US6699415B1 - Surfaces of transparent resin in which marble or other stones are embedded - Google Patents
Surfaces of transparent resin in which marble or other stones are embedded Download PDFInfo
- Publication number
- US6699415B1 US6699415B1 US09/913,011 US91301101A US6699415B1 US 6699415 B1 US6699415 B1 US 6699415B1 US 91301101 A US91301101 A US 91301101A US 6699415 B1 US6699415 B1 US 6699415B1
- Authority
- US
- United States
- Prior art keywords
- resin
- inserts
- brushing
- product
- depressions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920005989 resin Polymers 0.000 title claims abstract description 43
- 239000011347 resin Substances 0.000 title claims abstract description 43
- 239000004575 stone Substances 0.000 title claims abstract description 10
- 239000004579 marble Substances 0.000 title claims abstract description 6
- 238000000034 method Methods 0.000 claims abstract description 13
- 230000001680 brushing effect Effects 0.000 claims abstract description 12
- 239000003082 abrasive agent Substances 0.000 claims abstract description 6
- 238000000576 coating method Methods 0.000 claims abstract description 4
- 238000004519 manufacturing process Methods 0.000 claims abstract description 4
- 238000005498 polishing Methods 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims 6
- 230000000379 polymerizing effect Effects 0.000 claims 1
- 238000009827 uniform distribution Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000002699 waste material Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 2
- 238000010411 cooking Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000004069 differentiation Effects 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C5/00—Processes for producing special ornamental bodies
- B44C5/04—Ornamental plaques, e.g. decorative panels, decorative veneers
- B44C5/0438—Ornamental plaques, e.g. decorative panels, decorative veneers containing stone elements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44F—SPECIAL DESIGNS OR PICTURES
- B44F9/00—Designs imitating natural patterns
- B44F9/04—Designs imitating natural patterns of stone surfaces, e.g. marble
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/53—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone involving the removal of at least part of the materials of the treated article, e.g. etching, drying of hardened concrete
- C04B41/5323—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone involving the removal of at least part of the materials of the treated article, e.g. etching, drying of hardened concrete to make grain visible, e.g. for obtaining exposed aggregate concrete
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/60—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
- C04B41/72—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone involving the removal of part of the materials of the treated articles, e.g. etching
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/22—Nonparticulate element embedded or inlaid in substrate and visible
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
- Y10T428/24372—Particulate matter
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
- Y10T428/24372—Particulate matter
- Y10T428/24421—Silicon containing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
- Y10T428/24372—Particulate matter
- Y10T428/24421—Silicon containing
- Y10T428/2443—Sand, clay, or crushed rock or slate
Definitions
- the invention relates to a product with special charactestics, which can be used as a product for coatings, for components of sanitary ware and in kitchen fittings and domestic worktops.
- This product consists of a polymerized transparent resin—which may be colored—in which inserts consisting of gravel of marble and/or of other stones, which may also be obtained from waste recovered from other processes, preferably rounded, embedded substantially uniformly.
- the useful surface of the product should be worked by brushing with abrasives, so as to obtain slight depressions corresponding to the resin, whereas slight projections, distributed substantially uniformly and surrounded by the said depressions, are delineated corresponding to the said inserts.
- the product prior to brushing with abrasives the product is “decapitated” (i.e. machined for uniform removal of a limited thickness) whereby the inserts appear at the surface with smoothed surfaces; the slight projections formed by the inserts remain smoothed, co-planar (flush) and surrounded by the said slight depressions obtained by brushing.
- Brushing can be followed by a surface polishing treatment of the resin and of the inserts.
- the invention also relates to a product for coatings, for components of sanitary ware and kitchen fittings and for domestic worktops, consisting of a polymerized transparent resin—which may also be more or less colored—in which inserts consisting of gravel of marble and/or other stones, even obtained from waste recovered from other processes, are embedded substantially uniformly.
- This product according to the invention is characterized in that there are slight projections corresponding to the inserts, and slight depressions corresponding to the resin, on the useful surface of the said product.
- the inserts may be smoothed at the surface (as a result of the “decapitation” machining), so that the projections become smoothed and coplanar (flush) and surrounded by the said slight depressions.
- FIG. 1 shows a starting product that is to be processed according to the invention
- FIG. 2 shows the product from FIG. 1, processed by simple abrasion and brushing
- FIGS. 3 and 4 show the product that is first treated by removing a uniform thickness (decapitation) and is then treated by abrasion and brushing according to the invention
- FIG. 5 shows a view along line V—V in FIG. 4;
- FIG. 6 shows a greatly magnified detail of the product as in FIG. 4 .
- a conglomerate is formed from a transparent, and possibly colored, synthetic resin 1 , and a number of inserts 3 that are embedded in the resin and are in the form of gravel or other stone material, either natural, or possibly obtained from waste from previous processing, for example by treatment of fragments from previous processing to obtain the rounded shapes that are assumed in nature by gravel that is moved naturally by the water of stretches of water; the resin is then polymerized.
- the polymerized resin is sufficiently transparent or completely transparent, so that the inserts 3 can be seen through the thickness of the said resin.
- the surface obtained with the product of the aforementioned type, as illustrated in FIG. 1, has a surface S that is intended to be seen, which is normally geometrically flat.
- a flat surface as stated above offers an appearance that is very uniform and so has characteristics that are not always acceptable.
- the surface S consists almost entirely of the polymerized resin 1 , its resistance to mechanical wear and to stresses of the thermal type—for example caused by placing metallic cooking utensils thereon, which are at a relatively high temperature—does not offer the stability that should preferably be offered by surfaces that are to be used in the domestic situation, for example surfaces of kitchen worktops or surfaces in living rooms etc.
- the surface S 1 is defined by the projecting portions represented by the surfaces of the inserts coming to the surface and by zones where there are slight depressions and undulation, which are formed by the resin, which accordingly does not come into direct contact with any objects that are placed on the product that has been treated in this way.
- the starting product shown in FIG. 1 is first worked by removing a thickness X (so-called “decapitation”) which gives rise to the formation of a flat surface S 10 (FIG. 3 ); this surface S 10 consists partly of the resin and partly of the stone material of the inserts that was worn away together with the resin, and which therefore forms surfaces I that are substantially flat, flush, and appearing on surface S 10 .
- a thickness X i.e. after the so-called “decapitation” of the surface inserts—shown as 13 in FIG. 3 —brushing with abrasives is carried out as already indicated for the processing as in FIG. 2; therefore the final surface consists (FIGS.
- Decapitation tends to lower the percentage of surface created by the resin, so as to increase the resistance to heat, and to wear.
- a smooth surface such as that consisting of resin completely as designated by S in FIG. 1 or consisting of the surface S 10 and the surfaces I of the “decapitated” material 13 , as shown in FIG. 3 .
- the structure as obtained with reference to FIG. 2 or as obtained with reference to FIGS. 4 and 6 will have a more characteristic and varying appearance, than a surface that is completely and monotonously flat.
- the depressions such as those of surface S 1 or those of surface S 13 —formed by the polymerized resin—are protected from wear and from thermal effects that might otherwise be exerted on the resin by the placing, for example, of a cooking vessel or some other object that might be placed thereon for whatever purpose, for example on a kitchen worktop.
- the projecting surfaces (such as those I or such as those rounded off in FIG. 2 ), being formed by the stone inserts, are resistant to wear and to heat, and keep their polish for a long time.
- the polymerized resin must be transparent or substantially transparent after polymerization, so as to permit the inserts 3 or 13 to be visible, like gravel immersed in clear water. Since these resins may undergo a slight color change over time, the transparent resin can also advantageously be slightly colored at the start, so as to avoid an excessive color change such as can result from yellowing of resin that is purely transparent and colorless when polymerized, some time after manufacture of the product; this possible color change over time is added to the slight initial coloration of the transparent mass of polymerized resin, thus avoiding excessively pronounced differentiation due to the color change that occurs over time.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Laminated Bodies (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Finishing Walls (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Paints Or Removers (AREA)
- Aftertreatments Of Artificial And Natural Stones (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/697,212 US6951679B2 (en) | 1999-02-09 | 2003-10-30 | Surfaces of transparent resin in which marble or other stones are embedded |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ITFI99A0028 | 1999-02-09 | ||
IT1999FI000028A IT1310007B1 (it) | 1999-02-09 | 1999-02-09 | Procedimento per la formazione di un manufatto per rivestimenti, percomponenti di attrezzature idrosanitarie, di cucine ed altro, in |
PCT/IT2000/000036 WO2000047427A1 (en) | 1999-02-09 | 2000-02-07 | Surfaces of transparent resin in which marble or other stones are embedded |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/IT2000/000036 A-371-Of-International WO2000047427A1 (en) | 1999-02-09 | 2000-02-07 | Surfaces of transparent resin in which marble or other stones are embedded |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/697,212 Division US6951679B2 (en) | 1999-02-09 | 2003-10-30 | Surfaces of transparent resin in which marble or other stones are embedded |
Publications (1)
Publication Number | Publication Date |
---|---|
US6699415B1 true US6699415B1 (en) | 2004-03-02 |
Family
ID=11352799
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US09/913,011 Expired - Fee Related US6699415B1 (en) | 1999-02-09 | 2000-02-07 | Surfaces of transparent resin in which marble or other stones are embedded |
US10/697,212 Expired - Fee Related US6951679B2 (en) | 1999-02-09 | 2003-10-30 | Surfaces of transparent resin in which marble or other stones are embedded |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/697,212 Expired - Fee Related US6951679B2 (en) | 1999-02-09 | 2003-10-30 | Surfaces of transparent resin in which marble or other stones are embedded |
Country Status (14)
Country | Link |
---|---|
US (2) | US6699415B1 (pt) |
EP (1) | EP1161353B1 (pt) |
CN (1) | CN1123456C (pt) |
AT (1) | ATE231798T1 (pt) |
AU (1) | AU757515B2 (pt) |
CA (1) | CA2361488C (pt) |
DE (1) | DE60001306T2 (pt) |
ES (1) | ES2188506T3 (pt) |
HK (1) | HK1042456B (pt) |
IT (1) | IT1310007B1 (pt) |
PT (1) | PT1161353E (pt) |
RU (1) | RU2234422C2 (pt) |
TR (1) | TR200102260T2 (pt) |
WO (1) | WO2000047427A1 (pt) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20060003155A1 (en) * | 2005-07-08 | 2006-01-05 | Stonefaux, Llc | Composite core stiffened structures for lamination and tiling |
US20090277127A1 (en) * | 2008-05-08 | 2009-11-12 | Single Eagle, Inc. | Decorative aggregate concrete surface preparation process |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7504129B2 (en) * | 2005-03-16 | 2009-03-17 | Ra Golv Ab | Method of producing a flooring and a flooring produced according to the method |
US20070044685A1 (en) * | 2005-09-01 | 2007-03-01 | Harvinder Khanna | Mosaic marble flooring and driveway system |
US20090107069A1 (en) * | 2006-03-30 | 2009-04-30 | Ri.C.R.A.E.E. S.R.L. | Method for the Production of the End-Products for Civil and Urban Building and End-Products Thus Obtained |
KR20100001085A (ko) * | 2008-06-26 | 2010-01-06 | (주)엘지하우시스 | 체 원리를 이용한 인조석 제조방법 및 그 방법으로 제조된인조석 |
EP3486227A1 (en) | 2017-11-20 | 2019-05-22 | Cosentino Research and Development, S.L | Process for the functionalization of natural or artificial stone |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3170808A (en) * | 1958-12-09 | 1965-02-23 | Armstrong Cork Co | Method of fabricating a tessellated surface covering |
US3324213A (en) * | 1959-10-16 | 1967-06-06 | Anfi As | Method of making decorative articles |
US3344011A (en) * | 1964-11-02 | 1967-09-26 | Goozner Murray | Terrazzo tile |
US3378617A (en) * | 1965-02-24 | 1968-04-16 | Elmendorf Armin | Method of facing building products with exposed mineral granules |
DE2300674A1 (de) | 1972-01-06 | 1973-07-19 | Andre Cazenave | Durchscheinende verkleidung zur imitation von massivem stein |
EP0267997A1 (en) | 1986-11-20 | 1988-05-25 | Michael N. Moufarrege | Process for producing mosaic articles |
JPH07100816A (ja) | 1993-09-30 | 1995-04-18 | Tajima Inc | ノンスリップ加工した人造石材および該人造石材の製造法 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3420925A (en) * | 1966-06-21 | 1969-01-07 | Ahmed N Sharif | Method of fabricating a panel |
JPS5560076A (en) * | 1978-10-30 | 1980-05-06 | Shikoku Chem | Manufacture of floor artificial slab |
JPH01122403A (ja) * | 1987-11-07 | 1989-05-15 | Osaka Gas Co Ltd | 象眼状人造石 |
-
1999
- 1999-02-09 IT IT1999FI000028A patent/IT1310007B1/it active
-
2000
- 2000-02-07 WO PCT/IT2000/000036 patent/WO2000047427A1/en active IP Right Grant
- 2000-02-07 AU AU26888/00A patent/AU757515B2/en not_active Ceased
- 2000-02-07 EP EP00905265A patent/EP1161353B1/en not_active Expired - Lifetime
- 2000-02-07 US US09/913,011 patent/US6699415B1/en not_active Expired - Fee Related
- 2000-02-07 ES ES00905265T patent/ES2188506T3/es not_active Expired - Lifetime
- 2000-02-07 CA CA002361488A patent/CA2361488C/en not_active Expired - Fee Related
- 2000-02-07 TR TR2001/02260T patent/TR200102260T2/xx unknown
- 2000-02-07 PT PT00905265T patent/PT1161353E/pt unknown
- 2000-02-07 DE DE60001306T patent/DE60001306T2/de not_active Expired - Lifetime
- 2000-02-07 AT AT00905265T patent/ATE231798T1/de active
- 2000-02-07 RU RU2001124822/12A patent/RU2234422C2/ru not_active IP Right Cessation
- 2000-02-07 CN CN00803584A patent/CN1123456C/zh not_active Expired - Fee Related
-
2002
- 2002-05-31 HK HK02104061.4A patent/HK1042456B/zh not_active IP Right Cessation
-
2003
- 2003-10-30 US US10/697,212 patent/US6951679B2/en not_active Expired - Fee Related
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3170808A (en) * | 1958-12-09 | 1965-02-23 | Armstrong Cork Co | Method of fabricating a tessellated surface covering |
US3324213A (en) * | 1959-10-16 | 1967-06-06 | Anfi As | Method of making decorative articles |
US3344011A (en) * | 1964-11-02 | 1967-09-26 | Goozner Murray | Terrazzo tile |
US3378617A (en) * | 1965-02-24 | 1968-04-16 | Elmendorf Armin | Method of facing building products with exposed mineral granules |
DE2300674A1 (de) | 1972-01-06 | 1973-07-19 | Andre Cazenave | Durchscheinende verkleidung zur imitation von massivem stein |
EP0267997A1 (en) | 1986-11-20 | 1988-05-25 | Michael N. Moufarrege | Process for producing mosaic articles |
JPH07100816A (ja) | 1993-09-30 | 1995-04-18 | Tajima Inc | ノンスリップ加工した人造石材および該人造石材の製造法 |
Non-Patent Citations (2)
Title |
---|
Shikoku Chemical Industries Co. Ltd. 1980 Produce Artificial Stone Plate Floor . . . Database WPI, Section Ch, Week 198024. |
Shikoku Chemical Industries Co. Ltd. 1989 Clay Artificial Stone Build Contain . . . Database WPI, Section Ch, Week 198925. |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20060003155A1 (en) * | 2005-07-08 | 2006-01-05 | Stonefaux, Llc | Composite core stiffened structures for lamination and tiling |
US20090277127A1 (en) * | 2008-05-08 | 2009-11-12 | Single Eagle, Inc. | Decorative aggregate concrete surface preparation process |
Also Published As
Publication number | Publication date |
---|---|
ATE231798T1 (de) | 2003-02-15 |
ITFI990028A0 (it) | 1999-02-09 |
IT1310007B1 (it) | 2002-02-05 |
CN1340006A (zh) | 2002-03-13 |
PT1161353E (pt) | 2003-04-30 |
HK1042456B (zh) | 2004-03-05 |
US6951679B2 (en) | 2005-10-04 |
DE60001306T2 (de) | 2003-10-23 |
ITFI990028A1 (it) | 2000-08-09 |
CA2361488A1 (en) | 2000-08-17 |
RU2234422C2 (ru) | 2004-08-20 |
ES2188506T3 (es) | 2003-07-01 |
DE60001306D1 (de) | 2003-03-06 |
CA2361488C (en) | 2009-05-19 |
US20040091670A1 (en) | 2004-05-13 |
EP1161353A1 (en) | 2001-12-12 |
EP1161353B1 (en) | 2003-01-29 |
AU757515B2 (en) | 2003-02-20 |
HK1042456A1 (en) | 2002-08-16 |
WO2000047427A1 (en) | 2000-08-17 |
CN1123456C (zh) | 2003-10-08 |
AU2688800A (en) | 2000-08-29 |
TR200102260T2 (tr) | 2002-02-21 |
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