USRE49954E1 - Fabrication of nano-sheet transistors with different threshold voltages - Google Patents
Fabrication of nano-sheet transistors with different threshold voltages Download PDFInfo
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- USRE49954E1 USRE49954E1 US17/338,459 US202117338459A USRE49954E US RE49954 E1 USRE49954 E1 US RE49954E1 US 202117338459 A US202117338459 A US 202117338459A US RE49954 E USRE49954 E US RE49954E
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- H01L29/02—Semiconductor bodies ; Multistep manufacturing processes therefor
- H01L29/06—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions
- H01L29/0657—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions characterised by the shape of the body
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- H01L27/04—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being a semiconductor body
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- H01L27/085—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being a semiconductor body including only semiconductor components of a single kind including field-effect components only
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Definitions
- the present invention generally relates to the fabrication of two or more nano-sheet transistors on the same substrate having different threshold voltages, and more particularly to forming different sized recesses to provide nano-sheet channels having different gate lengths.
- a Field Effect Transistor typically has a source, a channel, and a drain, where current flows from the source to the drain, and a gate that controls the flow of current through the channel.
- Field Effect Transistors can have a variety of different structures, for example, FETs have been fabricated with the source, channel, and drain formed in the substrate material itself, where the current flows horizontally (i.e., in the plane of the substrate), and finFETs have been formed with the channel extending outward from the substrate, but where the current also flows horizontally from a source to a drain.
- the channel for the finFET can be an upright slab of thin rectangular Si, commonly referred to as the fin with a gate on the fin, as compared to a MOSFET with a single gate in the plane of the substrate.
- an n-FET or a p-FET can be formed.
- FETs can include a metal-oxide-semiconductor field effect transistor (MOSFET) and an insulated-gate field-effect transistor (IGFET). Two FETs also can be coupled to form a complementary metal oxide semiconductor (CMOS), where a p-channel MOSFET and n-channel MOSFET are coupled together.
- MOSFET metal-oxide-semiconductor field effect transistor
- IGFET insulated-gate field-effect transistor
- a method of forming two or more nano-sheet devices with varying electrical gate lengths includes forming at least two cut-stacks including a plurality of sacrificial release layers and at least one alternating nano-sheet channel layer on a substrate.
- the method further includes removing a portion of the plurality of sacrificial release layers to form indentations having an indentation depth in the plurality of sacrificial release layers.
- the method further includes removing a portion of the at least one alternating nano-sheet channel layer to form a recess having a recess depth in the at least one alternating nano-sheet channel layers, where the recess depth is greater than the indentation depth.
- a method of forming two or more nano-sheet devices with varying electrical gate lengths includes forming a channel stack including a plurality of sacrificial release layers and at least one alternating nano-sheet channel layer on a substrate.
- the method further includes forming two or more dummy gates including a dummy gate fill and a side spacer on the channel stack.
- the method further includes removing exposed portions of the channel stack not covered by the two or more dummy gates to form two or more cut-stacks.
- the method further includes removing a portion of the plurality of sacrificial release layers to form indentations having an indentation depth in the plurality of sacrificial release layers.
- the method further includes forming an indentation fill layer in the indentations.
- the method further includes forming a mask on at least one of the two or more cut-stacks.
- the method further includes removing a portion of the at least one alternating nano-sheet channel layer to form a recess in the unmasked cut-stacks.
- a pair of adjacent nano-sheet devices on the same substrate includes a first nano-sheet device including, two source/drain regions on a substrate, where the two source/drain regions are separated by a distance, at least one nano-sheet channel layer having a length spanning the distance between the two source/drain regions, and a gate structure on the at least one nano-sheet channel layer having a physical gate length.
- the pair of adjacent nano-sheet devices includes a second nano-sheet device including, two source/drain regions on a substrate, where the two source/drain regions are separated by a distance, at least one nano-sheet channel layer having a length spanning the distance between the two source/drain regions, and a gate structure on the at least one nano-sheet channel layer having a physical gate length.
- the physical gate length of the first nano-sheet device is the same as the physical gate length of the second nano-sheet device, and the length of the at least one nano-sheet channel layer of the first nano-sheet device is different than the length of the at least one nano-sheet channel layer of the second nano-sheet device.
- FIG. 1 is a cross-sectional isometric view showing a plurality of nano-sheet layers separated by sacrificial release layers on an insulating layer of a substrate, in accordance with an embodiment of the present invention
- FIG. 2 is a cross-sectional isometric view showing a plurality of patterned nano-sheet channel layers and sacrificial release layers on an insulating layer of a substrate, in accordance with an embodiment of the present invention
- FIG. 3 is a cross-sectional side view showing a patterned channel stack including nano-sheet channel layers and sacrificial release layers on an insulating layer of a substrate, in accordance with an embodiment of the present invention
- FIG. 4 is a cross-sectional side view showing two dummy gates with side spacers on a patterned channel stack of nano-sheet channel layers and sacrificial release layers, in accordance with an embodiment of the present invention
- FIG. 5 is a cross-sectional side view showing a dummy gate on each of two cut-stacks of nano-sheet channel layers and sacrifical release layers, in accordance with an embodiment of the present invention
- FIG. 6 is a cross-sectional side view showing indentations formed by removal of a portion of each sacrificial release layer in a cut-stack, in accordance with an embodiment of the present invention
- FIG. 7 is a cross-sectional side view showing enlarged indentations formed by removal of an additional portion of each sacrificial release layer of an unmasked cut-stack, in accordance with an embodiment of the present invention
- FIG. 8 is a cross-sectional side view showing indentation fill layers formed in the different sized indentations of each cut-stack, in accordance with an embodiment of the present invention.
- FIG. 9 is a cross-sectional side view showing a masked cut stack and an unmasked cut-stack, in accordance with an embodiment of the present invention.
- FIG. 10 is a cross-sectional side view showing recesses formed by removal of a portion of each nano-sheet channel layer of an unmasked cut-stack, in accordance with an embodiment of the present invention
- FIG. 11 is a cross-sectional side view of an unmasked cut-stack with recessed nano-sheet channel layers and an unmasked cut-stack without recessed nano-sheet channel layers, in accordance with an embodiment of the present invention
- FIG. 12 is a cross-sectional side view of two cut-stacks having different sized recesses formed in the nano-sheet channel layers, in accordance with an embodiment of the present invention.
- FIG. 13 is a cross-sectional side view of source/drain regions formed on the nano-sheet channel layers on either side of each of the two cut-stacks, in accordance with an embodiment of the present invention
- FIG. 14 is a cross-sectional side view of an interlayer dielectric (ILD) formed on the two cut-stacks and dummy gates, in accordance with an embodiment of the present invention
- FIG. 15 is a cross-sectional side view of an interlayer dielectric on the two cut-stacks after removal of the dummy gate fill, in accordance with an embodiment of the present invention.
- FIG. 16 is a cut-away isometric view of the long axis of the patterned nano-sheet device after removing the dummy gate fill from within the side spacer, in accordance with an embodiment of the present invention
- FIG. 17 is a cross-sectional side view of a plurality of freed nano-sheet channel layers after removal of the intervening sacrificial release layers in the two cut-stacks, in accordance with an embodiment of the present invention
- FIG. 18 is a cross-sectional side view of a gate dielectric layer on the exposed surfaces of the nano-sheets and side spacers, in accordance with an embodiment of the present invention.
- FIG. 19 is a cross-sectional side view of a gate structure on the nano-sheets of each of the cut-stacks, in accordance with an embodiment of the present invention.
- Principles and embodiments of the present invention relate to fabricating a plurality of transistor devices utilizing nano-sheets for the channel of the devices, where the nano-sheets have different lengths.
- the electrical gate length, L Ge , of the different devices can be varied by using a sequence of etching steps to modify the nano-sheet lengths.
- the different gate lengths can provide different threshold voltages, V T .
- Principles and embodiments of the present invention also relate to forming nano-sheet transistor devices having different threshold voltages adjacent to each other on the same substrate by controlling the number of etching steps each transistor device undergoes during fabrication. Multiple timed etches can be used to remove predetermined amounts of each exposed nano-sheet channel layer to produce a cut-stack with a predetermined electrical gate length and threshold voltage, while neighboring nano-sheet transistor devices are masked during the etching steps.
- Principles and embodiments of the present invention also relate to forming a plurality of nano-sheet devices having nano-sheets initially with the same dimensions, and selectively removing predetermined portions of the nano-sheets to produce nano-sheet devices having different nano-sheet channel layers with different final dimensions.
- Principles and embodiments of the present invention relate to controlling threshold voltages of nano-sheet devices without using channel doping.
- Exemplary applications/uses to which the present invention can be applied include, but are not limited to: transistors for complementary metal-oxide-semiconductor (CMOS) devices, logic devices (e.g., NAND gates, NOR gates, XOR gates, etc.), memory devices (e.g., DRAM, SRAM, flip-flops, etc.), etc.
- CMOS complementary metal-oxide-semiconductor
- logic devices e.g., NAND gates, NOR gates, XOR gates, etc.
- memory devices e.g., DRAM, SRAM, flip-flops, etc.
- the materials and layers can be deposited by physical vapor deposition (PVD), chemical vapor deposition (CVD), atomic layer deposition (ALD), molecular beam epitaxy (MBE), or any of the various modifications thereof, for example, plasma-enhanced chemical vapor deposition (PECVD), metal-organic chemical vapor deposition (MOCVD), low pressure chemical vapor deposition (LPCVD), electron-beam physical vapor deposition (EB-PVD), and plasma-enhanced atomic layer deposition (PEALD).
- PECVD plasma-enhanced chemical vapor deposition
- MOCVD metal-organic chemical vapor deposition
- LPCVD low pressure chemical vapor deposition
- EB-PVD electron-beam physical vapor deposition
- PEALD plasma-enhanced atomic layer deposition
- the depositions can be epitaxial processes, and the deposited material can be crystalline.
- formation of a layer may be by one or more deposition processes, where, for example, a conformal layer can be formed by a first process (e.g., ALD, PEALD, etc.) and a fill can be formed by a second process (e.g., CVD, electrodeposition, PVD, etc.).
- a first process e.g., ALD, PEALD, etc.
- a second process e.g., CVD, electrodeposition, PVD, etc.
- Source/drain projections, layers, regions, etc. is intended to indicate that the particular device feature can be implemented as a source or a drain except as expressly indicated otherwise.
- the role of source and drain for an active device can in some instances be reversed, so a previously indicated drain may instead be a source and vice versa.
- Reference to a source/drain is, therefore, intended to encompass the broadest reasonable scope of the term.
- FIG. 1 a cross-sectional isometric view of a plurality of nano-sheet layers separated by sacrificial release layers on an insulating layer of a substrate is shown, in accordance with an embodiment of the present invention.
- a substrate 110 can be a semiconductor or an insulator with an active surface semiconductor layer (ASL).
- the substrate can be crystalline, semi-crystalline, microcrystalline, or amorphous.
- the substrate can be essentially (i.e., except for contaminants) a single element (e.g., silicon), primarily (i.e., with doping) of a single element, for example, silicon (Si) or germanium (Ge), or the substrate can include a compound, for example, Al 2 O 3 , SiO 2 , GaAs, SiC, or SiGe.
- the substrate can have multiple material layers, for example, a semiconductor-on-insulator substrate (SeOI), a silicon-on-insulator substrate (SOI), germanium-on-insulator substrate (GeOI), or silicon-germanium-on-insulator substrate (SGOI), where an active surface semiconductor layer of the substrate 110 can be on a substrate insulator layer 120 (e.g., buried oxide layer (BOX)).
- the substrate 110 can also have other layers forming the substrate, including high-k oxides and/or nitrides.
- a substrate insulator layer 120 (e.g., BOX layer) can be formed on at least a portion of a substrate 110 .
- An active surface semiconductor layer can be on the BOX layer.
- the active surface semiconductor layer can be on the buried oxide (BOX) layer, which physically separates and electrically insulates the active surface layer from a mechanically supporting portion of the substrate 110 .
- BOX buried oxide
- the substrate may be a single crystal silicon (Si), silicon germanium (SiGe), or III-V semiconductor (e.g., GaAs) wafer, or have a single crystal silicon (Si), silicon germanium (SiGe), or III-V semiconductor (e.g., GaAs) active surface layer.
- the substrate 110 can be a silicon wafer.
- a plurality of sacrificial release layers 130 can be formed with one or more alternating nano-sheet channel layers 140 on a substrate 110 , where the substrate 110 can be a semiconductor-on-insulator (SeOI) substrate with either a sacrificial release layer 130 or a nano-sheet channel layer 140 forming the active surface semiconductor layer directly on the substrate insulator layer 120 .
- the plurality of sacrificial release layers 130 and at least one alternating nano-sheet channel layer(s) 140 can form a stack on the substrate 110 .
- N sacrificial release layers 130 and N ⁇ 1 nano-sheet channel layers 140 there can be N sacrificial release layers 130 and N ⁇ 1 nano-sheet channel layers 140 , where a sacrificial release layer can be between the substrate 110 and a nano-sheet channel layer 140 , and a sacrificial release layer can be the upper-most layer in the stack.
- a sacrificial release layer can be between the substrate 110 and a nano-sheet channel layer 140
- a sacrificial release layer can be the upper-most layer in the stack.
- the top-most sacrificial release layer 130 may be optional, such that there are N sacrificial release layers 130 and N nano-sheet channel layers 140 , where a sacrificial release layer 130 can be between the substrate insulator layer 120 and a nano-sheet channel layer 140 . Removal of a dummy gate fill could thereby expose the top-most nano-sheet channel layer 140 .
- the substrate 110 can be a silicon-germanium-on-insulator substrate having a silicon-germanium active surface layer as the bottom-most sacrificial release layer 130 on the substrate insulator layer 120 .
- a single crystal, active surface layer e.g., silicon, silicon-germanium, etc.
- the sacrificial release layers 130 can have a top surface, a bottom surface, and a thickness there between, where the sacrificial release layers 130 can be formed on the surface of the substrate 110 or substrate insulator layer 120 .
- the sacrificial release layer 130 or nano-sheet channel layer 140 can be epitaxially grown on a crystalline surface of the substrate 110 .
- the sacrificial release layers 130 can be heteroepitaxially deposited on an exposed crystalline surface, for example, on a crystalline nano-sheet channel layer 140 .
- the sacrificial release layers 130 can be a different material than the substrate material, substrate insulator layer 120 , and/or the material of the nano-sheet channel layer 140 , such that the sacrificial release layers 130 can be selectively removed, for example, by an etching process.
- the sacrificial release layers 130 can have a thickness in the range of about 5 nm to about 20 nm, or in the range of about 10 nm to about 15 nm, or about 10 nm, although other thicknesses are also contemplated.
- a sacrificial release layer 130 can be made of a material that can be selectively etched compared to the material of the nano sheet channel layer 140 and/or substrate 110 material, such that the sacrificial release layers 130 can be selectively removed from between nano-sheet channel layers 140 .
- the sacrificial release layer 130 can be silicon-germanium (Si x Ge 1-x ), where the germanium concentration can be about 20 at. % to about 70 at. %, or about 30 at. % to about 50 at. %, or about 30 at. % (atomic percent).
- the nano-sheet channel layer 140 can be epitaxially formed on an underlying crystalline sacrificial release layer 130 .
- the sacrificial release layers 130 can be crystalline SiGe layers having predetermined crystal orientation for growing nano-sheet channel layers 140 .
- the nano-sheet channel layer(s) 140 can be a single crystal silicon layer on the crystalline sacrificial release layer 130 .
- the sacrificial release layers 130 can be crystalline silicon layers and the nano-sheet channel layer(s) 140 can be a single crystal silicon-germanium layer(s), where the sacrificial release layers 130 can be selectively etched relative to the nano-sheet channel layer(s) 140 .
- FIG. 2 is a cross-sectional isometric view showing a plurality of patterned nano-sheet channel layers and sacrificial release layers on an insulating layer of a substrate, in accordance with an embodiment of the present invention.
- the stack of alternating sacrificial release layers 130 and nano-sheet channel layers 140 can be masked and patterned, as would be known in the art to form a channel stack 150 having a long lateral dimension (i.e., length), a short lateral dimension (i.e., width), and a height.
- a portion of the stack of sacrificial release layers 130 and nano-sheet channel layers 140 can be removed, for example, by a directional etch (e.g., reactive ion etch (RIE)) to form a channel stack 150 .
- RIE reactive ion etch
- the directional etch may be a non-selective, timed RIE to remove unmasked portions of the sacrificial release layers 130 and nano-sheet channel layers 140 through a single etching step, or alternating selective RIEs may be used to remove exposed portion(s) of each layer separately.
- FIG. 3 is a cross-sectional side view showing a patterned channel stack including nano-sheet channel layers and sacrificial release layers on an insulating layer of a substrate, in accordance with an embodiment of the present invention.
- the patterned channel stack 150 may be sufficiently long to form a plurality of dummy gates on the channel stack, where portions of the channel stack between dummy gates may be removed to form separate nano-sheet devices. Two or more dummy gates can be formed on the same channel stack 150 .
- FIG. 4 is a cross-sectional side view showing two dummy gates with side spacers on a patterned channel stack of nano-sheet channel layers and sacrificial release layers, in accordance with an embodiment of the present invention.
- one or more dummy gates 160 can be formed on the channel stack 150 .
- a dummy gate can include side spacers 163 and a dummy gate fill 167 .
- the dummy gate(s) 160 can be formed by processes known in the art, including masking, patterning, etching, deposition, and planarization processes/steps.
- the dummy gate(s) 160 can be formed by a double patterning process (e.g., sidewall image transfer (SIT)).
- SIT sidewall image transfer
- a dummy gate 160 can be formed on a channel stack 150 , where the dummy gate 160 can be formed over three sides of the channel stack.
- the dummy gate 160 can be a material that can be easily and selectively removed from the layers of the channel stack 150 , including, but not limited to, polysilicon (p-Si), amorphous silicon (a-Si), amorphous carbon (a-C), silicon oxide (SiO), silicon nitride (SiN), silicon oxynitride (SiON), and combinations thereof.
- the dummy gate 160 may include multiple material layers (e.g., a capping layer), where the dummy gate can be a dummy gate stack.
- a side spacer 163 can be formed on each of the dummy gate fills 167 .
- the side spacer 163 can be conformally deposited on the dummy gate fill 167 and exposed surfaces of the channel stack 150 , and etched back using a directional etch (e.g. RIE) to expose the top surface of the dummy gate fill 167 , the channel stack 150 , and the substrate surface, while remaining on the vertical surfaces of the dummy gate fills 167 .
- a directional etch e.g. RIE
- the side spacer 163 can be a silicon nitride (SiN), a silicon oxynitride (SiON), a silicon carbonitride (SiCN), a silicon boronitride (SiBN), a silicon borocarbide (SiBC), a silicon boro carbonitride (SiBCN), a boron carbide (BC), a boron nitride (BN), or combinations thereof, where the dummy gate fill 167 can be selectively etched relative to the side spacer 163 .
- FIG. 5 is a cross-sectional side view showing a dummy gate on each of two cut-stacks of nano-sheet channel layers and sacrificial release layers, in accordance with an embodiment of the present invention.
- the portions of the channel stack 150 exposed between the dummy gates 160 can be removed to form cut-stacks 155 , where the dummy gates can mask the cut-stacks, and the cut-stacks can have the same resulting lateral dimension as the dummy gate 160 .
- the exposed portions of the channel stacks can be removed using a directional etch (e.g., RIE) to form essentially vertical sides to the cut-stack 55 .
- the cut-stack 155 includes the alternating sacrificial release layers 130 and nano-sheet channel layer(s) 140 , where the ends of the sacrificial release layers 130 and nano-sheet channel layer(s) 140 are exposed.
- FIG. 6 is a cross-sectional side view showing indentations formed by removal of a portion of each sacrificial release layer in a cut-stack, in accordance with an embodiment of the present invention.
- a portion of the sacrificial release layers 130 can be removed to reduce the size of the sacrificial release layers in at least one lateral dimension (i.e., length, width).
- the portion of the sacrificial release layers 130 can be removed using an isotropic etch (e.g., wet chemical etch, non-directional dry plasma etch, etc.), where the isotropic etch etches laterally into the sacrificial release layers 130 .
- the isotropic etch can remove a predetermined amount of material from the sacrificial release layers 130 , where the etch can be a timed etch to uniformly remove an equal amount of material from each exposed end.
- the isotropic etch can form indentations 135 having a predetermined indentation depth into the sacrificial release layers 130 .
- the nano-sheet channel layers 140 can extend passed the sacrificial release layers 130 by a predetermined distance.
- Each of the indentations 135 can extend into the area below the side spacer 163 and dummy gate 167 .
- the indentations 135 can have an indentation depth in the range of about 2 nm to about 10 nm, or in the range of about 2 nm to about 5 nm, or in the range of about 5 nm to about 10 nm, although other depths are also contemplated.
- the depth of the indentation can determine the remaining length of the sacrificial release layers 130 below the dummy gate(s) 160 , and thereby the width of a subsequently formed gate fill layer and/or gate electrode at the bottom of the gate structure.
- the depth of the indentation can also determine, at least in part, the amount of capacitive overlap, C ov , between the gate structure and the nano-sheet channel layer(s) 140 .
- FIG. 7 is a cross-sectional side view showing enlarged indentations formed by removal of an additional portion of each sacrificial release layer of an unmasked cut-stack, in accordance with an embodiment of the present invention.
- a mask 170 can be formed on the one or more dummy gates 160 and cut-stacks 155 , for example, with an organic resist material or spin-on layer, leaving one or more dummy gates 160 and cut-stacks 155 exposed for etching, as would be known in the art.
- additional portions of the one or more exposed sacrificial release layers 130 can be removed using a second timed isotropic etch, for example, a wet etch or isotropic dry plasma etch, where the etchant can enter into the indentations 135 formed by the first etch.
- the indentations 135 can extend below the dummy gate fill 167 and side spacer 163 , where the isotropic etch selectively removes sacrificial release layer material not otherwise exposed. Additional etching steps may be used to remove additional material from one or more cut-stacks 155 . The indentation depth of the previously formed indentations 135 can thereby be increased.
- the sacrificial release layers 130 of the masked cut-stack 155 can remain unaffected by the second and any subsequent etching steps, so the initially formed indentations 135 can remain the same depth.
- the mask 170 can be removed from one or more of the masked cut-stacks 155 subsequent to the second etch, and a third timed etch may be used to remove additional material from both the previously masked cut-stack and the exposed cut-stack to achieve three different predetermined etch depths for the indentations 135 .
- the process can be repeated to prepare multiple cut-stacks 155 with different indentation depths on the substrate 110 .
- the indentation depth of the previously formed indentations 135 can thereby be increased, while indentations of a different depth can thereby be created in the sacrificial release layers 130 of a different cut-stack 155 .
- FIG. 8 is a cross-sectional side view showing indentation fill layers formed in the different sized indentations of each cut-stack, in accordance with an embodiment of the present invention.
- an indentation fill layer 180 can be formed on the one or more nano-sheet channel layer(s) 140 and one or more acrificial release layers 130 , where the indentation fill layer 180 can fill the indentations 135 adjacent to the remaining portion of the sacrificial release layers 130 , and between overhanging nano-sheet channel layer(s) 140 .
- the indentation fill layer 180 can be formed on at least a portion of the substrate 110 and dummy gate 160 , and may be etched back by the RIE to leave the indentation fill layers 180 in the indentations 135 .
- the indentation fill layer 180 can be formed by ALD, PEALD, CVD, PECVD, or combinations thereof, where the indentation fill layer 180 can be conformally deposited within the indentations 135 (e.g., by ALD) to fill the indentations. Portions of the indentation fill layer 180 that extend out beyond the side spacers 163 of the dummy gate can be removed by a directional etch (e.g., RIE).
- a directional etch e.g., RIE
- the indentation fill layer 180 can be a silicon nitride (SiN), a silicon oxide (SiO), silicon oxynitride (SiON), silicon oxycarbide (SiOC), a silicon boro carbonitride (SiBCN), a silicon oxy carbonitride (SiOCN), a silicon carbide (SiC), a high-k metal oxide, a low-k insulator, or suitable combinations thereof.
- SiN silicon nitride
- SiO silicon oxide
- SiON silicon oxynitride
- SiOC silicon oxycarbide
- SiBCN silicon boro carbonitride
- SiOCN silicon oxy carbonitride
- SiC silicon carbide
- SiC silicon carbide
- the low-k insulator can include, but is not limited to, a fluoride-doped silicon oxide (e.g., fluoride doped glass), a carbon-doped silicon oxide, a porous silicon oxide, a spin-on silicon based polymeric material (e.g., tetraethyl orthosilicatehydrogen (TEOS), silsesquioxane (HSQ) and methylsilsesquioxane (MSQ)), or combinations thereof.
- TEOS tetraethyl orthosilicatehydrogen
- HSQ silsesquioxane
- MSQ methylsilsesquioxane
- the high-K metal oxide can include, but is not limited to, transition metal oxides such as hafnium oxide (e.g., HfO 2 ), hafnium silicon oxide (e.g., HfSiO 4 ), hafnium silicon oxynitride (Hf w Si x O y N z ), lanthanum oxide (e.g., La 2 O 3 ), lanthanum aluminum oxide (e.g., LaAlO 3 ), zirconium oxide (e.g., ZrO 2 ), zirconium silicon oxide (e.g., ZrSiO 4 ), zirconium silicon oxynitride (Zr w Si x O y N z ), tantalum oxide (e.g., TaO 2 , Ta 2 O 5 ), titanium oxide (e.g., TiO 2 ), barium strontium titanium oxide (e.g., BaTiO 3 —SrTiO 3 ), barium titanium oxides such as
- FIG. 9 is a cross-sectional side view showing a masked cut stack and an unmasked cut-stack, in accordance with an embodiment of the present invention.
- one or more dummy gates 160 and cut-stacks 155 on the substrate 110 can be covered by a second masking layer 190 , where the second masking layer 190 can be an organic resist or organic planarization material (e.g., poly methyl methacrylate (PMMA)).
- PMMA poly methyl methacrylate
- FIG. 10 is a cross-sectional side view showing recesses formed by removal of a portion of each nano-sheet channel layer of an unmasked cut-stack, in accordance with an embodiment of the present invention.
- a portion of the nano-sheet channel layers 140 can be removed to reduce the size of the nano-sheet channel layers in at least one lateral dimension (i.e., length, width).
- the portion of the nano-sheet channel layers 140 can be removed using a selective isotropic etch (e.g., wet chemical etch, non-directional dry plasma etch, etc.), where the isotropic etch etches laterally into the nano-sheet channel layers 140 of the unmasked cut-stack 155 .
- the isotropic etch can remove a predetermined amount of material from the nano-sheet channel layers 140 , where the etch can be a timed etch to uniformly remove an equal amount of material from the exposed ends of the nano-sheet channel layers 140 .
- the isotropic etch can form recesses 145 having a predetermined recess depth into the nano-sheet channel layers 140 .
- the indentation fill layers 180 can extend passed the ends of the nano-sheet channel layers 140 by a predetermined distance.
- Each of the recesses 145 can extend into the area below the side spacer 163 and dummy gate 167 .
- the mask 190 can be removed from one or more of the masked cut-stacks 155 subsequent to the first etch.
- FIG. 11 is a cross-sectional side view of an unmasked cut-stack with recessed nano-sheet channel layers and an unmasked cut-stack without recessed nano-sheet channel layers, in accordance with an embodiment of the present invention.
- the second masking layer 190 can be removed from one or more cut-stacks 155 after the portions of the nano-sheet channel layers 140 have been removed using a selective isotropic etch.
- the second masking layer 190 can be removed using processes known in the art (e.g., ashing, stripping, etc.). Removal of the second masking layer 190 can expose the previously masked cut-stack 155 for removal of a portion of the nano-sheet channel layers 140 .
- the indentation fill layers 180 can protect the ends of the sacrificial release layers 130 during subsequent etching of the nano-sheet channel layers 140 .
- additional portions of the one or more exposed nano-sheet channel layer(s) 140 can be removed from previously etched nano-sheet channel layer(s) using a second timed isotropic etch, for example, a wet etch or dry plasma etch, where the etchant can enter into the recesses 145 formed by the first etch. Additional etching steps may be used to remove additional material from one or more exposed cut-stacks 155 .
- the isotropic etch selectively removes nano-sheet channel layer material not otherwise covered by the dummy gate 160 .
- portions of the one or more exposed nano-sheet channel layer(s) 140 can be removed from previously unetched cut-stacks 155 , where the nano-sheet channel layer(s) are exposed by removal of the second mask 190 , while nano-sheet channel layer(s) 140 of still masked cut-stack 155 can remain unaffected by the second and any subsequent etching steps.
- the duration of the timed etch may be selected to remove a predetermined amount of nano-sheet channel layer material from each exposed recess 145 , so the depth of the recess increases by the predetermined amount for all exposed nano-sheet channel layers 140 .
- an etch process that removes 1 nm of nano-sheet channel layer material per minute can be conducted for 2 minutes to increase the depth of the recesses 145 by 2 nm.
- the cut-stacks 155 that had previously undergone a 2 minute etch would therefore have recesses 145 that are 4 nm in depth, whereas the cut-stack that only underwent the second etch would have recesses with a 2 nm depth.
- the mask 190 can be removed from one or more of the still masked cut-stacks 155 subsequent to the second etch, and a third timed etch may be used to remove additional material from both the previously masked cut-stack and the exposed cut-stack to achieve three different predetermined etch depths for the recesses 145 .
- the process can be repeated to prepare multiple cut-stacks 155 with different reces depths on the substrate 110 .
- the recess depth can be greater than the indentation depth for at least one cut-stack 155 .
- the mask(s) 190 can be removed from different cut-stacks 155 after a predetermined number of etching steps to expose previously unetched nano-sheet channel layer(s) 140 , and masks 190 can be formed on previously etched nano-sheet channel layer(s) 140 to prevent further etching to thereby control the final recess depth of each of a plurality of cut-stacks 155 on a substrate 110 . Additional etching steps may be used to remove additional material from the nano-sheet channel layers 140 of one or more exposed cut-stacks 155 .
- FIG. 12 is a cross-sectional side view of two cut-stacks having different sized recesses formed in the nano-sheet channel layers, in accordance with an embodiment of the present invention.
- the nano-sheet channel layers 140 can have a length in the range of about 15 nm to about 25 nm, or in the range of about 15 nm to about 20 nm, or in the range of about 19 nm to about 25 nm, although other lengths are also contemplated.
- the nano-sheet channel layers of two different devices can have a difference in length in the range of about 2 nm to about 10 nm, or in the range of about 4 nm to about 10 nm, or in the range of about 2 nm to about 5 nm.
- the nano-sheet channel layers 140 of a first nano-sheet device can have a length in the range of about 15 nm to about 19 nm
- the nano-sheet channel layers 140 of a second nano-sheet device can have a length in the range of about 20 nm to about 25 nm, where the shorter nano-sheet channel layers can provide faster devices and the longer nano-sheet channel layers can provide devices with lower leakage current.
- the recesses 145 can extend below the dummy gate fill 167 and side spacer 163 , where the isotropic etch selectively removed nano-sheet channel layer material.
- Different V T s can be achieved by laterally undercutting the nano-sheet channel layers 140 in different cut-stacks 155 by different amounts.
- the source and drain of each nano-sheet device can then be formed on the endwalls of the recessed nano-sheet channel layers 140 by in-situ doped epitaxy.
- the nano-sheet devices can have about the same physically gate length, L G , but different electrical gate length, L Ge , due to different extents of lateral undercutting that reduces at least one lateral dimension (e.g., length) of the nano-sheet channel layers 140 to form the recesses 145 .
- FIG. 13 is a cross-sectional side view of source/drains formed on the nano-sheet channel layers on either side of each of the two cut-stacks, in accordance with an embodiment of the present invention.
- a source/drain (S/D) regions 200 can be formed on the nano-sheet channel layers 140 , where the source/drain regions 200 can be formed by an epitaxial growth process on exposed crystalline faces of the nano-sheet channel layers 140 .
- the source/drain regions 200 can be in physical and electrical contact with each of the one or more nano-sheet channel layer(s) 140 in the cut-stack 155 .
- the source/drain region(s) 200 can be silicon or silicon-germanium suitably doped to form an n-type or a p-type field effect transistor (nFET or pFET).
- the S/D region(s) can be doped in situ (i.e. during formation).
- FIG. 14 is a cross-sectional side view of an interlayer dielectric formed on the two cut-stacks and dummy gates, in accordance with an embodiment of the present invention.
- an interlayer dielectric (ILD) 210 can be formed on the source/drain region(s) 200 .
- the interlayer dielectric (ILD) 210 can be formed by a blanket deposition that covers the source/drain region(s) 200 , as well as portions of the dummy gate(s) 160 , substrate insulator layer 120 , and/or substrate surface.
- the interlayer dielectric (ILD) 210 can extend above the top surface of the dummy gates 160 , and chemical-mechanical polishing (CMP) can be utilized to remove the excess material and provide a smooth, flat surface.
- CMP chemical-mechanical polishing
- the interlayer dielectric (ILD) 210 can be silicon oxide or a low-k dielectric, where the ILD can be formed by CVD, LPCVD, or spun on.
- a low-k dielectric material can be a fluoride-doped silicon oxide (e.g., fluoride doped glass), a carbon-doped silicon oxide, a porous silicon oxide, a spin-on silicon based polymeric material (e.g., tetraethyl orthosilicatehydrogen (TEOS), silsesquioxane (HSQ) and methylsilsesquioxane (MSQ)), or combinations thereof.
- TEOS tetraethyl orthosilicatehydrogen
- HSQ silsesquioxane
- MSQ methylsilsesquioxane
- FIG. 15 is a cross-sectional side view of an interlayer dielectric on the two cut-stacks after removal of the dummy gate fills, in accordance with an embodiment of the present invention.
- the dummy gate fill 167 of the dummy gate(s) 160 can be removed to expose the underlying cut-stack 155 , where the dummy gate fill can be selectively removed. Selective removal of the dummy gate fill 167 can expose at least a portion of the underlying sacrificial release layer(s) 130 , and nano-sheet channel layer(s) 140 . Removal of the dummy gate fill 167 may also expose at least a portion of the indentation fill layer 180 directly below the side spacer 163 . The side spacer 163 can remain around at least a portion of the cut-stack 155 to provide a defined opening 220 for formation of an active gate structure.
- the dummy gate fill 167 can be removed by an isotropic etch, for example, a wet etch, that is selective for the material of the dummy gate fill 167 relative to the side spacer 163 , sacrificial release layer(s) 130 , and nano-sheet channel layers 140 .
- FIG. 16 is a cut-away isometric view of the long axis of the patterned nano-sheet device after removing the dummy gate fill from within the side spacer, in accordance with an embodiment of the present invention.
- the side spacer 163 can remain around at least a portion of the cut-stack 155 to provide a defined opening 220 for formation of an active gate structure, where a portion of the side spacer 163 has been cut away to show the opening formed by removal of the dummy gate fill 167 and the underlying cut-stack 155 . Only portions of the ILD 210 on the source/drain regions 200 are shown. The ILD 210 can surround the source/drain regions 200 and side spacer 163 . The dummy gate 160 can surround three sides of the patterned channel stack 150 , and subsequent cut-stack 155 .
- FIG. 17 is a cross-sectional side view of a plurality of freed nano-sheet channel layers after removal of the intervening sacrificial release layers in the two cut-stacks, in accordance with an embodiment of the present invention.
- the remaining portions of the sacrificial release layer(s) 130 of the cut-stack(s) 155 can be removed to release the nano-sheet channel layer(s) 140 , where the nano-sheet channel layer(s) 140 can be secured at the opposite end faces 142 to the source/drain regions 200 formed in the recess(es) 145 .
- the indentation fill layer 180 can be between the source/drain regions 200 in the recess(es) 145 .
- the nano-sheet channel layer(s) 140 can span the distance between the two source/drain regions 200 on opposites sides of the dummy gate.
- Removal of the sacrificial release layer(s) can form air gaps 139 between the nano-sheet channel layer(s) 140 , where the nano-sheet channel layer(s) 140 can be exposed on the four sides not in direct contact with the source/drain regions 200 at opposite end faces 142 .
- the sacrificial release layer(s) 130 can be removed using an isotropic etch, for example, a wet etch selective for the material of the sacrificial release layer(s) 130 .
- the etchant can be introduced into the opening 220 , such that the etchant can access the sides of the cut-stack 155 including the sidewalls of the sacrificial release layer(s) 130 .
- a sacrificial release layer 130 is between the substrate insulator layer 120 and the lower-most nano-sheet channel layer 140 , so a subsequently formed gate electrode (i.e., work function layer and gate fill layer) can wrap around the lower-most nano-sheet channel layer 140 .
- FIG. 18 is a cross-sectional side view of a gate dielectric layer on the exposed surfaces of the nano-sheets, in accordance with an embodiment of the present invention.
- a gate dielectric layer 230 can be formed on the exposed surfaces of the nano-sheet channel layer(s) 140 , where the gate dielectric layer 230 can be formed by a conformal deposition process, for example, ALD, CVD, or combinations thereof.
- the precursors for the gate dielectric layer 230 can be selected based on the ability of entering the spaces formed between the nanosheet channel layer(s) 140 vacated by the sacrificial release layer(s) 130 .
- the precursors for the gate dielectric layer 230 can be introduced into the opening(s) 220 .
- the gate dielectric layer 230 can be formed on the exposed surfaces of the substrate insulator layer 120 on opposite sides of the cut-stack 155 at the bottom of the opening 220 within the side spacer 163 .
- the gate dielectric layer 230 can also be formed on the inside surfaces of the side spacer 163 .
- the gate dielectric layer 230 can be an insulating dielectric layer, for example, a silicon oxide (SiO), silicon nitride (SiN), silicon oxynitride (SiON), a high-K dielectric, or a suitable combination of these materials.
- the gate dielectric layer 230 can be a high-K dielectric material that can include, but is not limited to, transition metal oxides such as hafnium oxide (e.g., HfO 2 ), hafnium silicon oxide (e.g., HfSiO 4 ), hafnium silicon oxynitride (Hf w Si x O y N z ), lanthanum oxide (e.g., La 2 O 3 ), lanthanum aluminum oxide (e.g., LaAlO 3 ), zirconium oxide (e.g., ZrO 2 ), zirconium silicon oxide (e.g., ZrSiO 4 ), zirconium silicon oxynitride (Zr w Si x O y N z ), tantalum oxide (e.g., TaO 2 , Ta 2 O 5 ), titanium oxide (e.g., TiO 2 ), barium strontium titanium oxide (e.g., BaTiO 3
- a work function layer 240 can be formed on the gate dielectric layer 230 , where the work function layer and gate dielectric layer 230 can surround at least a portion of each of the one or more nano-sheet channel layer(s) 140 .
- a work function layer 240 can be formed on the exposed portion(s) of the gate dielectric layer 230 between the nano-sheet channel layer(s) 140 .
- the work function layer 240 can be formed on the gate dielectric layer 230 to adjust the electrical properties of a gate electrode.
- the work function layer can be optional.
- a portion of the work function layer 240 can be formed on the gate dielectric layer 230 on the substrate insulator layer 120 beneath the bottom-most nano-sheet channel layer 140 .
- the work function layer 240 can fill in the spaces between the gate dielectric layer 230 on the nanosheet channel layer(s) 140 .
- the work function layer can be formed by a conformal deposition, for example, ALD.
- a work function layer 240 can be a conductive nitride, including but not limited to titanium nitride (TiN), titanium aluminum nitride (TiAlN), hafnium nitride (HfN), hafnium silicon nitride (HfSiN), tantalum nitride (TaN), tantalum silicon nitride (TaSiN), tungsten nitride (WN), molybdenum nitride (MoN), niobium nitride (NbN); a conductive carbide, including but not limited to titanium carbide (TiC), titanium aluminum carbide (TiAlC), tantalum carbide (TaC), hafnium carbide (HfC); or combinations thereof.
- the work function layer 240 can include multiple layers of work function materials, for example, a work function layer can be a TiN/TiC stack.
- the work function layer 240 can have a thickness in the range of about 3 nm to about 11 nm, or can have a thickness in the range of about 5 nm to about 8 nm.
- FIG. 19 is a cross-sectional side view of a gate structure on each of the cut-stacks, in accordance with an embodiment of the present invention.
- a gate fill layer 250 can be formed on the gate dielectric layer 230 and/or work function layer 240 if present, where the gate fill layer 250 can fill in the space of opening 220 in between side spacers 163 .
- the gate fill layer 250 , gate dielectric layer 230 , and optionally the work function layer 240 can form a gate structure on one or more nano-sheet channel layer(s) 140 , where the gate fill layer 250 and work function layer 240 can form a conductive gate electrode.
- the gate fill layer 250 can be blanket deposited on the exposed surfaces of the gate dielectric layer 230 and/or work function layer 240 .
- the formed gate fill layer 250 can extend above the top surface of the interlayer dielectric 210 , where the gate fill layer material above the top surfaces of the interlayer dielectric 210 can be removed by a CMP to provide a flat, uniform surface.
- the gate fill layer 250 can be a conductive metal, where the metal can be tungsten (W), titanium (Ti), molybdenum (Mo), cobalt (Co), or a conductive carbon material (e.g., carbon nanotube, graphene, etc.), or any suitable combinations thereof.
- the metal can be tungsten (W), titanium (Ti), molybdenum (Mo), cobalt (Co), or a conductive carbon material (e.g., carbon nanotube, graphene, etc.), or any suitable combinations thereof.
- the gate dielectric layer 230 and the work function layer 240 can wrap around each of the nano-sheet channel layer(s) 140 , and the gate fill layer 250 can surround the nano-sheet channel layer(s) 140 and work function layer 240 .
- the gate dielectric layer 230 can extend up the inside surface of the side spacer 163 , and the interlayer dielectric (ILD) 210 can be on the outside surface of the sidewall spacer 163 .
- the width of the gate fill layer 250 or gate electrode at the top of the gate structure can be the same for both (or all) of the nano-sheet devices, whereas the width of the gate fill layer 250 at the bottom of the gate structure (adjacent to the top-most nano-sheet channel layer 140 ) can be greater than the width at the top for one or more of the gate structure(s) and less than the width at the top for one or more other gate structure(s).
- the overlap between the gate fill layer 250 or gate electrode at the bottom of the gate structure adjacent to the top-most nano-sheet channel layer 140 and the portion of the source/drain regions 200 extending into the recess 145 can be the same, such that the overlap capacitance, C ov , of both nano-sheet devices is essentially the same (e.g., within process control tolerances), while the electrical gate lengths, L Ge , and threshold voltage, V T , are different for each nano-sheet device.
- the overlap can be measured between the source/drain region 200 and the bottom area of the gate electrode.
- the lengths of the indentation fill layer 180 can adjust for the difference in the lengths of the nano-sheet channel layer(s) 140 of two different devices.
- Nano-sheet transistor devices can thereby be fabricated with the same physical gate length, L G , but with different electrical gate lengths, L Ge , and resulting threshold voltages, V T .
- transistors with different threshold voltages, V T could achieve optimal tradeoff between performance and power consumption.
- electrical contacts can be formed to the gate structure and source/drain regions 200 for electrically connecting the nano-sheet devices.
- first, second, etc. may be used herein to describe various elements, these elements should not be limited by these terms. These terms are only used to distinguish one element from another element. Reference to first, second, third, etc., feature is intended to distinguish features without necessarily implying a particular order unless otherwise so stated or indicated. Thus, a first element discussed herein could be termed a second element without departing from the scope of the present concept.
- the present embodiments may include a design for an integrated circuit chip, which may be created in a graphical computer programming language, and stored in a computer storage medium (such as a disk, tape, physical hard drive, or virtual hard drive such as in a storage access network). If the designer does not fabricate chips or the photolithographic masks used to fabricate chips, the designer may transmit the resulting design by physical means (e.g., by providing a copy of the storage medium storing the design) or electronically (e.g., through the Internet) to such entities, directly or indirectly.
- the stored design is then converted into the appropriate format (e.g., GDSII) for the fabrication of photolithographic masks, which typically include multiple copies of the chip design in question that are to be formed on a wafer.
- the photolithographic masks are utilized to define areas of the wafer (and/or the layers thereon) to be etched or otherwise processed.
- the resulting integrated circuit chips can be distributed by the fabricator in raw wafer form (that is, as a single wafer that has multiple unpackaged chips), as a bare die, or in a packaged form.
- the chip is mounted in a single chip package (such as a plastic carrier, with leads that are affixed to a motherboard or other higher level carrier) or in a multichip package (such as a ceramic carrier that has either or both surface interconnections or buried interconnections).
- the chip is then integrated with other chips, discrete circuit elements, and/or other signal processing devices as part of either (a) an intermediate product, such as a motherboard, or (b) an end product.
- the end product can be any product that includes integrated circuit chips, ranging from toys and other low-end applications to advanced computer products having a display, a keyboard or other input device, and a central processor.
- any of the following “/”, “and/or”, and “at least one of”, for example, in the cases of “A/B”, “A and/or B” and “at least one of A and B”, is intended to encompass the selection of the first listed option (A) only, or the selection of the second listed option (B) only, or the selection of both options (A and B).
- such phrasing is intended to encompass the selection of the first listed option (A) only, or the selection of the second listed option (B) only, or the selection of the third listed option (C) only, or the selection of the first and the second listed options (A and B) only, or the selection of the first and third listed options (A and C) only, or the selection of the second and third listed options (B and C) only, or the selection of all three options (A and B and C).
- This may be extended, as readily apparent by one of ordinary skill in this and related arts, for as many items listed.
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Abstract
Description
Claims (41)
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US17/338,459 USRE49954E1 (en) | 2016-09-19 | 2021-06-03 | Fabrication of nano-sheet transistors with different threshold voltages |
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US15/268,993 US9653289B1 (en) | 2016-09-19 | 2016-09-19 | Fabrication of nano-sheet transistors with different threshold voltages |
US15/462,372 US10312337B2 (en) | 2016-09-19 | 2017-03-17 | Fabrication of nano-sheet transistors with different threshold voltages |
US17/338,459 USRE49954E1 (en) | 2016-09-19 | 2021-06-03 | Fabrication of nano-sheet transistors with different threshold voltages |
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US15/462,372 Reissue US10312337B2 (en) | 2016-09-19 | 2017-03-17 | Fabrication of nano-sheet transistors with different threshold voltages |
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US10177235B2 (en) | 2019-01-08 |
US9653289B1 (en) | 2017-05-16 |
US10312337B2 (en) | 2019-06-04 |
US20180082902A1 (en) | 2018-03-22 |
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Owner name: BANK OF AMERICA, N.A., AS COLLATERAL AGENT, NORTH CAROLINA Free format text: SECURITY INTEREST;ASSIGNORS:ADEIA GUIDES INC.;ADEIA MEDIA HOLDINGS LLC;ADEIA MEDIA SOLUTIONS INC.;AND OTHERS;REEL/FRAME:063707/0884 Effective date: 20230519 |