US4405995A - Semiconductor memory drive - Google Patents
Semiconductor memory drive Download PDFInfo
- Publication number
- US4405995A US4405995A US06/295,617 US29561781A US4405995A US 4405995 A US4405995 A US 4405995A US 29561781 A US29561781 A US 29561781A US 4405995 A US4405995 A US 4405995A
- Authority
- US
- United States
- Prior art keywords
- gate electrode
- insulating layer
- electrode
- erasing
- semiconductor memory
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11C—STATIC STORES
- G11C16/00—Erasable programmable read-only memories
- G11C16/02—Erasable programmable read-only memories electrically programmable
- G11C16/04—Erasable programmable read-only memories electrically programmable using variable threshold transistors, e.g. FAMOS
- G11C16/0408—Erasable programmable read-only memories electrically programmable using variable threshold transistors, e.g. FAMOS comprising cells containing floating gate transistors
- G11C16/0416—Erasable programmable read-only memories electrically programmable using variable threshold transistors, e.g. FAMOS comprising cells containing floating gate transistors comprising cells containing a single floating gate transistor and no select transistor, e.g. UV EPROM
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D30/00—Field-effect transistors [FET]
- H10D30/60—Insulated-gate field-effect transistors [IGFET]
- H10D30/68—Floating-gate IGFETs
- H10D30/681—Floating-gate IGFETs having only two programming levels
Definitions
- the present invention relates to an improvement in a semiconductor memory device called an "EPROM” (erasable programmable read only memory).
- EPROM erasable programmable read only memory
- U.S. Pat. No. 3,825,946 discloses the EPROM device which can be charged or discharged electrically.
- a second gate and a third gate are adapted so as to cooperatively enable a discharge to take place from a floating gate due to avalanche injection through an insulating layer having a thickness of about 500 to 1,000 angstroms.
- a positive pulse of a high voltage e.g., approximately 35 volts is applied to the second gate, with the third gate and the substrate grounded.
- a positive pulse of a similarly high voltage is applied to the second and third gates, with the substrate grounded.
- application of a high voltage at a time during which the floating gate is charged and discharged is liable to cause a breakdown. If the floating gate is charged by applying a low voltage, no breakdown is caused even when a high voltage is applied to discharge the floating gate.
- two electrodes for high and low voltages, respectively, must be provided. If both a charge and a discharge of the floating gate is conducted at a relatively low voltage, reliability of the writing and erasing would be reduced.
- an improved semiconductor memory device which comprises a first gate electrode in an electrically floating state, at least a part of which confronts a channel region of a semiconductor device and which is separated by an insulating layer from the channel region. Also includes is a second gate electrode comprising a control electrode, at least a part of which confronts the first gate electrode and is separated by an insulating layer from the first gate electrode. Furthermore, a third gate electrode is included comprising an erasing electrode, at least a part of which confronts the first gate electrode and is separated by an insulating layer from the first gate electrode.
- Said insulating layer separating at least a part of the erasing electrode from the first gate electrode, has a thickness sufficient to allow the passage of charge from the first gate electrode to the erasing electrode through a tunneling effect, thereby discharging the first gate electrode.
- FIGS. 1A through 6A and 1B through 6B are diagrams illustrating manufacturing steps for one embodiment of the semiconductor memory device of the present invention.
- FIGS. 1A through 6A are top plan views showing a main part of the device and FIGS. 1B through 6B are cross-sectional views thereof.
- Boron ions (B + ) are injected in a silicon (Si) semiconductor substrate 1 in a dose of, for example, about 1 ⁇ 10 13 ions per cm 2 according to an ion implantation method to form a p + type channel cut region 2.
- Arsenic ions are injected in a dose of, for example, about 5 ⁇ 10 15 per cm 2 according to the ion implantation method to form an n + type region 3 for a line for a power power source Vss having a ground potential level.
- a silicon dioxide (SiO 2 ) field insulating layer 4 having a thickness of, for example, about 5,000 to about 10,000 A is formed, for example, according to a selective thermal oxidation method using a silicon nitride (Si 3 N 4 ) film mask. When the mask is removed, the surface of an active region of the substrate 1 is exposed.
- a first insulating layer 5 of silicon dioxide having a thickness of about 700 to about 1,000 A is formed on the exposed surface of the active region of the substrate 1, for example, according to the thermal oxidation method.
- a polycrystalline silicon layer 6, forming a first gate electrode having an electrically floating state, is formed in a thickness of about 4,000 to about 5,000 A, for example, according to a chemical vapor phase deposition method.
- a silicide of a refractory metal such as molybdenum silicide or tungsten silicide, may be used.
- the polycrystalline silicon layer 6 and the silicon dioxide insulating layer 5 are patterned according to a photolithographic technique.
- a second silicon dioxide insulating layer 7 having a thickness of about 800 to about 1,000 A is formed on the exposed surface of the active region of the substrate 1 and on the polycrystalline silicon layer 6, for example, according to the thermal oxidation method.
- the second polycrystalline silicon layer 8 and the second insulating layer 7 are patterned according to the photolithographic technique.
- the portion of the second silicon dioxide layer 7 formed on the polycrystalline silicon layer 6 in the above-mentioned step (7), which portion has not been covered with the polycrystalline silicon layer 8 in the above-mentioned step (8), is removed whereby a portion of the polycrystalline silicon layer 6 is exposed.
- a third insulating layer 9 of silicon dioxide is grown to a thickness of, for example, about 50 to about 300 A, according to the thermal oxidation method on the exposed surface of the polycrystalline silicon layer 8, on the exposed surface of the polycrystalline silicon layer 6 and on the exposed surface of the substrate 1.
- the third insulating layer 9 of silicon dioxide should have a thickness sufficient for the passage of electrons from the first polycrystalline silicon layer 6 (i.e., first gate electrode) to a third polycrystalline silicon layer 10 (i.e., an erasing or third electrode to be formed on the third insulating layer 9) through a tunneling effect.
- the tunnelling of the electrons discharging the first gate electrode 6, when the written information is erased in the resulting memory device.
- the thickness of the third insulating layer 9 should preferably be maintained at least at a part of a side wall 6' of the first polycrystalline silicon layer 6.
- Such thickness for the intended passage of electrons by the tunnel effect is usually in the range of from 50 to 300 A, more preferably from 100 to 200 A.
- a polycrystalline silicon layer 10 for the third gate electrode (i.e., the erasing electrode) is grown to a thickness of about 4,000 A according to the chemical vapor phase decomposition method.
- the polycrystalline silicon layer 10 and the third insulating layer 9 are patterned according to the photolithographic technique.
- Arsenic ions are injected according to the ion implantation method or other appropriate technique to form an n + type line region 11.
- An insulating layer 12 of phosphosilicate glass or silicon dioxide is formed with a thickness of, for example, about 1 micron according to the chemical vapor phase deposition method.
- the insulating layer 12 is patterned according to the photolithographic technique to form electrode contact windows 12A.
- An aluminum (Al) film having a thickness of, for example, about 1 micron is formed according to a vacuum evaporation deposition method, and the aluminum film is patterned according to the photolithographic technique to form a bit line electrode lead 13.
- FIGS. 6A and 6B a semiconductor memory device is obtained as illustrated in FIGS. 6A and 6B.
- this device one or more pairs of the first gate electrodes 6 and one or more pairs of the control electrodes 8 are disposed so that the two first gate electrodes 6 in each pair are symmetric to each other, relative to the erasing electrode 10; and the two control electrodes 8 in each pair are also symmetric to each other, relative to the erasing electrode 10.
- the device which has been fabricated according to the above procedures is operated as follows.
- the polycrystalline silicon layer 10 for the third gate electrode which acts as a charge-releasing gate or an erasing electrode, and the n + type region 3 acting, as a source region, are maintained at the same potential level (ground potential level).
- a positive high voltage is applied to the polycrystalline silicon layer 8 for the second gate electrode which acts as a control gate, whereby electrons are injected into the polycrystalline silicon layer 6 for the first floating gate electrode and the first floating gate electrode 6 is charged.
- the high voltage applied is usually in the range of from about 20 to about 30 volts, preferably from about 20 to about 25 volts.
- the polycrystalline silicon layer 10 for the third gate electrode which acts as a charge-releasing gate, is maintained at the ground potential level.
- a voltage of, for example, +5 V is applied to the polycrystalline silicon layer 8 forming the second gate electrode and a voltage of, for example, +1 V is applied to the aluminum lead 13, which acts as a bit line to read a difference of a threshold voltage (Vth) among respective memory cells.
- Vth threshold voltage
- the high voltage is applied to both the polycrystalline silicon layer 8, forming the second gate electrode which acts as a control gate, and the polycrystalline silicon layer 10, forming the third gate electrode which acts as a charge-releasing gate.
- the positive high voltage can also be applied only to the polycrystalline silicon layer 10 forming the third gate electrode.
- the application of the high voltage allows the charge accumulated in the polycrystalline silicon layer 6 for the first gate electrode to be released.
- the voltage applied in this erasing stage may be approximately the same as that applied in the above-mentioned writing stage, that is, usually in the range of from about 20 to about 30 volts, preferably from about 20 to about 25 volts.
- This release of charge from the polycrystalline silicon layer 6 forming the first gate electrode and the passing of the charge to the polycrystalline silicon layer 10, forming the third gate electrode, is accomplished by utilizing the tunnel effect.
- the tunnel effect is generated, because the intervening insulating layer 9 is very thin, that is, 50 to 300 A.
- an improved EPROM device comprising (i) a first gate electrode in an electrically floating state, at least a part of which confronts a channel region of a semiconductor substrate and which is separated by a thin insulating layer from the channel region; (ii) a second gate electrode (i.e., a control electrode), at least a part of which confronts the first gate electrode and is separated by a thin insulating layer from the first gate electrode; and (iii) a third gate electrode (i.e., an erasing electrode), at least a part of which confronts the first gate electrode (and, preferably, also the second gate electrode) and which is separated by a very thin insulating layer.
- charge accumulated in the first gate electrode i.e., the floating gate
- a relatively low voltage i.e., about 20 to about 30 volts
Landscapes
- Engineering & Computer Science (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Non-Volatile Memory (AREA)
- Semiconductor Memories (AREA)
Abstract
Description
Claims (10)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP55119213A JPS5743470A (en) | 1980-08-29 | 1980-08-29 | Semiconductor device |
| JP55-119213 | 1980-08-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US4405995A true US4405995A (en) | 1983-09-20 |
Family
ID=14755735
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US06/295,617 Expired - Lifetime US4405995A (en) | 1980-08-29 | 1981-08-24 | Semiconductor memory drive |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US4405995A (en) |
| EP (1) | EP0047153B1 (en) |
| JP (1) | JPS5743470A (en) |
| DE (1) | DE3168790D1 (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4853895A (en) * | 1987-11-30 | 1989-08-01 | Texas Instruments Incorporated | EEPROM including programming electrode extending through the control gate electrode |
| US4912676A (en) * | 1988-08-09 | 1990-03-27 | Texas Instruments, Incorporated | Erasable programmable memory |
| US4924437A (en) * | 1987-12-09 | 1990-05-08 | Texas Instruments Incorporated | Erasable programmable memory including buried diffusion source/drain lines and erase lines |
| EP0372614A1 (en) * | 1988-12-05 | 1990-06-13 | STMicroelectronics S.r.l. | Matrix of EPROM memory cells with a tablecloth structure having an improved capacitative ratio and a process for its manufacture |
| US4996668A (en) * | 1988-08-09 | 1991-02-26 | Texas Instruments Incorporated | Erasable programmable memory |
| US5117269A (en) * | 1989-03-09 | 1992-05-26 | Sgs-Thomson Microelectronics S.R.L. | Eprom memory array with crosspoint configuration |
| US5143860A (en) * | 1987-12-23 | 1992-09-01 | Texas Instruments Incorporated | High density EPROM fabricaiton method having sidewall floating gates |
| US5296396A (en) * | 1988-12-05 | 1994-03-22 | Sgs-Thomson Microelectronics S.R.L. | Matrix of EPROM memory cells with a tablecloth structure having an improved capacitative ratio and a process for its manufacture |
| DE4407248A1 (en) * | 1993-10-28 | 1995-05-04 | Gold Star Electronics | Flash EEPROM memory cell, memory device and method for forming the same |
| US5736443A (en) * | 1996-03-11 | 1998-04-07 | Hyundai Electronics Industries Co., Ltd. | Flash EEPROM cell and method of manufacturing the same |
| US9666850B2 (en) * | 2004-02-06 | 2017-05-30 | Polyplus Battery Company | Safety enhanced Li-ion and lithium metal battery cells having protected lithium electrodes with enhanced separator safety against dendrite shorting |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0053878B1 (en) * | 1980-12-08 | 1985-08-14 | Kabushiki Kaisha Toshiba | Semiconductor memory device |
| JPS57157573A (en) * | 1981-03-25 | 1982-09-29 | Fujitsu Ltd | Semiconductor non-volatile memory cell |
| US4861730A (en) * | 1988-01-25 | 1989-08-29 | Catalyst Semiconductor, Inc. | Process for making a high density split gate nonvolatile memory cell |
| US5095344A (en) * | 1988-06-08 | 1992-03-10 | Eliyahou Harari | Highly compact eprom and flash eeprom devices |
| US5168465A (en) * | 1988-06-08 | 1992-12-01 | Eliyahou Harari | Highly compact EPROM and flash EEPROM devices |
| US5268319A (en) * | 1988-06-08 | 1993-12-07 | Eliyahou Harari | Highly compact EPROM and flash EEPROM devices |
| JPH0287676A (en) * | 1988-09-26 | 1990-03-28 | Ricoh Co Ltd | Floating gate nonvolatile memory device |
| JP2515009B2 (en) * | 1989-01-13 | 1996-07-10 | 株式会社東芝 | Manufacturing method of nonvolatile semiconductor memory |
| US5036378A (en) * | 1989-11-01 | 1991-07-30 | At&T Bell Laboratories | Memory device |
| JPH085146B2 (en) * | 1990-09-29 | 1996-01-24 | 福山ゴム工業株式会社 | Rubber crawler manufacturing method |
| FR2693308B1 (en) * | 1992-07-03 | 1994-08-05 | Commissariat Energie Atomique | THREE-GRID EEPROM MEMORY AND MANUFACTURING METHOD THEREOF. |
| US5579259A (en) * | 1995-05-31 | 1996-11-26 | Sandisk Corporation | Low voltage erase of a flash EEPROM system having a common erase electrode for two individually erasable sectors |
| JPH1187539A (en) | 1997-09-04 | 1999-03-30 | Mitsubishi Electric Corp | Nonvolatile semiconductor memory device and method of manufacturing the same |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3825946A (en) * | 1971-01-15 | 1974-07-23 | Intel Corp | Electrically alterable floating gate device and method for altering same |
| US4161039A (en) * | 1976-12-15 | 1979-07-10 | Siemens Aktiengesellschaft | N-Channel storage FET |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52106275A (en) * | 1976-03-03 | 1977-09-06 | Nec Corp | Floating type nonvoltile semiconductor memory element |
| US4099196A (en) * | 1977-06-29 | 1978-07-04 | Intel Corporation | Triple layer polysilicon cell |
| US4203158A (en) * | 1978-02-24 | 1980-05-13 | Intel Corporation | Electrically programmable and erasable MOS floating gate memory device employing tunneling and method of fabricating same |
| US4274012A (en) * | 1979-01-24 | 1981-06-16 | Xicor, Inc. | Substrate coupled floating gate memory cell |
-
1980
- 1980-08-29 JP JP55119213A patent/JPS5743470A/en active Pending
-
1981
- 1981-08-24 US US06/295,617 patent/US4405995A/en not_active Expired - Lifetime
- 1981-08-28 DE DE8181303949T patent/DE3168790D1/en not_active Expired
- 1981-08-28 EP EP81303949A patent/EP0047153B1/en not_active Expired
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3825946A (en) * | 1971-01-15 | 1974-07-23 | Intel Corp | Electrically alterable floating gate device and method for altering same |
| US4161039A (en) * | 1976-12-15 | 1979-07-10 | Siemens Aktiengesellschaft | N-Channel storage FET |
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4853895A (en) * | 1987-11-30 | 1989-08-01 | Texas Instruments Incorporated | EEPROM including programming electrode extending through the control gate electrode |
| US4924437A (en) * | 1987-12-09 | 1990-05-08 | Texas Instruments Incorporated | Erasable programmable memory including buried diffusion source/drain lines and erase lines |
| US5143860A (en) * | 1987-12-23 | 1992-09-01 | Texas Instruments Incorporated | High density EPROM fabricaiton method having sidewall floating gates |
| US4912676A (en) * | 1988-08-09 | 1990-03-27 | Texas Instruments, Incorporated | Erasable programmable memory |
| US4996668A (en) * | 1988-08-09 | 1991-02-26 | Texas Instruments Incorporated | Erasable programmable memory |
| US5296396A (en) * | 1988-12-05 | 1994-03-22 | Sgs-Thomson Microelectronics S.R.L. | Matrix of EPROM memory cells with a tablecloth structure having an improved capacitative ratio and a process for its manufacture |
| US5160986A (en) * | 1988-12-05 | 1992-11-03 | Sgs-Thomson Microelectronics S.R.L. | Matrix of EPROM memory cells with a tablecloth structure having an improved capacitative ratio and a process for its manufacture |
| EP0372614A1 (en) * | 1988-12-05 | 1990-06-13 | STMicroelectronics S.r.l. | Matrix of EPROM memory cells with a tablecloth structure having an improved capacitative ratio and a process for its manufacture |
| US5475250A (en) * | 1988-12-05 | 1995-12-12 | Sgs-Thomson Microelectronics S.R.L. | Matrix of EPROM memory cells with a tablecloth structure having an improved capacitive ratio and a process for its manufacture |
| US5723351A (en) * | 1988-12-05 | 1998-03-03 | Sgs-Thomson Microelectronics S.R.L. | Method of making matrix of EPROM memory cell with a tablecloth structure having an improved capacitative ratio |
| US5117269A (en) * | 1989-03-09 | 1992-05-26 | Sgs-Thomson Microelectronics S.R.L. | Eprom memory array with crosspoint configuration |
| DE4407248B4 (en) * | 1993-10-28 | 2006-11-09 | Lg Semicon Co. Ltd., Cheongju | EEPROM flash memory cell and method of forming an EEPROM flash memory cell |
| DE4407248A1 (en) * | 1993-10-28 | 1995-05-04 | Gold Star Electronics | Flash EEPROM memory cell, memory device and method for forming the same |
| US5736443A (en) * | 1996-03-11 | 1998-04-07 | Hyundai Electronics Industries Co., Ltd. | Flash EEPROM cell and method of manufacturing the same |
| GB2311167B (en) * | 1996-03-11 | 2000-09-06 | Hyundai Electronics Ind | Flash EEPROM cell and method of manufacturing the same |
| US9666850B2 (en) * | 2004-02-06 | 2017-05-30 | Polyplus Battery Company | Safety enhanced Li-ion and lithium metal battery cells having protected lithium electrodes with enhanced separator safety against dendrite shorting |
| US10529971B2 (en) | 2004-02-06 | 2020-01-07 | Polyplus Battery Company | Safety enhanced li-ion and lithium metal battery cells having protected lithium electrodes with enhanced separator safety against dendrite shorting |
| US10916753B2 (en) | 2004-02-06 | 2021-02-09 | Polyplus Battery Company | Lithium metal—seawater battery cells having protected lithium electrodes |
| US11646472B2 (en) | 2004-02-06 | 2023-05-09 | Polyplus Battery Company | Making lithium metal—seawater battery cells having protected lithium electrodes |
Also Published As
| Publication number | Publication date |
|---|---|
| DE3168790D1 (en) | 1985-03-21 |
| EP0047153B1 (en) | 1985-02-06 |
| EP0047153A1 (en) | 1982-03-10 |
| JPS5743470A (en) | 1982-03-11 |
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