Classifications

• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
  • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
  • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
  • B05D3/10—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by other chemical means
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B26—HAND CUTTING TOOLS; CUTTING; SEVERING
  • B26B—HAND-HELD CUTTING TOOLS NOT OTHERWISE PROVIDED FOR
  • B26B21/00—Razors of the open or knife type; Safety razors or other shaving implements of the planing type; Hair-trimming devices involving a razor-blade; Equipment therefor
  • B26B21/54—Razor-blades
  • B26B21/58—Razor-blades characterised by the material
  • B26B21/60—Razor-blades characterised by the material by the coating material
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
  • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
  • B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
  • B05D5/08—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface
  • B05D5/083—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface involving the use of fluoropolymers
  • B05D5/086—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface involving the use of fluoropolymers having an anchoring layer
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
  • C08J3/00—Processes of treating or compounding macromolecular substances
  • C08J3/28—Treatment by wave energy or particle radiation
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
  • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
  • B05D2202/00—Metallic substrate
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
  • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
  • B05D2506/00—Halogenated polymers
  • B05D2506/10—Fluorinated polymers
  • B05D2506/15—Polytetrafluoroethylene [PTFE]
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
  • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
  • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
  • C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
  • C08J2327/18—Homopolymers or copolymers of tetrafluoroethylene
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/31504—Composite [nonstructural laminate]
  • Y10T428/3154—Of fluorinated addition polymer from unsaturated monomers
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/31504—Composite [nonstructural laminate]
  • Y10T428/3154—Of fluorinated addition polymer from unsaturated monomers
  • Y10T428/31544—Addition polymer is perhalogenated

Definitions

• This invention relates to an improved method of producing razor blade cutting edges by coating the blade edge with an aqueous polyfluorocarbon dispersion and subsequently heating the polyfluorocarbon.
• the present method provides good telomer adhesion and blade wear yet eliminates the need to utilize environmentally hazardous solvents. Uncoated razor blades, despite their sharpness, cannot be employed for shaving a dry beard without excessive discomfort and pain, and it is as a practical matter necessary to employ with them a beard-softening agent such as water and/or a shaving cream or soap.
• the blades may be coated by (1) placing the blade edge in close proximity to a supply of the fluorocarbon and subsequently heating the blade, (2) spraying blade with a fluorocarbon dispersion, (3) dipping the blade into a fluorocarbon dispersion or (4) by use of electrophoresis.
• Example 2 shows a blade which is dip-coated with an aqueous colloidal dispersion containing 25% (wt) finely divided solid tetrafluoroethylene polymer (DuPont's Teflon Clear Finish) . The resulting blade was later sintered.
• Example 2 discloses an aqueous dispersion of 0.5% polytetrafluoroethylene, PTFE, (Impurities: 0.44% Chlorine and 0.06% Hydrogen), and 0.5% Triton X-100 wetting agent. The dispersion is electrostatically sprayed onto stainless steel blades.
• Example 8 states that the polymerization of tetrafluoroethylene is achieved in an aqueous dispersion with methyl alcohol as the telogen and ammonium persulfate as the catalyst.
• Fish et al U.S. Patent No. 3,658,742, issued April 25, 1972, discloses an aqueous polytetrafluoroethylene (PTFE) dispersion containing Triton X-100 wetting agent which is electrostatically sprayed on blade edges.
• the aqueous dispersion is prepared by exchanging the Freon solvent in Vydax brand PTFE dispersion (PTFE + Freon solvent), distributed by E.I. DuPont, Wilmington, Delaware, with isopropyl alcohol and then exchanging the isopropyl alcohol with water.
• Example 1 discloses an aqueous PTFE dispersion containing 0.4% PTFE and 0.1% Triton X-100 wetting agent.
• Dillon U.S. Patent No. 3,766,031, issued October 16, 1973, incorporated herein by reference, indicates that the application of a critical dose of ionizing radiation to sintered or unsintered polytetrafluoroethylene renders such material capable of being comminuted to microfineness with no adverse heat side effects, and the resulting particles are readily dispersible in diverse media. Such particles possess the extremely low coefficient of friction associated with polytetrafluoroethylene resin.
• the dosage level of ionizing radiation in accordance with the process of this invention lies within the range of from about 5 megarads to about 25 megarads, and is preferably maintained between about 10 megarads and 25 megarads.
• An object of the present invention is to provide an environmentally-friendly method of coating razor blade edges with polyfluorocarbons, particularly polytetrafluoroethylene. Specifically, it is an object of the present invention to eliminate chlorofluorocarbon solvents and volatile organic solvents from the blade coating process.
• the present invention relates to an improved method of forming a polyfluorocarbon coating on a razor blade cutting edge comprising the steps of subjecting a fluorocarbon polymer powder having a molecular weight of at least about 1,000,000 to ionizing radiation to reduce the average molecular weight to from about 700 to about 700,000; dispersing the irradiated fluorocarbon polymer in an aqueous solution; coating said razor blade cutting edge with the dispersion; and heating the coating obtained to melt, partially melt or sinter the fluorocarbon polymer. All percentages and ratios described herein are on a weight basis unless otherwise indicated.
• the term "razor blade cutting edge" includes the cutting point and facets of the blade. Applicant recognizes that the entire blade could be coated in the manner described herein; however, an enveloping coat of this type is not believed to be essential to the present invention. Also, the terms “ionizing radiation” or “irradiated”, as used herein, refers to the emission of X-rays, Beta-rays, Gamma-rays, electrons or positrons. Gamma radiation is preferred.
• Various methods have been proposed in the past for preparing and utilizing aqueous dispersions of fluorocarbon polymer to coat razor blade cutting edges. All of these methods invariably produced a blade which rapidly decreased in cutting effectiveness.
• the blades exhibit a significant improvement in long-term effectiveness compared with prior art aqueous systems.
• the blades produced by the present invention require much less force to cut water-softened hair. This reduction in cutter force persists during several successive shaves with the same blade cutting edge.
• an aqueous dispersion is prepared from an irradiated fluorocarbon polymer.
• the preferred non irradiated fluorocarbon polymers are those which contain a chain of carbon atoms including a preponderance of -CF.-CF 2 - groups, such as polymers of tetrafluoroethylene, including copolymers such as those with a minor proportion, e.g. up to 5% by weight of hexafluoropropylene.
• These polymers have terminal groups at the ends of the carbon chains which may vary in nature, depending, as is well known, upon the method of making the polymer.
• the common terminal groups of such polymers are, -H, -COOH, -Cl, -CC1 3 , -CFC1CF 2 C1, -CH 2 OH, -CH j and the like. While the precise molecular weights and distribution of molecular weights of the preferred polymers are not known with certainty, it is believed that they have molecular weights over 1,000,000.
• the preferred chlorine- containing polymers are those containing from 0.15 to 0.45% by weight of chlorine (which is present in the terminal groups) .
• the most preferred starting material is polytetrafluoroethylene.
• a method of forming a polyfluorocarbon coating on a razor blade cutting edge which comprises subjecting the abovementioned fluorocarbon polymer starting material having a molecular weight of at least 1,000,000 in dry powder form, to ionizing irradiation to reduce the average molecular weight of the polymer to from about 700 to about 700,000, preferably to from about 700 to about 51,000 and most preferably to about 25,000, forming a dispersion of the irradiated polymer in an aqueous medium, spraying the dispersion on to a razor blade cutting edge and heating the coating obtained to cause the polymer to adhere to the blade edge.
• the heating of the coating is intended to cause the polymer to adhere to the blade.
• the heating operation can result in a sintered, partially melted or melted coating.
• a partially melted or totally melted coating is preferred as it allows the coating to spread and cover the blade more thoroughly.
• the radiation dose is preferably from
• the polyfluorocarbon is preferably polytetrafluoroethylene and irradiation is preferably effected to obtain a telomer having an average molecular weight of about 25,000.
• the irradiated polyfluorocarbon should have a fine particle size, preferably an average particle size of not more than about 100 microns. Powdered polyfluorocarbon starting material is normally available as a coarser material than this and it may be ground to this fineness either before or after the irradiation step, preferably the latter.
• the level of the polyfluorocarbon, in the dispersion is from about 0.5% to about 2.0% (wt) , preferably from about 0.7% to about 1.0% (wt) .
• the particle size range is from about 2 ⁇ m to about 8 ⁇ m.
• a wetting agent is required.
• the wetting agents for use in the present invention may be selected from the various surface active materials which are available, for use in aqueous, polymeric dispersions.
• Such wetting agents include alkali metal salts of dialkyl sulfosuccinates, soaps of higher fatty acids, fatty amines, sorbitan mono- and di-esters of fatty acids and their polyoxyalkyleneether derivatives, alkali metal salts of alkylarylsulfonates, polyalkyleneether glycols and the mono- and di-fatty acid esters of said glycols.
• the preferred wetting agents for use in the present invention are the non- ionics and more particularly the alkylphenylpolyalkyleneether alcohols such as Triton X-100 and Triton X-114 sold by Union Carbide, Ipegal CO- 10 sold by Rhone-Poulenc and Tergitol 12P12 sold by Union Carbide Company. Especially useful results have been obtained with the Tergitol 12P12 which is dodecylphenylpolyethyleneether alcohol containing 12 ethylene oxide groups.
• the amount of wetting agent employed may be varied. Usually, the wetting agent is used in amounts equal to at least about 1% by weight of the fluorocarbon polymer, preferably at least about 3% by weight of the fluorocarbon polymer. In preferred embodiments, the wetting agent is used in amounts ranging between about 3% to about 50% by weight of the polymer with lower levels of wetting agent being desirable. Particularly good results were obtained using between about 3% to about 6%.
• Nonionic surfactants are often characterized in terms of their HLB (hydrophile- lipophile balance) number.
• HLB hydrophile- lipophile balance
• the HLB number may be calculated from
• HLB E/5 where E is the weight percentage of ethylene oxide in the molecule.
• Hydrophile-Lipophile Balance number of from about 12.4 to about 18, preferably from about 13.5 to about 18.0, can be utilized in the present invention.
• HLB numbers see Kirk-Othmer, Encyclopedia of Chemical Technology, Vol. 22, pp 360-362, incorporated herein by reference.
• the dispersion may be applied to the cutting edge in any suitable manner to give as uniform a coating as possible, as for example, by dipping or spraying; nebulization is especially preferred for coating the cutting edges, in which case, an electrostatic field is preferably employed in conjunction with the nebulizer in order to increase the efficiency of deposition.
• electrostatic spraying technique see U.S.
• Preheat of the dispersion may be desirable to facilitate spraying, the extent of preheating depending on the nature of the dispersion. Preheating of the blades to a temperature approaching the boiling point of the volatile liquid may also be desirable.
• the blades carrying the deposited polymer particles on their cutting edges must be heated at an elevated temperature to form an adherent coating on the cutting edge.
• the period of time during which the heating is continued may vary widely, from as little as several seconds to as long as several hours, depending upon the identity of the particular polymer used, the nature of the cutting edge, the rapidity with which the blade is brought up to the desired temperature, the temperature achieved, and the nature of the atmosphere in which the blade is heated.
• the blades may be heated in an atmosphere of air, it is preferred that they be heated in an atmosphere of inert gas such as helium, nitrogen, etc., or in an atmosphere of reducing gas such as hydrogen, or in mixtures of such gases, or in vacuo.
• the heating must be sufficient to permit the individual particles of polymer to, at least, sinter. Preferably, the heating must be sufficient to permit the polymer to spread into a substantially continuous film of the proper thickness and to cause it to become firmly adherent to the blade edge material.
• the heating conditions i.e., maximum temperature, length of time, etc., obviously must be adjusted so as to avoid substantial decomposition of the polymer and/or excessive tempering of the metal of the cutting edge.
• the temperature. should not exceed 430°C.
• the quality of the first shave obtained with blades of each of the following examples is equal to the quality obtained with the fluorocarbon-polymer-coated blades manufactured with a chlorofluorocarbon solvent presently available; and the decrease in quality with successive shaves in the case of blades of each particular example is less than the decrease in quality in the case of the fluorocarbon polymer- coated blades manufactured with an aqueous solvent previously known.
• EXAMPLE 1 Polytetrafluoroethylene powder with an average molecular weight of about 3 million is subjected to gamma irradiation so that the dosage received was 25 megarads and the number- average molecular weight is about 25,000 as calculated by the method described in Sewa et al., J. App. Polymer Science, _J_ 3258 (1973), incorporated herein by reference.
• EXAMPLE 2 A dispersion containing 1% by weight of the irradiated material from Example 1 ground to a particle size of from about 2 ⁇ m to about 8 ⁇ m and 0.03% of Triton X-100 brand wetting agent (Union Carbide) in 50°C. water is prepared and homogenized with a blender. Stainless steel razor blade cutting edges are then sprayed electrostatically with the dispersion. After drying, the coating on the blade edges is heated in nitrogen at 650°F. for 35 minutes. The blades so treated exhibit equivalent blade performance and same coating durability as similar blades which had been treated the same way with commercial nonirradiated telomer dispersed in trichlorotrifluoroethane solvent.
• EXAMPLE 3 A dispersion containing 1% by weight of the irradiated material from Example 1 ground to a particle size of from about 2 ⁇ m to about 8 ⁇ m and 0.03% of Triton X-100 brand wetting agent (Union Carbide) in 50°C. water is prepared
• a dispersion containing 0.7% by weight of the irradiated material of Example 1, 50°C. water and 0.05% of Brij 58 brand wetting agent (ICI Americas) is prepared and homogenized with a blender. Stainless steel razor blade cutting edges are then sprayed electrostatically with the dispersion. After drying, the coating on the blade edges is sintered in nitrogen at 650°F. for 35 minutes. The blades so treated exhibit equivalent blade performance and the same coating durability as similar blades which had been treated the same way with commercial, nonirradiated telomer in isopropanol or trichlorotrifluoroethane.

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• Chemical & Material Sciences (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Mechanical Engineering (AREA)
• Health & Medical Sciences (AREA)
• Engineering & Computer Science (AREA)
• Forests & Forestry (AREA)
• Medicinal Chemistry (AREA)
• Polymers & Plastics (AREA)
• Organic Chemistry (AREA)
• Life Sciences & Earth Sciences (AREA)
• General Chemical & Material Sciences (AREA)
• Application Of Or Painting With Fluid Materials (AREA)
• Processes Of Treating Macromolecular Substances (AREA)
• Dry Shavers And Clippers (AREA)
• Paints Or Removers (AREA)
• Compositions Of Macromolecular Compounds (AREA)
• Grinding-Machine Dressing And Accessory Apparatuses (AREA)
• Treatments Of Macromolecular Shaped Articles (AREA)
• Finish Polishing, Edge Sharpening, And Grinding By Specific Grinding Devices (AREA)
• Knives (AREA)
• Details Of Cutting Devices (AREA)
• Meat, Egg Or Seafood Products (AREA)
• Crystals, And After-Treatments Of Crystals (AREA)
• Mechanical Treatment Of Semiconductor (AREA)
• Processing Of Stones Or Stones Resemblance Materials (AREA)

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• 1992
  • 1992-04-17 US US07/870,364 patent/US5263256A/en not_active Expired - Lifetime
• 1993
  • 1993-04-13 WO PCT/US1993/003500 patent/WO1993020952A1/en active IP Right Grant
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  • 1993-04-13 AU AU42855/93A patent/AU673838B2/en not_active Ceased
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• 2000
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