WO1995024302A1 - Paraison tubulaire multi-couches ainsi que procede et appareil pour sa fabrication - Google Patents
Paraison tubulaire multi-couches ainsi que procede et appareil pour sa fabrication Download PDFInfo
- Publication number
- WO1995024302A1 WO1995024302A1 PCT/FR1994/000267 FR9400267W WO9524302A1 WO 1995024302 A1 WO1995024302 A1 WO 1995024302A1 FR 9400267 W FR9400267 W FR 9400267W WO 9524302 A1 WO9524302 A1 WO 9524302A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- layers
- middle layer
- layer
- parison
- extrusion
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/30—Extrusion nozzles or dies
- B29C48/32—Extrusion nozzles or dies with annular openings, e.g. for forming tubular articles
- B29C48/335—Multiple annular extrusion nozzles in coaxial arrangement, e.g. for making multi-layered tubular articles
- B29C48/336—Multiple annular extrusion nozzles in coaxial arrangement, e.g. for making multi-layered tubular articles the components merging one by one down streams in the die
- B29C48/3366—Multiple annular extrusion nozzles in coaxial arrangement, e.g. for making multi-layered tubular articles the components merging one by one down streams in the die using a die with concentric parts, e.g. rings, cylinders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/09—Articles with cross-sections having partially or fully enclosed cavities, e.g. pipes or channels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/16—Articles comprising two or more components, e.g. co-extruded layers
- B29C48/18—Articles comprising two or more components, e.g. co-extruded layers the components being layers
- B29C48/21—Articles comprising two or more components, e.g. co-extruded layers the components being layers the layers being joined at their surfaces
Definitions
- the present invention relates to a tubular parison with several layers of coaxial thermoplastic materials and to a method and an apparatus for manufacturing such a tubular parison.
- Tubular parisons with several layers are used in particular in the field of extrusion-blowing of thermoplastic material for the manufacture of hollow bodies intended to contain or convey liquid, pasty, powdery, solid or gaseous products, food or not (products chemical, parachemical, phytosanitary, petroleum etc ).
- plastic materials are used which are heated and pressurized by a screw / sleeve assembly at a precise temperature corresponding to the technology of the polymer treated to supply, via an extrusion head, a hot tubular parison.
- This parison is then taken between two half-molds, the imprints of which correspond to the external shape of the hollow body to be blown.
- a blowing rod is then introduced, from the top of the parison, to form the interior of the neck of the manufactured container and to introduce pressurized air into the parison so that the hot, still soft, thermoplastic material s 'stretch under the action of pressure and takes the form of the mold imprint which, once cooled to low temperature, freezes the plastic to obtain the final shape taking into account the compulsory withdrawals from the plastic.
- the bars of material lying around the hollow body obtained by blowing and which result from the nip of the parison by the half-molds, are removed by a mechanical system, crushed then reused, so as to obtain the finished hollow body.
- the tubular parison used at the start may have a single layer or several layers regularly superimposed with possibly adhesives between layers so that these layers hold together.
- EP-A-0 298 908 already discloses a co-extrusion device making it possible to continuously manufacture a tubular parison with several coaxial layers which can then be used for blowing hollow bodies with several layers. Also known, as described in patent GB-A-1 370 281, an apparatus for extruding flexible pipes made of reinforced plastic comprising a tube made of a first plastic material having rings spaced apart axially from a second material plastic, these rings being partially or totally embedded in the wall of the tube.
- the present invention relates to improvements made to the manufacture of multi-layer tubular parisons with the aim of obtaining, after blowing, finished products having high mechanical strength, of optimally using crushed, recycled and recycled waste. '' very easily adapt the properties of a tubular parison to the requirements of a particular application.
- this tubular parison with several layers of coaxial thermoplastic materials comprising at least one structure with three inner, middle and outer layers, is characterized in that the middle layer consists of an alternation of first and second transverse rings, constituted respectively in first and second thermoplastic materials, and individual longitudinal rods in a third plastic material, distributed around the axis of the parison, cutting the alternating transverse rings of the middle layer by delimiting, with the first transverse rings, cells made of the second thermoplastic material and of a longitudinal dimension greater than the longitudinal dimension of the first transverse rings.
- the invention also relates to a method of manufacturing a tubular parison with several layers of coaxial thermoplastic materials in which an inner layer, then a middle layer, then an outer layer is successively extruded, one on the other, characterized in that in order to form the middle layer successively extruded first and second alternating transverse rings constituted respectively by a first thermoplastic material and a second thermoplastic material and then extruded, at several points distributed in the circumferential direction around the axis of the parison, individual longitudinal rods in a third thermoplastic material, cutting the middle layer and possibly at least one of the inner and outer layers.
- the invention also relates to an apparatus for manufacturing, by coextrusion, a tubular parison with several layers of thermoplastic materials comprising at least one structure with three inner, middle and outer layers, this apparatus comprising an extrusion head in which several coaxial and vertical cylindrical extrusion channels are formed, namely an inner channel for extruding the inner layer, an intermediate channel for extruding the middle layer and an outer channel for extruding the outer layer, and a block supply supplying the channels with thermoplastic materials, characterized in that the intermediate extrusion channel is connected in common to first and second devices, operating alternately for the supply of first and second respective thermoplastic materials, each of these first and second supply devices comprising an extrusion screw forcing the thermoplastic material co corresponding in a chamber forming a material accumulator, from which it is discharged into the extrusion channel of the middle layer by a piston driven by a reciprocating movement, and at least one set of independent channels distributed around the axis of the extrusion head, connected in common to a device for supplying a
- FIG. 1 is a diagram illustrating the manufacture of a tubular parison with several layers according to the invention.
- FIG. 2 is a perspective view, partially in section, of a tubular parison according to the invention.
- FIG. 3 is an axial sectional view taken along line III-III of Figure 2.
- - Figure 4 is an axial sectional view taken along the line IV-IV of Figure 2.
- - Figure 5 is a cross-sectional view taken along the line V-V of Figure 4.
- FIGS 6, 7, 8 and 9 are views in partial cross section of the wall of the tubular parison illustrating different arrangements of a longitudinal rod of the middle layer.
- FIG. 10 is a longitudinal sectional view of an alternative embodiment of the wall of the tubular parison.
- FIG. 11 is a cross-sectional view of another alternative embodiment of the tubular parison.
- FIG. 12 is an axial sectional view of a tubular parison provided for a particular application in the blowing of a hollow body.
- FIG. 13 is a simplified axial sectional view of an extrusion head used for the manufacture of a tubular parison according to the invention.
- FIG. 14 is a schematic sectional view of the power supply of the extrusion head, made according to the line XIV-XIV of figure 15.
- FIG. 15 is a sectional view of the power supply unit taken along the line XV-XV of Figure 14.
- the parison essentially consists of an inner layer 1, a middle layer 2 and an outer layer 3 which are formed successively on top of each other, in this order, by an extrusion process of multiple coaxial layers.
- the inner 1 and outer 3 layers are each made of a virgin thermoplastic material mixed, with or without grind, the materials of these two layers can be the same or different.
- the layers of thermoplastic material are formed in an extrusion head which will be described later with reference to FIG. 13 and their constituent thermoplastic materials are supplied by respective supply devices 4 and 5 which will be described in more detail further on with reference to FIGS. 14 and 15.
- the middle layer 2 consists of an alternation of transverse and horizontal rings 2a. and 2b, of different lengths or longitudinal dimensions, made respectively of different plastics A and B, successively in the longitudinal direction, and vertical rods 2c., that is to say longitudinal, made of a third plastic material C
- rods 2c are extruded, so as to cut the alternating transverse rings 2a., 2b_, in an extrusion zone 6 which is located downstream of the zone 7 for extruding the alternating transverse rings 2a., 2b and upstream of the extrusion zone 8 of the outer layer 3.
- the tubular parison according to the present invention therefore a structure as illustrated in a more detailed manner in FIGS. 2 to 5.
- This parison has a circular cross section but it could as well have any other desired shape such as oval, square, rectangular etc. ..
- the transverse rings or level 2a rings are supplied to the extrusion zone 7 by supply devices 9, 10 operating alternately, then that the third plastic material C, constituting the longitudinal and vertical rods 2ç_, is supplied to the extrusion zone 6 by an independent supply device 11.
- This parison has a circular cross section but it could as well have any other desired shape such as oval, square, rectangular etc. ..
- the transverse rings or level 2a rings are supplied to the extrusion zone 7 by supply devices 9, 10 operating alternately, then that the third plastic material C, constituting the longitudinal and vertical rods 2ç_, is supplied to the extrusion zone 6 by an independent supply device 11.
- the tubular parison according to the present invention therefore a structure as illustrated in a more detailed manner in FIGS
- thermoplastic material A constituting the transverse rings of level 2a. is a virgin material, with or without ground material, adhering to the inner 1 and outer 3 layers.
- the plastic material C of the vertical rods 2.c is also a virgin material, with or without ground material, adhering to the inner 1 and outer 3 layers.
- the vertical rods 2c can be continuous in a given section of the parison or else they can be interrupted in precise zones of this parison.
- the vertical rods 2c. can have a diameter equal to or slightly greater than the thickness of the middle layer 2 so as to be substantially tangent internally to the inner layers 1 and outer 3, as shown in FIG. 6. They can also have a diameter greater than 1 thickness of the middle layer 2 and in this case they can either be substantially tangent internally to the layer outer 3 and cut the inner layer 1, as shown in Figure 7, either tangent internally to the inner layer 1 and cut the outer layer 3, as shown in Figure 8, or again they can cut both the inner 1 and outer 3 layers as shown in Figure 9.
- the number of cells 2b_ is determined by the number of vertical rods 2ç_ and the number of level 2a transverse rings. The density of cells 2b varies depending of the desired structure for each parison or parison.
- the distribution of the vertical rods 2ç_ is not necessarily regular all around the parison in other words the distance, in the circumferential direction, between the successive rods can be constant or variable.
- the distribution of level 2a transverse rings. may or may not be regular over the entire length of the parison, the distance between the different rings 2a. can be constant or variable.
- the second thermoplastic material constituting the cells 2b_ can have a composition Bl, B2 ... which is different from one cell 2b_ to the next, in the longitudinal direction, for example to obtain more or less hard zones or more or less soft.
- These different thermoplastic materials Bl, B2 ... are then supplied by independent supply devices, analogous to device 10, put into service in a selective manner to supply the desired thermoplastic materials Bl, B2 ... in the area d extrusion 7.
- the vertical rods 2ç_ may preferably have a cylindrical shape or any other shape.
- the materials constituting the inner layer 1, the outer layer 3 and the transverse rings 2a. can be the same or even different materials but which have a characteristic of adhesion between them either naturally, or by the addition of adhesives.
- These layers are made of virgin material or homogeneous mixture of virgin materials, ground material (waste from operation) and additives (adhesive, binder, stabilizer, dye, perfume, etc.).
- the material B constituting the cells 2b can be any one of the extrudable thermoplastic materials such as LDPE Low density polyethylene, HDPE High density polyethylene, THPM Very high molecular weight polyethylene, PP Polypropylene, PVC Polyvinyl chloride, PET Poly terephthalate ethylene, PA Polyamide, EVA Poly ethylene / vinyl acetate, EVOH Ethylene / vinyl alcohol copolymer, etc. It may contain regenerable extrudable waste in the form of granules or powder and mineral or non-extrudable fillers (chalk, fiberglass, fiber vegetable, sawdust etc ).
- the thickness of the layers 1, 2, 3 of the parison can be constant or variable depending on the length of the parison.
- FIG. 10 illustrates an exemplary embodiment in which the thicknesses of the layers 1, 2, 3 of the parison are smaller in the intermediate central part of this parison than in its end parts.
- the tubular parison consists of several coaxial elementary tubular parisons, housed in each other, produced independently and successively as described above.
- the parison according to the invention makes it possible to manufacture finished extruded and extruded-blown products such as flasks, bottles, cans, jerry cans, as well as all the extrudable-blowable hollow bodies such as fuel tanks, hydraulic tanks for brake, for washes - ice, expansion etc. It can also be used for the manufacture of multilayer palletizing films, hoses, tubes and pipes, furniture walls, a covering of computer equipment (office automation) and any extrudable part and extrudable- painful.
- the finished product obtained from the tubular parison according to the invention offers better mechanical resistance to compression, drop, impact and vibration. Referring now to FIG.
- the upper extreme zone 12 of the tubular parison represents the high waste
- the next zone 13, located immediately below, represents the neck and the neck of the container to be manufactured, with or without the handle
- the following lower zone 14 represents the body of the container
- the parison presents, from top to bottom, an alternation of rings of levels 2a . and cells 2b_, indicated successively by the references 2a. ⁇ , 2b_ ⁇ , 2a.2, 2b_2, 2a.3, 2t> 3 2a.4 / 2b_4, 2a, 5.
- the cells 2b_ ⁇ and 2 ⁇ 4 of the upper and lower levels are composed from a mixture of virgin and crushed material, that is to say waste from the operation of the extrusion blow molding, with the pinch by the molds of the parison at the top and bottom, and the cutout of the handle.
- the cells 2b_2 and 2b_3 of the two intermediate levels are composed from fillers (chalk, regenerated extrudable waste, etc.). This distribution makes it possible to ensure, in zones 12, 13, 15 and 16, perfect welds, not to pollute the ground material and to lower the cost price by using charges at a lower price than virgin material, all by improving the mechanical characteristics of the products to be manufactured thanks to the multi-cell structure.
- the rings of level 2a. ⁇ , 2a.2, a.3, 2a_4, 2a.5 are composed from a mixture of virgin material and crushed.
- Another example of industrial application is the manufacture of transparent PET soft drink bottles.
- it can have, in different zones of the manufactured part, a variable rigidity, that is to say more or less hard zones Bl, B2 .... or more or less soft, by using more or less hard materials in the different cells 2b_.
- a separate feeding device must be used for each different material.
- This device comprises an extrusion head 17, shown in FIG. 13, which is produced, for the most part, in a traditional manner.
- This head 17, with a vertical axis ZZ ′ comprises several coaxial cylindrical parts, fitted closely together and defining, from inside to outside, several extrusion channels cylindrical coaxial, vertical, namely an internal channel 18 for extruding the inner layer 1, an intermediate channel 19 for extruding the alternating rings 2a, 2b_ of the middle layer 2 and an external channel 20 for extruding the layer outer 3.
- the channels 19 and 20 meet at their lower ends and they are extended by a frustoconical channel 21, converging downwards, joining, at its lower end, the central channel 18.
- the two channels 18, 21 are then extended by a short vertical channel 22 then a frusto-conical channel 23 converging downwards, delimited by an internal extrusion core 24 and an external nozzle 25.
- the extrusion head further comprises several channels for the injection of vertical rods 2c cutting the middle layer 2.
- second independent inclined channels 27 open into the frustoconical junction channel 21 for the injection of longitudinal rods cutting the outer layer 3 and the middle layer 2.
- third independent inclined channels 28 open into the short vertical cylindrical channel 22 for the extrusion of rods cutting all of the three layers 1, 2, 3 of the parison.
- FIGS. 14 and 15 represent an embodiment of a power supply unit 31 for the extrusion head 17.
- the thermoplastic materials are supplied by extrusion screws which possibly make them penetrate into accumulators of material from from which they are discharged, through flow control valves, by means of pistons.
- the corresponding extrusion channel can be fed either directly or by The intermediary of a material accumulator.
- the power supply unit 31 comprises, in this non-limiting embodiment, five individual supply devices corresponding to the various extruded materials.
- the extruded material intended to constitute the inner layer 1 is forced, by an extrusion screw 32, into a chamber 33 forming a material accumulator, from which this material is discharged, by a piston 34 driven by a reciprocating movement, in the central channel 18 for extruding the inner layer 1.
- the extrusion screw 32 could directly push the material from the inner layer 1 into the channel 18.
- thermoplastic material A constituting the level rings 2a.
- the second thermoplastic material B constituting the cells 2b_, is forced by an extrusion screw 38 into a chamber 39 forming a material accumulator, from which it is discharged into the channel extrusion 19 by means of a piston 40, driven by a reciprocating movement.
- thermoplastic material C constituting the rods 2ç_, is forced, by an extrusion screw 41, into a chamber 42 forming a material accumulator, from which it is discharged, by a movable piston 43 in the extrusion channel 26
- This feeding device makes it possible to interrupt at will, in the same parison, the longitudinal rods 2c., At appropriate locations.
- thermoplastic material constituting the outer layer 3 is forced, by an extrusion screw 44, into a chamber 45 forming a material accumulator, from which it is discharged, by a movable piston 46, into the extrusion channel 20
- this material could be discharged directly by the extrusion screw 44 into the channel 20.
- the extrusion of the thermoplastic materials A and B, respectively constituting the level 2a rings. and the cells 2b_ are alternately extruded, in other words the devices for feeding these materials operate alternately, this alternative operation being determined by an electronic control.
- thermoplastic materials for example the material A accumulated in the chamber 36 by the extrusion screw 35 driven in rotation, the piston 37 then being held stationary in the high position, the other material thermoplastic B is gradually pushed back into the extrusion channel 19 due to the movement of the piston 40 downwards in the chamber 39.
- the piston 40 is raised, the extrusion screw 38 is rotated to accumulate the material B again in the chamber 39 and during this time the extrusion screw 35 is stopped and the piston 37 is moved downwards to push the thermoplastic material back into the extrusion channel 19 A immediately following the previously extruded material B.
- certain extrusion screws could be used jointly for several layers made of the same thermoplastic material (for example for the interior layers 1 and exterior 3).
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU62114/94A AU6211494A (en) | 1994-03-11 | 1994-03-11 | Tubular multilayer preform and method and device for the manufacture thereof |
PCT/FR1994/000267 WO1995024302A1 (fr) | 1994-03-11 | 1994-03-11 | Paraison tubulaire multi-couches ainsi que procede et appareil pour sa fabrication |
EP94909174A EP0787065B1 (fr) | 1994-03-11 | 1994-03-11 | Paraison tubulaire multi-couches ainsi que procede et appareil pour sa fabrication |
DE69414425T DE69414425D1 (de) | 1994-03-11 | 1994-03-11 | Rohrförmiger mehrschichtvorformling und verfahren und vorrichtung zu dessen herstellung |
CA002185110A CA2185110A1 (fr) | 1994-03-11 | 1994-03-11 | Paraison tubulaire multi-couches ainsi que procede et appareil pour sa fabrication |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/FR1994/000267 WO1995024302A1 (fr) | 1994-03-11 | 1994-03-11 | Paraison tubulaire multi-couches ainsi que procede et appareil pour sa fabrication |
CA002185110A CA2185110A1 (fr) | 1994-03-11 | 1994-03-11 | Paraison tubulaire multi-couches ainsi que procede et appareil pour sa fabrication |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1995024302A1 true WO1995024302A1 (fr) | 1995-09-14 |
Family
ID=25678667
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/FR1994/000267 WO1995024302A1 (fr) | 1994-03-11 | 1994-03-11 | Paraison tubulaire multi-couches ainsi que procede et appareil pour sa fabrication |
Country Status (3)
Country | Link |
---|---|
CA (1) | CA2185110A1 (fr) |
DE (1) | DE69414425D1 (fr) |
WO (1) | WO1995024302A1 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2020178783A1 (fr) * | 2019-03-05 | 2020-09-10 | 3M Innovative Properties Company | Articles multicouches co-extrudés comprenant une couche continue et une couche discontinue |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3825036A (en) * | 1971-05-19 | 1974-07-23 | Creators Ltd | Reinforced plastics tubes |
GB1370281A (en) * | 1971-09-02 | 1974-10-16 | Creators Ltd | Flexible plastics hoses |
DE2508919A1 (de) * | 1975-03-01 | 1976-09-09 | Barmag Barmer Maschf | Verfahren zur herstellung von mehrschichtigen kunststoffverbundfolien |
EP0298908A1 (fr) * | 1987-07-08 | 1989-01-11 | Soplar Sa | Dispositif de coextrusion |
EP0573683A1 (fr) * | 1992-06-09 | 1993-12-15 | Jean Rubie | Procédé pour la fabrication de containers montés par soufflage en matière plastique renforcée et containers ainsi obtenus |
FR2698581A1 (fr) * | 1992-11-30 | 1994-06-03 | Lefort Olivier | Procédé de fabrication d'une paraison en extrusion-soufflage de thermo-plastiques pour réaliser des corps creux. |
-
1994
- 1994-03-11 WO PCT/FR1994/000267 patent/WO1995024302A1/fr active IP Right Grant
- 1994-03-11 CA CA002185110A patent/CA2185110A1/fr not_active Abandoned
- 1994-03-11 DE DE69414425T patent/DE69414425D1/de not_active Expired - Lifetime
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3825036A (en) * | 1971-05-19 | 1974-07-23 | Creators Ltd | Reinforced plastics tubes |
GB1370281A (en) * | 1971-09-02 | 1974-10-16 | Creators Ltd | Flexible plastics hoses |
DE2508919A1 (de) * | 1975-03-01 | 1976-09-09 | Barmag Barmer Maschf | Verfahren zur herstellung von mehrschichtigen kunststoffverbundfolien |
EP0298908A1 (fr) * | 1987-07-08 | 1989-01-11 | Soplar Sa | Dispositif de coextrusion |
EP0573683A1 (fr) * | 1992-06-09 | 1993-12-15 | Jean Rubie | Procédé pour la fabrication de containers montés par soufflage en matière plastique renforcée et containers ainsi obtenus |
FR2698581A1 (fr) * | 1992-11-30 | 1994-06-03 | Lefort Olivier | Procédé de fabrication d'une paraison en extrusion-soufflage de thermo-plastiques pour réaliser des corps creux. |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2020178783A1 (fr) * | 2019-03-05 | 2020-09-10 | 3M Innovative Properties Company | Articles multicouches co-extrudés comprenant une couche continue et une couche discontinue |
CN113543951A (zh) * | 2019-03-05 | 2021-10-22 | 3M创新有限公司 | 包括连续层和不连续层的共挤出多层制品 |
US11618237B2 (en) * | 2019-03-05 | 2023-04-04 | 3M Innovative Properties Company | Co-extruded multilayer articles including continuous layer and discontinuous layer |
Also Published As
Publication number | Publication date |
---|---|
CA2185110A1 (fr) | 1995-09-14 |
DE69414425D1 (de) | 1998-12-10 |
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