WO1991014906A1 - A heat-storing body of metal and a heat storage means - Google Patents
A heat-storing body of metal and a heat storage means Download PDFInfo
- Publication number
- WO1991014906A1 WO1991014906A1 PCT/FI1991/000055 FI9100055W WO9114906A1 WO 1991014906 A1 WO1991014906 A1 WO 1991014906A1 FI 9100055 W FI9100055 W FI 9100055W WO 9114906 A1 WO9114906 A1 WO 9114906A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- heat
- steel
- storage means
- core
- heat storage
- Prior art date
Links
- 238000005338 heat storage Methods 0.000 title claims abstract description 28
- 239000002184 metal Substances 0.000 title claims description 7
- 229910052751 metal Inorganic materials 0.000 title claims description 7
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 51
- 239000010959 steel Substances 0.000 claims abstract description 51
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 16
- 239000000956 alloy Substances 0.000 claims abstract description 16
- 239000013529 heat transfer fluid Substances 0.000 claims abstract description 6
- 230000001590 oxidative effect Effects 0.000 claims abstract description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 8
- 239000011248 coating agent Substances 0.000 claims description 8
- 238000000576 coating method Methods 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 238000003466 welding Methods 0.000 claims description 5
- 238000005485 electric heating Methods 0.000 claims description 3
- 230000003647 oxidation Effects 0.000 abstract description 2
- 238000007254 oxidation reaction Methods 0.000 abstract description 2
- 239000000463 material Substances 0.000 description 14
- 229910000746 Structural steel Inorganic materials 0.000 description 6
- 229910001018 Cast iron Inorganic materials 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 229910000953 kanthal Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 235000000396 iron Nutrition 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 229910001256 stainless steel alloy Inorganic materials 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910000601 superalloy Inorganic materials 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D20/00—Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00
- F28D20/0056—Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00 using solid heat storage material
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24H—FLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
- F24H7/00—Storage heaters, i.e. heaters in which the energy is stored as heat in masses for subsequent release
- F24H7/002—Storage heaters, i.e. heaters in which the energy is stored as heat in masses for subsequent release using electrical energy supply
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/14—Thermal energy storage
Definitions
- the invention relates to a heat-storing body of metal.
- the invention is also concerned with a heat storage means comprising a heat storing body one sur ⁇ face of which forms a contact surface with a heat- transfer fluid.
- Heat-storing bodies are used widely in various applications to transfer heat supplied to the body and stored therein to a point where it is needed.
- the heat transfer or transmission fluid is often a liquid, typically water, but is it also possible to use a gas.
- the present invention can be applied when the heat transfer medium is either a liquid or a gas.
- Heat-storing bodies are, of course, made of materials of high heat-storing capacity. In many cases, it is also desirable that the heat-storing capacity of the material per unit volume is high. It is well-known to use soapstone as a heat-storing material as it has a high heat-storing capacity as compared with other stone materials. Ceramic and fire-resistant materials as well as mineral materials, such as ferrosilicate, are used widely in the cores of heat storage means.
- the metal heat-storing body of the invention is charac- terized in that it comprises a core of steel, an alloy of good heat resistance being sprayed on the surface of the steel core.
- the core is made of general structural steel.
- the composition of the alloy used as a coating preferably corresponds substantially to the composition of stainless extra- low carbon austenitic steel.
- the heat storage means of the invention is mainly characterized in that the heat-storing body comprises a core of steel, an alloy of good heat resistance being sprayed on that portion of the core surface which is exposed to oxidizing ambient con ⁇ ditions.
- Preferred embodiments of the heat storage means are disclosed in the attached claims 6 to 10.
- the present invention is based on the idea that the • core of the heat-storing body is made of in ⁇ expensive standard steel having excellent heat- storing properties.
- the steel is protected against oxidation and other chemical reactions by means of an alloy which is sprayed on the surface of the steel.
- a major advantage of the invention is that a compact heat-storing body with a high heat-storing capacity per unit volume can be manufactured at low costs.
- the core is made of general structural steel, it is ensured that the material is readily available in different shapes and dimensions to meet the requirements of each particular application.
- the steel core can be manufactured or assembled by welding, which is particularly advantageous in the production of extremely large cores.
- Figure 1 shows the principal features of a heat storage means
- Figure 2 is a back view of the heat storage means of Figure 1;
- Figure 3 is a sectional view along the line III-III of Figure 1; and Figure 4 shows a cartridge provided in the heat storage means of Figure 1 for heat resistors.
- FIG. 1 shows a heat storage means typically connected to a heat exchanger (not shown) for the recovery of heat.
- the heat storage means comprises a heat-storing body generally indicated with the refer ⁇ ence numeral 1.
- the heat-storing body 1 is formed by placing four substantially rectangular steel bodies 2 to 5 side by side.
- the steel bodies 2 to 5 are of general structural steel, such as Fe 52-c (St 52-3), as this type of steel is low in cost and readily available, in addition to which it is easy to weld.
- a contact surface between the adjacent steel bodies 2 and 3, and 4 and 5, comprises a space for an electric heating resistor 6, 7.
- the heat-storing body 1 is heated by the electric resistors, by means of which the temperature is raised to about 550 to 750 C C, a typical operating temperature being about 600°C.
- the temperature of the body 1 may be clearly above 750°C and below 550°C. Above the latter temperature, unalloyed or carbon steels show a high tendency to scale off.
- Each heating resistor 6 and 7 is fitted in a separate cartridge 8 and 9, respectively, which forms a holder for the resistor.
- the cartridges 8, 9, the structure of which will be described in connection with Figure 4, are in close thermal contact with the steel bodies 2 and 3, and 4 and 5, and the heating resistors 6, 7 are in close thermal contact with the cartridges 8, 9, respective ⁇ ly. In this way, it is ensured that the transfer of heat from the heating resistors 6, 7 to the steel bodies 2 to 5 is efficient.
- the heating resistors 6, 7 are indicated with broken lines within the heat storing body 1.
- a cover 10 is fitted tightly to that surface of the heat storing body 1 which is in con- tact with a heat transfer fluid, in this case water, so that a heat transfer space is formed between the cover and the contact surface.
- the cover 10 is provided with an inlet 11 for water and an outlet 12 for steam.
- As the surface of the heat storing body 1 and the cover 10 is surrounded with air and the sur ⁇ face is heated up to a temperature at which general structural steel is oxidized and scales off, an alloy of good heat resistance is sprayed on the surface of the heat-storing body.
- the cover 10 also has to be coated if it is made of steel scaling off at the operating temperature.
- the cover 10 of the total material consumption of the heat storage means could be made of a material of good heat resistance, in which case it need not be coated.
- a suitable starting material for the coating material is a filament material or a powder having a composition that cor ⁇ responds substantially to that of a 18-8-type stain ⁇ less extra-low carbon austenitic steel.
- a low carbon content has proved to be important for the adhesive properties of the coating.
- the carbon content of an effective mixture is about 0.03%. Not even a carbon content below this has proved disadvantageous.
- This kind of steel is readily available and its price is fairly reasonable as compared with many other types of stainless steel or superalloys.
- a Kanthal alloy coating is used in place of stainless steel. The walls surrounded by the heat transfer space are left uncoated as the heat transfer space is free from oxygen.
- FIG. 2 is a back view of the heat storage means, that is, from the side of the cover 10.
- Figure 3 is a sectional view along the line III-III of Figure 1.
- the reference numerals 13 to 15 indicate welds joining the steel bodies 2 to 5. It should be noted in this connection that the steel bodies 2 to 5 are welded together only on the side of the contact surface, that is, the heat-storing body 1 is not welded at the top, at the bottom or in the front, i.e. on the side of the heat ⁇ ing resistors 6, 7. This enables the seams between the steel bodies 2 to 5 to be opened slightly for inserting the cartridges 8, 9 for the heating resistors into close contact with the steel bodies.
- the reference numeral 17' indicates a locking member which is fixed by means of bolts to the steel bodies 2 to 5 to prevent them from being displaced apart from each other.
- FIG. 3 further shows baffle plates 17 to 20 for water positioned one below another in the heat transfer space so as to spread water and steam over the entire contact surface of the heat-storing body 1.
- the baffle plates 17 to 20 are therefore arranged to slant alternately in reverse directions.
- the baffle plates 17 to 20 are preferably attached to the steel bodies 2 to 5 by welding.
- Figure 4 shows the cartridge 8 to be inserted between the steel bodies 2 and 3.
- the cartridge 8 comprises two plate-like parts 21 and 22 so shaped that the heating resistor 6 can be removed from the heat-storing body 1 by withdrawing only the inner part 22.
- the outer part 21 remains in place in the body 1.
- the two-part cartridge 8 is to be preferred in view of maintenance.
- the invention has been described above only by means of its one preferred embodiment. It is to be understood that the details of the invention can be modified in various ways within the scope of the attached claims. Accordingly, it is possible that the heat-storing body is formed by an ingot- or brick- shaped body which is heated e.g. by heat generated in a heat-storing fireplace, the heat-storing body being built inside the fireplace.
- the heat- storing body is not at all heated by electricity, and the heat transfer fluid is not water but air or gas. In place of electricity, the heating can be realized with an oil or gas flame.
- the core need not be made of conventional general structural steel but it is possible to use various low alloy steels and heat refining steels, which are coated; they are, however, more expensive than conventional structural steel so their use is not particularly advisable - especially in view of the object of the invention, that is, the achievement of an inexpensive body having a good heat-storing capacity and resistance to high temperatures.
- the coating may be of some other material suited for high temperatures.
- One suitable alternative might be austenitic-ferritic steel. A criterion for selecting the material is that its heat resistance and adhesive properties are sufficiently good.
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Laminated Bodies (AREA)
- Coating By Spraying Or Casting (AREA)
- Central Heating Systems (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB9220354A GB2263165B (en) | 1990-03-26 | 1991-02-21 | A heat-storing body of metal and a heat storage means |
DE4190616A DE4190616C2 (de) | 1990-03-26 | 1991-02-21 | Wärmespeichernder Körper aus Metall und Wärmespeicher |
SE9202623A SE505707C2 (sv) | 1990-03-26 | 1992-09-11 | Värmelagrande kropp av metall och värmelagrande anordning |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FI901496A FI86474C (fi) | 1990-03-26 | 1990-03-26 | Metallisk, vaerme ackumulerande kropp samt vaermeackumulator. |
FI901496 | 1990-03-26 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1991014906A1 true WO1991014906A1 (en) | 1991-10-03 |
Family
ID=8530125
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/FI1991/000055 WO1991014906A1 (en) | 1990-03-26 | 1991-02-21 | A heat-storing body of metal and a heat storage means |
Country Status (6)
Country | Link |
---|---|
AU (1) | AU7303691A (enrdf_load_stackoverflow) |
DE (2) | DE4190616C2 (enrdf_load_stackoverflow) |
FI (1) | FI86474C (enrdf_load_stackoverflow) |
GB (1) | GB2263165B (enrdf_load_stackoverflow) |
SE (1) | SE505707C2 (enrdf_load_stackoverflow) |
WO (1) | WO1991014906A1 (enrdf_load_stackoverflow) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1730460A4 (en) * | 2004-03-12 | 2013-03-20 | Larkden Pty Ltd | METHOD AND DEVICE FOR STORING HEAT ENERGY |
WO2020254001A1 (en) | 2019-06-17 | 2020-12-24 | E2S Power AG | Energy storage device and method for storing energy |
CN114041036A (zh) * | 2019-06-17 | 2022-02-11 | E2S电力公司 | 能量存储装置及存储能量的方法 |
WO2022272098A1 (en) * | 2021-06-25 | 2022-12-29 | Antora Energy, Inc. | Sub-systems and methods within a thermal storage solution |
EP4257908A1 (en) | 2022-04-05 | 2023-10-11 | E2S Power Ag | Energy storage device and method for storing energy using serially connected thermal energy storage units |
US11876254B2 (en) | 2019-11-13 | 2024-01-16 | Antora Energy, Inc. | System and method for a solid-state thermal battery |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102020107014A1 (de) | 2020-03-13 | 2021-09-16 | Deutsches Zentrum für Luft- und Raumfahrt e.V. | Energiespeichersystem und Verfahren zum Betreiben eines Energiespeichersystems |
DE102023129979A1 (de) * | 2023-10-30 | 2025-04-30 | Eugen Arnold GmbH. | Thermovorrichtung und Verfahren zum Betrieb einer Thermovorrichtung |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1990004140A1 (en) * | 1988-10-05 | 1990-04-19 | Imatran Voima Oy | A heat-storing heating device |
-
1990
- 1990-03-26 FI FI901496A patent/FI86474C/fi not_active IP Right Cessation
-
1991
- 1991-02-21 DE DE4190616A patent/DE4190616C2/de not_active Expired - Fee Related
- 1991-02-21 GB GB9220354A patent/GB2263165B/en not_active Expired - Fee Related
- 1991-02-21 AU AU73036/91A patent/AU7303691A/en not_active Abandoned
- 1991-02-21 WO PCT/FI1991/000055 patent/WO1991014906A1/en active Application Filing
- 1991-02-21 DE DE19914190616 patent/DE4190616T/de active Pending
-
1992
- 1992-09-11 SE SE9202623A patent/SE505707C2/sv not_active IP Right Cessation
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1990004140A1 (en) * | 1988-10-05 | 1990-04-19 | Imatran Voima Oy | A heat-storing heating device |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1730460A4 (en) * | 2004-03-12 | 2013-03-20 | Larkden Pty Ltd | METHOD AND DEVICE FOR STORING HEAT ENERGY |
WO2020254001A1 (en) | 2019-06-17 | 2020-12-24 | E2S Power AG | Energy storage device and method for storing energy |
CN114041036A (zh) * | 2019-06-17 | 2022-02-11 | E2S电力公司 | 能量存储装置及存储能量的方法 |
US11920484B2 (en) | 2019-06-17 | 2024-03-05 | E2S Power AG | Energy storage device and method for storing energy |
US11876254B2 (en) | 2019-11-13 | 2024-01-16 | Antora Energy, Inc. | System and method for a solid-state thermal battery |
WO2022272098A1 (en) * | 2021-06-25 | 2022-12-29 | Antora Energy, Inc. | Sub-systems and methods within a thermal storage solution |
US11994347B2 (en) | 2021-06-25 | 2024-05-28 | Antora Energy, Inc. | Systems for managing thermal energy within a thermal storage solution |
EP4360150A4 (en) * | 2021-06-25 | 2025-05-07 | Antora Energy, Inc. | SUBSYSTEMS AND PROCESSES IN A HEAT STORAGE SOLUTION |
EP4257908A1 (en) | 2022-04-05 | 2023-10-11 | E2S Power Ag | Energy storage device and method for storing energy using serially connected thermal energy storage units |
WO2023194305A1 (en) | 2022-04-05 | 2023-10-12 | E2S Power AG | Energy storage device and method for storing energy using serially connected thermal energy storage units |
Also Published As
Publication number | Publication date |
---|---|
FI901496L (fi) | 1991-09-27 |
SE505707C2 (sv) | 1997-09-29 |
AU7303691A (en) | 1991-10-21 |
SE9202623L (sv) | 1992-09-11 |
GB2263165A (en) | 1993-07-14 |
FI86474C (fi) | 1992-08-25 |
GB9220354D0 (en) | 1992-11-18 |
GB2263165B (en) | 1994-11-30 |
DE4190616C2 (de) | 1994-06-30 |
FI901496A0 (fi) | 1990-03-26 |
SE9202623D0 (sv) | 1992-09-11 |
DE4190616T (enrdf_load_stackoverflow) | 1993-01-28 |
FI86474B (fi) | 1992-05-15 |
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