Classifications

• • C—CHEMISTRY; METALLURGY
  • C06—EXPLOSIVES; MATCHES
  • C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
  • C06B25/00—Compositions containing a nitrated organic compound
  • C06B25/34—Compositions containing a nitrated organic compound the compound being a nitrated acyclic, alicyclic or heterocyclic amine
• • C—CHEMISTRY; METALLURGY
  • C06—EXPLOSIVES; MATCHES
  • C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
  • C06B31/00—Compositions containing an inorganic nitrogen-oxygen salt
  • C06B31/28—Compositions containing an inorganic nitrogen-oxygen salt the salt being ammonium nitrate
  • C06B31/32—Compositions containing an inorganic nitrogen-oxygen salt the salt being ammonium nitrate with a nitrated organic compound
• • C—CHEMISTRY; METALLURGY
  • C06—EXPLOSIVES; MATCHES
  • C06D—MEANS FOR GENERATING SMOKE OR MIST; GAS-ATTACK COMPOSITIONS; GENERATION OF GAS FOR BLASTING OR PROPULSION (CHEMICAL PART)
  • C06D5/00—Generation of pressure gas, e.g. for blasting cartridges, starting cartridges, rockets
  • C06D5/06—Generation of pressure gas, e.g. for blasting cartridges, starting cartridges, rockets by reaction of two or more solids

Definitions

• This invention relates to chemical compositions for generating large volumes of gas. More particularly, a mixture of nitroguanidine, ammonium nitrate, potassium nitrate and an elastomeric binder is ignited and the gaseous combustion products used to inflate an automotive airbag.
• Airbags as a component of a passive automobile restraint system, are installed in the steering column and passenger side dashboard of passenger automobiles.
• the airbags inflate in a collision and, by restraining the passengers, minimize injury.
• sensors mounted in the automobile detect a collision and send an electric signal igniting a chemical mixture that generates a large quantity of gas during deflagration. This gas is used to deploy the airbag.
• one common chemical mixture contains an azide, such as sodium azide, and an inorganic oxidizer, such as potassium perchlorate.
• the chemical mixture should generate a large volume of benign gases with minimal generation of noxious gases such as carbon monoxide (CO) and nitrogen oxides (N0 X ) .
• noxious gases such as carbon monoxide (CO) and nitrogen oxides (N0 X ) .
• CO carbon monoxide
• N0 X nitrogen oxides
• One problem with azide based compositions is a low gas output, typically less than 1.5 moles of gas per 100 grams of the mixture.
• Azide alternatives can provide a significant increase in gas output, typically through the addition of C0 2 and H 2 0 to the exhaust.
• the co-generation of CO and NO x is limited by proper selection of propellant composition and proper combustion.
• the chemical mixture must be thermally stable at temperatures in excess of 100°C. Automobiles may remain in service for many years and are subject to temperature extremes.
• the gas generating composition must have a working temperature in the range of from about -40°C to about 100°C. The chemical compounds when heated to a temperature of 100°C should not exhibit a significant net weight loss nor any evidence of physical change.
• the flame temperature or the combustion temperature of the chemical mixture should be as low as possible. At lower temperatures, decreased levels of CO are generated due to formation of more carbon dioxide. Lower levels of NO x are generated because of more favorable equilibrium and kinetic considerations.
• the chemical mixture should be deflagrating as opposed to detonating. On ignition, the mixture should burn rapidly rather than explode.
• One substitute for azide/inorganic oxidizer gas generating mixtures is a mixture of 5-aminotetrazole and strontium nitrate plus other additives as disclosed in U.S. Patent No. 5,035,757 to Poole. These compositions typically have greater gas outputs than azide generating gas compositions and exhibit good thermal stability. However, the flame temperature exceeds 2500K resulting in excessively high levels of CO and NO x . Furthermore, although toxicity concerns are considerably reduced, as compared to azide propellants, gas output levels are limited by the high levels of solids in the exhaust composition.
• one category of gas evolving compounds includes a guanidine salt.
• Gas is generated by igniting a mixture consisting essentially of (by weight) 55%-75% guanidine nitrate, 25%-45% of an oxidizer selected from the group consisting of potassium perchlorate and ammonium perchlorate, 0.5%-5% of a flow enhancer and up to 5% of a binder.
• the mixture disclosed in PCT Publication W095/25709 is for use an augmented airbag system.
• the main use of the propellant is to heat a pressurized gas which is the primary gas source for inflation of the bag.
• the amount of gas produced by the propellant is a small fraction of the total gas required to inflate the airbag.
• An extrudable, non-azide based, propellant is disclosed in U.S. Patent No. 5,125,684 to Cartwright.
• This propellant contains from about 45- 80 wt. % of an oxidizer salt; an effective amount of a cellulose based binder; and from about 10-35 wt. % of at least one energetic component.
• a nitrocellulose binder is not particularly favored for propellants intended for automobile airbag applications because of its poor chemical stability at the high temperatures experienced in the automobile environment. Additionally, the nitro (N0 2 ») groups of the nitrocellulose contribute to the formation of higher levels of N0 X during combustion.
• Ammonium nitrate (AN) based propellants offer the capability of meeting many of the targets for airbag inflation. Many AN-based propellants and explosives are known.
• German Patentschrift 851,919 published October 1952 by Imperial Chemicals Industries Limited, discloses a gas generating compound containing ammonium nitrate, sodium nitrate, guanidine nitrate and nitroguanidine.
• U.S. Patent No. 4,421,578 by Voreck, Jr. discloses an explosive mixture containing ammonium nitrate, potassium nitrate, nitroguanidine and ethylenediamine dinitrate. This composition was developed for explosive applications with an intent to replace TNT (2,4,6-trinitrotoluene) .
• the eutectic formed when ammonium nitrate, ethylene diamine dinitrate and guanidine nitrate are mixed in the disclosed proportion has a melting temperature below 100°C. Propellant mixtures with such a low melting point are not suitable for applications such as automobile airbag inflators where temperature stability in excess of 107°C is frequently required.
• IPDI isophorone di-isocyanate
• Milori blue an iron blue pigment.
• ick composition of U.S. Patent No. 4,421,578
• a problem with the use of pure ammonium nitrate is that the compound undergoes a series of structural phase transformations over the typical operating range of automobile airbag inflators.
• structural phase transitions are observed at -18°C, 32.3°C, 84.2°C and 125.2°C.
• the phase transition at 32.3°C is particularly problematic during temperature cycling because of a large change in the associated volume, on the order of 3.7%, by volume. Generally, any volumetric change is detrimental and it is desired to limit any volumetric change as much as possible.
• Phase stabilization of ammonium nitrate by the inclusion of potassium salts, such as potassium nitrate and potassium perchlorate is known.
• PSAN containing 15% by weight potassium nitrate will successfully avoid the problematic phase changes and volume changes associated with pure AN.
• an object of the invention to provide a chemical mixture that generates a volume of gas to inflate an automobile airbag.
• the chemical mixture is azide free, that the gas generated has a minimum amount of solids and noxious gases and that the propellant is physically and chemically stable through the range of temperatures required for automobile airbags.
• One unique feature of the invention is that the chemical mixture resists thermal decomposition at temperatures in excess of 100°C. Mixtures of many chemical compounds with ammonium nitrate are not stable at temperatures in excess of 100°C, and these mixtures are not suitable for use in automobile airbags.
• the chemical mixture includes nitroguanidine and ammonium nitrate in a stoichiometric ratio that minimizes the generation of noxious gases such as CO and NO ⁇ .
• the combination of phase stabilized ammonium nitrate and an elastomeric binder increases the flexibility of the composition preventing physical degradation of the propellant during thermal cycling. Physical degradation of a compacted propellant is manifest by volumetric changes, fracture, reduction in resistance to fracture, an increase in the burn rate and combinations thereof.
• the chemical mixture includes a mixture of nitroguanidine and ammonium nitrate in a ratio effective to produce deflagration rather than detonation on ignition. It is another feature of the invention that phase stabilized ammonium nitrate is used to prevent physical breakdown of the propellant on thermal cycling. In one embodiment, potassium nitrate is added to provide thermal stability up to 110°C. In addition, it is a feature of the invention that the flame temperature is less than 2450K. It is an advantage of the invention that by using a mixture of nitroguanidine, ammonium nitrate and potassium nitrate in a specified ratio, a non- explosive chemical mixture generates a large volume of benign gases on ignition. The flame temperature is below 2450K, minimizing generation of noxious gases such as CO and N0 ⁇ .
• a gas generating composition consisting essentially of from about 35% to about 55% by weight nitroguanidine and from about 45% to about 65% by weight phase stabilized ammonium nitrate.
• the composition has a melting temperature in excess of 100°C and deflagrates when ignited.
• a gas generating composition consisting essentially of from about 5% to about 40% by weight nitroguanidine, from an amount effective to increase the flexibility of the composition up to about 10%, by weight of an elastomeric binder, and from about 60% to about 85% by weight phase stabilized ammonium nitrate.
• the composition has a melting temperature in excess of 100°C and deflagrates when ignited.
• phase stabilized ammonium nitrate and nitroguanidine produces a series of chemical compositions that, when ignited, generate high levels of a gas that has a low content of noxious constituents such as CO and N0 ⁇ .
• the gas is characterized by a low level of residual solids and ballistics suitable for use as an inflator of automobile airbag units.
• An unexpected benefit of these chemical compositions is thermal stability. Aging of the chemical composition at temperatures in excess of 100°C does not cause a significant weight loss or a change in ballistic properties. This thermal stability in the ammonium nitrate - nitroguanidine combination was unexpected because of the typically high reactivity observed between ammonium nitrate and other materials at elevated temperatures.
• compositions Another unexpected benefit of these compositions is enhanced stability during thermal cycling. Thermal cycling of these compositions between -30°C and +80°C results in only very small changes in physical size and ballistic performance.
• Ammonium nitrate based propellants are particularly useful in automobile airbag inflators because of the high gas outputs and the low levels of residual solids resulting from their combustion. The only solids produced by phase stabilized ammonium nitrate are derived from the additives used to accomplish the phase stabilization.
• the chemical compositions of the invention include nitroguanidine (CH 4 N 4 0 2 ) , a highly energetic fuel having a large negative oxygen balance (-30.7%).
• Nitroguanidine can be combined in a stoichiometric ratio with phase stabilized ammonium nitrate to produce chemical mixtures that are relatively insensitive to ircpact (>180 kg/cm) , friction (>360 N) and electrostatic discharge (>3 J) .
• the stoichiometric ratio of oxidizer to fuel is adjusted to provide a level of free hydrogen in the exhaust gases of between zero and about 3% by volume. More preferably, the level of free hydrogen is between zero and about 0.5% by volume.
• the stoichiometric ratio of oxidizer to fuel is also adjusted to provide a level of free oxygen in the exhaust gases of from zero to about 4% by volume. More preferably, the level of free oxygen is from zero to about 0.5% by volume.
• Potassium salts such as potassium nitrate, potassium perchlorate, potassium dichromate, potassium oxalate and mixtures thereof, are the preferred phase stabilizers with potassium nitrate being most preferred.
• Other compounds and modifiers that are effective to phase stabilize ammonium nitrate are also suitable.
• the stabilizing agent is present in an amount effective to minimize a volumetric and structural change associated with the Phase IV * * ⁇ Phase III structural phase transition that is inherent to pure ammonium nitrate.
• the preferred phase stabilized ammonium nitrate contains from about 5% to about 25% by weight potassium nitrate and more preferably from about 10% to about 15% by weight potassium nitrate.
• the ratio of nitroguanidine to PSAN is, when substantially free of a binder, by weight, from about 1:1 to about 1:2 and more preferably from about 1:1.1 to about 1:1.5.
• the gas generating composition of the invention generally consists essentially of, by weight, from about 35% to about 55% nitroguanidine and from about 45% to about 65% phase stabilized ammonium nitrate. Additions such as flow enhancers or molding facilitators may be present provided the additions do not detract from the deflagratory characteristic of the composition.
• the gas generating composition consists essentially of, by weight, from about 40% to about 46% nitroguanidine and from about 54% to about 60% phase stabilized ammonium nitrate.
• the composition consists essentially of, by weight, from about 43% to about 44% nitroguanidine and from about 56% to about 57% potassium perchlorate stabilized ammonium nitrate.
• the composition consists essentially of, by weight, from about 42% to about 44% nitroguanidine and from about 56% to about 58% potassium nitrate stabilized ammonium nitrate.
• the binder is present in an amount of from that effective to increase the elasticity of the propellant composition up to about 10%, by weight. More preferably, the propellant contains from about 0.5% to about 6%, by weight, of the binder. Lower amounts of the binder do not provide the necessary elasticity. Excessive amounts of the binder increase the amount of CO generated in combustion and generally have a negative effect on ballistic performance.
• the binder is generally classified as an elastomeric binder and is preferably selected from the group consisting of polyurethanes, polycarbonates, polyethers, polysuccinates, thermoplastic rubbers and mixtures thereof.
• a most preferred binder is a polyurethane based on hexanediol/adipate/IPDI. Examples of binder based propellants and the associated properties are given in Table 2 below. When the binder is present, the ratio of ammonium nitrate to nitroguanidine is altered because the hydrocarbon based binders require an increased amount of oxidizer for complete combustion.
• the gas generating composition contains from about 5% to about 40%, by weight, of nitroguanidine and from about 60% to about 85%, by weight, of phase stabilized ammonium nitrate.
• the nitroguanidine is present in an amount of from about 10% to about 30%, by weight, and the ammonium nitrate in an amount of from 70% to about 80%, by weight.
• a plasticizer such as hydroxy-terminated polybutadiene or dioctyladipate and a surface modifier such as an amino-silane (i.e.
• an organotitanate or an organoziranate may be present, either singly or in combination, both in amounts of from about 0.1% to about 3%, by weight. Preferably, both are present in an amount of from 0.25% to 1.0%, by weight.
• the function of the plasticizer is to enhance binder rheology through modification of the glass transition temperature.
• the function of the surface modifier is to improve the bond between the binder and the propellant solids.
• a mixture of the phase stabilized ammonium nitrate and nitroguanidine powders of the desired chemical composition may be ground, commingled and compression molded into a tablet of a desired size using standard compression molding techniques.
• the powders are pressed into pellets having a diameter of about 12.7 mm (0.5 inch), a length of about 12.7 mm and a mass of approximately 3 grams.
• the pellets are coated with a flame inhibitor, such as an epoxy/titanium dioxide mixture to prevent burning along the sides of the pellet.
• Example 1 A quantity of 10% potassium nitrate in a phase stabilized ammonium nitrate mixture (10% KN-PSAN) was prepared by co-precipitating ammonium nitrate with 10 weight percent potassium nitrate from an aqueous solution. After drying, the solid was ball milled to reduce particle size producing a fine granular material. A mixture of 16.40 grams nitroguanidine and
• the theoretical combustion temperature of the mixture is 2409°C.
• the burning rate of the pellets was measured and found to be 8.6 mm (0.34 inch) per second at 6.9 MPa (1000 psi) with a pressure exponent of 0.47.
• the primary gas produced by combustion was, by volume, 53% water, 37% nitrogen, 9% carbon dioxide and 0.3% oxygen.
• the primary solid product produced by combustion was potassium carbonate.
• Example 2 A mixture of nitroguanidine and 15% KN-PSAN was prepared according to the process of Example 1 and pellets formed by compression molding. The composition, by weight, of this mixture was 42.3% nitroguanidine and 57.7% PSAN.
• the theoretical combustion temperature of this mixture is 2399°C.
• the primary gas produced by combustion was, by volume, 52% water, 38% nitrogen, 9% carbon dioxide and 0.2% oxygen.
• the primary solid product produced by combustion was potassium carbonate.
• the linear burn rate of these pellets was measured at 6.9 MPa (1000 psi) and found to be 8.1 mm (0.32 inch) per second.
• Differential scanning calorimetry (DSC) measurements revealed no endotherms characteristic of ammonium nitrate phase transitions over the temperature range of 0°C-115°C; confirming incorporation of potassium nitrate into ammonium nitrate to form PSAN.
• Endotherms corresponding to the ammonium nitrate Phase Ill-to- II and the Phase II-to-I structural phase transitions occurred at approximately 120°C and 130°C, respectively.
• the onset of AN melting occurred at approximately 165°C and the onset of an exotherm was approximately 245°C.
• Example 3 A quantity of PSAN consisting of 13.7%, by weight, potassium perchlorate (KP) and 86.3% ammonium nitrate was prepared by co-precipitating the salts from an aqueous solution followed by drying. The solid was then ball milled to reduce particle size.
• KP potassium perchlorate
• KP-PSAN A mixture consisting of 43.6% nitroguanidine and 56.4%, by weight, KP-PSAN was prepared by dry blending using a ball mill with pellets then formed by compression molding.
• the combustion temperature is theoretically 2571 °K.
• the primary gas produced by combustion contains (by volume) 52% water, 37% nitrogen, 11% carbon dioxide and 0.1% hydrogen.
• the solid product produced by combustion is potassium chloride. Weight loss measurements of propellant pellets at 100°C indicated 0.1% weight loss after 400 hours and 0.2% weight loss after 1000 hours.
• Example 4 A 1.5 kg batch of 41.8% nitroguanidine and 58.2% of 10% KN-PSAN was prepared by ball milling
• the theoretical combustion temperature of this mixture is 2423°C.
• the primary gas produced by combustion, by volume, was 52% water, 37% nitrogen, 11% carbon dioxide and 0.1% hydrogen.
• the primary solid produced by combustion was potassium carbonate.
• the pellets formed on the high speed tableting press were tested in a gas generator and found to inflate an airbag satisfactorily.
• Example 5 Propellant mixes having the compositions specified, in weight percent, in Table 2 were formed into pellets. Representative of the pellet forming process are:
• the propellant mix having the composition 20.0% nitroguanidine, 75.0% of 15% KN-PSAN and 5.0% polycarbonate binder was prepared and pressed into pellets as follows.
• a mixture of 200.0 grams of nitroguanidine and 750.0 grams of PSAN was prepared by dry blending using a ball mill. 50.0 grams of polycarbonate dissolved in methylene chloride was added to the dry blend. The resulting slurry was mixed in 250 gram batches on a Baker-Perkins pint mixer and the solvent then removed under vacuum. The four 250 gram batches were then reco bined and pellets were prepared by compression molding on a high-speed tableting press.
• the propellant mix having the composition 10.5% nitroguanidine, 83.5% of 15% KN-PSAN and 4.0% R45M-IPDI was prepared by dry blending 5.25 grams of nitroguanidine and 41.75 grams of PSAN in a ball mill. A solution of 3.71 grams of R45M and 0.29 grams IPDI in 50 milliliters of methylene chloride was added to the dry mix. The resulting slurry was mixed and the solvent evaporated by heating. The resulting powder was partially cured for 12 hours at 60°C and then pressed into pills at 26.69 k N (6000 lb-f) . The partially cured pills were then fully cured for 3 days at 60°C.
• the densities of the pellets was determined and the pellets were then thermal cycled. After 100 cycles between -30°C and +80°C, the density was measured again. The density change (J density) is recorded in Table 2.
• Kraton is a polyethylene/butylene-polystyrene block copolymer manufactured by Shell Chemical Company.
• R45M is a hydroxyterminated polybutadiene manufactured by the Arco Chemical Company.
• IPDI isophorone diisocyanate, manufactured by Huls America, Inc.
• KM1733 is a hydroxyterminated polycarbonate manufactured by Stahl USA.
• N100 is a biuret polymer based on 1, 6-hexamethylene diisocyanate manufactured by Desmodur.
• HDO-AD is a polyester diol adduct of hexanediol/adipic acid manufactured by Ruco Polymer Corp.
• B.R. is the burn rate measured at 6.9 MPa (1000 psi).

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• Chemical & Material Sciences (AREA)
• Organic Chemistry (AREA)
• Inorganic Chemistry (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Engineering & Computer Science (AREA)
• Combustion & Propulsion (AREA)
• Air Bags (AREA)
• Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)

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• 1996
  • 1996-02-08 US US08/582,079 patent/US5641938A/en not_active Expired - Lifetime
  • 1996-02-20 JP JP52687796A patent/JP4021476B2/ja not_active Expired - Lifetime
  • 1996-02-20 AU AU49891/96A patent/AU4989196A/en not_active Abandoned
  • 1996-02-20 WO PCT/US1996/002259 patent/WO1996027574A1/en not_active Ceased
  • 1996-02-20 EP EP96906546A patent/EP0813512A4/en not_active Withdrawn

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