WO1991014906A1 - A heat-storing body of metal and a heat storage means - Google Patents

A heat-storing body of metal and a heat storage means Download PDF

Info

Publication number
WO1991014906A1
WO1991014906A1 PCT/FI1991/000055 FI9100055W WO9114906A1 WO 1991014906 A1 WO1991014906 A1 WO 1991014906A1 FI 9100055 W FI9100055 W FI 9100055W WO 9114906 A1 WO9114906 A1 WO 9114906A1
Authority
WO
WIPO (PCT)
Prior art keywords
heat
steel
storage means
core
heat storage
Prior art date
Application number
PCT/FI1991/000055
Other languages
English (en)
French (fr)
Inventor
Pentti Salmelin
Original Assignee
Imatran Voima Oy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imatran Voima Oy filed Critical Imatran Voima Oy
Priority to DE4190616A priority Critical patent/DE4190616C2/de
Priority to GB9220354A priority patent/GB2263165B/en
Publication of WO1991014906A1 publication Critical patent/WO1991014906A1/en
Priority to SE9202623A priority patent/SE505707C2/sv

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D20/00Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00
    • F28D20/0056Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00 using solid heat storage material
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24HFLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
    • F24H7/00Storage heaters, i.e. heaters in which the energy is stored as heat in masses for subsequent release
    • F24H7/002Storage heaters, i.e. heaters in which the energy is stored as heat in masses for subsequent release using electrical energy supply
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/14Thermal energy storage

Definitions

  • the invention relates to a heat-storing body of metal.
  • the invention is also concerned with a heat storage means comprising a heat storing body one sur ⁇ face of which forms a contact surface with a heat- transfer fluid.
  • Heat-storing bodies are used widely in various applications to transfer heat supplied to the body and stored therein to a point where it is needed.
  • the heat transfer or transmission fluid is often a liquid, typically water, but is it also possible to use a gas.
  • the present invention can be applied when the heat transfer medium is either a liquid or a gas.
  • Heat-storing bodies are, of course, made of materials of high heat-storing capacity. In many cases, it is also desirable that the heat-storing capacity of the material per unit volume is high. It is well-known to use soapstone as a heat-storing material as it has a high heat-storing capacity as compared with other stone materials. Ceramic and fire-resistant materials as well as mineral materials, such as ferrosilicate, are used widely in the cores of heat storage means.
  • the metal heat-storing body of the invention is charac- terized in that it comprises a core of steel, an alloy of good heat resistance being sprayed on the surface of the steel core.
  • the core is made of general structural steel.
  • the composition of the alloy used as a coating preferably corresponds substantially to the composition of stainless extra- low carbon austenitic steel.
  • the heat storage means of the invention is mainly characterized in that the heat-storing body comprises a core of steel, an alloy of good heat resistance being sprayed on that portion of the core surface which is exposed to oxidizing ambient con ⁇ ditions.
  • Preferred embodiments of the heat storage means are disclosed in the attached claims 6 to 10.
  • the present invention is based on the idea that the • core of the heat-storing body is made of in ⁇ expensive standard steel having excellent heat- storing properties.
  • the steel is protected against oxidation and other chemical reactions by means of an alloy which is sprayed on the surface of the steel.
  • a major advantage of the invention is that a compact heat-storing body with a high heat-storing capacity per unit volume can be manufactured at low costs.
  • the core is made of general structural steel, it is ensured that the material is readily available in different shapes and dimensions to meet the requirements of each particular application.
  • the steel core can be manufactured or assembled by welding, which is particularly advantageous in the production of extremely large cores.
  • Figure 1 shows the principal features of a heat storage means
  • Figure 2 is a back view of the heat storage means of Figure 1;
  • Figure 3 is a sectional view along the line III-III of Figure 1; and Figure 4 shows a cartridge provided in the heat storage means of Figure 1 for heat resistors.
  • FIG. 1 shows a heat storage means typically connected to a heat exchanger (not shown) for the recovery of heat.
  • the heat storage means comprises a heat-storing body generally indicated with the refer ⁇ ence numeral 1.
  • the heat-storing body 1 is formed by placing four substantially rectangular steel bodies 2 to 5 side by side.
  • the steel bodies 2 to 5 are of general structural steel, such as Fe 52-c (St 52-3), as this type of steel is low in cost and readily available, in addition to which it is easy to weld.
  • a contact surface between the adjacent steel bodies 2 and 3, and 4 and 5, comprises a space for an electric heating resistor 6, 7.
  • the heat-storing body 1 is heated by the electric resistors, by means of which the temperature is raised to about 550 to 750 C C, a typical operating temperature being about 600°C.
  • the temperature of the body 1 may be clearly above 750°C and below 550°C. Above the latter temperature, unalloyed or carbon steels show a high tendency to scale off.
  • Each heating resistor 6 and 7 is fitted in a separate cartridge 8 and 9, respectively, which forms a holder for the resistor.
  • the cartridges 8, 9, the structure of which will be described in connection with Figure 4, are in close thermal contact with the steel bodies 2 and 3, and 4 and 5, and the heating resistors 6, 7 are in close thermal contact with the cartridges 8, 9, respective ⁇ ly. In this way, it is ensured that the transfer of heat from the heating resistors 6, 7 to the steel bodies 2 to 5 is efficient.
  • the heating resistors 6, 7 are indicated with broken lines within the heat storing body 1.
  • a cover 10 is fitted tightly to that surface of the heat storing body 1 which is in con- tact with a heat transfer fluid, in this case water, so that a heat transfer space is formed between the cover and the contact surface.
  • the cover 10 is provided with an inlet 11 for water and an outlet 12 for steam.
  • As the surface of the heat storing body 1 and the cover 10 is surrounded with air and the sur ⁇ face is heated up to a temperature at which general structural steel is oxidized and scales off, an alloy of good heat resistance is sprayed on the surface of the heat-storing body.
  • the cover 10 also has to be coated if it is made of steel scaling off at the operating temperature.
  • the cover 10 of the total material consumption of the heat storage means could be made of a material of good heat resistance, in which case it need not be coated.
  • a suitable starting material for the coating material is a filament material or a powder having a composition that cor ⁇ responds substantially to that of a 18-8-type stain ⁇ less extra-low carbon austenitic steel.
  • a low carbon content has proved to be important for the adhesive properties of the coating.
  • the carbon content of an effective mixture is about 0.03%. Not even a carbon content below this has proved disadvantageous.
  • This kind of steel is readily available and its price is fairly reasonable as compared with many other types of stainless steel or superalloys.
  • a Kanthal alloy coating is used in place of stainless steel. The walls surrounded by the heat transfer space are left uncoated as the heat transfer space is free from oxygen.
  • FIG. 2 is a back view of the heat storage means, that is, from the side of the cover 10.
  • Figure 3 is a sectional view along the line III-III of Figure 1.
  • the reference numerals 13 to 15 indicate welds joining the steel bodies 2 to 5. It should be noted in this connection that the steel bodies 2 to 5 are welded together only on the side of the contact surface, that is, the heat-storing body 1 is not welded at the top, at the bottom or in the front, i.e. on the side of the heat ⁇ ing resistors 6, 7. This enables the seams between the steel bodies 2 to 5 to be opened slightly for inserting the cartridges 8, 9 for the heating resistors into close contact with the steel bodies.
  • the reference numeral 17' indicates a locking member which is fixed by means of bolts to the steel bodies 2 to 5 to prevent them from being displaced apart from each other.
  • FIG. 3 further shows baffle plates 17 to 20 for water positioned one below another in the heat transfer space so as to spread water and steam over the entire contact surface of the heat-storing body 1.
  • the baffle plates 17 to 20 are therefore arranged to slant alternately in reverse directions.
  • the baffle plates 17 to 20 are preferably attached to the steel bodies 2 to 5 by welding.
  • Figure 4 shows the cartridge 8 to be inserted between the steel bodies 2 and 3.
  • the cartridge 8 comprises two plate-like parts 21 and 22 so shaped that the heating resistor 6 can be removed from the heat-storing body 1 by withdrawing only the inner part 22.
  • the outer part 21 remains in place in the body 1.
  • the two-part cartridge 8 is to be preferred in view of maintenance.
  • the invention has been described above only by means of its one preferred embodiment. It is to be understood that the details of the invention can be modified in various ways within the scope of the attached claims. Accordingly, it is possible that the heat-storing body is formed by an ingot- or brick- shaped body which is heated e.g. by heat generated in a heat-storing fireplace, the heat-storing body being built inside the fireplace.
  • the heat- storing body is not at all heated by electricity, and the heat transfer fluid is not water but air or gas. In place of electricity, the heating can be realized with an oil or gas flame.
  • the core need not be made of conventional general structural steel but it is possible to use various low alloy steels and heat refining steels, which are coated; they are, however, more expensive than conventional structural steel so their use is not particularly advisable - especially in view of the object of the invention, that is, the achievement of an inexpensive body having a good heat-storing capacity and resistance to high temperatures.
  • the coating may be of some other material suited for high temperatures.
  • One suitable alternative might be austenitic-ferritic steel. A criterion for selecting the material is that its heat resistance and adhesive properties are sufficiently good.

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Laminated Bodies (AREA)
  • Coating By Spraying Or Casting (AREA)
  • Central Heating Systems (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)
PCT/FI1991/000055 1990-03-26 1991-02-21 A heat-storing body of metal and a heat storage means WO1991014906A1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
DE4190616A DE4190616C2 (de) 1990-03-26 1991-02-21 Wärmespeichernder Körper aus Metall und Wärmespeicher
GB9220354A GB2263165B (en) 1990-03-26 1991-02-21 A heat-storing body of metal and a heat storage means
SE9202623A SE505707C2 (sv) 1990-03-26 1992-09-11 Värmelagrande kropp av metall och värmelagrande anordning

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FI901496A FI86474C (fi) 1990-03-26 1990-03-26 Metallisk, vaerme ackumulerande kropp samt vaermeackumulator.
FI901496 1990-03-26

Publications (1)

Publication Number Publication Date
WO1991014906A1 true WO1991014906A1 (en) 1991-10-03

Family

ID=8530125

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FI1991/000055 WO1991014906A1 (en) 1990-03-26 1991-02-21 A heat-storing body of metal and a heat storage means

Country Status (6)

Country Link
AU (1) AU7303691A (fi)
DE (2) DE4190616C2 (fi)
FI (1) FI86474C (fi)
GB (1) GB2263165B (fi)
SE (1) SE505707C2 (fi)
WO (1) WO1991014906A1 (fi)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1730460A1 (en) * 2004-03-12 2006-12-13 Larkden PTY Limited Method and apparatus for storing heat energy
WO2020254001A1 (en) 2019-06-17 2020-12-24 E2S Power AG Energy storage device and method for storing energy
CN114041036A (zh) * 2019-06-17 2022-02-11 E2S电力公司 能量存储装置及存储能量的方法
WO2022272098A1 (en) * 2021-06-25 2022-12-29 Antora Energy, Inc. Sub-systems and methods within a thermal storage solution
EP4257908A1 (en) 2022-04-05 2023-10-11 E2S Power Ag Energy storage device and method for storing energy using serially connected thermal energy storage units
US11876254B2 (en) 2019-11-13 2024-01-16 Antora Energy, Inc. System and method for a solid-state thermal battery

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102020107014A1 (de) 2020-03-13 2021-09-16 Deutsches Zentrum für Luft- und Raumfahrt e.V. Energiespeichersystem und Verfahren zum Betreiben eines Energiespeichersystems

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1990004140A1 (en) * 1988-10-05 1990-04-19 Imatran Voima Oy A heat-storing heating device

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1990004140A1 (en) * 1988-10-05 1990-04-19 Imatran Voima Oy A heat-storing heating device

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1730460A1 (en) * 2004-03-12 2006-12-13 Larkden PTY Limited Method and apparatus for storing heat energy
EP1730460A4 (en) * 2004-03-12 2013-03-20 Larkden Pty Ltd METHOD AND DEVICE FOR STORING HEAT ENERGY
WO2020254001A1 (en) 2019-06-17 2020-12-24 E2S Power AG Energy storage device and method for storing energy
CN114041036A (zh) * 2019-06-17 2022-02-11 E2S电力公司 能量存储装置及存储能量的方法
US11920484B2 (en) 2019-06-17 2024-03-05 E2S Power AG Energy storage device and method for storing energy
US11876254B2 (en) 2019-11-13 2024-01-16 Antora Energy, Inc. System and method for a solid-state thermal battery
WO2022272098A1 (en) * 2021-06-25 2022-12-29 Antora Energy, Inc. Sub-systems and methods within a thermal storage solution
US11994347B2 (en) 2021-06-25 2024-05-28 Antora Energy, Inc. Systems for managing thermal energy within a thermal storage solution
EP4257908A1 (en) 2022-04-05 2023-10-11 E2S Power Ag Energy storage device and method for storing energy using serially connected thermal energy storage units
WO2023194305A1 (en) 2022-04-05 2023-10-12 E2S Power AG Energy storage device and method for storing energy using serially connected thermal energy storage units

Also Published As

Publication number Publication date
SE9202623D0 (sv) 1992-09-11
FI901496A (fi) 1991-09-27
GB2263165B (en) 1994-11-30
GB9220354D0 (en) 1992-11-18
SE505707C2 (sv) 1997-09-29
SE9202623L (sv) 1992-09-11
FI901496A0 (fi) 1990-03-26
GB2263165A (en) 1993-07-14
DE4190616C2 (de) 1994-06-30
FI86474B (fi) 1992-05-15
FI86474C (fi) 1992-08-25
DE4190616T (fi) 1993-01-28
AU7303691A (en) 1991-10-21

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