WO1994021776A1 - Oven-cleaning composition - Google Patents

Oven-cleaning composition Download PDF

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Publication number
WO1994021776A1
WO1994021776A1 PCT/EP1994/000681 EP9400681W WO9421776A1 WO 1994021776 A1 WO1994021776 A1 WO 1994021776A1 EP 9400681 W EP9400681 W EP 9400681W WO 9421776 A1 WO9421776 A1 WO 9421776A1
Authority
WO
WIPO (PCT)
Prior art keywords
weight
composition
composition according
propylene glycol
ether
Prior art date
Application number
PCT/EP1994/000681
Other languages
German (de)
French (fr)
Inventor
Patrice Lago Gitareux
François BETSCHER
Claire Lapprand
Vincent Baudrillard
Original Assignee
Henkel Kommanditgesellschaft Auf Aktien
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel Kommanditgesellschaft Auf Aktien filed Critical Henkel Kommanditgesellschaft Auf Aktien
Priority to DE59401211T priority Critical patent/DE59401211D1/en
Priority to EP94909120A priority patent/EP0689583B1/en
Publication of WO1994021776A1 publication Critical patent/WO1994021776A1/en
Priority to GR960403165T priority patent/GR3021915T3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/10—Carbonates ; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/65—Mixtures of anionic with cationic compounds
    • C11D1/652—Mixtures of anionic compounds with carboxylic amides or alkylol amides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0057—Oven-cleaning compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
    • C11D3/1266—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2068—Ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/30—Amines; Substituted amines ; Quaternized amines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides

Definitions

  • the present invention relates to a composition which is suitable for cleaning ovens of all kinds, in particular for stoves, ovens and grills.
  • compositions currently on the market which are intended for cleaning classic enamel stoves, essentially have as active constituents, on the one hand, a suitable basic raw material, which acts on fats and burnt-on residues, and, on the other hand, solvents and organic active substances, which act as solvents and moistening or wetting agents.
  • active constituents on the one hand, a suitable basic raw material, which acts on fats and burnt-on residues, and, on the other hand, solvents and organic active substances, which act as solvents and moistening or wetting agents.
  • the mixtures are mostly filled as sprays and other components such as.
  • B. surfactants and / or foaming agents, thickeners and foam stabilizers It should be noted that consumers particularly appreciate the products in the form of a stable foam, which have the advantage of making the spraying process visible.
  • the cleaning products for ovens currently on the market essentially have, in weight ratios, 5 to 10% solvents and 10 to 15% basic raw materials, which are generally composed of a mixture of an alkaline base such as soda or pattas and one or more amino acids, especially of monoethanolamine.
  • Such products have been developed with a satisfactory effectiveness for cleaning the classic enamel stoves, but not for cleaning the so-called self-cleaning stoves (catalysis, pyrolysis).
  • the object of the present invention is to remedy this problem by proposing a new composition for cleaning the furnaces which has the advantages of the known composition for cleaning classic enamel furnaces but at the same time has the property that it is in can be used satisfactorily for cleaning the new non-oxidizing steel and "grill / hot air" ovens.
  • this composition is characterized in that, in addition to a basic base material which contains an alkaline base such as soda or potash and / or one or more amines, it has 10 to 30% by weight of a mixture of low-volatile solvent which is used for one part contains at least one propylene glycol ether and the other part contains at least one dipropylene glycol ether, the weight ratio of propylene glycol ether to dipropylene glycol ether being between 30:70 and 90:10.
  • composition according to the invention thus differs from classic compositions of the same type equally in that it has a higher solvent content and in the particular nature of the solvent, which consists exclusively of a mixture of propylene glycol ether and dipropylene glycol ether. It is preferably the glycol monoethers. A wide range of these ethers can be used without departing from the invention; The choice of the ether actually used is primarily determined by considerations regarding economy and solvency.
  • the composition has between 10 and 15 percent by weight of solvent, the amount of the propylene glycol ether preferably being about 2 to 4 times higher than the amount of the dipropylene glycol ether.
  • the composition can have between 0.5 and 10% by weight sodium carbonate (soda). Taking into account the safety of use and to better prevent the risk of accidents by contacting or taking these products, manufacturers have been trying for several years to reduce the maximum amount of the caustic and pickling substances used in cleaning ovens certain compositions are included.
  • the cleaning agent according to the invention shows its effectiveness with a sodium carbonate content already below 2%, and it is advantageous not to exceed this limit.
  • the basic base material preferably consists of a mixture of 0.5 to 2% sodium carbonate and 2 to 10, preferably 2 to 6% by weight A in, preferably monoethanolamine.
  • the composition has between 0.5 and 2% of a thickener, for example Smectitton. It has been found that the presence of a thickening agent in the composition according to the invention facilitates adhesion of the sprayed product to the furnace walls.
  • a thickener for example Smectitton.
  • the composition has up to 2% by weight, preferably 0.1 to 1% by weight, of a surface-active agent, in particular a sodium sulfate of a fatty alcohol with 8 to 15, preferably 10 to 12 carbon atoms, which is ethoxylated with 2 to 5 moles of ethylene oxide.
  • a surface-active agent in particular a sodium sulfate of a fatty alcohol with 8 to 15, preferably 10 to 12 carbon atoms, which is ethoxylated with 2 to 5 moles of ethylene oxide.
  • the composition has up to 2% by weight, preferably 0.1 to 1% by weight, of a foam-stabilizing agent, in particular an amide of a fatty acid with 8 to 14 carbon atoms or Copra oil.
  • a foam-stabilizing agent in particular an amide of a fatty acid with 8 to 14 carbon atoms or Copra oil.
  • composition with a particularly satisfactory effect may be mentioned as an example, the proportions of the different ingredients being given in parts by weight:
  • this composition differs from the classic compositions not only by a higher content of solvents and particularly by their nature, but also by a lower content of basic raw materials, al-, o corrosive or aggressive components.
  • this composition according to the invention also has the advantage that it is non-flammable, which is a particularly important advantage if the composition is intended for a spray.

Abstract

Described is a composition for cleaning ovens, stoves and grills, the composition containing as active ingredients on the one hand a basic primary material consisting, in particular, of an alkaline base such as sodium carbonate or potash and/or one or more amines and on the other hand a non-volatile solvent, the composition containing 10 to 30 % by wt. of a solvent mixture made up on the one hand of at least one propylene glycol ether and on the other hand of at least one dipropylene glycol ether, the ratio of propylene glycol ether to dipropylene glycol ether being between 30:70 and 90:10. The composition is suitable above all for use on self-cleaning ovens and stainless-steel ovens.

Description

"Zusammensetzung zur Reinigung von Öfen" "Composition for cleaning ovens"
Die vorliegende Erfindung betrifft eine Zusammensetzung, die zur Reinigung von Öfen aller Art, insbesondere für Herde, Backöfen und Grillgeräte, ge¬ eignet ist.The present invention relates to a composition which is suitable for cleaning ovens of all kinds, in particular for stoves, ovens and grills.
Die derzeit auf dem Markt befindlichen Zusammensetzungen, die für die Rei¬ nigung von klassischen Emailleöfen bestimmt sind, weisen im wesentlichen als aktive Bestandteile einerseits einen geeigneten basischen Grundstoff, der auf Fette und angebrannte Rückstände einwirkt, und andererseits Lö¬ sungsmittel und organische Wirkstoffe auf, die als Lösungsmittel und An¬ feuchte- bzw. Benetzungsmittel wirken. Um eine einfache Handhabung zu er¬ möglichen, sind die Mischungen meistens als Sprays abgefüllt und können andere Bestandteile wie z. B. Tenside und/oder schäumende Mittel, Ver- dickungsmittel und Schaumstabilisatoren enthalten. Es ist anzumerken, daß die Verbraucher besonders die Produkte in Form eines stabilen Schaumes schätzen, die den Vorteil haben, den Sprühvorgang sichtbar zu machen.The compositions currently on the market, which are intended for cleaning classic enamel stoves, essentially have as active constituents, on the one hand, a suitable basic raw material, which acts on fats and burnt-on residues, and, on the other hand, solvents and organic active substances, which act as solvents and moistening or wetting agents. In order to make handling easy, the mixtures are mostly filled as sprays and other components such as. B. surfactants and / or foaming agents, thickeners and foam stabilizers. It should be noted that consumers particularly appreciate the products in the form of a stable foam, which have the advantage of making the spraying process visible.
Die derzeit auf dem Markt befindlichen Reinigungsprodukte für Öfen weisen im wesentlichen, in Gewichtsverhältnissen, 5 bis 10 % Lösungsmittel und 10 bis 15 % basische Grundstoffe auf, die im allgemeinen durch ein Gemisch einer alkalischen Base wie Soda oder Pattasche und eines oder mehrerer A ine, besonders des Monoethanolamins gebildet werden. Solche Produkte sind mit einer zufriedenstellenden Wirksamkeit für die Reinigung der klas¬ sischen Emailleöfen entwickelt worden, jedoch nicht für die Reinigung der sogenannten selbstreinigenden Öfen (Katalyse, Pyrolyse).The cleaning products for ovens currently on the market essentially have, in weight ratios, 5 to 10% solvents and 10 to 15% basic raw materials, which are generally composed of a mixture of an alkaline base such as soda or pattas and one or more amino acids, especially of monoethanolamine. Such products have been developed with a satisfactory effectiveness for cleaning the classic enamel stoves, but not for cleaning the so-called self-cleaning stoves (catalysis, pyrolysis).
Weiterhin gibt es heute auf dem Markt neben den klassischen Öfen mit Back¬ röhren aus Emaille auch Backöfen aus rostfreiem Stahl, die mit einer Hei߬ luftheizung ausgestattet sind und die entweder als nur "Heißluft-Backöfen oder als gemischte "Heißluft/Grill"-Backöfen ausgeführt sein können. Dabei ist festzustellen, daß die Beschaffenheit der Verkleidungen dieser Öfen (nichtoxidierender Stahl) große Schwierigkeiten bei der Reinigung mit den auf dem Markt bekannten Produkten, wie oben definiert, verursacht und so¬ mit die Entwicklung wirksamerer Reinigungszusammensetzung erforderlich macht. Man hat bis zum heutigen Tage den Verbrauchern keine geeigneten Zusammensetzungen anbieten können, die eine zufriedenstellende Reinigung der Öfen mit Umluftbackröhren aus nichtoxidierende Stahl erlauben.Furthermore, in addition to the classic ovens with baking tubes made of enamel, there are also ovens made of stainless steel on the market which are equipped with hot air heating and which are either only available as "hot air ovens or as mixed" hot air / grill "ovens It should be noted that the nature of the cladding of these ovens (non-oxidizing steel) causes great difficulties in cleaning with the products known on the market, as defined above, and thus requires the development of more effective cleaning compositions makes. To this day, it has not been possible to offer consumers suitable compositions which allow the ovens to be cleaned satisfactorily with non-oxidizing steel convection ovens.
Der vorliegenden Erfindung liegt die Aufgabe zugrunde, diesen Mißstand zu beheben, indem eine neue Zusammensetzung zum Reinigen der Öfen vorgeschla¬ gen wird, die die Vorteile der bekannten Zusammensetzung für die Reinigung von klassischen Emailleöfen aufweist aber gleichzeitig mit der Eigen¬ schaft, daß sie in zufriedenstellender Weise für die Reinigung der neuen Öfen aus nichtioxidierendem Stahl und "Grill/Heißluft"-Backöfen benutzbar ist.The object of the present invention is to remedy this problem by proposing a new composition for cleaning the furnaces which has the advantages of the known composition for cleaning classic enamel furnaces but at the same time has the property that it is in can be used satisfactorily for cleaning the new non-oxidizing steel and "grill / hot air" ovens.
Gemäß der Erfindung ist diese Zusammensetzung dadurch gekennzeichnet, daß sie zusätzlich zu einem basischen Grundstoff, welcher eine alkalische Base wie Soda oder Pottasche und/oder ein oder mehrere Amine enthält, 10 bis 30 Gewichtsprozent eines Gemisches aus wenig flüchtigem Lösungsmittel auf¬ weist, welches zum einen Teil mindestens einen Propylenglykolether und zum anderen Teil mindestens einen Dipropylenglykolether enthält, wobei das Gewichtsverhältnis Propylenglykolether zu Dipropylenglykolether zwischen 30 : 70 und 90 : 10 liegt.According to the invention, this composition is characterized in that, in addition to a basic base material which contains an alkaline base such as soda or potash and / or one or more amines, it has 10 to 30% by weight of a mixture of low-volatile solvent which is used for one part contains at least one propylene glycol ether and the other part contains at least one dipropylene glycol ether, the weight ratio of propylene glycol ether to dipropylene glycol ether being between 30:70 and 90:10.
Die Zusammensetzung gemäß der Erfindung unterscheidet sich also von klas¬ sischen Zusammensetzungen gleichen Typs gleichermaßen durch einem höheren Gehalt an Lösungsmittel und durch die besondere Beschaffenheit des Lö¬ sungsmittels, welches ausschließlich aus einem Gemisch aus Propylenglykol¬ ether und Dipropylenglykolether besteht. Vorzugsweise handelt es sich um die Glykolmonoether. Man kann einen weiten Bereich dieser Ether benutzen, ohne die Erfindung zu verlassen; die Wahl der tatsächlich benutzten Ether wird in erster Linie durch Überlegungen bezüglich Wirtschaftlichkeit und Lösungsfähigkeit bestimmt.The composition according to the invention thus differs from classic compositions of the same type equally in that it has a higher solvent content and in the particular nature of the solvent, which consists exclusively of a mixture of propylene glycol ether and dipropylene glycol ether. It is preferably the glycol monoethers. A wide range of these ethers can be used without departing from the invention; The choice of the ether actually used is primarily determined by considerations regarding economy and solvency.
Man hat beispielsweise sehr zufriedenstellende Ergebisse erzielt, wenn man in Verbindung mit Dipropylenglykolmethylether ein Gemisch des n- oder t- Butylethers und des Methylethers des Propylenglykols im Verhältnis 30 : 70 bis 70 : 30 verwendete. Gemäß einer bevorzugten Ausgestaltung der Erfindung wird eine besonders starke Schaumbildung bei der Verwendung als Spray erreicht, wenn das Lö¬ sungsmittel durch ein Gemisch aus Dipropylenglykol ethylether und Pro- pylenglykolmethylether gebildet wird.For example, very satisfactory results have been achieved if a mixture of the n- or t-butyl ether and the methyl ether of the propylene glycol in a ratio of 30:70 to 70:30 is used in conjunction with dipropylene glycol methyl ether. According to a preferred embodiment of the invention, particularly strong foaming when used as a spray is achieved if the solvent is formed by a mixture of dipropylene glycol ethyl ether and propylene glycol methyl ether.
Man hat außerdem besonders zufriedenstellende Ergebnisse bei der Reinigung von Öfen mit Heißluftröhren und mit Röhren aus nichtoxidierbare Stahl erhalten und bei klassischen Emailleöfen die Wirksamkeit mit dem Ziel ei¬ ner schnelleren Einwirkung verbessert. Man kann tatsächlich in Zahlen wiedergeben, daß eine derzeit auf dem Markt erhältliche entsprechende Zu¬ sammensetzung nach einer Einwirkungszeit von einer Nacht die gleiche Wir¬ kung zeigt, wie die Zusammensetzung gemäß der Erfindung nacir einer Ein¬ wirkdauer von 30 Minuten aufgrund einer bessseren Lösung der Fette infolge einer geringeren Verdunstung des Lösungsmittels.In addition, particularly satisfactory results have been obtained in the cleaning of ovens with hot air tubes and with tubes made of non-oxidizable steel, and the effectiveness with classic enamel ovens has been improved with the aim of a faster action. In fact, it can be shown in figures that a corresponding composition currently available on the market after a contact time of one night has the same effect as the composition according to the invention after a contact time of 30 minutes due to a better solution of the Fats due to less evaporation of the solvent.
Entsprechend einer besonderen Ausführungsform der Erfindung weist die Zu¬ sammensetzung zwischen 10 und 15 Gewichtsprozent Lösungsmittel auf, wobei die Menge des Propylenglykolethers vorzugsweise etwa 2 bis 4 mal höher ist als die Menge des Dipropylenglykolethers.According to a particular embodiment of the invention, the composition has between 10 and 15 percent by weight of solvent, the amount of the propylene glycol ether preferably being about 2 to 4 times higher than the amount of the dipropylene glycol ether.
Entsprechend einer anderen Ausführungsform kann die Zusammensetzung zwi¬ schen 0,5 und 10 Gew.-% Natriumcarbonat (Soda) aufweisen. Unter Berück¬ sichtigung der Gebrauchssicherheit und zur besseren Vorbeugung von Un- fal irisiken durch Kontakt oder Einnahme dieser Produkte, besteht bei den Herstellern seit mehreren Jahren das Bestreben, die maximale Menge der ätzenden und beizenden Stoffe zu vermindern, die in den zur Reinigung von Öfen bestimmten Zusammensetzungen enthalten sind. Das Reinigungsmittel gemäß der Erfindung zeigt seine Wirksamkeit mit einem Natriumcarbonatge- halt bereits unter 2 %, und es ist vorteilhaft, diese Grenze nicht zu überschreiten. In einer besonders vorteilhaften Ausführungsform der Er¬ findung besteht der basische Grundstoff vorzugsweise aus einem Gemisch von 0,5 bis 2 % Natriumcarbonat und 2 bis 10, vorzugsweise 2 bis 6 Gew.-% A in, vorzugsweise Monoethanolamin.According to another embodiment, the composition can have between 0.5 and 10% by weight sodium carbonate (soda). Taking into account the safety of use and to better prevent the risk of accidents by contacting or taking these products, manufacturers have been trying for several years to reduce the maximum amount of the caustic and pickling substances used in cleaning ovens certain compositions are included. The cleaning agent according to the invention shows its effectiveness with a sodium carbonate content already below 2%, and it is advantageous not to exceed this limit. In a particularly advantageous embodiment of the invention, the basic base material preferably consists of a mixture of 0.5 to 2% sodium carbonate and 2 to 10, preferably 2 to 6% by weight A in, preferably monoethanolamine.
Gemäß einer weiteren Ausführungsform der Erfindung weist die Zusammen¬ setzung zwischen 0,5 und 2 % eines Verdickungsmittels auf, beispielsweise Smectitton. Es wurde festgestellt, daß das Vorhandensein eines Ver¬ dickungsmittels in der Zusammensetzung gemäß der Erfindung ein Anhaften des versprühten Produktes an den Ofenwänden erleichtert.According to a further embodiment of the invention, the composition has between 0.5 and 2% of a thickener, for example Smectitton. It has been found that the presence of a thickening agent in the composition according to the invention facilitates adhesion of the sprayed product to the furnace walls.
Gemäß einer weiteren Ausführungsform der Erfindung weist die Zusammen¬ setzung bis zu 2 Gew.-%, vorzugsweise 0,1 bis 1 Gew.-% eines grenz¬ flächenaktiven Mittels auf, insbesondere ein Natriumsulfat eines Fettal¬ kohols mit 8 bis 15, vorzugsweise 10 bis 12 C-Atomen, der mit 2 bis 5 Mol Ethylenoxid ethoxyliert ist.According to a further embodiment of the invention, the composition has up to 2% by weight, preferably 0.1 to 1% by weight, of a surface-active agent, in particular a sodium sulfate of a fatty alcohol with 8 to 15, preferably 10 to 12 carbon atoms, which is ethoxylated with 2 to 5 moles of ethylene oxide.
Gemäß einer weiteren Ausführungsform der Erfindung weist die Zusammen¬ setzung bis zu 2 Gew.-%, vorzugsweise 0,1 bis 1 Gew.-% eines schaumstabi¬ lisierenden Mittels auf, insbesondere ein Amid einer Fettsäure mit 8 bis 14 C-Atomen oder ein Kopraöl. According to a further embodiment of the invention, the composition has up to 2% by weight, preferably 0.1 to 1% by weight, of a foam-stabilizing agent, in particular an amide of a fatty acid with 8 to 14 carbon atoms or Copra oil.
Beispielexample
Als Beispiel sei die folgende Zusammensetzung mit besonders zufriedenstel¬ lender Wirkung angführt, wobei die Anteile der unterschiedlichen Inhalts¬ stoffe in Gewichtsteilen angegeben sind:The following composition with a particularly satisfactory effect may be mentioned as an example, the proportions of the different ingredients being given in parts by weight:
Natriumcarbonat ,f.Sodium carbonate, f.
Monoethanola in 6Monoethanola in 6
Propylenglykolmethylether 9Propylene glycol methyl ether 9
Dipropylenglykol ethylether 4,5Dipropylene glycol ethyl ether 4.5
Ton vom Smectittyp 1Smectite type 1 clay
Fettsäureamid 0,5Fatty acid amide 0.5
Natriumlaurylethersulfat 0,5Sodium lauryl ether sulfate 0.5
Duftstoffe 0,05Perfumes 0.05
Wasser 79,95Water 79.95
Es ist zu bemerken, daß sich diese Zusammensetzung von den klassischen Zusammensetzungen nicht nur durch einen höheren Gehalt an Lösungsmitteln und besonders durch deren Beschaffenheit unterscheidet, sondern ebenso durch einen geringeren Gehalt an basischen Grundstoffen, al-;o ätzenden oder agressiven Bestandteilen. Über die oben erwähnten Vorteile hinaus¬ gehend zeigt diese Zusammensetung gemäß der Erfindung ebenso den Vorteil, daß sie nicht entflammbar ist, was ein besonders wichtiger Vorteil ist, wenn die Zusammensetzung für ein Spray bestimmt ist. It should be noted that this composition differs from the classic compositions not only by a higher content of solvents and particularly by their nature, but also by a lower content of basic raw materials, al-, o corrosive or aggressive components. In addition to the advantages mentioned above, this composition according to the invention also has the advantage that it is non-flammable, which is a particularly important advantage if the composition is intended for a spray.

Claims

Patentansprüche Claims
1. Zusammensetzung zur Reinigung von Öfen, enthaltend als wirksame Be¬ standteile zum einen Teil einen basischen Grundstoff, bestehend aus wenigstens einer alkalischen Base, wie Natriumcarbonat und/oder einem oder mehreren Aminen, und zum anderen Teil ein schwerflüchtiges Lö¬ sungsmittel, dadurch gekennzeichnet, daß die Zusammensetzung 10 bis 30 Gew.-% eines Lösungsmittelgemischs enthält, das zum einen Teil durch wenigstens einen Propylenglykolether und zum anderen Teil durch we¬ nigstens einen Dipropylenglykolether gebildet wird, wobei das Ge¬ wichtsverhältnis Propylenglykolether zu Dipropylenglykolether zwischen 30 : 70 und 90 : 10 liegt.1. Composition for cleaning ovens, containing as active components on the one hand a basic base material consisting of at least one alkaline base, such as sodium carbonate and / or one or more amines, and on the other hand a low-volatility solvent, characterized that the composition contains 10 to 30% by weight of a solvent mixture which is formed partly by at least one propylene glycol ether and partly by at least one dipropylene glycol ether, the weight ratio of propylene glycol ether to dipropylene glycol ether being between 30:70 and 90 : 10 lies.
2. Zusammensetzung nach Anspruch 1, dadurch gekennzeichnet, daß das Lö¬ sungsmittel durch ein Gemisch aus Dipropylenglykolmethylether und Pro- pylenglykolmethylether gebildet ist.2. Composition according to claim 1, characterized in that the solvent is formed by a mixture of dipropylene glycol methyl ether and propylene glycol methyl ether.
3. Zusammensetzung nach Anspruch 2, dadurch gekennzeichnet, daß die Zu¬ sammensetzung zwischen 10 und 15 Gew.- an Lösungsmittel aufweist, wo¬ bei die Menge des Propylenglykolethers vorzugsweise 2 bis 4 mal größer als die Menge des Dipropylenglykolethers ist.3. Composition according to claim 2, characterized in that the composition comprises between 10 and 15% by weight of solvent, the amount of the propylene glycol ether preferably being 2 to 4 times greater than the amount of the dipropylene glycol ether.
4. Zusammensetzung nach einem der Ansprüche 1 bis 3, dadurch gekennzeich¬ net, daß die Zusammensetzung zwischen 0,5 und 10 Gew.-% Natriumcarbo¬ nat enthält.4. Composition according to one of claims 1 to 3, characterized gekennzeich¬ net that the composition contains between 0.5 and 10 wt .-% sodium carbonate.
5. Zusammensetzung nach einem der Ansprüche 1 bis 4, dadurch gekennzeich¬ net, daß die Zusammensetzung weniger als 2 Gew.-% Natriumcarbonat ent¬ hält.5. Composition according to one of claims 1 to 4, characterized gekennzeich¬ net that the composition contains less than 2 wt .-% sodium carbonate ent.
6. Zusammensetzung nach Anspruch 5, dadurch gekennzeichnet, daß der ba¬ sische Grundstoff eine Mischung von 0,5 bis 2 Gew.-% Natriumcarbonat und von 2 bis 6 Gew.-% A in, vorzugsweise Monoethanolamin ist. 6. Composition according to claim 5, characterized in that the basic basic material is a mixture of 0.5 to 2% by weight sodium carbonate and from 2 to 6% by weight A in, preferably monoethanolamine.
7. Zusammensetzung nach einem der Ansprüche 1 bis 6, dadurch gekennzeich¬ net, daß die Zusammensetzung zwischen 0,5 und 2 Gew.-% eines Ver¬ dickungsmittels enthält.7. Composition according to one of claims 1 to 6, characterized gekennzeich¬ net that the composition contains between 0.5 and 2 wt .-% of a thickening agent.
8. Zusammensetzung nach einem der Ansprüche 1 bis 7, dadurch gekennzeich¬ net, daß die Zusammensetzung bis zu 2 Gew.-% eines grenzflächenaktiven Mittels enthält.8. Composition according to one of claims 1 to 7, characterized gekennzeich¬ net that the composition contains up to 2 wt .-% of a surfactant.
9. Zusammensetzung nach einem der Ansprüche 1 bis 8, dadurch gekennzeich¬ net, daß die Mischung bis zu 2 Gew.-% eines schaumstabilisierenden Mittels enthält.9. Composition according to one of claims 1 to 8, characterized gekennzeich¬ net that the mixture contains up to 2 wt .-% of a foam stabilizing agent.
10. Zusammensetzung nach einem der Ansprüche 1 bis 9, dadurch gekennzeich¬ net, daß die Zusammensetzung folgende Bestandteile enthält:10. Composition according to one of claims 1 to 9, characterized gekennzeich¬ net that the composition contains the following components:
0,5 bis 10, vorzugsweise 0,2 bis 2 Gew.-% Natriumcarbonat, 2 bis 10, vorzugsweise 2 bis 6 Gew.-% Monoethanolamin, 10 bis 30. vorzugsweise 10 bis 15 Gew.-% eines Gemischs aus Di- propylenglykol ethylether und Propylenglykolmethyl- ether, 0,5 bis 2, vorzugsweise etwa 1 Gew.-% eines Smectittons, 0 bis 2 Gew.-%, vorzugsweise 0,1 bis 1 Gew.-% eines Fettsäure- amids, 0 bis 2 Gew.-%, vorzugsweise 0,1 bis 1 Gew.-% Natriumlaurylether- sulfat, 0 bis 0,1 Gew.-%, vorzugsweise etwa 0,05 Gew.-% Duftstoff und Wasser. 0.5 to 10, preferably 0.2 to 2% by weight of sodium carbonate, 2 to 10, preferably 2 to 6% by weight of monoethanolamine, 10 to 30, preferably 10 to 15% by weight of a mixture of propylene glycol ethyl ether and propylene glycol methyl ether, 0.5 to 2, preferably about 1% by weight of a smectite clay, 0 to 2% by weight, preferably 0.1 to 1% by weight of a fatty acid amide, 0 to 2% by weight. %, preferably 0.1 to 1% by weight of sodium lauryl ether sulfate, 0 to 0.1% by weight, preferably about 0.05% by weight of fragrance and water.
PCT/EP1994/000681 1993-03-15 1994-03-07 Oven-cleaning composition WO1994021776A1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
DE59401211T DE59401211D1 (en) 1993-03-15 1994-03-07 COMPOSITION FOR CLEANING OVENS
EP94909120A EP0689583B1 (en) 1993-03-15 1994-03-07 Oven-cleaning composition
GR960403165T GR3021915T3 (en) 1993-03-15 1996-12-05 Oven-cleaning composition

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9302951A FR2702775B1 (en) 1993-03-15 1993-03-15 Composition for cleaning ovens.
FR93/02951 1993-03-15

Publications (1)

Publication Number Publication Date
WO1994021776A1 true WO1994021776A1 (en) 1994-09-29

Family

ID=9444957

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1994/000681 WO1994021776A1 (en) 1993-03-15 1994-03-07 Oven-cleaning composition

Country Status (8)

Country Link
EP (1) EP0689583B1 (en)
AT (1) ATE145935T1 (en)
DE (1) DE59401211D1 (en)
DK (1) DK0689583T3 (en)
ES (1) ES2094650T3 (en)
FR (1) FR2702775B1 (en)
GR (1) GR3021915T3 (en)
WO (1) WO1994021776A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2286198A (en) * 1994-02-02 1995-08-09 Solution Ind Limited Decarbonising using dipropylene glycol monomethyl ether

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU719487B2 (en) * 1995-07-18 2000-05-11 Diversey, Inc. Concentrated aqueous degreasing cleanser

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CH510107A (en) * 1968-09-09 1971-07-15 Johnson & Son Inc S C Cleaning agents and their use
US4105574A (en) * 1975-01-24 1978-08-08 American Cyanamid Company Process for formulating a non-caustic oven cleaner which will remove pyrolyzed fat efficaciously
FR2571279A1 (en) * 1984-10-04 1986-04-11 Dow Chemical France Rinsing agent for spraying and atomising units, especially for agricultural use, based on a glycol ether derived from propylene glycol
US4686065A (en) * 1986-05-23 1987-08-11 Miles Laboratories, Inc. Caustic based cleaning composition containing THFA and a propoxylated alcohol or phenol
EP0275987A2 (en) * 1987-01-20 1988-07-27 The Dow Chemical Company Composition and method for cleaning gas turbine compressors
EP0286075A2 (en) * 1987-04-10 1988-10-12 Colgate-Palmolive Company Detergent composition
EP0344847A2 (en) * 1988-06-03 1989-12-06 The Procter & Gamble Company Improved liquid cleaners
EP0347110A1 (en) * 1988-06-13 1989-12-20 Colgate-Palmolive Company Stable and homogeneous concentrated all purpose cleaner
EP0379093A1 (en) * 1989-01-19 1990-07-25 Sterling Drug Inc. Hard surface cleaning composition

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH510107A (en) * 1968-09-09 1971-07-15 Johnson & Son Inc S C Cleaning agents and their use
US4105574A (en) * 1975-01-24 1978-08-08 American Cyanamid Company Process for formulating a non-caustic oven cleaner which will remove pyrolyzed fat efficaciously
FR2571279A1 (en) * 1984-10-04 1986-04-11 Dow Chemical France Rinsing agent for spraying and atomising units, especially for agricultural use, based on a glycol ether derived from propylene glycol
US4686065A (en) * 1986-05-23 1987-08-11 Miles Laboratories, Inc. Caustic based cleaning composition containing THFA and a propoxylated alcohol or phenol
EP0275987A2 (en) * 1987-01-20 1988-07-27 The Dow Chemical Company Composition and method for cleaning gas turbine compressors
EP0286075A2 (en) * 1987-04-10 1988-10-12 Colgate-Palmolive Company Detergent composition
EP0344847A2 (en) * 1988-06-03 1989-12-06 The Procter & Gamble Company Improved liquid cleaners
EP0347110A1 (en) * 1988-06-13 1989-12-20 Colgate-Palmolive Company Stable and homogeneous concentrated all purpose cleaner
EP0379093A1 (en) * 1989-01-19 1990-07-25 Sterling Drug Inc. Hard surface cleaning composition

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2286198A (en) * 1994-02-02 1995-08-09 Solution Ind Limited Decarbonising using dipropylene glycol monomethyl ether

Also Published As

Publication number Publication date
ES2094650T3 (en) 1997-01-16
FR2702775A1 (en) 1994-09-23
FR2702775B1 (en) 1995-05-19
ATE145935T1 (en) 1996-12-15
DE59401211D1 (en) 1997-01-16
EP0689583B1 (en) 1996-12-04
EP0689583A1 (en) 1996-01-03
GR3021915T3 (en) 1997-03-31
DK0689583T3 (en) 1997-04-28

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