WO1996041241A1 - Oil delivery sheet material for use in various printer devices - Google Patents

Oil delivery sheet material for use in various printer devices Download PDF

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Publication number
WO1996041241A1
WO1996041241A1 PCT/US1996/007734 US9607734W WO9641241A1 WO 1996041241 A1 WO1996041241 A1 WO 1996041241A1 US 9607734 W US9607734 W US 9607734W WO 9641241 A1 WO9641241 A1 WO 9641241A1
Authority
WO
WIPO (PCT)
Prior art keywords
web
release agent
contact surface
assembly
membrane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US1996/007734
Other languages
English (en)
French (fr)
Inventor
Alex R. Hobson
Robert L. Sassa
Beth P. Powell
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WL Gore and Associates Inc
Original Assignee
WL Gore and Associates Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by WL Gore and Associates Inc filed Critical WL Gore and Associates Inc
Priority to EP96916650A priority Critical patent/EP0774133A1/en
Priority to AU59332/96A priority patent/AU690849B2/en
Priority to CA 2190617 priority patent/CA2190617C/en
Priority to JP50073497A priority patent/JPH10503860A/ja
Publication of WO1996041241A1 publication Critical patent/WO1996041241A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G15/00Apparatus for electrographic processes using a charge pattern
    • G03G15/20Apparatus for electrographic processes using a charge pattern for fixing, e.g. by using heat
    • G03G15/2003Apparatus for electrographic processes using a charge pattern for fixing, e.g. by using heat using heat
    • G03G15/2014Apparatus for electrographic processes using a charge pattern for fixing, e.g. by using heat using heat using contact heat
    • G03G15/2017Structural details of the fixing unit in general, e.g. cooling means, heat shielding means
    • G03G15/2025Structural details of the fixing unit in general, e.g. cooling means, heat shielding means with special means for lubricating and/or cleaning the fixing unit, e.g. applying offset preventing fluid
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G2215/00Apparatus for electrophotographic processes
    • G03G2215/20Details of the fixing device or porcess
    • G03G2215/2093Release agent handling devices
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G2215/00Apparatus for electrophotographic processes
    • G03G2215/20Details of the fixing device or porcess
    • G03G2215/2093Release agent handling devices
    • G03G2215/2096Release agent handling devices using porous fluoropolymers for wicking the release agent
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S118/00Coating apparatus
    • Y10S118/15Roller structure
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24826Spot bonds connect components
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24843Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] with heat sealable or heat releasable adhesive layer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/249921Web or sheet containing structurally defined element or component
    • Y10T428/249953Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249955Void-containing component partially impregnated with adjacent component
    • Y10T428/249958Void-containing component is synthetic resin or natural rubbers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/249921Web or sheet containing structurally defined element or component
    • Y10T428/249953Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249962Void-containing component has a continuous matrix of fibers only [e.g., porous paper, etc.]
    • Y10T428/249964Fibers of defined composition
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/3154Of fluorinated addition polymer from unsaturated monomers
    • Y10T428/31544Addition polymer is perhalogenated

Definitions

  • a web has oil self contained within it and therefore will deliver the oil consistently as the web is indexed to expose an unused portion of the web in contact with the fuser roller.
  • the web has all of the oil contained within the pores of the material and therefore does not require a separate reservoir of oil which, depending on the configuration of the assembly, can be messy and difficult to meter. Webs tend to have superior cleaning ability because the collected toner and dirt is removed from the fuser roller with the taken up web material.
  • sintered PTFE material such as that disclosed in PCT/GB92/01958 is brittle and, thus, has to be relatively thick to avoid breakage in use.
  • the necessary thickness of the material means that less material can be used due to space constraints.
  • the material is 0.010" (0.25 mm) thick or thicker in order to provide enough structural integrity for a web application. This material is suitable for some applications, but in no way addresses all of the demands for printer applications, especially those applications in which a lot of release agent is necessary.
  • the sintered PTFE particle material has extremely low elongation, which causes it to prematurely crack, break or tear in applications if the stress applied is too high.
  • Figure 11 is an enlarged cross-section view of the web material used in the present invention having a gravure print adhesive pattern;
  • Figure 12 is a top plane view of a 45° gravure pattern;
  • Figure 13 is a top plane view of a rosette gravure pattern:
  • Figure 14 is a top plane view, microporous membrane up. of the web material with continuous adhesive from Example 5.
  • ICP-AES Inductively Coupled Plasma-Atomic Emission Spectroscopy
  • Fabric substrate materials may be nonwoven, such as a spunbonded, wet-laid, melt blown or felted polyester, nylon, polypropylene, aramid, or may be light woven material of polyester, nylon, polypropylene, aramid, PTFE, FEP, PFA, or the like.
  • the substrate material is chosen to meet the specifications of the system, such as heat, mechanical, and chemical compatibility requirements.
  • the ePTFE membrane employed in the present invention should have the following properties: a thickness of about 0.0005" (0.0127 mm) to 0.125" (3.175 mm); a porosity of about 30 to 98%: and a bubble point (with isopropyl alcohol) of 0.4 to 60 psi (0.03 to 4.2 kg/cm 2 ).
  • the preferred ePTFE membrane properties are: a thickness of about 0.0254 mm to 0.381 mm; a porosity of about 70 to 95%; and a bubble point of about 1.0 to 30 psi (0.07 to 2.1 kg/cm 2 ), with the most preferable being from 2.0 to 20 psi (0.14 to 1.4 kg/cm 2 ).
  • the ePTFE membrane provides an even distribution and consistent delivery of the release agent.
  • the rate of distribution of release agent can be tightly controlled by adjusting one or more of a number of different properties. For instance, dimensions, porosity, equivalent pore size and other properties of the expanded PTFE membrane may be modified to provide specific properties.
  • the pattern formed on the membrane may be varied, for example, in degree of densification, depth, and amount of surface area densified. All of these factors can be controlled to provide required amounts and uniform dissemination of the release agent to the fuser.
  • ePTFE has a low coefficient of friction and exceptional wear characteristics, reducing wear on component parts and extending operational life of the apparatus. Fourth, the ePTFE can be readily cleaned of deposited toner and other contaminates, which may be necessary for refurbishment of the oiling webs.
  • the ePTFE can hold extremely high amounts of oil in its microporous structure.
  • the ePTFE membrane can hold up to 95% oil (or 0.95 cc oil per 1.0 cc of ePTFE membrane).
  • the oil holding capacity of the membrane may be adjusted from 0.35 cc of oil/cc of ePTFE to 0.95 cc of oil/cc of ePTFE, with the preferred being 0.55 to 0.87 cc of oil/cc (or 55 to 87%) of ePTFE.
  • the release agent is added to the membrane.
  • the release agent can be added to the membrane through a variety of techniques.
  • One method of application is by soaking the web material in a bath of the fluid. Over time, the voids of the ePTFE will be filled with the fluid through capillary action. After the pores of the ePTFE are filled to a desired amount, the web may be pulled out of the fluid and the excess fluid removed, such as by wiping, blotting or any other means which is appropriate to remove excess fluid.
  • Another method of application is by passing the web material between transfer coating rollers or spray apparatus in which the release fluid is added.
  • the web can be passed through a bath of the release fluid and then passed through calendering rollers to press the fluid in. In each of these instances, heat may be added to the fluid or to the web in order to facilitate the filling of the voids of the ePTFE membrane with the release fluid.
  • Any type of release agent may be used, such as silicone fluid, hydrocarbon fluids, alcohols, functionalized silicone fluids, water and others.
  • the preferred release fluid for most printer applications is dimethylsiloxane fluid, or silicone oil.
  • the release agent web assembly may comprise any configuration which is desirable to achieve delivery of release agent from the web to at least one contact surface of the printer device.
  • the release agent web is typically positioned so as to continually provide a clean web surface to the contact surface of the fuser.
  • the assembly may comprise one or more rotating members in order to meet this need.
  • the release agent web assembly comprises at least two rotating members which permit the web and the contact surface to move relative to each other.
  • Shown in Figure 4 is one apparatus for applying release fluid in a printer by employing a web 10 of the present invention.
  • This apparatus comprises a payoff shaft 42, a takeup shaft 44, a housing or frame 46, and an elastomeric roller or member 48 that can apply pressure to hold the web 10 to a fuser roller 50.
  • the elastomeric member 48 is spring loaded or includes some other form of mechanical biasing device 52 to maintain contact with the fixation roller 50.
  • a fresh release coating 54 is supplied on the fuser roller 50 to protect against adhesion of paper and toner 58 to the fuser roller 50 during the fixing process as the paper 58 passes between the fuser roller 50 and a pressure roller 60. Further, toner particles 56 adhered to the fuser roller are cleaned off as the roller passes the web 10.
  • the regular indexing of the web 10 assures that a fresh supply of oil and a clean web surface is always supplied.
  • the web material 62 comprises an ePTFE membrane 64 bonded to a substrate 66 of a spunbonded nonwoven polyester
  • the membrane 64 and the substrate 66 are adhered together along layer 68, comprising the polyester layer 66 melted and flowed into and around the nodes and fibrils of the ePTFE membrane 64.
  • the polyester cools and hardens, the polyester and ePTFE are mechanically adhered together.
  • the adhesive is provided as a continuous film, then the tension is no longer localized, but rather is distributed across the entire web. As displayed in Figure 14, wrinkles 98 form in the machine direction when the continuous film backing 92 buckles around the microporous membrane 12. As a result, the contact area between the membrane and the fuser roller may be decreased and irregular, thus dramatically increasing tracking and rewind problems.
  • the transition zone 100 between the saturated 102 and unsaturated 104 sections on the used portion of the web mirrors the paper edge on the fuser roller.
  • the web was assembled into a XEROX® Model 5028 web cartridge and placed into a Model 5028 copier, Xerox Corporation, Rochester, NY.
  • the oil rate on a per page basis was determined by Inductively Coupled Plasma (ICP) analysis. Samples were taken every 500 copies with the following sampling scheme: The copier ran 3 then 97 copies for the set of 100 from which three data points were obtained. Then the rest of the sets of 100 were run at 1 then 99 copies. The dwell time between sets was limited to the electronic reset rate of the 5028 copy machine. A transfer efficiency of 61.4% was calculated based on the following measurements. Page Oil/Page (mg)
  • the web was assembled into a Model 5028 web cartridge and placed into a Model 5028 copier, Xerox Corporation, Rochester, NY.
  • the oil rate on a per page basis was determined by Inductively Coupled Plasma (ICP) analysis. Samples were taken every 500 copies with the following sampling scheme: The copier ran 3 then 97 copies for the set of 100 from which three data points were obtained. Then rest of the sets of 100 were run at 1 then 99 copies. The dwell time between sets was limited to the electronic reset rate of the 5028 copy machine. A transfer efficiency of 94.9% was calculated based on the following measurements.
  • ICP Inductively Coupled Plasma

Landscapes

  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Fixing For Electrophotography (AREA)
  • Impression-Transfer Materials And Handling Thereof (AREA)
  • Laminated Bodies (AREA)
PCT/US1996/007734 1995-06-07 1996-05-28 Oil delivery sheet material for use in various printer devices Ceased WO1996041241A1 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP96916650A EP0774133A1 (en) 1995-06-07 1996-05-28 Oil delivery sheet material for use in various printer devices
AU59332/96A AU690849B2 (en) 1995-06-07 1996-05-28 Oil delivery sheet material for use in various printer devices
CA 2190617 CA2190617C (en) 1995-06-07 1996-05-28 Oil delivery sheet material for use in various printer devices
JP50073497A JPH10503860A (ja) 1995-06-07 1996-05-28 各種印刷装置において使用するための油送達シート材

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US48553395A 1995-06-07 1995-06-07
US08/485,533 1995-06-07
US08/594,046 US5800908A (en) 1995-06-07 1996-01-30 Oil delivery sheet material for use in various printer devices
US08/594,046 1996-01-30

Publications (1)

Publication Number Publication Date
WO1996041241A1 true WO1996041241A1 (en) 1996-12-19

Family

ID=27048385

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1996/007734 Ceased WO1996041241A1 (en) 1995-06-07 1996-05-28 Oil delivery sheet material for use in various printer devices

Country Status (6)

Country Link
US (3) US5800908A (enExample)
EP (1) EP0774133A1 (enExample)
JP (1) JPH10503860A (enExample)
AU (1) AU690849B2 (enExample)
CA (1) CA2190617C (enExample)
WO (1) WO1996041241A1 (enExample)

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US5800908A (en) * 1995-06-07 1998-09-01 W. L. Gore & Associates, Inc. Oil delivery sheet material for use in various printer devices
US6026273A (en) * 1997-01-28 2000-02-15 Kabushiki Kaisha Toshiba Induction heat fixing device
JP3374058B2 (ja) * 1997-09-29 2003-02-04 シャープ株式会社 画像形成装置に具備される定着装置
US6253045B1 (en) 2000-04-13 2001-06-26 Lexmark International, Inc. Multi-level oiling device drive mechanism
US6266496B1 (en) 2000-04-13 2001-07-24 Lexmark International, Inc. Constant displacement oil web system and method of operating the same
US6223005B1 (en) 2000-04-13 2001-04-24 Lexmark International, Inc. Multi-level oiling device and process for a fuser system
US6537664B2 (en) * 2000-04-26 2003-03-25 Japan Vilene Company, Ltd. Cleaning sheet for a fuser member, a cleaning sheet supplier, and a cleaning apparatus
US6263182B1 (en) 2000-05-09 2001-07-17 Lexmark International, Inc. Fuser oil dispenser for an image forming apparatus
JP2002143738A (ja) 2000-11-14 2002-05-21 Nichias Corp オイル塗布装置用部材、その製造方法及びオイル塗布装置
US6434358B1 (en) 2000-12-13 2002-08-13 Lexmark International, Inc Oil secreting supply roller for an electrophotographic printer, including a method for applying a toner repelling substance to a fuser roller
US6434357B1 (en) * 2000-12-13 2002-08-13 Lexmark International, Inc. Oil exuding roller for an electrophotographic printer, including a method for its fabrication, and its function encompassed by a method for applying a toner repelling substance to a fuser roller
US6887305B2 (en) * 2002-05-29 2005-05-03 Exxonmobil Chemical Patents Inc. Release agent and uses for same
AU2005237985B2 (en) 2004-04-20 2010-10-21 Genzyme Corporation Surgical mesh-like implant
JP2006039465A (ja) * 2004-07-30 2006-02-09 Oki Data Corp 定着装置及び画像形成装置
JP4219358B2 (ja) * 2005-08-31 2009-02-04 シャープ株式会社 クリーニング部材及びこれを用いた画像形成装置
US20070084099A1 (en) * 2005-10-13 2007-04-19 Sarbo Benjamin C Toilet paper for potty training
US7540600B2 (en) * 2006-02-06 2009-06-02 Xerox Corporation Release agent applicator for imaging members in solid ink jet imaging systems
US9062219B2 (en) * 2009-01-21 2015-06-23 Xerox Corporation Superhydrophobic nano-fabrics and coatings
US9217968B2 (en) * 2009-01-21 2015-12-22 Xerox Corporation Fuser topcoats comprising superhydrophobic nano-fabric coatings
US9329544B2 (en) 2010-01-25 2016-05-03 Xerox Corporation Polymer-based long life fusers and their methods of making
US9471019B2 (en) 2010-01-25 2016-10-18 Xerox Corporation Polymer-based long life fusers
JP5812791B2 (ja) * 2011-03-28 2015-11-17 キヤノン株式会社 プリンター、複写機
JP6195790B2 (ja) * 2013-12-26 2017-09-13 株式会社美和テック 電子写真複写機用クリーニングウェブ

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WO1993008512A1 (en) * 1991-10-26 1993-04-29 W.L. Gore & Associates (Uk) Limited Oil transfer component
EP0616271A2 (en) * 1993-03-19 1994-09-21 Japan Gore-Tex, Inc. A liquid metering and coating device
EP0619534A2 (en) * 1993-04-08 1994-10-12 Japan Gore-Tex, Inc. An elastic fixing roll
US5478423A (en) * 1993-09-28 1995-12-26 W. L. Gore & Associates, Inc. Method for making a printer release agent supply wick

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US5800908A (en) * 1995-06-07 1998-09-01 W. L. Gore & Associates, Inc. Oil delivery sheet material for use in various printer devices

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4096227A (en) * 1973-07-03 1978-06-20 W. L. Gore & Associates, Inc. Process for producing filled porous PTFE products
WO1993008512A1 (en) * 1991-10-26 1993-04-29 W.L. Gore & Associates (Uk) Limited Oil transfer component
EP0616271A2 (en) * 1993-03-19 1994-09-21 Japan Gore-Tex, Inc. A liquid metering and coating device
EP0619534A2 (en) * 1993-04-08 1994-10-12 Japan Gore-Tex, Inc. An elastic fixing roll
US5478423A (en) * 1993-09-28 1995-12-26 W. L. Gore & Associates, Inc. Method for making a printer release agent supply wick

Also Published As

Publication number Publication date
US5800908A (en) 1998-09-01
US5788770A (en) 1998-08-04
JPH10503860A (ja) 1998-04-07
CA2190617C (en) 2000-01-18
EP0774133A1 (en) 1997-05-21
AU5933296A (en) 1996-12-30
US6117528A (en) 2000-09-12
AU690849B2 (en) 1998-04-30

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