos with the same composition, but without the addition of serine, were also used. Special investigations have shown that only the attacked hair treated with shampoos according to Example 1 and Example 2 has received clearly measurable structural improvements. Thus, a "repair effect" was found on the damaged hair.
  • the physical, chemical and morphological properties of hair are negatively influenced by various types of action.
  • the hair is affected by cosmetic treatments, such as repeated bleaching, perming and dyeing, but also by frequent washing of the hair with degreasing surfactants, by climatic influences, such as differences in humidity and temperature, or by the intensive action of sunlight and by mechanical treatment such as brushing, combing and terry towels, especially in the area of the ends of the hair, subject to severe wear and tear, while the hair at the hairline has a healthy, undamaged structure.
  • the mostly different hair structure between the hairline and the hair tips is a big problem with the permanent wave treatment of the hair.
  • the permanent wave agent is adjusted in its wave effectiveness to the stressed and damaged hair tips, then you get an insufficient permanent deformation of the hair at the hairline. If, on the other hand, you adapt the permanent wave agent in its wave effectiveness to the healthy, undamaged structure of the hair at the hairline, the hair at the damaged hair tip can be damaged so much that it can lead to a severely restricted curl up to breaking off the hair.
  • the procedure is generally such that the hair which has been washed and wiped off with a towel is divided into strands, these strands are individually wound onto permanent wave curlers and then moistened with the shaping agent.
  • the hair is rinsed with water, then fixed by oxidation, then the curlers are removed and, if appropriate, the fixative is applied again, the hair is rinsed again with water and, if appropriate, aftertreated with a treatment preparation.
  • the hair is known to be mechanically and chemically damaged after a permanent wave shaping treatment, so that aftertreatment with a hair treatment agent is necessary in order to give the hair a natural feel and shine again
  • EP-PS 0 014 479 describes an agent for the treatment of hair before winding on permanent wave curlers, which has a content of a methylpolysiloxane and / or paraffin or isoparaffin, a cationic compound and an ampholytic compound.
  • this agent is in relation to the protection of the damaged hair tips during the permanent waving process and thus on the uniformity of the permanent waving is not fully satisfactory
  • EP-OS 0 260 641 discloses an emulsion-like hair treatment agent with hair-fixing properties containing a hair-fixing polymer, a silicone oil, a non-ionic surfactant and ethanol.
  • US Pat. No. 4,954,335 discloses clear, non-emulsion-like ones Hair conditioning agents are described which contain, among other things, a combination of non-ionic surfactant, ethanol and a volatile silicone oil.
  • Thickeners in the form of polyacrylic acid derivatives can be added to the agents, but they necessarily contain quaternary ammonium compounds and an amidoamine compound with a conditioning effect from the PCT ⁇ VO 89/04164 is a hair conditioning agent containing thickener, a non-volatile polydiorganosiloxane in Form of an oil-in-water emulsion and a non-ionic surfactant known A care and protective effect of the agents during a permanent wave treatment is not described
  • the object was therefore to provide a hair treatment agent which protects the hair from severe damage during or after the permanent wave process. It has been found that by adding at least one of the compounds according to claim 1 to the base curl or by means of a post-treatment agent which contains at least one of the compounds of the general formula (I) according to claim 1 as a care component, the object is achieved in an outstanding manner
  • This may contain 0.1 to 10% by weight, preferably 0.8 to 5% by weight, of a care substance of the general formula (I) in the one-component or two-component corrugating agent system
  • the pH of component A is 6 0
  • the pH of component B is 8 5 Before use, 14 g of component A and 66 g of component B are mixed with one another.
  • the pH of the hair styling agent thus obtained is 7.3
  • the washed and terry hair is wound on rollers with a diameter of 6 millimeters and then moistened evenly with the hair shaping agent described above. After an exposure time of 18 minutes, the hair is rinsed thoroughly with water and then oxidatively treated with 80 g of a 3 percent aqueous hydrogen peroxide solution. After removing the curlers, the hair is again with
  • One-component hair styling agent is one-component hair styling agent
  • Means for setting the hair are described in DE 40 34 315. There, an agent for setting the hair is claimed which contains a combination of a partially or completely neutralized amphoteric polymer and a nonionic polymer. This results in good hair strengthening and good hairstyle durability. However, it is not possible to improve the structure of damaged hair with such a product
  • the hair fixatives according to the invention which contain one or more compounds of the general formula (I) in amounts of 0.01 to 10% by weight as a care substance, improve not only good and stable hair but also an improvement in the damaged structure of the hair
  • the hair fixatives according to the invention can be hair waxes, hair gels, liquid hair fixes, hair sprays or hair foams
  • Nonionic polymers such as polyvinylpyrrolidone, copolymers of vinylpyrrolidone and vinyl acetate or terpolymers of vinylpyrrolidone, vinyl acetate and vinyl propionate can be used as film formers in the hair setting agent according to the invention
  • copolymers of vinylpyrrolidone and vinyl acetate which are sold, for example, by the company BASF, Ludwigshafen / FRG under the name LUVISKOL VA, and terpolymers of vinylpyrrolidone, vinyl acetate and vinyl propionate, which are sold by the company BASF, Ludwigshafen / FRG the name LUVISKOL VAP
  • a liquid hair-strengthening composition according to the invention preferably has a pH of 7 to 9.5 and can be in the form of an alcoholic or aqueous-alcoholic solution
  • Suitable alcohols are, in particular, the lower alcohols with 1 to 4 carbon atoms usually used for cosmetic purposes, such as ethanol and isopropanol, for example. These alcohols can be used in the agent according to the invention in an amount of 10 to 98% by weight, preferably in an amount of 20 to 90% by weight
  • further hair cosmetic additives such as perfume oils, herbal extracts, bactericidal or fungicidal substances, solubilizers for perfume oils, plasticizers such as phthalic acid esters or alkyl citrates, or hydrophobicizing substances such as silicone oils, can of course also be contained in the agent according to the invention, provided such additives appear useful and expedient .
  • the agent according to the invention for setting the hair can also be in the form of an aerosol hair spray or aerosol hair lacquer or a non-aerosol hair spray or non-aerosol hair lacquer sprayable with the aid of a suitable spray device (for example a spray pump).
  • a suitable spray device for example a spray pump
  • the agent according to the invention is in the form of an aerosol hairspray or aerosol hair lacquer, it additionally contains 2 to 80% by weight of a propellant and is filled into a pressure vessel.
  • a propellant such as, for example, are suitable as blowing agents.
  • gaseous blowing agents such as N 2 , N 2 O and CO 2 , and mixtures of the above-mentioned compounds , suitable.
  • dimethyl ether and mixtures of lower alkanes with dimethyl ether are preferred, the use of dimethyl
  • the means for setting the hair according to the present invention bring about an improvement in the hair structure with, at the same time, excellent setting. This was not to be expected from the content of compounds of the general formula (I).
  • the present invention also relates to cosmetic hair care products in the form of hair washers, hair pomades, hair rinses, hair treatments, spray preparations, etc. with 0.01 to 10% by weight of the compounds of the general formula (I).
  • compositions are usually used for this purpose which contain cationic surface-active substances, in particular quaternary ammonium compounds and / or film-forming polymers, in particular those of a cationic type, and / or protein hydrolyzates as conditioning agents.
  • cationic surface-active substances in particular quaternary ammonium compounds and / or film-forming polymers, in particular those of a cationic type, and / or protein hydrolyzates.
  • active ingredients are not only added to aftertreatment agents, but can also be used in so-called conditioning shampoos, which likewise improves the appearance, feel and shine of the hair.
  • compositions mentioned are not or only insufficiently able to regenerate damaged hair from "inside", there is still a great need for the new and further development of corresponding products.
  • the invention solves this need in that it provides hair care products based on conventional carrier materials, ie solutions, emulsions, dispersions, lotions, aerosol spray compositions, etc., from conventional combinations of active substances, as described, for example, in documents DE 43 24 962 and DE 4234413, exist and additionally contain at least one of the compounds of the general formula (I) as a care substance.
  • Emulgin B 2 2.0 g
  • Emulgin B 2 2.0 g
  • Promois Silk 1000 0.5 g
  • Emulgin B 2 2.0 g
  • Thermoanalytical investigations are particularly suitable for the characterization of two-phase systems, which also include human hair as fiber keratins with their crystalline ⁇ -helix component and amorphous matrix component.
  • glass transitions and aging behavior of the amorphous matrix can be examined, on the other hand, the melting behavior of the crystalline, helical phase provides important insights.
  • Thermal analysis was first described in 1899 (WC Roberts-Austen, Proc. Inst. Mech. Eng., London 1899, page 35ff), first differential thermal analysis (DTA) on protein fibers was carried out in the late 1950s (F. Schwenker, JH Dusenbury, text Res. J. 1963, 30, page 800ff; WD Felix, MA Mcdowall, H.
  • thermoanalytical measuring methods such as DTA, HP-DTA (high pressure, high pressure DTA) and DSC (differential scanning calorimetry, dynamic differential calorimetry), were applied to keratin fibers (G. Ebert, FH Müller, Proc. Int. Woll Text. Res. Conf., Cirtel, Paris 1965, 4, page 487ff; G. Ebert, J. Wendorff, Kolloid-Zeitschrfit and Zeitschrift. Harrison Polymer 1967, 216/217, page 277ff; M. Spei, R Holzem, Colloid and Polymer Sei. 1987, 265, page 965ff; M. Spei, R.
  • the HP-DSC method has been used to investigate keratin fibers that solve the problems with pyrolytic effects, as they occur in conventional DSC, and problems with data acquisition and interpretation, such as those contained in the DTA, rule out.
  • DSC measurements are carried out on keratins that are mixed with water in commercially available, pressure-resistant measuring capsules are included.
  • high water pressure develops in the encapsulated steel crucibles when heated above 100 ° C, from which the HP-DSC analysis is derived.
  • DSC dynamic differential calorimetry
  • structural and chemical states and changes in fiber keratins and in particular in human hair can thus be recorded.
  • the calorimetrically detectable processes can be recorded on human hair using thermograms and their peak positions, structures and areas as indicators for influencing order-disorder transitions by changing internal and / or external parameters, e.g. by cosmetic treatment of the hair. That From the endothermic peaks recorded in the thermogram of human hair, statements about the strength or damage of the human hair fiber can be made based on the peak position (transition point) and peak area (conversion enthalpy).
  • the care substance (s) contained in the hair treatment compositions according to the invention such as e.g. Serine penetrate the hair and, due to their polar character, form additional hydrogen bonds and salt bonds in the matrix, which in turn leads to increased stability against deformation and thus causes a general structural stabilization of the hair. This can be seen in thermoanalytical studies on the human hair treated with hair treatment agents according to the invention by a shift in the transformation or melting point of the human hair fibers to higher temperatures.
  • Table III shows the result of comparative tests using DSC (dry heating), in which damaged human hair is compared to the same hair samples, but treated on the one hand with tap water for 20 minutes and on the other hand with a 1% aqueous L-serine solution for 20 minutes.
  • the structural stabilization caused by the hair treatment agents according to the invention is demonstrated by the so-called fatigue test.
  • the human hair to be examined is individually clamped on a platform at the upper end and provided with a weight (30 to 40 g) at the lower end so that it lies straight on the floor.
  • the platform rises and falls vertically, so that the hair fibers are alternately loaded and relieved.
  • 100,000 cycles are performed at a frequency of 1 cycle / second and the survival rate is determined.
  • the stability of the fibers relative to one another is determined from this survival rate.
  • Tension-elongation measurements were also carried out on human hair, each in triplicate using a permanent wave preparation according to Example 3, but containing 2% by weight D / L-serine or 2% by weight L-lysine hydrochloride as a care substance. Compared to human hair, treated with the appropriate permanent wave preparation without a care substance, significantly higher strengths were achieved. Table V shows the tensile strength required in each case, which results from the tensile / stretch tests.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne des produits de soins capillaires contenant des composants usuels en cosmétique ainsi qu'au moins une substance de soins capillaires. L'invention vise à créer des produits de soins capillaires contenant des composants usuels en cosmétique ainsi qu'au moins une substance de soins capillaires, qui permettent d'améliorer, de l'intérieur, l'état des cheveux pendant le traitement. Les substances de soins utilisées doivent pénétrer dans les cheveux à traiter et être stables sur une plage de pH comprise entre 2 et 12, ce qui doit permettre de provoquer une stabilisation de la structure des cheveux nettement mesurable, notamment dans des régions endommagées. A cet effet, on utilise les produits de soins capillaires, mentionnés dans les revendications 1 à 25, qui contiennent comme substance(s) de soins les composés de formule (I) décrits dans ces revendications.
PCT/EP1996/002481 1995-06-26 1996-06-07 Produits de soins capillaires contenant au moins une substance de soins capillaires WO1997001322A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU63013/96A AU6301396A (en) 1995-06-26 1996-06-07 Hair care products with at least one conditioner

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE19522569 1995-06-26
DE1996117569 DE19617569A1 (de) 1996-05-02 1996-05-02 Haarbehandlungsmittel mit mindestens einem Pflegestoff
DE19617569.0 1996-05-02
DE19522569.4 1996-05-02

Publications (1)

Publication Number Publication Date
WO1997001322A1 true WO1997001322A1 (fr) 1997-01-16

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WO (1) WO1997001322A1 (fr)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2771289A1 (fr) * 1997-11-20 1999-05-28 Unilever Nv Composition de traitement capillaire abase de precurseurs de ceramide
WO2000048556A1 (fr) * 1999-02-18 2000-08-24 Unilever Plc Composes d'ammonium quaternaire mono et dialkyliques et silicone dans des compositions de tonification des cheveux
EP1515715A2 (fr) * 2002-06-26 2005-03-23 Nicholas V. Dr. Perricone Traitements pour les cheveux et les ongles a base d'alcanolamines
FR2939037A1 (fr) * 2008-12-02 2010-06-04 Oreal Association de glycine, de serine, de valine et de threonine pour proteger le cheveu chez l'homme
FR2939028A1 (fr) * 2008-12-02 2010-06-04 Oreal Association d'acide glutamique, de glutathion reduit et de threonine pour proteger le cheveu chez la femme
WO2010064203A1 (fr) * 2008-12-02 2010-06-10 L'oreal Combinaison de glutathion réduit et d'acides aminés pour améliorer la qualité des cheveux de femmes
EP1326577B2 (fr) † 2000-10-19 2012-08-01 Henkel AG & Co. KGaA Nouvelle utilisation d'acides carboxyliques a chaine courte

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0161811A2 (fr) * 1984-04-16 1985-11-21 Nippon Oil And Fats Company, Limited Composition pour le rinçage des cheveux
EP0303792A1 (fr) * 1987-06-19 1989-02-22 S.C. Johnson & Son, Inc. Composition pour revivifier les cheveux contenant des sels d'acides aminés formant une pellicule
US4906460A (en) * 1988-08-05 1990-03-06 Sorenco Additive for hair treatment compositions
EP0358528A2 (fr) * 1988-09-09 1990-03-14 Unilever Plc Composition cosmétique
EP0530865A1 (fr) * 1991-07-08 1993-03-10 Crinos Industria Farmacobiologica S.p.A. Composition de nettoyage de la peau, du cuir chevelu et des cheveux
FR2685201A1 (fr) * 1991-12-23 1993-06-25 Oreal Utilisation du methylsulfate de 4-[(2-oxo-3-bornylidene)methyl]-phenyltrimethylammonium dans une composition de deformation permanente des cheveux pour la protection, contre la lumiere.

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0161811A2 (fr) * 1984-04-16 1985-11-21 Nippon Oil And Fats Company, Limited Composition pour le rinçage des cheveux
EP0303792A1 (fr) * 1987-06-19 1989-02-22 S.C. Johnson & Son, Inc. Composition pour revivifier les cheveux contenant des sels d'acides aminés formant une pellicule
US4906460A (en) * 1988-08-05 1990-03-06 Sorenco Additive for hair treatment compositions
EP0358528A2 (fr) * 1988-09-09 1990-03-14 Unilever Plc Composition cosmétique
EP0530865A1 (fr) * 1991-07-08 1993-03-10 Crinos Industria Farmacobiologica S.p.A. Composition de nettoyage de la peau, du cuir chevelu et des cheveux
FR2685201A1 (fr) * 1991-12-23 1993-06-25 Oreal Utilisation du methylsulfate de 4-[(2-oxo-3-bornylidene)methyl]-phenyltrimethylammonium dans une composition de deformation permanente des cheveux pour la protection, contre la lumiere.

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2771289A1 (fr) * 1997-11-20 1999-05-28 Unilever Nv Composition de traitement capillaire abase de precurseurs de ceramide
WO2000048556A1 (fr) * 1999-02-18 2000-08-24 Unilever Plc Composes d'ammonium quaternaire mono et dialkyliques et silicone dans des compositions de tonification des cheveux
AU764709B2 (en) * 1999-02-18 2003-08-28 Unilever Plc Mono and dialkyl quats with silicone in conditioning compositions
EP1326577B2 (fr) † 2000-10-19 2012-08-01 Henkel AG & Co. KGaA Nouvelle utilisation d'acides carboxyliques a chaine courte
EP1515715A2 (fr) * 2002-06-26 2005-03-23 Nicholas V. Dr. Perricone Traitements pour les cheveux et les ongles a base d'alcanolamines
EP1515715A4 (fr) * 2002-06-26 2006-06-14 Perricone Nicholas V Dr Traitements pour les cheveux et les ongles a base d'alcanolamines
FR2939037A1 (fr) * 2008-12-02 2010-06-04 Oreal Association de glycine, de serine, de valine et de threonine pour proteger le cheveu chez l'homme
FR2939028A1 (fr) * 2008-12-02 2010-06-04 Oreal Association d'acide glutamique, de glutathion reduit et de threonine pour proteger le cheveu chez la femme
WO2010064203A1 (fr) * 2008-12-02 2010-06-10 L'oreal Combinaison de glutathion réduit et d'acides aminés pour améliorer la qualité des cheveux de femmes

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