US744170A - Process of depositing metallic coatings on metallic objects. - Google Patents
Process of depositing metallic coatings on metallic objects. Download PDFInfo
- Publication number
- US744170A US744170A US72860499A US1899728604A US744170A US 744170 A US744170 A US 744170A US 72860499 A US72860499 A US 72860499A US 1899728604 A US1899728604 A US 1899728604A US 744170 A US744170 A US 744170A
- Authority
- US
- United States
- Prior art keywords
- metallic
- objects
- cyanid
- chlorid
- depositing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title description 5
- 238000000576 coating method Methods 0.000 title description 4
- 238000000151 deposition Methods 0.000 title description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- 239000004411 aluminium Substances 0.000 description 7
- 229910052782 aluminium Inorganic materials 0.000 description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 7
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 6
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 6
- 235000011180 diphosphates Nutrition 0.000 description 6
- 229910052700 potassium Inorganic materials 0.000 description 6
- 239000011591 potassium Substances 0.000 description 6
- 229910019142 PO4 Inorganic materials 0.000 description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 5
- 239000003513 alkali Substances 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 5
- 239000010452 phosphate Substances 0.000 description 5
- 229910052725 zinc Inorganic materials 0.000 description 5
- 239000011701 zinc Substances 0.000 description 5
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 2
- 229910001369 Brass Inorganic materials 0.000 description 2
- 229910000906 Bronze Inorganic materials 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 239000001099 ammonium carbonate Substances 0.000 description 2
- 235000012501 ammonium carbonate Nutrition 0.000 description 2
- 239000010951 brass Substances 0.000 description 2
- 239000010974 bronze Substances 0.000 description 2
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052718 tin Inorganic materials 0.000 description 2
- 239000011135 tin Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- LUTSRLYCMSCGCS-BWOMAWGNSA-N [(3s,8r,9s,10r,13s)-10,13-dimethyl-17-oxo-1,2,3,4,7,8,9,11,12,16-decahydrocyclopenta[a]phenanthren-3-yl] acetate Chemical compound C([C@@H]12)C[C@]3(C)C(=O)CC=C3[C@@H]1CC=C1[C@]2(C)CC[C@H](OC(=O)C)C1 LUTSRLYCMSCGCS-BWOMAWGNSA-N 0.000 description 1
- 150000003868 ammonium compounds Chemical class 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/56—Electroplating: Baths therefor from solutions of alloys
- C25D3/58—Electroplating: Baths therefor from solutions of alloys containing more than 50% by weight of copper
Definitions
- My invention relates to an improved process for electroplating metal objects without the use of an electric battery; and it consists in bringing the object to be plated into contact with metallic aluminium in a bath containing a salt of the metal to be deposited and a salt adapted to insure the constant attack of the aluminium, which latter is kept constantly bright.
- the continuous attack of the aluminium surface is assured by the alkaline character of the solution, while a deposit on the aluminium of the metal to be plated is prevented by the alkaline phosphate or pyrophosphate or by the alkali cyanid, respectively.
- the ammonium compound serves to improve the conductivity of the solution.
- the alkaline phosphate or pyrophosphate serves the double purpose of attacking the aluminium and preventing the deposit thereon of the plating metal.
- the following proportions may be given: water, ten quarts; chlorid of ammonium and nickel, one pound; py rophosphate of sodium, four pounds; carbonate of ammonium, ten ounces.
- Such abath will electroplate small objects of about the quarts of water, three and one-half ounces chlorid of zinc.
- the chlorid of zinc in this bath is precipitated by means of cyanid of potassium and the resulting cyanid of zinc dissolved again in an excess of cyanid of potassium.
- To the solution eight ounces of carbonate of sodium are added. With such a bath hooks and eyes can be galvanized in two to three minutes.
- the temperature of these baths may vary according to requirements, being, as a rule, between 35 to 100 centigrade.
- the first type of bath is more particularly suitable for deposits of nickel and cobalt and the second type for zinc, tin, copper, brass, bronze, and silver.
- Gold can be deposited with equal success in baths of either type.
- Several substances can be deposited with either one or the other of the baths mentioned. The best results are, however, obtained by choosing the baths as above stated.
- brass can be used a solution of a double cyanid of zinc and cyanid of potassium mixed with a solution of a double cyanid composed of cyanid of copper and cyanid of potassium, to which mixture a small quantity of soda or the like is added.
- a process for depositing metallic coatings on metallic objects consisting in bringing the objects to be plated into contact with metallic aluminium in an alkaline bath containing a double chlorid composed of ammonium chlorid and of the chlorid of the metal to be deposited, a great excess of a pyrophosphate of an alkali metal and ammonium carbonate, substantially as set forth.
- a process for depositing metallic coatings on metallic objects consisting in bringing the objects to be plated into contact with metallic aluminium in an alkaline bath containing 21 pyrophosphate of an alkali and a presence of ammonium chlorid, substantially as set forth.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating And Plating Baths Therefor (AREA)
Description
Patented November 17, 1903.
ATENT FFICE.
ANDRE DARLAY, or PARIS, FRANCE,
PROCESS OF DEPOSITING METALLIC COATINGS 0N METALLIC OBJECTS.
SPEUIFIGATIQN forming part of Letters Patent No. 744,170, dated November 1'7, 1903.
. Application filed August 26, 1899, Serial No. 728,604. (No specimens.)
To all whom it may concern:
Be it known that I, ANDRE DARLAY, a citizen of France, residing at Paris, France, have invented a certain new and useful Improved Process of Depositing Metallic Coatings on Metallic Objects, (for which I have applied for patents in France, dated January 27, 1899, No. 285,354; in Germany, dated February 14:, 1899; in England, dated July 27, 1899, and in Belgium, dated July 27, 1899,) of which the following is a specification.
My invention relates to an improved process for electroplating metal objects without the use of an electric battery; and it consists in bringing the object to be plated into contact with metallic aluminium in a bath containing a salt of the metal to be deposited and a salt adapted to insure the constant attack of the aluminium, which latter is kept constantly bright. V
In carrying out my invention I prepare a solution of a chlorid, cyanid, or other compoundof the metal to be deposited containing ammonium chlorid or other compound of ammonium and an alkali, an alkaline phosphate or pyrophosphate, or an alkali-metal cyanid.
The continuous attack of the aluminium surface is assured by the alkaline character of the solution, while a deposit on the aluminium of the metal to be plated is prevented by the alkaline phosphate or pyrophosphate or by the alkali cyanid, respectively. The ammonium compound serves to improve the conductivity of the solution.
Suitable baths for practical purposes-can be obtained in the following manner:
Type I.-Solutions of a double chlorid composed of ammonium chlorid and of the chlorid of the metal to be deposited, to which solutions a great excess of an alkaline phosphate or pyrophosphate is added, with or without addition of ammonium carbonate: In this case the alkaline phosphate or pyrophosphate serves the double purpose of attacking the aluminium and preventing the deposit thereon of the plating metal. As an example of such a bath the following proportions may be given: water, ten quarts; chlorid of ammonium and nickel, one pound; py rophosphate of sodium, four pounds; carbonate of ammonium, ten ounces. Such abath will electroplate small objects of about the quarts of water, three and one-half ounces chlorid of zinc. The chlorid of zinc in this bath is precipitated by means of cyanid of potassium and the resulting cyanid of zinc dissolved again in an excess of cyanid of potassium. To the solution eight ounces of carbonate of sodium are added. With such a bath hooks and eyes can be galvanized in two to three minutes.
The temperature of these baths may vary according to requirements, being, as a rule, between 35 to 100 centigrade.
The first type of bath is more particularly suitable for deposits of nickel and cobalt and the second type for zinc, tin, copper, brass, bronze, and silver. Gold can be deposited with equal success in baths of either type. Several substances can be deposited with either one or the other of the baths mentioned. The best results are, however, obtained by choosing the baths as above stated. In the case of brass can be used a solution of a double cyanid of zinc and cyanid of potassium mixed with a solution of a double cyanid composed of cyanid of copper and cyanid of potassium, to which mixture a small quantity of soda or the like is added. For bronze I use a mixture of cyanid of copper and potassium, together with cyanid of tin and potassium, which solution is of the metal to be deposited, a great excess of a phosphate of an alkali, and a carbonate of an alkali, substantially as set forth.
2. A process for depositing metallic coatings on metallic objects, consisting in bringing the objects to be plated into contact with metallic aluminium in an alkaline bath containing a double chlorid composed of ammonium chlorid and of the chlorid of the metal to be deposited, a great excess of a pyrophosphate of an alkali metal and ammonium carbonate, substantially as set forth.
3. A process for depositing metallic coatings on metallic objects, consisting in bringing the objects to be plated into contact with metallic aluminium in an alkaline bath containing 21 pyrophosphate of an alkali and a presence of ammonium chlorid, substantially as set forth.
In testimony whereof I have hereunto set my hand in the presence of two witnesses. ANDRE DARLAY. Witnesses:
ALFRED LEVY, ALFRED EIVOLY.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US72860499A US744170A (en) | 1899-08-26 | 1899-08-26 | Process of depositing metallic coatings on metallic objects. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US72860499A US744170A (en) | 1899-08-26 | 1899-08-26 | Process of depositing metallic coatings on metallic objects. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US744170A true US744170A (en) | 1903-11-17 |
Family
ID=2812667
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US72860499A Expired - Lifetime US744170A (en) | 1899-08-26 | 1899-08-26 | Process of depositing metallic coatings on metallic objects. |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US744170A (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2488246A (en) * | 1944-08-25 | 1949-11-15 | United Chromium Inc | Process of electroplating zinc, and baths and compositions for use therein |
| US2501737A (en) * | 1946-09-11 | 1950-03-28 | Jr Ralph W Porter | Solution for plating metals with gold |
| US2504272A (en) * | 1944-10-25 | 1950-04-18 | Ewald H Mccoy | Electrodeposition of silver |
| US2511952A (en) * | 1950-06-20 | Process of plating zinc on aluminum | ||
| US2526544A (en) * | 1947-10-06 | 1950-10-17 | Dow Chemical Co | Method of producing a metallic coating on magnesium and its alloys |
| US2822325A (en) * | 1955-02-11 | 1958-02-04 | Metal & Thermit Corp | Process of, and composition for cleaning and tinning |
| US2969295A (en) * | 1958-05-05 | 1961-01-24 | Pacific Semiconductors Inc | Chemical gold plating |
| US2976181A (en) * | 1957-12-17 | 1961-03-21 | Hughes Aircraft Co | Method of gold plating by chemical reduction |
| US3406107A (en) * | 1964-12-07 | 1968-10-15 | Ibm | Non-cyanide silver plating bath |
| US3423295A (en) * | 1966-02-23 | 1969-01-21 | Engelhard Ind Inc | Gold plating |
| US3515651A (en) * | 1966-02-07 | 1970-06-02 | Katsuhiro Ohkubo | Plating solutions for rhodium and rhodium alloy platings having low internal stress |
| US4024031A (en) * | 1975-10-28 | 1977-05-17 | Amp Incorporated | Silver plating |
-
1899
- 1899-08-26 US US72860499A patent/US744170A/en not_active Expired - Lifetime
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2511952A (en) * | 1950-06-20 | Process of plating zinc on aluminum | ||
| US2488246A (en) * | 1944-08-25 | 1949-11-15 | United Chromium Inc | Process of electroplating zinc, and baths and compositions for use therein |
| US2504272A (en) * | 1944-10-25 | 1950-04-18 | Ewald H Mccoy | Electrodeposition of silver |
| US2501737A (en) * | 1946-09-11 | 1950-03-28 | Jr Ralph W Porter | Solution for plating metals with gold |
| US2526544A (en) * | 1947-10-06 | 1950-10-17 | Dow Chemical Co | Method of producing a metallic coating on magnesium and its alloys |
| US2822325A (en) * | 1955-02-11 | 1958-02-04 | Metal & Thermit Corp | Process of, and composition for cleaning and tinning |
| US2976181A (en) * | 1957-12-17 | 1961-03-21 | Hughes Aircraft Co | Method of gold plating by chemical reduction |
| US2969295A (en) * | 1958-05-05 | 1961-01-24 | Pacific Semiconductors Inc | Chemical gold plating |
| US3406107A (en) * | 1964-12-07 | 1968-10-15 | Ibm | Non-cyanide silver plating bath |
| US3515651A (en) * | 1966-02-07 | 1970-06-02 | Katsuhiro Ohkubo | Plating solutions for rhodium and rhodium alloy platings having low internal stress |
| US3423295A (en) * | 1966-02-23 | 1969-01-21 | Engelhard Ind Inc | Gold plating |
| US4024031A (en) * | 1975-10-28 | 1977-05-17 | Amp Incorporated | Silver plating |
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