WO1985000379A1 - Compositions de viscosite variable a base d'acide telles que des produits eliminant la corrosion et la graisse et des produits de polissage - Google Patents

Compositions de viscosite variable a base d'acide telles que des produits eliminant la corrosion et la graisse et des produits de polissage Download PDF

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Publication number
WO1985000379A1
WO1985000379A1 PCT/US1983/001014 US8301014W WO8500379A1 WO 1985000379 A1 WO1985000379 A1 WO 1985000379A1 US 8301014 W US8301014 W US 8301014W WO 8500379 A1 WO8500379 A1 WO 8500379A1
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WO
WIPO (PCT)
Prior art keywords
composition
set forth
weight
level
acid
Prior art date
Application number
PCT/US1983/001014
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English (en)
Inventor
Richard K. Vitek
Original Assignee
Fotodyne, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fotodyne, Inc. filed Critical Fotodyne, Inc.
Priority to EP19830902583 priority Critical patent/EP0151114B1/fr
Priority to DE8383902583T priority patent/DE3381414D1/de
Priority to JP50270583A priority patent/JPS60501817A/ja
Priority to PCT/US1983/001014 priority patent/WO1985000379A1/fr
Publication of WO1985000379A1 publication Critical patent/WO1985000379A1/fr

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Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02Cleaning or pickling metallic material with solutions or molten salts with acid solutions
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G5/00Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
    • C23G5/06Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using emulsions

Definitions

  • the present invention is concerned with improved, acid-based corrosion, grease removal and polishing compositions for treating metallic surfaces and objects. More particularly, it is concerned with such compositions which are compounded so as to substantially prevent oxidation-reduction reactions that would normally take place at a metallic surface, and allow only acid attack of the oxides on the metal.
  • the compositions hereof may include polyvinyl pyrrolidone as a viscosity control agent and inhibitor, a derivative of hydrogen tated tallow as an emulsifier, and an N-substituted oxazolidine as an acid inhibitor.
  • compositions for removing corrosion from metallic surfaces and objects have long been available.
  • corrosion metal oxides
  • Such materials are acid based, i.e., they rely upon an acidic attack in order to remove corrosion.
  • compositions of the present invention overcomes the problems noted above, and provides greatly improved, flowable, aqueous, highly penetrating compositions of acidic pH which are effective for polishing and removal of corrosion from metallic surfaces, and also to degrease the same.
  • the compositions of the present invention may include respective quantities of an acid, an organic compound having a nitrogen, oxygen or sulfur atom therein, an alcohol or other organic solvent, water and at least one emulsifier.
  • the acid component is selected from the group consisting of hydrochloric, sulfuric, phosphoric, acetic, citric, nitric, boric and mixtures thereof.
  • the acid is further preferably present at a level of from about 2% to 95% by weight, and more preferably from about 5% to 37% by weight.
  • the organic compound is advantageously selected from the group consisting of N-substituted oxazolidines (most preferably N-(2-hydroxyethyl) oxazolidine), the p-alkyl benzyl pyridine chlorides, phenylthiourea, 2-mercaptobenzothiazole, di-orthotolyl-thiourea, pyridine, quinoline, decylamine, the dibenzyl sulf oxides, 2-butyne-1, 4-diol, 1-hexyne 3-ol, 4-ethyl-1-octyne-3-ol, decyclamine, soyaamine, octadecylamine, trimethylsoyaammonium chloride, trimethyloctadecylammonium chloride, trimethyldodecyl ammonium chloride, trimethyltallowammonium chloride, N-coco-1, 3-diaminopropane, the
  • Such compounds should be used at a level of from about 0.01% to 20% by weight, and more preferably from about .5% to 5% by weight.
  • the alcohol component is most preferably 1-pro ⁇ anol, but other alcohols could also be employed.
  • other alcohols refers to an alcohol having an alkyl group with from about 1 to 10 carbon atoms, inclusive.
  • the alcohol should be used at a level of up to 40% by weight, and most preferably at a level of about 1 to 8% by weight.
  • the water should be present at a level of from about 30% to 80% by weight, and most advantageously at a level of from about 50% to 80% by weight.
  • the most preferred emulsifiers for use in the invention are selected from the group consisting of the derivatives of hydrogenated tallow (e.g., N, N', N'-tris (2-hydroxy- ethyl)-N-tallow-1, 3-diaminopropane or amine acetate hydrogenated tallow), polyoxyethylene ethers, polyoxyethylene ester alcohols, polyoxyethylene esters of mixed fatty and resin acids and mixtures thereof, although other specific types referred to hereinafter also have utility.
  • the total amount of emulsifier present in the composition should be from about 0.1% to 15% by weight, and more preferably from about .5% to 5% by weight.
  • a viscosity control agent can also be used in the compositions hereof to give variations in viscosity.
  • Such viscosity control has heretofore proved to be difficult or impossible to obtain in acidic compositions, inasmuch as most conventional thickeners tend to flocculate at low pH.
  • the control agents of the invention should be selected from the group consisting of polyvinylpyrrolidone and the allylamine emulsion polymers.
  • the pyrrolidone is preferred, however, inasmuch as it also acts as a corrosion inhibitor on metallic surfaces.
  • the viscosity control agent should be used at a level of up to about 35% by weight, and most preferably at a level of from about 0.5% to 5% by weight.
  • a synergistic effect is observed by the use of the mixture of polyvinyl pyrrolidone, Ethoduomeen T/13, and N-(2-hydroxyethyl)-oxazolidine as a corrosion inhibitor in preventing base metal attack, inasmuch as the attack with the preferred mixture is less than that of any of the individual corrosion inhibitors.
  • a mild abrasive such as activated silica gel (at a level of up to about 10% by weight) can be employed.
  • Perfumes and coloring agents can be added as desired.
  • the system can be modified for corrosion removal on metal surfaces having a heavy grease or oil coating by preparing a two-phase emulsified system fay the addition of toluene or related organic solvents.
  • the single feature is a graphical representation depicting the extent of base metal attack when using a commercially available corrosion remover, 10% HCl, and the preferred corrosion removing composition of the invention.
  • the most preferred rust removal compositions in accordance with the present, invention contain commercial hydrochloric acid, commercial phosphoric acid, 1-propanol, N-(2 hydroxyethyl) oxazolidine, water, a thickening agent, and N,N', N'-tris (2-hydroxyethyl)-N-tallow-1, 3-diaminopropane as an emulsifier.
  • the following table sets forth the single most preferred rust removal composition, as well as ranges of use of the above identified components.
  • the oxazolidine base metal inhibitor component of Table I is prepared by slowly adding, with mixing, 435.7 grams of formaldehyde to a beaker containing 564.3 grams of diethanolamine. After all formaldehyde is added, the mixture should be stirred for an additional hour.
  • a base metal inhibitor component can be produced as the reaction product of a lower aldehyde (i.e., containing from about 1-4 carbon atoms) and an alkanolamine (containing one or more alkyl group each having from about 2-8 carbon atoms).
  • a lower aldehyde i.e., containing from about 1-4 carbon atoms
  • an alkanolamine containing one or more alkyl group each having from about 2-8 carbon atoms
  • a beaker containing 590 grams of water is provided.
  • Ten grams of the Ethoduomeen T/13 hydrogenated tallow emulsifier, 270 grams hydrochloric acid, 40 grams phosphoric acid, and 50 grams of 1-propanol are all added to the beaker, with continual mixing.
  • the mixture is then heated to 50° C.; and 30 grams polyvinylpyrrolidine is slowly added thereto. Mixing is continued until all of the polymer has dissolved.
  • the drawing graphically illustrates the inhibition against base metal attack provided with the preferred composition of Table I.
  • a commercially available corrosion remover sold under the designation "Naval Jelly” was tested, along with a solution of 10% hydrochloric acid, and the preferred composition hereof.
  • testing conditions were identical, and the extent of attack on a base metal substrate was measured.
  • the extent of such attack is very high with the Naval Jelly and hydrochloric acid, but is significantly lower with the preferred inhibitor composition of the invention.
  • emulsifier As noted above, a number of different materials can be employed for the various components. With respect to the emulsifier (s), surfactants available from ICI Americas, Inc., Wilmington, Delaware, and Armak Chemicals Division, Chicago, Illinois, can be employed in lieu of or in addition to the preferred tallow based emulsifiers. An exemplary list of such surfactants is provided in Table III.
  • compositions of the invention are effective to remove corrosion from base metallic surfaces while substantially preventing oxidation-reduction reactions with the metal itself.
  • grease removal is enhanced by virtue of the presence of a single phase, aqueous system.
  • Use of the preferred single phase system also enhances the penetration of corrosion where the latter is present.
  • Representative metals which can be cleaned and/ or degreased using the compositions hereof include iron and steel, bronze, brass, copper, monel, nickel, chromium plated metals and aluminum.
  • a cleaner for tubes of boilers may also be provided by incorporting in the formulation a high foaming agent plus thickeners such as polyvinylpyrrolidone to improve wall adherence.
  • An additive such as Arlatone G may also be included as desired to help prevent surface rerusting.
  • This type of corrosion remover is advantageous in that a small amount will cover a large surface area and does not require heating to permit the corrosion removal action to take place. Also, since all components are water soluble, removal of the corrosion remover can be performed by flushing water through the system.
  • An exemplary formulation of a- composition containing at least one foaming agent and a thickener is as follows:
  • the preferred boiler tube cleaner is prepar ed in the same manner as the rust remover and cleaner/ polisher descr ibed above .
  • the Arlatone G component is added initially with the HCl , oxazolidine and Ethoduomeen .
  • An additional use and formulation for the removal of carbonate deposits and scales for the application of salts to non-metallic surfaces can be made by using the above formulations with the deletion of the base metal corrosion inhibitor .
  • This formulation enhances surface deposit removal without penetration to the base .
  • An exemplary formulation of a composi tion containing at least one degreasing agent and a thickener is as follows: Other acids such as sulfuric, nitric, phosphoric, acetic, citric, boric, or mixtures thereof can be substituted as well as other salts such as sodium perborate, tri-sodium phosphate, ammonium acetate, sodium chloride, etc.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)

Abstract

Une composition améliorée, à pénétration élevée, éliminant la rouille et/ou la graisse des surfaces métalliques est inhibée chimiquement pour empêcher sensiblement les réactions d'oxydation-réduction avec un substrat métallique et limiter l'action de la composition à une attaque chimique sur la corrosion. La composition se compose de préférence d'une dispersion à phase unique et comprend des quantités respectives d'un acide tel qu'un acide chlorhydrique et un acide phosphorique, un composé organique contenant un atome d'azote, d'oxygène ou de soufre tel que du N-(2-hydroxyéthyle) oxazolidine, un alcool ou un autre solvant organique éliminant la graisse, de l'eau et un ou plusieurs émulsifiants (par exemple un dérivé de suif hydrogéné) pour stabiliser et abaisser la tension de surface de la composition résultante. Ces compositions peuvent être obtenues sous la forme de liquides ou avec un agent régulateur de la viscosité tel qu'un polymère de vynile pyrrolidone, conférant à la composition une consistance pâteuse qui en permet une utilisation aisée sur des surfaces verticales. Dans des variantes, ces compositions peuvent comprendre un abrasif doux tel qu'un gel de silice activé.
PCT/US1983/001014 1983-07-06 1983-07-06 Compositions de viscosite variable a base d'acide telles que des produits eliminant la corrosion et la graisse et des produits de polissage WO1985000379A1 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP19830902583 EP0151114B1 (fr) 1983-07-06 1983-07-06 Compositions de viscosite variable a base d'acide telles que des produits eliminant la corrosion et la graisse et des produits de polissage
DE8383902583T DE3381414D1 (de) 1983-07-06 1983-07-06 Auf saeure basierte zusammensetzungen mit variabler viskositaet wie korrosion- und fettentferner und glaenzer.
JP50270583A JPS60501817A (ja) 1983-07-06 1983-07-06 腐食及びグリ−スリム−バ−及び研磨剤のような粘度可変性の酸ベ−ス組成物
PCT/US1983/001014 WO1985000379A1 (fr) 1983-07-06 1983-07-06 Compositions de viscosite variable a base d'acide telles que des produits eliminant la corrosion et la graisse et des produits de polissage

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US1983/001014 WO1985000379A1 (fr) 1983-07-06 1983-07-06 Compositions de viscosite variable a base d'acide telles que des produits eliminant la corrosion et la graisse et des produits de polissage

Publications (1)

Publication Number Publication Date
WO1985000379A1 true WO1985000379A1 (fr) 1985-01-31

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Application Number Title Priority Date Filing Date
PCT/US1983/001014 WO1985000379A1 (fr) 1983-07-06 1983-07-06 Compositions de viscosite variable a base d'acide telles que des produits eliminant la corrosion et la graisse et des produits de polissage

Country Status (4)

Country Link
EP (1) EP0151114B1 (fr)
JP (1) JPS60501817A (fr)
DE (1) DE3381414D1 (fr)
WO (1) WO1985000379A1 (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5460797A (en) * 1991-05-08 1995-10-24 Streck Laboratories, Inc. Method for fixing tissues and cells for analysis using oxazolidine compounds
EP1764426A1 (fr) * 2005-09-15 2007-03-21 Delmet - Dissosidazione Elettronica Metalli S.r.l. Procédé, installation et solution acide colloidale pour le décapage des articles en métal, en particulier barils pour des produits alimentaires
EP1699278A3 (fr) * 1998-09-28 2007-04-18 Ibiden Co., Ltd. Plaquette à circuits multicouches et procédé de fabrication
RU2532919C1 (ru) * 2013-09-12 2014-11-20 Общество с ограниченной ответственностью "СИКМО" (ООО "СИКМО") Беспенное средство для мойки металлических поверхностей
RU2532921C1 (ru) * 2013-09-12 2014-11-20 Общество с ограниченной ответственностью "СИКМО" (ООО "СИКМО") Антикоррозионное средство для мойки внутренних и наружных металлических поверхностей

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2524825A (en) * 1945-09-14 1950-10-10 Socony Vacuum Oil Co Inc Metal cleaning composition
US2814593A (en) * 1953-12-18 1957-11-26 Gen Aniline & Film Corp Corrosion inhibition
US3113113A (en) * 1958-11-07 1963-12-03 Armour & Co Corrosion inhibitor compositions
FR2209858A3 (en) * 1972-12-07 1974-07-05 Colloides Ind Fs Liq. decarbonising and scouring compsns. - contg. polyvinyl pyrrolidone or its derivs, to prevent galvanic corrosion
JPS5415485A (en) * 1977-07-06 1979-02-05 Masami Kobayashi Creamy derust detergent
US4216032A (en) * 1978-09-27 1980-08-05 Stephen Gradowski Oil composition and method for treating phosphated metal surfaces
US4247344A (en) * 1975-10-15 1981-01-27 Nippon Steel Corporation Rust preventing treatment of metal-plated steel materials
US4325744A (en) * 1980-07-25 1982-04-20 The United States Of America As Represented By The Secretary Of The Navy Method and composition for cleaning metal surfaces with a film-forming composition

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2737491A (en) * 1952-06-13 1956-03-06 Cities Service Res & Dev Co Method of inhibiting corrosion of metals
US3575881A (en) * 1967-12-26 1971-04-20 Dow Chemical Co Method of gelling ionic liquids and gelled composition

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2524825A (en) * 1945-09-14 1950-10-10 Socony Vacuum Oil Co Inc Metal cleaning composition
US2814593A (en) * 1953-12-18 1957-11-26 Gen Aniline & Film Corp Corrosion inhibition
US3113113A (en) * 1958-11-07 1963-12-03 Armour & Co Corrosion inhibitor compositions
FR2209858A3 (en) * 1972-12-07 1974-07-05 Colloides Ind Fs Liq. decarbonising and scouring compsns. - contg. polyvinyl pyrrolidone or its derivs, to prevent galvanic corrosion
US4247344A (en) * 1975-10-15 1981-01-27 Nippon Steel Corporation Rust preventing treatment of metal-plated steel materials
JPS5415485A (en) * 1977-07-06 1979-02-05 Masami Kobayashi Creamy derust detergent
US4216032A (en) * 1978-09-27 1980-08-05 Stephen Gradowski Oil composition and method for treating phosphated metal surfaces
US4325744A (en) * 1980-07-25 1982-04-20 The United States Of America As Represented By The Secretary Of The Navy Method and composition for cleaning metal surfaces with a film-forming composition

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP0151114A4 *

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5460797A (en) * 1991-05-08 1995-10-24 Streck Laboratories, Inc. Method for fixing tissues and cells for analysis using oxazolidine compounds
EP1699278A3 (fr) * 1998-09-28 2007-04-18 Ibiden Co., Ltd. Plaquette à circuits multicouches et procédé de fabrication
US7504719B2 (en) 1998-09-28 2009-03-17 Ibiden Co., Ltd. Printed wiring board having a roughened surface formed on a metal layer, and method for producing the same
US7535095B1 (en) 1998-09-28 2009-05-19 Ibiden Co., Ltd. Printed wiring board and method for producing the same
EP1764426A1 (fr) * 2005-09-15 2007-03-21 Delmet - Dissosidazione Elettronica Metalli S.r.l. Procédé, installation et solution acide colloidale pour le décapage des articles en métal, en particulier barils pour des produits alimentaires
RU2532919C1 (ru) * 2013-09-12 2014-11-20 Общество с ограниченной ответственностью "СИКМО" (ООО "СИКМО") Беспенное средство для мойки металлических поверхностей
RU2532921C1 (ru) * 2013-09-12 2014-11-20 Общество с ограниченной ответственностью "СИКМО" (ООО "СИКМО") Антикоррозионное средство для мойки внутренних и наружных металлических поверхностей

Also Published As

Publication number Publication date
EP0151114A1 (fr) 1985-08-14
EP0151114B1 (fr) 1990-04-04
JPS60501817A (ja) 1985-10-24
DE3381414D1 (de) 1990-05-10
EP0151114A4 (fr) 1985-12-05

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