Classifications

• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
  • A61Q5/00—Preparations for care of the hair
  • A61Q5/02—Preparations for cleaning the hair
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
  • A61K8/0241—Containing particulates characterized by their shape and/or structure
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
  • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
  • A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
  • A61K8/73—Polysaccharides
  • A61K8/731—Cellulose; Quaternized cellulose derivatives
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
  • A61K8/73—Polysaccharides
  • A61K8/736—Chitin; Chitosan; Derivatives thereof
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
  • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
  • A61K8/8105—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
  • A61K8/8111—Homopolymers or copolymers of aliphatic olefines, e.g. polyethylene, polyisobutene; Compositions of derivatives of such polymers
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
  • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
  • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
  • A61K8/8147—Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
  • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
  • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
  • A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
  • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
  • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
  • A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
  • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
  • A61K8/88—Polyamides
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
  • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
  • A61K2800/41—Particular ingredients further characterized by their size
  • A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
  • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
  • A61K2800/54—Polymers characterized by specific structures/properties
  • A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
  • A61K2800/5424—Polymers characterized by specific structures/properties characterized by the charge anionic
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
  • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
  • A61K2800/54—Polymers characterized by specific structures/properties
  • A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
  • A61K2800/5426—Polymers characterized by specific structures/properties characterized by the charge cationic
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
  • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
  • A61K2800/59—Mixtures
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
  • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
  • A61K2800/60—Particulates further characterized by their structure or composition
  • A61K2800/65—Characterized by the composition of the particulate/core
  • A61K2800/654—The particulate/core comprising macromolecular material

Definitions

• the present invention relates to a liquid hair cleaning composition containing a combination of at least one cationic polymer, at least one specific anionic polymer, at least one anionic surfactant and at least one solid which is insoluble in the composition and which, in addition to having a good hair-cleaning action, has a good hair-setting action having.
• Hair cleaning agents usually contain, in addition to the surfactants that are responsible for the cleaning action, hair-care additives which are intended to ensure that the hair is easy to comb both in the wet and in the dry state, shows a reduced static charge and has a soft natural feel.
• hair fixers are usually applied to the hair in the form of alcoholic or aqueous-alcoholic polymer solutions after shampooing, which are not rinsed out again.
• This procedure is time-consuming and costly for the user, since he needs two agents, a hair cleanser and a hair fixative.
• a hair shampoo is known from US Pat. No. 4,299,817
• the basis of a water-soluble polyelectrolyte complex which is said to have not only a hair-cleaning but also a hair-fixing effect. That from the
• the object was therefore to provide a liquid hair cleanser which, in addition to having a good hair cleansing action, has a good hair-setting action.
• Medium insoluble solid with an average grain size of 1 to 200 ⁇ m which is selected from nylon Powder, polyethylene powder and poly-methyl methacrylate powder, contains and free of silicone oils and cationic
• the hair cleanser according to the invention preferably contains 10 to 20 percent by weight of component (A).
• the anionic surfactant of component (A) is preferably selected from the alkali or alkaline earth salts of C 10 - C 18 alkyl sulfates his, the C 10 - to C 18 -Alkylsulfo- nate, the C 10 - to C 18 alkyl benzene sulfonates, the C 10 - to C 18 -Xylolsulfonate and the oxide units with 1 to 10 ethylene ethoxylated C 10 - to C 18 alkyl ether sulfates, the ethoxylated sulfosuccinic acid monoesters of the general formula (I)
• R, 0 SO 3 M where R 1 is a C 10 to C 18 alkyl radical, M is an alkali or alkaline earth metal cation and m is an integer from 1 to 10, and the alkyl ether carboxylates of the general formula (II)
• R 2 (OCH 2 CH 2 ) n OCH 2 COOM (II), where R 2 is a C 10 - to C 18 -alkyl radical, M is an alkali or alkaline earth metal application and n is an integer from 1 to 20, where the Alkali and earth alkali salts of C 10 to C 18 alkyl ether sulfates ethoxylated with 1 to 10 ethylene oxide units are particularly preferred.
• Suitable alkyl sulfates include sodium lauryl sulfate, which is available, for example, from Henkel KGaA,
• the mixture of the sodium salts of the secondary C 12 - to C 16 -alkanesulfonates is, for example, that of
• Hoechst AG Frankfurt, Germany under the trade name Hostapur ® SAS 30 in the form of a 30 percent
• alkylbenzene sulfonates the sodium salt of linear dodecylbenzenesulfonate, which is marketed a 55prozentigen paste under the trade name Maranil ® Paste A 55 by Henkel KGaA, Dusseldorf, FRG, for example in the form is preferred.
• xylene sulfonates suitable as component (A) the sodium salt of xylene sulfonate, which is available, for example, from Albright & Wilson Ltd.,
• alkyl ether sulfates suitable as component (A) preference is given to those which have a C 12 alkyl radical and are ethoxylated with 3 ethylene oxide units.
• a material suitable for use as component (A) of the inventive composition with 3 ethylene oxide units inputs ethoxylated lauryl ether sulfate, for example in the form of a 70prozentigen aqueous solution under the trade name Texapon ® N 70 by the company
• ethoxylated sulfosuccinic acid half-esters suitable as component (A)
• a half-ester of laurylsulfosuccinic acid ethoxylated with 3 ethylene oxide units is described, for example, in
• alkyl ether carboxylates which may be present as component (A) in the agent according to the invention, preference is given to that which is ethoxylated with 10 ethylene oxide units and has an alkyl radical with 12 carbon atoms.
• An ethoxylated with 10 ethylene oxide units Laurylethercarboxylat example, Mari, sold in the form of a 22prozentigen aqueous solution of its sodium salt by Huls AG FRG under the trade designation CM Marlmat ® 105/80.
• the hair cleanser according to the invention preferably contains 0.5 to 1.2 percent by weight of component (B).
• the cationic polymer of component (B) is preferably selected from diallyldimethylammonium chloride / acrylamide copolymers, vinylpyrrolidone / dimethylaminoethyl methacrylate copolymers quaternized with dimethyl sulfate, polymeric quaternaries
• Diallyldimethylammonium chloride / acrylamide copolymers suitable as component (B) are, for example, from Calgon, Pittsburgh, USA in the form of a
• Ammonium salts of hydroxyethyl cellulose are sold, for example, by Union Carbide Europa SA, Geneva, Switzerland under the trade name Polymer JR ® .
• suitable vinylpyrrolidone / methacrylic amidopropyltrimethylammoniumchlorid copolymers are, for example, under the trade name Gafquat ®
• HS-100 in the form of a 20 percent aqueous solution sold by Gaf, New York, USA.
• the hair cleansing agent according to the invention particularly preferably contains a polymeric quaternary ammonium salt of hydroxyethyl cellulose as component (B).
• Component (C) is preferably contained in the hair cleanser according to the invention in an amount of 0.3 to 3 percent by weight.
• the anionic polymer of component (C) of the hair cleanser according to the invention is according to the
• the neutralizing agent is preferably selected from alkali hydroxides, organic amines and alkanolamines.
• amines or alkanolamines suitable for neutralization are:
• the anionic polymer of component (C) is particularly preferably neutralized to 50 to 100 percent with sodium hydroxide.
• Suitable as component (C) Acrylate / acrylamide copoly mers are sold, for example under the trade name Ultrahold 8 ® from BASF AG, Ludwigshafen, BRD. Vinyl acetate suitable as component (C) /
• Crotonic acid copolymers are, for example, from the
• Neodecanoate copolymers are sold, for example, by the company National Starch and Chem. Ltd., New Jersey, USA under the trade name Resyn ® 28-2930 in the form of a solid.
• the hair cleansing agent according to the invention preferably contains a 50 to 100 percent neutralized vinyl acetate / crotonic acid copolymer as component (C).
• the agent according to the invention preferably contains components (B) and (C) in a weight ratio of
• the agent according to the invention preferably contains component (D) in an amount of 0.1 to 2 percent by weight.
• the solid contained as component (D) in the agent according to the invention preferably has an average grain size of 2 to 40 ⁇ m (micrometers).
• suitable nylon powder is contributed play as sold under the trade name Orgasol ® by Atochem, Paris, France.
• component (D) suitable polyethylene powder is, for example, under the trade designation Lupolen ®
• Component (D) of the inventive polymethyl methacrylate suitable example is marketed by the company Ziegler & Co., Wunsiedel, Germany under the trade name Jurymer ®.
• the hair cleansing agent according to the invention preferably contains nylon powder with a grain size of 2 to 40 ⁇ m (micrometer) as component (D).
• the composition according to the invention can contain 0.1 to 20 percent by weight of at least one amphoteric surfactant suitable for hair cleansing agents.
• amphoteric surfactants suitable for hair cleansing agents are, for example, the C 8 to C 18 alkyl betaines, the C 8 to C 18 alkyl sulfobetaines, the carboxyl derivatives of imidazole, the C 8 to C 18 alkyl dimethyl ammonium acetates and the C 8 to C 18 - Alkyldimethylcarboxylmethylammoniumsalze and the C 8 - to C 18 fatty acid alkyl amido betaines called.
• C 8 to C 18 fatty acid alkylamidobetaine is, for example, coconut fatty acid amidopropyl betaine, which, for example, is in the form of a 30 percent aqueous solution under the trade name Tego Betain ® L7 from 'Goldschmidt AG, Essen,
• N- [2- (carboxymethoxy) ethyl] glycine (CTFA name: Cocoamphocarboxyglycinate), which, for example, in the form of a 50 percent aqueous solution under the trade name Miranol ® C2M from Miranol Chemical
• the agent according to the invention is preferably free of amphoteric surfactants.
• the hair cleanser for hair cleaners according to the invention can contain conventional additives, for example non-ionic surfactants in an amount of 0.1 to 5 percent by weight, such as, for example, ethoxylated fatty alcohols with 12 to 18 carbon atoms, for example with up to 40 moles of ethylene oxide per mole of fatty alcohol, oxyethylated lauryl -, tetradecyl, cetyl, oleyl and stearyl alcohol, alone or in
• the fatty alcohols of ethoxylated lanolin or ethoxylated lanolin polyglyceryl ethers of saturated or unsaturated fatty alcohols and alkylphenols with 8 to 30 carbon atoms in the alkyl radical and 1 to 10 glyceryl units in the molecule; Fatty acid alkanolamides, and ethoxylated sorbitan fatty acid esters; Perfume oils in an amount of about 0.5 to 5.0 percent by weight; Opacifiers such as ethylene glycol distearate in an amount of about 0.5 to 5.0 percent by weight; Pearlescent agents, such as a mixture of fatty acid monoalkylolamide / ethylene glycol distearate, in an amount of about 1.0 to 10.0 percent by weight; bactericidal or fungicidal active ingredients, such as, for example, 2,4,4-trichloro-2-hydroxy-diphenyl ether or methyl chloroisothiazolinone, in an amount
• Sorbitan monolaurate in an amount of about 0.5 to 5.0 percent by weight; Buffer substances such as sodium citrate or sodium phosphate in an amount of about 0.1 to 1.0 percent by weight; Solubilizers, such as ethoxylated, if necessary
• Example fluorescein sodium salt contained in an amount of about 0.1 to 1.0 weight percent.
• the water content of the hair cleanser according to the invention is preferably between 30 and 90 percent by weight.
• the agent according to the invention has a pH of 4 to 9, preferably 4.5 to 7.5.
• the pH of the agent according to the invention can be adjusted, for example, with citric acid, phosphoric acid, hydrochloric acid or sodium hydroxide.
• the agent according to the invention has a good hair-cleaning effect in combination with a good hair-fixing effect.
• the hair cleaned with the agent according to the invention has good wet and dry combability, good hair styling and an appealing volume.
• the agent according to the invention gives the hair a firm and flexible hold at the same time without affecting the natural feel of the hair.
• Example 1 Hair cleanser 11.20 g with 3 units of ethylene oxide ethoxylated sodium lauryl ether sulfate
• nylon powder (Orgasol ® 2002 UD Nat Cos Atochem, France)
• nylon powder (Orgasol ® 2002 UD Nat Cos Atochem, France)
• Example 3 Hair cleanser 11.20 g with 3 units of ethylene oxide ethoxylated sodium lauryl ether sulfate
• nylon powder (Orgasol ® 2002 UD Nat Cos Atochem, France)
• Example 4 Hair cleanser 11.20 g with 3 units of ethylene oxide ethoxylated sodium lauryl ether sulfate
• nylon powder (Orgasol ® 2002 UD Nat Cos Atochem, France)
• Example 7 Hair Cleanser 11.2 g of sodium lauryl ether sulfate ethoxylated with 3 units of ethylene oxide
• polyethylene powder 0.50 g polyethylene powder (Lupolen ® 1800 SP 15 from BASF AG, FRG)
• a hair cleanser according to the invention is a hair cleanser according to the invention.
• Example 3 was compared for its strengthening properties to Example II, Composition II of Table V of U.S. Patent 4,299,817.
• Composition II of Example II of U.S. Patent 4,299,817 (hereinafter referred to as Example II) has the following composition:
• Example 3 For the comparison with regard to the setting effect, the hair of 10 test persons whose hair was undamaged to moderately damaged was treated in a parallel test (half-side test) with Example 3 according to the invention and Example II of the US Pat. No. 4,299,817 not according to the invention.
• the test person's hair was first moistened with water and then parted in the middle.
• the right half of the hair, depending on the hair volume of the test person, was washed (shampooed) with 5 to 15 g of Example 3 according to the invention in the usual way, while the left
• Treated hair invention was judged to be better.
• the hairdressing expert group then assessed the firming effect of the two hair cleaners.
• the following in Table 1 The ratings given represent the mean obtained from the individual ratings.
• hair cleaners A, B and C not according to the invention had the following compositions:
• test person's hair was first moistened with water and then parted in the middle.
• the right half of the hair depending on the hair volume of the test person, washed with 5 to 15 g each of the hair cleansing agents according to the invention according to Examples 1, 2 or 3 in the usual manner, while the left half of the hair was washed with the same amount of one of the non-inventive Examples A, B or C
• the half-side tests according to comparative test B show that only the inventive examples 1, 2 and 3 achieve a good strengthening effect.
• Comparative experiment B shows that, surprisingly, only the combination of components (A) to (D) according to the invention gives rise to a synergistic effect which brings about good setting of the hair.

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• Life Sciences & Earth Sciences (AREA)
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• Animal Behavior & Ethology (AREA)
• General Health & Medical Sciences (AREA)
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• Birds (AREA)
• Epidemiology (AREA)
• Cosmetics (AREA)
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Cited By (12)

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Citations (4)

• 1994
  • 1994-06-15 DE DE19944420880 patent/DE4420880A1/de not_active Withdrawn
• 1995
  • 1995-03-01 EP EP95910539A patent/EP0713382A1/de not_active Withdrawn
  • 1995-03-01 BR BR9506264A patent/BR9506264A/pt active Search and Examination
  • 1995-03-01 JP JP8501523A patent/JPH09501956A/ja active Pending
  • 1995-03-01 WO PCT/EP1995/000739 patent/WO1995034271A1/de not_active Application Discontinuation
  • 1995-03-01 ES ES95910539T patent/ES2086287T1/es active Pending

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