US6165245A - Foliar fertilizer and method for using the same - Google Patents

Foliar fertilizer and method for using the same Download PDF

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US6165245A
US6165245A US09/149,930 US14993098A US6165245A US 6165245 A US6165245 A US 6165245A US 14993098 A US14993098 A US 14993098A US 6165245 A US6165245 A US 6165245A
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ppm
composition
pyridoxine
amount ranging
folic acid
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Thomas T. Yamashita
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Priority to US09/149,930 priority Critical patent/US6165245A/en
Priority to AU55804/99A priority patent/AU5580499A/en
Priority to MXPA01002538A priority patent/MXPA01002538A/en
Priority to PCT/US1999/019156 priority patent/WO2000013502A1/en
Priority to ARP990104546A priority patent/AR020417A1/en
Priority to PE1999000909A priority patent/PE20001174A1/en
Priority to EG113499A priority patent/EG21708A/en
Priority to US09/669,259 priority patent/US6475258B1/en
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F11/00Other organic fertilisers
    • C05F11/10Fertilisers containing plant vitamins or hormones
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00Fertilisers characterised by their form
    • C05G5/20Liquid fertilisers
    • C05G5/23Solutions

Definitions

  • the field of this invention is fertilizers.
  • Fertilizers are materials that are used to supply elements needed for plant nutrition. Fertilizer materials may be in the form of solids, semi-solids, slurry suspensions, pure liquids, aqueous solutions and gases. Fertilizing materials may be introduced into a plant's environment in a number of different ways, including through addition to the soil, through application directly to a plant's foliage, and the like. The use of fertilizers is critical to commercial agriculture as fertilizers are essential to correct natural deficiencies and/or replace components in soil.
  • a fertilizer directly to the foliage of a plant, i.e. to use a foliar fertilizer.
  • a foliar fertilizer Such instances include situations where a given soil has characteristics such that the transport properties of nutrients through the soil are poor.
  • the use of a foliar fertilizing composition overcomes the soil disadvantages.
  • U.S. Patents of interest include: U.S. Pat. Nos. 4,473,648; 4,652,294; 4,952,229; 5,549,729; 5,582,627 and 5,696,094. Also of interest are JP 68-022206 and EP 161395.
  • references of interest include: Berrie, "The Effect of Sucrose Sprays on the Growth of Tomato,” Physiologia Plantarum (1960) 13: 9-19; Brasher et al., "Foliar Nutrition Sprays on Vegetable Crops” Bullentin No.
  • the subject compositions are aqueous solutions that include at least one coenzyme, where the coenzyme(s) is preferably a vitamin B, and more preferably at least one of, and in many embodiments both of, folic acid (vitamin Bc) and pyridoxine (vitamin B 6 ).
  • the subject fertilizing compositions may further include at least one of a carbohydrate source, a complexing agent and a preservative. The subject compositions find use in methods of enhancing plant growth through foliar application.
  • the subject compositions are aqueous solutions of at least one coenzyme, where the coenzyme(s) is preferably a vitamin B, and more preferably at least one of, and many cases both of, folic acid and pyridoxine.
  • the subject compositions may also include one or more of the following agents: (a) a carbohydrate source; (b) a complexing agent; and (c) a preservative.
  • the subject compositions find use in methods of enhancing plant growth where the compositions are applied to the foliage of plants, i.e. the subject compositions find use as foliar fertilizers.
  • the compositions will be described first followed by a discussion of methods for their use.
  • compositions used as foliar fertilizers in the subject methods are aqueous compositions that include at least one coenzyme.
  • Coenzymes of interest include: biotin, vitamin B compounds, inositol, etc.
  • the coenzyme is a vitamin B.
  • vitamin B is meant a water soluble vitamin which is generally a member of the vitamin B complex.
  • vitamin B 1 thiamine
  • vitamin B 1 disulfide thiamine disulfide
  • vitamin B 1 propyl disulfide thiamine propyl disulfide
  • prosultiamine vitamin B 2
  • vitamin B 2 phosphate riboflavin monophosphate
  • vitamin B 3 nicotinamide, niacin, nicotinic acid
  • vitamin B 4 adenine
  • vitamin B 5 pantothenic acid
  • vitamin B 6 hydrochloride pyridoxine hydrochloride
  • vitamin B 12 cyanobolamin
  • vitamin B 12r vitamin B 12 -Co(II)
  • vitamin B 12 coenzyme cobamamide
  • the foliar fertilizer composition may include one or more different vitamin B compounds, preferably the composition includes one or two different vitamin B compounds, where the vitamin B compounds are preferably folic acid and pyridoxine, where the foliar fertilizer composition may include just one of, or both of, folic acid and pyridoxine.
  • the amount of each of these coenzymes will be effective to enhance the rate of growth of the plant to which the composition is applied.
  • the amount of folic acid i.e. N-[4[[(2-Amino-1,4-dihydro-4-oxo-6-pteridinyl)methyl]amino]benzoyl]-L-glutamic acid, PGA, liver Lactobacillus casei factor; vitamin Bc; vitamin M, folsaure, cytofol; folacin, foldine, foliamin, foliacet, folipac, folettes, folsan, folvite, inafolic and millafol) will range from about 0.50 to 20, usually from about 0.50 to 10 and more usually from about 1.0 to 5.0 ppm w/w, where in many embodiments the preferred range in the composition that is applied to foliage is from about 1.0 to 3.0 ppm w/w, and more preferably from about 1.0 to 2.0 ppm.
  • the preferred range in the composition that is applied to foliage is from about 1.0 to 3.0 ppm w/w, and more preferably
  • the amount of pyridoxine or vitamin B 6 (e.g. from pyridoxine hydrochloride, 5-hydroxy-6-methyl-3,4-pyridinedimethanol hydrochloride; pyridoxol hydrochloride, vitamin B 6 hydrochloride, pyridoxinium chloride, adermine, hydrochloride, bonasanit, hexabione hydrochloride, hexabetalin, hexavibex, pyridipea, pyridox, becilan, benadon, hexermin, campovitron 6, hexabion ) will range from about 0.50 to 20, usually from about 0.50 to 10 and more usually from about 1.0 to 5.0 ppm w/w, where in many embodiments the preferred range in the composition that is applied to foliage is from about 1.0 to 3.0 ppm w/w, and more preferably from about 1.0 to 2.0 ppm.
  • pyridoxine or vitamin B 6 e.g. from pyridox
  • the foliar fertilizer composition includes both of the above coenzymes, where the amounts of each enzyme are the same as those described above, such that the total coenzyme amount (i.e. the amount of both of the above coenzymes together) in the composition ranges from about 1.0 to 40, usually from about 1.0 to 20 and more usually from about 2.0 to 10 ppm w/w, where in many embodiments the preferred range in the composition that is applied to foliage is from about 2.0 to 6.0 ppm w/w, and more preferably from about 2.0 to 4.0 ppm.
  • the foliar fertilizer composition may further include a carbohydrate source.
  • a carbohydrate source Any convenient carbohydrate source may be employed, where suitable carbohydrates that may be present in the solution include: monosaccharides, including 4 carbon (e.g. erythrose, threose, erythrulose), 5 carbon (e.g. ribose, arabinose, xylose, lyxose, ribulose, xylulose) and 6 carbon (e.g.
  • alfose alfose, altrose, glucose, mannose, gulose, idose, galactose, talose, psicose, fructose, sorbose, tagatose) monosaccharides, as well as disaccharides thereof, e.g. sucrose, lactose, maltose etc., and derivatives thereof, e.g. mannitol, sorbitol etc.; where in many embodiments the carbohydrate will be one or more of a carbohydrate selected from the group consisting of glucose, fructose, sucrose, galactose, lactose, sorbitol, and mannitol.
  • the total amount of carbohydrate in the foliar fertilizer composition e.g. combined amount of the disparate types of carbohydrates present in the composition, will generally range from about 10,000 to 900,000, usually from about 10,000 to 850,000 and more usually from about 10,000 to 500,000 ppm w/w, where in many embodiments the amount will range form about 10,000 to 600,000 and more usually from about 50,000 to 250,000 ppm w/w.
  • the subject foliar compositions may further include one or more complexing agents, where by "complexing agent” is meant a chelating agent, i.e. an agent that is capable of complexing with a metal ion.
  • Complexing agents of interest include: humic acid, fulvic acid, ulmic acid, citric acid, amino acids, nucleic acids, lignosulfonates, e.g. Ca--, K--, Na--, and ammonium lignosulfonates, EDTA, EDDA, EDDHA, HEDTA, CDTA, PTPA, NTA and the like.
  • the total amount of complexing agent in the foliar fertilizer composition e.g.
  • the combined amount of the disparate types of complexing agents present in the composition will generally range from about 100 to 100,000, usually from about 100 to 75,000 and more usually from about 100 to 50,000 ppm w/w, where in many embodiments the amount will range form about 100 to 60,000 and more usually from about 1000 to 50,000 ppm w/w.
  • the foliar fertilizer composition may further include a preservative agent.
  • preservative agents of interest include: proprionic acid, acetic acid, potassium sorbate, tartaric acid, malic acid and the like, where the amount of preservative in the composition will typically range from about 100 to 20,000, usually from about 100 to 10,000 and more usually from about 100 to 5,000 ppm w/w.
  • the above foliar fertilizer compositions are prepared by combining water with the various agents under conditions sufficient to produce an aqueous solution containing the various agents.
  • the water that is used to produce the subject compositions may be tap water obtained from any convenient water source, e.g. a municipal water district, where the water may be purified or otherwise treated, e.g. to remove certain undesirable agents that may be initially present therein.
  • the various agents to be solubilized in the water to produce the foliar fertilizer composition may be obtained from any convenient source, e.g. commercial vendor.
  • the carbohydrate component may be derived from a commercially available carbohydrate source, such as high fructose corn syrup, etc.
  • a concentrated or parent composition may first be produced, which parent composition or mix is then diluted with water, usually at least about 5 fold, more usually at least about 10 fold and often at least about 20 fold, in order to obtain the final composition that is suitable for foliar application.
  • the total coenzyme component will typically range from about 1 to 100, usually from about 1 to 50 and more usually from about 1 to 10 (to provide for a concentration ranging from about 0.5 to 20, usually 0.5 to 10 and more usually 1.0 to 5.0 ppm w/w upon dilution as described supra, page 4);
  • the total carbohydrate source component will typically range from about 100,000 to 900,000, usually from about 100,000 to 700,000 and more usually from about 100,000 to 850,000 ;
  • the total complexing agent component will typically range from about 100 to 100,000, usually from about 100 to 75,000 and more usually from about 100 to 50,000; while the total preservative component will typically range from about 100 to 20,000, usually from about 100 to 16,000 and more usually from about 100 to 5,000.
  • the foliar fertilizer composition is contacted with at least a portion of the foliage of the plant for which growth is to be enhanced.
  • contact is meant that the aqueous fertilizer composition is placed on the surface of the foliage of the plant(s) to be treated, where the term “foliage” is used broadly to encompass not only the leaves of the plant, but every other part of the plant that is not underground, i.e. below the soil surface, such that the term “foliage” includes leaves, stems, flowers, fruit, etc.
  • Contact may be by any convenient methods, including spraying, applying etc.
  • the amount of aqueous composition that is used during any one application will vary greatly depending on the nature of the plant, the nature of the composition, the environmental conditions, etc. Where crops are treated with the subject compositions, the amount that is applied based on acreage is generally at least about 0.25 to 10 gal per acre, usually at least about 0.25 to 5 gal per acre, and more usually at least about 0.25 to 2.5 gal per acre, where the amount that is applied may be as high as 10 gal per acre or higher, but will usually not exceed about 5 gal per acre.
  • the foliar fertilizer composition may be applied more than once over a given period of time.
  • the fertilizer composition may be applied daily, weekly, every two weeks, monthly etc.
  • the subject methods also include a dilution step, in which water is combined with the concentrate in order to reduce the amount of agent in the composition.
  • This dilution step will comprise introducing a sufficient amount of water to the concentrate to obtain at least about a 5 fold dilution, usually at least about a 10 fold dilution, and in many instances at least about a 20 fold dilution.
  • the subject methods result in an enhancement of growth of the plant that is treated, as compared to a control.
  • enhancement of growth is meant that over a set period of time, the treated plant attains a higher total mass than the control.
  • the amount of enhancement will typically be at least about 5%, usually at least about 10% and more usually at least about 25%, where in many embodiments the amount of enhancement may be 50% or greater. In many embodiments, the amount of enhancement will be at least about 100%.
  • a variety of different plants may be treated according to the subject methods, where such plants include both crop and ornamental plants.
  • a representative list of plants that may be treated according to the subject invention is provided in Table 1, infra.
  • a 1 ppm folic acid aqueous solution (FA 1 ppm) was prepared by combining 1 mg folic acid with 1 L tap water (obtained from the laboratory tap, Tulock Calif. municipal water supply).
  • a 2 ppm folic acid aqueous solution (FA 2 ppm) was prepared by combining 2 mg (amount) folic acid with 1 L tap water.
  • Rutger's tomato seedlings were sprayed with either tap water, the 1 ppm folic acid composition or the 2 ppm folic acid composition at 14 day intervals for 2 months beginning at the 4 th leaf stage. 4 sprays were applied over the 2 month period. Plants were then cut at the soil line and air dried for 72 hours. The results are provided in Table 1 below. Weights of plants are expressed in grams.
  • a 1 ppm pyridoxine solution (P 1 ppm) was prepared by combining 1 mg pyridoxine hydrochloride with 1 L tap water.
  • a 2 ppm pyridoxine aqueous solution (P 2 ppm) was prepared by combining 2 mg pyridoxine with 1 L tap water.
  • Rutger's tomato seedlings were sprayed with either tap water, the 1 ppm pyridoxine composition or the 2 ppm pyridoxine composition at 14 day intervals for 2 months beginning at the 4 th leaf stage. 4 sprays were applied over the 2 month period. The plants were then cut at the soil line and air dried for 72 hours. The results are provided in Table 2 below. Weights of plants are expressed in grams.
  • An aqueous solution (FA& P@1) having 1 ppm folic acid and 1 ppm pyridoxine was prepared in a manner analogous to that described above.
  • an aqueous solution (FA&P@2) having 2 ppm folic acid and 2 ppm pyridoxine was prepared.
  • Rutger's tomato seedlings were sprayed with either tap water, the FA& P@1 composition or the FA& P@2 composition at 14 day intervals for 2 months beginning at the 4 th leaf stage. 4 sprays were applied over the 2 month period. The plants were then cut at the soil line and air dried for 72 hours. The results are provided in Table 3 below. Weights of plants are expressed in grams.
  • composition Having Both Pyridoxine and Folic Acid, a Carbohydrate, and a Complexing Agent.
  • Rutger's tomato seedlings were sprayed with either tap water or the resultant fertilizer composition (fert.) at 14 day intervals for 2 months beginning at the 4 th leaf stage. 4 sprays were applied over the 2 month period. The plants were then cut at the soil line and air dried for 72 hours. The results are provided in Table 4 below. Weights of plants are expressed in grams
  • the subject fertilizer compositions are relatively simple formulations in that they include a minimum of agents, and are readily prepared. Despite their simplicity, the subject compositions provide for substantial plant growth enhancement.

Abstract

Foliar fertilizer compositions and methods for their use are provided. The subject compositions are aqueous solutions of at least one coenzyme, where the coenzyme(s) is preferably a vitamin B, and more preferably folic acid and/or pyridoxine, where in many preferred embodiments the compositions include both folic acid and pyridoxine. The subject compositions may further include at least one of a carbohydrate source, a complexing agent and a preservative. The subject foliar fertilizer compositions find use in enhancing the growth of a variety of plants through foliar application.

Description

TECHNICAL FIELD
The field of this invention is fertilizers.
BACKGROUND OF THE INVENTION
Fertilizers are materials that are used to supply elements needed for plant nutrition. Fertilizer materials may be in the form of solids, semi-solids, slurry suspensions, pure liquids, aqueous solutions and gases. Fertilizing materials may be introduced into a plant's environment in a number of different ways, including through addition to the soil, through application directly to a plant's foliage, and the like. The use of fertilizers is critical to commercial agriculture as fertilizers are essential to correct natural deficiencies and/or replace components in soil.
In many instances, it is beneficial to apply a fertilizer directly to the foliage of a plant, i.e. to use a foliar fertilizer. Such instances include situations where a given soil has characteristics such that the transport properties of nutrients through the soil are poor. In such instances, the use of a foliar fertilizing composition overcomes the soil disadvantages.
As such, a number of different foliar fertilizer compositions have been developed and/or used with a variety of different types of crops.
Despite the number of different foliar fertilizers that have been developed, there is a continued need to develop new compositions. Of particular interest would be the development of fertilizer compositions that include a minimum of different components, preferably naturally occurring components, where such compositions nonetheless provide for significant enhancement in plant growth.
Relevant Literature
U.S. Patents of interest include: U.S. Pat. Nos. 4,473,648; 4,652,294; 4,952,229; 5,549,729; 5,582,627 and 5,696,094. Also of interest are JP 68-022206 and EP 161395.
References of interest include: Berrie, "The Effect of Sucrose Sprays on the Growth of Tomato," Physiologia Plantarum (1960) 13: 9-19; Brasher et al., "Foliar Nutrition Sprays on Vegetable Crops" Bullentin No. 295, (April 1953)(University of Delaware, Newark Del.); Klinker et al., "Effect of Foliar Applications of Urea, Sucrose, and Dextrose on Tomato Yield and Quality," Bulletin 595 (April 1953)(Kentucky Agricultural Experiment Station)(University of Kentucky); Mederski et al., "Foliar Fertilization of Plant Crops," Research Circulation (1956) Ohio Agricultural Experimentation Station; and Went et al., "Growth Response to Tomato Plants of Applied Sucrose," American J. Botany (1948) 35: 93-106.
SUMMARY OF THE INVENTION
Foliar fertilizing compositions and methods for their use are provided. The subject compositions are aqueous solutions that include at least one coenzyme, where the coenzyme(s) is preferably a vitamin B, and more preferably at least one of, and in many embodiments both of, folic acid (vitamin Bc) and pyridoxine (vitamin B6). The subject fertilizing compositions may further include at least one of a carbohydrate source, a complexing agent and a preservative. The subject compositions find use in methods of enhancing plant growth through foliar application.
DESCRIPTION OF THE SPECIFIC EMBODIMENTS
Methods and compositions for enhancing plant growth are provided. The subject compositions are aqueous solutions of at least one coenzyme, where the coenzyme(s) is preferably a vitamin B, and more preferably at least one of, and many cases both of, folic acid and pyridoxine. The subject compositions may also include one or more of the following agents: (a) a carbohydrate source; (b) a complexing agent; and (c) a preservative. The subject compositions find use in methods of enhancing plant growth where the compositions are applied to the foliage of plants, i.e. the subject compositions find use as foliar fertilizers. In further describing the subject invention, the compositions will be described first followed by a discussion of methods for their use.
Before the subject invention is further described, it is to be understood that the invention is not limited to the particular embodiments of the invention described below, as variations of the particular embodiments may be made and still fall within the scope of the appended claims. It is also to be understood that the terminology employed is for the purpose of describing particular embodiments, and is not intended to be limiting. Instead, the scope of the present invention will be established by the appended claims.
In this specification and the appended claims, the singular forms "a," "an," and "the" include plural reference unless the context clearly dictates otherwise. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood to one of ordinary skill in the art to which this invention belongs.
The compositions used as foliar fertilizers in the subject methods are aqueous compositions that include at least one coenzyme. Coenzymes of interest include: biotin, vitamin B compounds, inositol, etc. In preferred embodiments, the coenzyme is a vitamin B. By vitamin B is meant a water soluble vitamin which is generally a member of the vitamin B complex. Specific vitamin B compounds of interest include: vitamin B1 (thiamine); vitamin B1 disulfide (thiamine disulfide); vitamin B1 propyl disulfide (thiamine propyl disulfide; prosultiamine); vitamin B2 (riboflavin); vitamin B2 phosphate (riboflavin monophosphate); vitamin B3 (nicotinamide, niacin, nicotinic acid); vitamin B4 (adenine); vitamin B5 (pantothenic acid); vitamin B6 hydrochloride (pyridoxine hydrochloride); vitamin B12 (cyanobolamin); vitamin B12r (vitamin B12 -Co(II)); vitamin B12 coenzyme (cobamamide); vitamin B12a ; vitamin B12b ; vitamin B12c ; vitamin B12d ; vitamin B12p ; vitamin B12s ; vitamin B13 (orotic acid); vitamin Bx (p-aminobenzoic acid, PABA); and vitamin Bc (folic acid).
While the foliar fertilizer composition may include one or more different vitamin B compounds, preferably the composition includes one or two different vitamin B compounds, where the vitamin B compounds are preferably folic acid and pyridoxine, where the foliar fertilizer composition may include just one of, or both of, folic acid and pyridoxine. The amount of each of these coenzymes will be effective to enhance the rate of growth of the plant to which the composition is applied.
In preferred embodiments in which folic acid and/or pyridoxine are the vitamin B compounds, the amount of folic acid (i.e. N-[4[[(2-Amino-1,4-dihydro-4-oxo-6-pteridinyl)methyl]amino]benzoyl]-L-glutamic acid, PGA, liver Lactobacillus casei factor; vitamin Bc; vitamin M, folsaure, cytofol; folacin, foldine, foliamin, foliacet, folipac, folettes, folsan, folvite, inafolic and millafol) will range from about 0.50 to 20, usually from about 0.50 to 10 and more usually from about 1.0 to 5.0 ppm w/w, where in many embodiments the preferred range in the composition that is applied to foliage is from about 1.0 to 3.0 ppm w/w, and more preferably from about 1.0 to 2.0 ppm. Generally, the amount of pyridoxine or vitamin B6 (e.g. from pyridoxine hydrochloride, 5-hydroxy-6-methyl-3,4-pyridinedimethanol hydrochloride; pyridoxol hydrochloride, vitamin B6 hydrochloride, pyridoxinium chloride, adermine, hydrochloride, bonasanit, hexabione hydrochloride, hexabetalin, hexavibex, pyridipea, pyridox, becilan, benadon, hexermin, campovitron 6, hexabion ) will range from about 0.50 to 20, usually from about 0.50 to 10 and more usually from about 1.0 to 5.0 ppm w/w, where in many embodiments the preferred range in the composition that is applied to foliage is from about 1.0 to 3.0 ppm w/w, and more preferably from about 1.0 to 2.0 ppm. As mentioned above, in many embodiments of the invention the foliar fertilizer composition includes both of the above coenzymes, where the amounts of each enzyme are the same as those described above, such that the total coenzyme amount (i.e. the amount of both of the above coenzymes together) in the composition ranges from about 1.0 to 40, usually from about 1.0 to 20 and more usually from about 2.0 to 10 ppm w/w, where in many embodiments the preferred range in the composition that is applied to foliage is from about 2.0 to 6.0 ppm w/w, and more preferably from about 2.0 to 4.0 ppm.
In addition to the above coenzymes, the foliar fertilizer composition may further include a carbohydrate source. Any convenient carbohydrate source may be employed, where suitable carbohydrates that may be present in the solution include: monosaccharides, including 4 carbon (e.g. erythrose, threose, erythrulose), 5 carbon (e.g. ribose, arabinose, xylose, lyxose, ribulose, xylulose) and 6 carbon (e.g. alfose, altrose, glucose, mannose, gulose, idose, galactose, talose, psicose, fructose, sorbose, tagatose) monosaccharides, as well as disaccharides thereof, e.g. sucrose, lactose, maltose etc., and derivatives thereof, e.g. mannitol, sorbitol etc.; where in many embodiments the carbohydrate will be one or more of a carbohydrate selected from the group consisting of glucose, fructose, sucrose, galactose, lactose, sorbitol, and mannitol. The total amount of carbohydrate in the foliar fertilizer composition, e.g. combined amount of the disparate types of carbohydrates present in the composition, will generally range from about 10,000 to 900,000, usually from about 10,000 to 850,000 and more usually from about 10,000 to 500,000 ppm w/w, where in many embodiments the amount will range form about 10,000 to 600,000 and more usually from about 50,000 to 250,000 ppm w/w.
The subject foliar compositions may further include one or more complexing agents, where by "complexing agent" is meant a chelating agent, i.e. an agent that is capable of complexing with a metal ion. Complexing agents of interest include: humic acid, fulvic acid, ulmic acid, citric acid, amino acids, nucleic acids, lignosulfonates, e.g. Ca--, K--, Na--, and ammonium lignosulfonates, EDTA, EDDA, EDDHA, HEDTA, CDTA, PTPA, NTA and the like. The total amount of complexing agent in the foliar fertilizer composition, e.g. combined amount of the disparate types of complexing agents present in the composition, will generally range from about 100 to 100,000, usually from about 100 to 75,000 and more usually from about 100 to 50,000 ppm w/w, where in many embodiments the amount will range form about 100 to 60,000 and more usually from about 1000 to 50,000 ppm w/w.
In addition to the above components, the foliar fertilizer composition may further include a preservative agent. While any convenient preservative agent may be employed, preservative agents of interest include: proprionic acid, acetic acid, potassium sorbate, tartaric acid, malic acid and the like, where the amount of preservative in the composition will typically range from about 100 to 20,000, usually from about 100 to 10,000 and more usually from about 100 to 5,000 ppm w/w.
The above foliar fertilizer compositions are prepared by combining water with the various agents under conditions sufficient to produce an aqueous solution containing the various agents. The water that is used to produce the subject compositions may be tap water obtained from any convenient water source, e.g. a municipal water district, where the water may be purified or otherwise treated, e.g. to remove certain undesirable agents that may be initially present therein. The various agents to be solubilized in the water to produce the foliar fertilizer composition may be obtained from any convenient source, e.g. commercial vendor. For example, the carbohydrate component may be derived from a commercially available carbohydrate source, such as high fructose corn syrup, etc.
In preparing the subject aqueous foliar fertilizer compositions, a concentrated or parent composition may first be produced, which parent composition or mix is then diluted with water, usually at least about 5 fold, more usually at least about 10 fold and often at least about 20 fold, in order to obtain the final composition that is suitable for foliar application. In such parent compositions or concentrates, the total coenzyme component will typically range from about 1 to 100, usually from about 1 to 50 and more usually from about 1 to 10 (to provide for a concentration ranging from about 0.5 to 20, usually 0.5 to 10 and more usually 1.0 to 5.0 ppm w/w upon dilution as described supra, page 4); the total carbohydrate source component will typically range from about 100,000 to 900,000, usually from about 100,000 to 700,000 and more usually from about 100,000 to 850,000 ; the total complexing agent component will typically range from about 100 to 100,000, usually from about 100 to 75,000 and more usually from about 100 to 50,000; while the total preservative component will typically range from about 100 to 20,000, usually from about 100 to 16,000 and more usually from about 100 to 5,000.
In practicing the subject methods, the foliar fertilizer composition is contacted with at least a portion of the foliage of the plant for which growth is to be enhanced. By contact is meant that the aqueous fertilizer composition is placed on the surface of the foliage of the plant(s) to be treated, where the term "foliage" is used broadly to encompass not only the leaves of the plant, but every other part of the plant that is not underground, i.e. below the soil surface, such that the term "foliage" includes leaves, stems, flowers, fruit, etc. Contact may be by any convenient methods, including spraying, applying etc.
The amount of aqueous composition that is used during any one application will vary greatly depending on the nature of the plant, the nature of the composition, the environmental conditions, etc. Where crops are treated with the subject compositions, the amount that is applied based on acreage is generally at least about 0.25 to 10 gal per acre, usually at least about 0.25 to 5 gal per acre, and more usually at least about 0.25 to 2.5 gal per acre, where the amount that is applied may be as high as 10 gal per acre or higher, but will usually not exceed about 5 gal per acre.
Depending on the nature of the plant, the nature of the composition, and the environmental conditions, as well as other factors, the foliar fertilizer composition may be applied more than once over a given period of time. As such, the fertilizer composition may be applied daily, weekly, every two weeks, monthly etc.
Where one starts with a parent mix or concentrate, as described above, the subject methods also include a dilution step, in which water is combined with the concentrate in order to reduce the amount of agent in the composition. This dilution step will comprise introducing a sufficient amount of water to the concentrate to obtain at least about a 5 fold dilution, usually at least about a 10 fold dilution, and in many instances at least about a 20 fold dilution.
The subject methods, i.e. foliar application of the aqueous composition, result in an enhancement of growth of the plant that is treated, as compared to a control. By enhancement of growth is meant that over a set period of time, the treated plant attains a higher total mass than the control. The amount of enhancement will typically be at least about 5%, usually at least about 10% and more usually at least about 25%, where in many embodiments the amount of enhancement may be 50% or greater. In many embodiments, the amount of enhancement will be at least about 100%.
A variety of different plants may be treated according to the subject methods, where such plants include both crop and ornamental plants. A representative list of plants that may be treated according to the subject invention is provided in Table 1, infra.
The following is offered by way of illustration and not by way of limitation.
EXPERIMENTAL
I. Folic Acid Composition
A 1 ppm folic acid aqueous solution (FA 1 ppm) was prepared by combining 1 mg folic acid with 1 L tap water (obtained from the laboratory tap, Tulock Calif. municipal water supply). Similarly, a 2 ppm folic acid aqueous solution (FA 2 ppm) was prepared by combining 2 mg (amount) folic acid with 1 L tap water.
Rutger's tomato seedlings were sprayed with either tap water, the 1 ppm folic acid composition or the 2 ppm folic acid composition at 14 day intervals for 2 months beginning at the 4th leaf stage. 4 sprays were applied over the 2 month period. Plants were then cut at the soil line and air dried for 72 hours. The results are provided in Table 1 below. Weights of plants are expressed in grams.
              TABLE 1                                                     
______________________________________                                    
       Replications                                                       
Treatment                                                                 
         1       2     3     4   5     Total                              
                                            Mean                          
______________________________________                                    
Control  58      64    45    55  60    282  56a                           
FA 1 ppm 71      74    69    79  75    368  74b                           
FA 2 ppm 73      80    78    78  74    383  77b                           
______________________________________                                    
 ppm expressed as w/w. Mean separation via Duncan's MRT @ 5%.             
II. Pyridoxine Composition
A 1 ppm pyridoxine solution (P 1 ppm) was prepared by combining 1 mg pyridoxine hydrochloride with 1 L tap water. Similarly, a 2 ppm pyridoxine aqueous solution (P 2 ppm) was prepared by combining 2 mg pyridoxine with 1 L tap water.
Rutger's tomato seedlings were sprayed with either tap water, the 1 ppm pyridoxine composition or the 2 ppm pyridoxine composition at 14 day intervals for 2 months beginning at the 4th leaf stage. 4 sprays were applied over the 2 month period. The plants were then cut at the soil line and air dried for 72 hours. The results are provided in Table 2 below. Weights of plants are expressed in grams.
              TABLE 2                                                     
______________________________________                                    
       Replications                                                       
Treatment                                                                 
         1       2     3     4   5     Total                              
                                            Mean                          
______________________________________                                    
Control  54      58    62    51  59    284  57a                           
P 1 ppm  73      74    71    67  65    350  70b                           
P 2 ppm  77      73    78    70  68    366  73b                           
______________________________________                                    
 ppm expressed as w/w. Mean separation via Duncan's MRT @ 5%.             
III. Composition Having Both Pyridoxine and Folic Acid.
An aqueous solution (FA& P@1) having 1 ppm folic acid and 1 ppm pyridoxine was prepared in a manner analogous to that described above. Similarly, an aqueous solution (FA&P@2) having 2 ppm folic acid and 2 ppm pyridoxine was prepared.
Rutger's tomato seedlings were sprayed with either tap water, the FA& P@1 composition or the FA& P@2 composition at 14 day intervals for 2 months beginning at the 4th leaf stage. 4 sprays were applied over the 2 month period. The plants were then cut at the soil line and air dried for 72 hours. The results are provided in Table 3 below. Weights of plants are expressed in grams.
              TABLE 3                                                     
______________________________________                                    
       Replications                                                       
Treatment                                                                 
         1       2     3     4   5     Total                              
                                            Mean                          
______________________________________                                    
Control  55      60    50    53  58    276  55a                           
FA&P@1   81      85    77    89  92    424  85b                           
FA&P@2   90      92    86    95  89    452  90b                           
______________________________________                                    
 ppm expressed as w/w. Mean separation via Duncan's MRT @ 5%.             
IV. Composition Having Both Pyridoxine and Folic Acid, a Carbohydrate, and a Complexing Agent.
An aqueous solution having 1 ppm folic acid, 1 ppm pyridoxine, 7,000 ppm sucrose, 100 ppm fulvic acid and 100 ppm citric acid was prepared as follows:
______________________________________                                    
Material    Source          Amount/L                                      
______________________________________                                    
Folic Acid  Pteroylglutamic Acid                                          
                              1      mg                                   
Pyridoxine  Pyridoxine Hydrochloride                                      
                              1      mg                                   
Sucrose     Table Sugar       7      g                                    
Fulvic Acid 2% Fulvic Acid    5      ml                                   
Citric Acid Citric Acid Monohydrate                                       
                              109    mg                                   
______________________________________                                    
Rutger's tomato seedlings were sprayed with either tap water or the resultant fertilizer composition (fert.) at 14 day intervals for 2 months beginning at the 4th leaf stage. 4 sprays were applied over the 2 month period. The plants were then cut at the soil line and air dried for 72 hours. The results are provided in Table 4 below. Weights of plants are expressed in grams
              TABLE 4                                                     
______________________________________                                    
       Replications                                                       
Treatment                                                                 
       1       2      3     4     5     Total                             
                                             Mean                         
______________________________________                                    
Control                                                                   
        53      62     55    61    63   294   59a                         
fert   105     115    134   126   145   625  125b                         
______________________________________                                    
 ppm expressed as w/w. Mean separation via Duncan's MRT @ 5%.             
                                  TABLE 1                                 
__________________________________________________________________________
VEGETABLE CROPS                                                           
          FRUIT & NUT CROPS                                               
                       FIELD CROPS                                        
                               MISCELLANEOUS CROPS                        
__________________________________________________________________________
Artichoke Pome  Apple  Alfalfa Avocado                                    
Asparagus       Pear   Barley  Breadfruit                                 
Balsam Pear     Quince Beans   Cashew                                     
Beet      Stone:                                                          
                Almond Buckwheat                                          
                               Date                                       
Broccoli        Apricot                                                   
                       Canola  Fig                                        
Brussels Sprout Cherry Corn    Maracuja                                   
Cabbage         Nectarine                                                 
                       Cotton  Olive                                      
Cauliflower     Peach  Crambe                                             
Celery          Plum   Flax                                               
Chard           Pluot  Millet                                             
Chayote         Prune  Oats                                               
Chinese Cabbage                                                           
          Nuts: Black Walnuts                                             
                       Peanuts                                            
Collards        Brazil Nuts                                               
                       Rapeweed                                           
Cowpeas         Cashews                                                   
                       Red Clover                                         
Cucumber        Coconuts                                                  
                       Rice                                               
Cucurbits (group)                                                         
                Filberts                                                  
                       Rye                                                
Eggplant        Hazel Nuts                                                
                       Safflower                                          
Endive          Hickory Nuts                                              
                       Sorghum                                            
Garlic          Macadamia                                                 
                       Soybeans                                           
Gherkin         Pecan  Sugar Beets                                        
Gourds          Pistachio                                                 
                       Sugar Cane                                         
Kale            Walnuts                                                   
                       Sunflower                                          
Kohlrabi  Misc Nuts.-                                                     
                Acorns Tobacco                                            
Leeks           Beechnuts                                                 
                       Wheat                                              
Lettuce         Chestnuts                                                 
                       Wild Rice                                          
Melons          Hackberry                                                 
Mustards        Locust Bean                                               
Okra            Oysternuts                                                
Onions          Peanuts                                                   
Parsley         Pignolia                                                  
Peas            Wingnut                                                   
Peppers   Citrus:                                                         
                Grapefruit                                                
Rhubarb         Lemon                                                     
Scallions       Lime                                                      
Shallots        Orange                                                    
Spinach         Pomelo                                                    
Squash          Tangerine                                                 
Tomato    Small Fruit:                                                    
                Blueberries                                               
                Brambles                                                  
                Cranberries                                               
                Currants                                                  
                Gooseberries                                              
                Grapes                                                    
                Litchi                                                    
                Mango                                                     
                Papaya                                                    
                Pineapple                                                 
                Pomegranate                                               
__________________________________________________________________________
TURFGRASS      PERENNIAL ORNAMENTALS                                      
__________________________________________________________________________
African Bermudagrass                                                      
               Acanthus   Dodecatheon                                     
                                   Nepeta                                 
Annual Bluegrass                                                          
               Achillea   Doronicum                                       
                                   Oenothera                              
Annual Ryegrass                                                           
               Aconitum   Echinacea                                       
                                   Opuntia                                
Bahiagrass     Aegopodium Echinops Paeonia                                
Bermudagrass   Ajuga      Epimedium                                       
                                   Papaver                                
Blue Couchgrass                                                           
               Alcea      Eremurus Patrinia                               
Blue Grama     Alchemilla Erigeron Penstemon                              
Bradley Bluegrass                                                         
               Allium     Eryngium Perovskia                              
Bradley Bermudagrass                                                      
               Amsonia    Erythronium                                     
                                   Phlox                                  
Buffalograss   Anaphalis  Eupatorium                                      
                                   Physostegia                            
Centipedegrass Anchusa    Euphorbia                                       
                                   Platycodon                             
Canada Bluegrasss                                                         
               Anemone    Filipendula                                     
                                   Polemonium                             
Chewings Fescue                                                           
               Anthemis   Fritillaria                                     
                                   Polygonatum                            
Colonial Bentgrass                                                        
               Aquilegia  Gaillardia                                      
                                   Polygonum                              
Common Carpetgrass                                                        
               Arabis     Galium   Potentilla                             
Common Timothy Arenaria   Gaura    Primula                                
Creeping Bentgrass                                                        
               Arisaema   Gentiana Pulmonaria                             
Creeping Red Fescue                                                       
               Armeria    Geranium Ranunculus                             
Crested Wheatgrass                                                        
               Artemisia  Geum     Rodgersia                              
Hard Fescue    Arum       Gillenia Rudbeckia                              
Italian Ryegrass                                                          
               Aruncus    Gladiolus                                       
                                   Ruta                                   
Japanese Lawngrass                                                        
               Asarum     Gypsophila                                      
                                   Salvia                                 
Kentucky Bluegrass                                                        
               Asclepias  Helenium Santolina                              
Kikuyugrass    Aster      Helianthus                                      
                                   Saponaria                              
Magennis Bermudagrass                                                     
               Astilbe    Heliopsis                                       
                                   Scabiosa                               
Manilagrass    Aubrieta   Helleborus                                      
                                   Sedum                                  
Mascarenegrass Aurinia    Hemerocallis                                    
                                   Senecio                                
Meadow Fescue  Babtisia   Hesperis Sidalcea                               
Redtop         Begonia    Heuchera Silene                                 
Rough Bluegrass                                                           
               Belamcanda Heucherella                                     
                                   Sisrynchium                            
Saint Augustinegrass                                                      
               Bergenia   Hibiscus Smilacina                              
Saltwater Couch                                                           
               Boltonia   Hosta    Solidago                               
Sheep Fescue   Brunnera,  Houttuynia                                      
                                   Stachys                                
Slender Creeping Red Fescue                                               
               Caltha     Iberis   Stokesia                               
Smooth Bromegrass                                                         
               Campanula  Iris     Tanacetum                              
Tall Fescue    Catananche Kniphofia                                       
                                   Thalictrum                             
Tropical Carpetgrass                                                      
               Centaurea  Lamiastrum                                      
                                   Thermopsis                             
Turf Timothy   Centranthus                                                
                          Lamium   Tiarella                               
Velvet Bentgrass                                                          
               Cerastium  Lavandula                                       
                                   Tradescantia                           
Weeping Alkaligrass                                                       
               Ceratostigma                                               
                          Liatris  Tricyrtis                              
               Chelone    Ligularia                                       
                                   Trillium                               
               Chrysanthemum                                              
                          Lilium   Trollius                               
               Chysopsis  Limonium Tulipa                                 
               Cimicifuga Linum    Uvularia                               
               Clematis   Liriope  Verbascum                              
               Convallaria                                                
                          Lobelia  Verbena                                
               Coreopsis  Lupinus  Ver6nica                               
               Crocosmia  Lychnis  Vinca                                  
               Crocus     Lycoris  Viola                                  
               Delphinium Lysimachia                                      
                                   Yucca                                  
               Dianthus   Lythrum                                         
               Dicentra   Maiva                                           
               Dictamnus  Mertensia                                       
               Digitalis  Monarda                                         
               Disporum   Narcissus                                       
__________________________________________________________________________
ORNAMENTAL TREES                                                          
__________________________________________________________________________
Abies (Fir)   Eugenia (Surinam Cherry)                                    
                              Podocarpus (Yew Pine)                       
Acacia        Fagus (Beech)   Populus (Poplar)                            
Acer (Maple)  Feijoa (P Guava)                                            
                              Prosopis (Mesquite)                         
Acrocarpus (PI Cedar)                                                     
              Ficus (Fig)     Prunus                                      
Aesculus (R Horsechestnut)                                                
              Frnklinia       Pseudotsuga (Douglas Fir)                   
Agathis (Kauri)                                                           
              Fraxinus (Ash)  Pseudopanax                                 
Agonis (Peppermint Tree)                                                  
              Geijera (A Willow)                                          
                              Pyrus (Pear)                                
Ailanthus (Tree-Of-Heaven)                                                
              Ginkgo          Quercus (Oak)                               
Albizia (Silk Tree)                                                       
              Gleditsia (Honey Locust)                                    
                              Quillaja (Soapbark Tree)                    
Alnus (Alder) Grevillea (Silk Oak)                                        
                              Rhamnus (Italian Buckthorn)                 
Amelanchier   Gymnocladus (K Coffee Tree)                                 
                              Rhus (Sumac)                                
Angophora (Gum Myrtle)                                                    
              Hakea (Sea Urchin)                                          
                              Robinia (Locust)                            
Araucaria     Halesia (Snowdrop)                                          
                              Salix (Willow)                              
Arbutus (Madrone)                                                         
              Harpephyllum (Kaffir Plum)                                  
                              Sambucus (Elderberry)                       
Bauhinia      Harpullia       Sapium (Chinese Tallow)                     
Betula (Birch)                                                            
              Jacaranda       Sassafras                                   
Bombax (Silk-Cotton Tree)                                                 
              Ilex (Holly)    Sequoia (Redwood)                           
Brachychiton  Juniperus (Juniper)                                         
                              Sciadopitys (Umbrella Tree)                 
Callistemon (Bottlebrush)                                                 
              Koelreuteria    Schinus (Peppers)                           
Calocedrus (Incense Cedar)                                                
              Laburnum (G Chain Tree)                                     
                              Sophora (Japanese Pagoda)                   
Calodendrum (Cape Chestnut)                                               
              Lagerstroemia (Crape Myrtle)                                
                              Sorbus (Mountain Ash)                       
Carpinus (E. Hornbeam)                                                    
              Lagunaria (Primrose Tree)                                   
                              Stenocarpus (Firewheel)                     
Carya (Pecan) Lafix (Larch)   Stewartia                                   
Cassia        Laurus (Sweet Bay)                                          
                              Styrax (Japanese Snowbell)                  
Castanospermum                                                            
              Leptospermum (Tea Tree)                                     
                              Tabebuia                                    
Casuarina (Beefwood)                                                      
              Leucodendron (Silver Tree)                                  
                              Talauma                                     
Catalpa       Ligustrum (Glossy Privet)                                   
                              Tamarix (Athel Tree)                        
Cedrela (Cigar Box Tree)                                                  
              Liquidambar (A Sweet Gum)                                   
                              Taxodium (Bald Cypress)                     
Cedrus (Cedar)                                                            
              Liriodendron (Tulip Tree)                                   
                              Thuja (Arborvitae)                          
Celtis (Hackberry)                                                        
              Lyonothamnus    Tilia (Linden)                              
Ceratonia (Carob)                                                         
              Magnolia        Tipuana (Tipu Tree)                         
Cercidiphyllum (Katsura)                                                  
              Malus (Crabapple)                                           
                              Tristania                                   
Cercis (E. Redbud)                                                        
              Maclura (Osage Orange)                                      
                              Tsuga (Hemlock)                             
Chamaecyparis (F Cypress)                                                 
              Markhamia       Ulmus (Elm)                                 
Chilopsis (Desert Willow)                                                 
              Maytenus (Mayten Tree)                                      
                              Umbellularia (California Bay)               
Chionanthus (Fringe Tree)                                                 
              Melaleuca       Vitex (NZ Chaste Tree)                      
Chorisia (Floss-Silk Tree)                                                
              Melia (Chinaberry)                                          
                              Zelkova (Sawleaf)                           
Cinnamomum (Camphor)                                                      
              Metasequoia (Dawn Redwood)                                  
                              Zizyphus (Chinese Jujube)                   
Cladrastis (Yellowwood)                                                   
              Metrosideros                                                
Clethra (Lily-Of-The-Valley)                                              
              Michelia                                                    
Comus (Dogwood)                                                           
              Morus (White Mulberry)                                      
Corynocarpus (NZ Laurel)                                                  
              Myoporum                                                    
Cotinus (Smoke Tree)                                                      
              Myrica (PW Myrtle)                                          
Crataegus (Hawthorn)                                                      
              Nyssa (Black Tulepo)                                        
Cryptomeria (J Cedar)                                                     
              Olea (Olive)                                                
Cunninghamia (China Fir)                                                  
              Oxydendrum (Sorrel Tree)                                    
Cuponiopsis (Carrotwood)                                                  
              Parkinsonia (Jerusalem Thorn)                               
Cupressocyparis                                                           
              Phellodendron (Amur Cork)                                   
Cupressus (Cypress)                                                       
              Phytolacca (Umbu)                                           
Cydonia (Quince)                                                          
              Picea (Spruce)                                              
Dalbergia (Sissoo)                                                        
              Pinus (Pine)                                                
Elaeagnus (R Olive)                                                       
              Pistacia (Pistachio)                                        
Efiobotrya (Loquat)                                                       
              Pittosporum                                                 
Erythrina (Coral Tree)                                                    
              Platanus (Sycamore)                                         
Eucalyptus    Platycladus (O Arborvitae)                                  
__________________________________________________________________________
ORNAMENTAL HOUSEPLANTS                                                    
__________________________________________________________________________
Abutilon                                                                  
       Celosia Echinocactus                                               
                       Kohleria                                           
                              Platycerium                                 
                                     Torenia                              
Acacia Celsia  Echinocereus                                               
                       Lachenalia                                         
                              Pittosporum                                 
                                     Tradescantia                         
Acalypha                                                                  
       Cephalocereus                                                      
               Echium  Lantana                                            
                              Plectranthus                                
                                     Trichocereus                         
Achimenes                                                                 
       Ceropegia                                                          
               Epidendrum                                                 
                       Lapageria                                          
                              Pleione                                     
                                     Tropaeolum                           
Adiantum                                                                  
       Cestrum Epiphyllum                                                 
                       Leptospermum                                       
                              Plumbago                                    
                                     Tulipa                               
Adromischus                                                               
       Chamaecereus                                                       
               Episcia Leucadendron                                       
                              Polianthes                                  
                                     Vallota                              
Aechmea                                                                   
       Chamaedorea                                                        
               Erica   Lilium Polypodium                                  
                                     Veltheimia                           
Aeoniumn                                                                  
       Chamaerops                                                         
               Erythrina                                                  
                       Limonium                                           
                              Primula                                     
                                     Venidoarctotis                       
Aeschynanthus                                                             
       Chirita Eucalyptus                                                 
                       Lippia Prostanthera                                
                                     Venidium                             
Agapanthus                                                                
       Chlorophytum                                                       
               Eucharis                                                   
                       Lycaste                                            
                              Protea Vinca                                
Agave  Chorizema                                                          
               Eucomis Malvaviscus                                        
                              Punica Vriesea                              
Aglaonema                                                                 
       Chrysanthemum                                                      
               Eupatorium                                                 
                       Mammillaria                                        
                              Rebutia                                     
                                     Vuylstekeara                         
Allamanda                                                                 
       Cineraria                                                          
               Euphorbia                                                  
                       Mandevilla                                         
                              Rechsteineria                               
                                     Wilsonara                            
Aloe   Cissus  Exacum  Maranta                                            
                              Reinwardtia                                 
                                     Zantedeschia                         
Alonsoa                                                                   
       Citrus  Fabiana Martynia                                           
                              Rhipsalidopsis                              
                                     Zebrina                              
Amaryllis                                                                 
       Cleistocactus                                                      
               Fatshedera                                                 
                       Maurandia                                          
                              Rhododendron                                
                                     Zephyranthes                         
Ananas Clerodendrum                                                       
               Fatsia  Maxillaria                                         
                              Roicissus                                   
Anchusa                                                                   
       Clianthus                                                          
               Faucaria                                                   
                       Medinilla                                          
                              Ricinus                                     
Anthurium                                                                 
       Clivia  Ferocactus                                                 
                       Miltonia                                           
                              Rochea                                      
Aphelandra                                                                
       Cobaea  Ficus   Mitraria                                           
                              Rondeletia                                  
Aporocactus                                                               
       Coccoloba                                                          
               Fittonia                                                   
                       Momordica                                          
                              Ruellia                                     
Araucaria                                                                 
       Codiaeum                                                           
               Freesia Monstera                                           
                              Saintpaulia                                 
Arctotis                                                                  
       Coelogyne                                                          
               Fuchsia Moraea Salpiglossis                                
Ardisia                                                                   
       Coleus  Gardenia                                                   
                       Musa   Salvinia                                    
Aristochia                                                                
       Columnea                                                           
               Gasteria                                                   
                       Mutisia                                            
                              Sanchezia                                   
Arum   Cordyline                                                          
               Geogenanthus                                               
                       Narcissus                                          
                              Sansevieria                                 
Asclepias                                                                 
       Coronilla                                                          
               Gerbera Neoregelia                                         
                              Sarracenia                                  
Asparagus                                                                 
       Coryphantha                                                        
               Gladioius                                                  
                       Nepenthes                                          
                              Saxifraga                                   
Aspidistra                                                                
       Crassula                                                           
               Globba  Nephrolepis                                        
                              Schizanthus                                 
Asplenium                                                                 
       Crinum  Gloriosa                                                   
                       Nerine Schlumbergera                               
Astrophytum                                                               
       Crocus  Guzmania                                                   
                       Nerium Scindapsus                                  
Asystasia                                                                 
       Crossandra                                                         
               Gymno-calycium                                             
                       Nidularium                                         
                              Sedum                                       
Babiana                                                                   
       Cryptanthus                                                        
               Gynura  Nopalxchia                                         
                              Selaginella                                 
Begonia                                                                   
       Ctenanthe                                                          
               Haemanthus                                                 
                       Nymphaea                                           
                              Senecio                                     
Beloperone                                                                
       Cunonia Haworthia                                                  
                       Odontoglossum                                      
                              Ssinningia                                  
Billbergia                                                                
       Cuphea  Hedera  Odontonia                                          
                              Smithiantha                                 
Blechnum                                                                  
       Cupressus                                                          
               Hedychium                                                  
                       Ophiopogon                                         
                              Solanum                                     
Bougainvil                                                                
       Cycas   Heliocereus                                                
                       Oplismenus                                         
                              Sollya                                      
Bouvardia                                                                 
       Cyclamen                                                           
               Heliotropium                                               
                       Opuntia                                            
                              Sonerila                                    
Brunfelsia                                                                
       Cymbidium                                                          
               Hibiscus                                                   
                       Ornithogalum                                       
                              Sparmannia                                  
Byophyllum                                                                
       Cyperus Hippeastrum                                                
                       Pachystachys                                       
                              Sphathiphylium                              
Caladium                                                                  
       Datura  Hoya    Pamianthe                                          
                              Sphaeralcea                                 
Calandrinia                                                               
       Dendrobium                                                         
               Hyacinthus                                                 
                       Paphiopedilum                                      
                              Stapelia                                    
Calathea                                                                  
       Dianella                                                           
               Hydrangea                                                  
                       Parodia                                            
                              Stephanotix                                 
Calceolaria                                                               
       Dianthus                                                           
               Hymonocallis                                               
                       Passiflora                                         
                              Strelitzia                                  
Callicarpa                                                                
       Dicentra                                                           
               Hypoestes                                                  
                       Pelargonium                                        
                              Streptocarpus                               
Callistemon                                                               
       Dicksonia                                                          
               Impatiens                                                  
                       Pellaea                                            
                              Streptosolen                                
Camelia                                                                   
       Dieffenbachia                                                      
               Hypocyrta                                                  
                       Pellionia                                          
                              Sstrobilanthes                              
Campanula                                                                 
       Dionaea Impatiens                                                  
                       Pentas Tecomaria                                   
Canna  Dipladenia                                                         
               Ipomoea Peperomia                                          
                              Telopea                                     
Cantua Dizygotheca                                                        
               Ixia    Peristrophe                                        
                              Tetrastigma                                 
Capsicum                                                                  
       Dracaena                                                           
               Jacobinia                                                  
                       Philesia                                           
                              Thunbergia                                  
Caralluma                                                                 
       Drosera Jasminurn                                                  
                       Philodendron                                       
                              Tibouchina                                  
Casia  Eccremocarpus                                                      
               Jovellana                                                  
                       Phoenix                                            
                              Tigridia                                    
Cattleya                                                                  
       Echeveria                                                          
               Kalanchoe                                                  
                       Pilea  Tillandsia                                  
__________________________________________________________________________
It is evident from the above results and discussion that useful fertilizer compositions capable of enhancing plant growth are provided. The subject fertilizer compositions are relatively simple formulations in that they include a minimum of agents, and are readily prepared. Despite their simplicity, the subject compositions provide for substantial plant growth enhancement.
All publications and patent applications cited in this specification are herein incorporated by reference as if each individual publication or patent application were specifically and individually indicated to be incorporated by reference. The citation of any publication is for its disclosure prior to the filing date and should not be construed as an admission that the present invention is not entitled to antedate such publication by virtue of prior invention.
Although the foregoing invention has been described in some detail by way of illustration and example for purposes of clarity of understanding, it is readily apparent to those of ordinary skill in the art in light of the teachings of this invention that certain changes and modifications may be made thereto without departing from the spirit or scope of the appended claims.

Claims (15)

What is claimed is:
1. A method for enhancing plant growth in a crop, said method consisting of:
applying to said crop at a rate of 0.25 to 10 gal/acre a fertilizing composition consisting of:
(a) water;
(b) folic acid;
(c) pyridoxine; and
(d) a carbohydrate source in an amount ranging from about 100,000 to 900,000 ppm w/w;
which composition after dilution of at least 20-fold has a folic acid concentration in an amount ranging from about 0.5 to 20 ppm and pyridoxine in an amount ranging from about 0.5 to 20 ppm;
said diltuted composition enhancing plant growth.
2. The method according to claim 1, wherein said carbohydrate source is a monosaccharide, disaccharide or derivative thereof.
3. The method according to claim 2, wherein said carbohydrate source is selected from the group consisting of glucose, fructose, sucrose, galactose, lactose, sorbitol, and mannitol.
4. The method according to claim 1, wherein said folic acid is present in said composition after dilution in an amount ranging from about 0.50 to 10 ppm w/w.
5. The method according to claim 1, wherein said pyridoxine is present in said composition after dilution in an amount ranging from about 0.50 to 10 ppm w/w.
6. A method for enhancing plant growth in a crop, said method consisting of:
applying to said crop at a rate of 0.25 to 10 gal/acre a fertilizing composition consisting of:
(a) water;
(b) folic acid;
(c) pyridoxine;
(d) a carbohydrate source in an amount ranging from about 100,000 to 900,000 ppm w/w; and
(e) a complexing agent
which composition after dilution of at least 20-fold has a folic acid concentration in an amount ranging from about 0.5 to 20 ppm and pyridoxine in an amount ranging from about 0.5 to 20 ppm;
said diltuted composition enhancing plant growth.
7. The method according to claim 6, wherein said carbohydrate source is a monosaccharide, disaccharide or derivative thereof.
8. The method according to claim 7, wherein said carbohydrate source is selected from the group consisting of glucose, fructose, sucrose, galactose, lactose, sorbitol, and mannitol.
9. The method according to claim 6, wherein said complexing agent is selected from the group consisting of: humic acid, fulvic acid, a lignosulfonate; and citric acid.
10. The method according to claim 6, wherein said folic acid is present in said composition after dilution in an amount ranging from about 0.50 to 10 ppm w/w.
11. The method according to claim 6, wherein said pyridoxine is present in said composition after dilution in an amount ranging from about 0.50 to 10 ppm w/w.
12. A method for enhancing plant growth in a crop, said method consisting of:
applying to said crop at a rate of 0.25 to 10 gal/acre a fertilizing composition consisting of:
(a) water;
(b) folic acid;
(c) pyridoxine;
(d) a carbohydrate source, wherein said carbohydrate source is present in said composition in an amount ranging from about 100.000 to 900,000 ppm w/w; and
(e) a complexing agent
which composition after dilution of at least 20-fold has a folic acid concentration in an amount ranging from about 1.0 to 5.0 ppm and pyridoxine in an amount ranging from about 1.0 to 5.0 ppm;
said diltuted composition enhancing plant growth.
13. The method according to claim 12, wherein said carbohydrate source is a monosaccharide, disaccharide or derivative thereof.
14. The method according to claim 13, wherein said carbohydrate source is selected from the group consisting of glucose, fructose, sucrose, galactose, lactose, sorbitol, and mannitol.
15. The method according to claim 12, wherein said complexing agent is selected from the group consisting of: humic acid, fulvic acid, a lignosulfonate; and citric acid.
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PCT/US1999/019156 WO2000013502A1 (en) 1998-09-09 1999-08-24 Foliar fertilizer and method for using the same
AU55804/99A AU5580499A (en) 1998-09-09 1999-08-24 Foliar fertilizer and method for using the same
ARP990104546A AR020417A1 (en) 1998-09-09 1999-09-09 FOLIAL FERTILIZER AND EMPLOYMENT METHOD.
PE1999000909A PE20001174A1 (en) 1998-09-09 1999-09-09 FOLIAL FERTILIZER AND METHOD OF USE
EG113499A EG21708A (en) 1998-09-09 1999-09-09 Method of improving plant growth using foliar fertilizer
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