US3922511A - Specific gravity monitor - Google Patents

Specific gravity monitor Download PDF

Info

Publication number
US3922511A
US3922511A US356771A US35677173A US3922511A US 3922511 A US3922511 A US 3922511A US 356771 A US356771 A US 356771A US 35677173 A US35677173 A US 35677173A US 3922511 A US3922511 A US 3922511A
Authority
US
United States
Prior art keywords
float
specific gravity
solution
sleeve
sensor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US356771A
Other languages
English (en)
Inventor
Raymond A Letize
James A Johnson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
MacDermid Inc
Original Assignee
MacDermid Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by MacDermid Inc filed Critical MacDermid Inc
Priority to US356771A priority Critical patent/US3922511A/en
Priority to IL43928A priority patent/IL43928A0/xx
Priority to AU64107/74A priority patent/AU6410774A/en
Priority to IT48107/74A priority patent/IT1004311B/it
Priority to FR7403636A priority patent/FR2228248B3/fr
Priority to BE140649A priority patent/BE810725A/fr
Priority to NL7402366A priority patent/NL7402366A/xx
Priority to JP2131574A priority patent/JPS5425505B2/ja
Priority to DE2420496A priority patent/DE2420496C3/de
Application granted granted Critical
Publication of US3922511A publication Critical patent/US3922511A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N9/00—Investigating density or specific gravity of materials; Analysing materials by determining density or specific gravity
    • G01N9/10—Investigating density or specific gravity of materials; Analysing materials by determining density or specific gravity by observing bodies wholly or partially immersed in fluid materials
    • G01N9/12—Investigating density or specific gravity of materials; Analysing materials by determining density or specific gravity by observing bodies wholly or partially immersed in fluid materials by observing the depth of immersion of the bodies, e.g. hydrometers
    • G01N9/18—Special adaptations for indicating, recording, or control

Definitions

  • ABSTRACT Apparatus for sensing small changes in the specific gravity of a solution system undergoing change, whereby through periodic withdrawal and replenishment thereof to compensate for chemical reac tion taking place within the solution, the specific gravity can be maintained substantially uniform.
  • a portion of the solution is continuously moni tored for specific gravity by a float operated sensor whose effective density is equal to a predetermined minimum specific gravity condition, and whose float volume bears a predetermined minimum numerical ratio to the minimum predetermined specific gravity, the sensor being employed to control operation of a pump which simultaneously withdraws solution which has undergone reaction and reintroduces an equal vol ume of fresh solution to the reaction site.
  • FIG. 1 A first figure.
  • the invention is concerned with problems of maintaining specific gravity of a solution as nearly constant as possible under conditions where some portion of the solution is caused to react in a treatment site with a material introduced into the solution, thereby changing the solution composition and hence its specific gravity.
  • the problem is commonly encountered in metal etchant systems where an etchant solution is brought into contact with a metal object, as for removal of a portion of the metal, and in which periodic withdrawals of used etchant and replacement with fresh etchant are made in order to approximate a steady-state etching action on the metal.
  • portions of a copper foil cladding on a nonconductive substrate are temporarily masked to outline a desired circuit pattern, and the blank circuit board is then placed in an etching tank or more commonly in a spray etcher.
  • Etchant solution is pumped from a sump and sprayed over the surface of the board to dissolve away exposed copper foil. After rinsing the board, the temporary masking is removed, leaving a printed conductive circuit of the desired configuration on the nonconductive substrate.
  • metal etchants are in common use, including acid, neutral and alkaline agents.
  • typical etchants used are hydrochloric acid, ferric chloride, cupric chloride, ammonium persulfate, ammoniacal chlorite and ammoniacal cupric chloride.
  • the successful commercial operation of the etching cycle is highly etch-rate dependent, and the etch rate of course depends in turn on the composition of the etchant solution.
  • one of the principal objectives of the present invention is directed to providing a sensor device of the gravimetric type having substantially better response to changes of specific gravity of the etchant solution than has been available heretofore. It is a further objective of the invention to provide a sensor which is of simpli fied mechanical construction, free ofexposed mechanical joints, pivots or the like subject to corrosive attack, friction and thus having poor response. It is a further object to facilitate a means of adjusting the sensor so that it will be operative at any preselected specific grav ity value within a given range. It is yet another object to arrange all electrical components of the sensor so as to be totally and permanently sealed, yet enable changes to be made in the selected operating range of the sensor without disturbing the electrical portion of the sensor.
  • FIG. I is a schematic illustration of a typical copper etching system, such as a type commonly employed in producing printed circuit boards, in which a sensor of the invention is incorporated.
  • FIG. 2 is an enlarged view of one embodiment of the improved sensor unit, parts being shown broken away and in section to facilitate understanding;
  • FIG. 3 is a plan view. also partly in section, taken on line 3-3 of FIG. 2, showing details of the float element of the sensor unit.
  • FIG. 1 represents a continuous copper etching system of the type suitable for producing printed circuit boards from copper clad plastic substrate laminates.
  • Spray etcher 10 comprises a tank or etch chamber 12 through which circuit boards B are carried by conveyor 14 while an etchant solution is sprayed on them from a series of spray heads 16.
  • the etchant solution collects in a sump 18 at the bottom of chamber 12 and is recirculated continuously to spray head 16 by pump 20.
  • the level of etchant in sump 18 is kept substantially constant by outlet pipe 22. However periodic withdrawals of the etchant are made by one section of a two-section pump 24 connected into outlet pipe 22. The withdrawn solution is then pumped through suitable ducting 26 to a spent etchant collection tank 28. Simultaneously with such withdrawal, another section of pump 24 introduces an equal volume of fresh etch ant to the etch chamber from storage tank 30 through duct 32 and delivery nozzle 34. Actuation of pump 24 to provide the withdrawal of used etchant and delivery of fresh etchant is controlled automatically through an electrical control console 36 to which a specific gravity sensor 38 is connected by cable 40.
  • sensor 38 signals control unit 36 to activate dual pump 24 whenever the specific gravity of the solution increases above a predetermined value, and the pump continues to run until the sensor signals the control unit that the specific gravity of the solution has been lowered to another predetermined value, as the result of withdrawal of used etchant and replenishment with fresh etchant solution.
  • specific gravity sensor 38 comprises a cylindrical cage consisting in this case of a foraminous tubular outer wall 42 closed at its opposite ends by discs 44, 46.
  • the assembly of wall 42 and discs 44, 46 is held together by a central tubular sleeve 48 to provide a supporting structure for the operating members of the sensor.
  • One end of sleeve 48 is threaded into a threaded hole 50in lower end wall 46.
  • the upper end of sleeve 48 is similarly threaded through an aperture 52 in upper disc 44.
  • the upper end of the sleeve projects beyond end wall 44 and receives a washer and locking nut 54, 56, respectively.
  • This projecting upper end of sleeve 48 serves for attachment thereto of a standard water-tight electrical connector plug 58 to which the aforesaid cable 40 is connected.
  • Sleeve 48 is made of non-magnetic material, as for example extruded plastic tubing, and a conventional hermetically sealed magnetic reed switch 60 is received axially within the sleeve.
  • Reed switch 60 is supported at its lower end on a tubular spacer 62 which in turn is supported by a closure plug 64 threaded into the lower end of sleeve 48.
  • Electrical leads 66 are soldered to the respective projecting terminals of the reed members at each end of the switch, and these leads are connected to terminals in the upper end of the sleeve for engagement by complementary terminals of plug 58. As shown in FIG.
  • reed switch 60 is of the type in which the reed contacts 68 are normally spaced apart, in open-circuit condition, and the switch is adapted to close the electrical circuit whenever a magnetic field is disposed in surrounding relation to both reed members of the switch, causing them to be attracted toward each other against a normal spring bias. This completes the electrical circuit in which the switch is located, in this case the circuit of pump 24 causing it to run.
  • Sensor 38 includes a toroidal float 70 which is disposed about sleeve 48 as an axis.
  • Float 70 is hollow and as seen in FIGS. 2 and 3 is composed of inner and outer cylindrical walls 72, '74, respectively, which are held in concentrically spaced relation by annular plates 76, 78. These hermetically seal the ends of the float to form a closed chamber 80 in which a ring magnet 82 is suitably secured to the inner wall 72.
  • Inner wall 72 is of sufficiently larger diameter than sleeve 48 so that the float assembly 70 may slide up and down easily on the sleeve between discs 44, 46 in accordance with changes in the specific gravity of the solution being sensed.
  • a stop nut 84 provided on the lower end of sleeve 48 forms a rest on which float 70 is normally supported until its buoyancy becomes suffi- 4 cient to cause it to rise on the sleeve.
  • ring magnet 82 is brought into conjunction with the overlap of the reed members of switch 60, thereby causing them to be attracted together to close the elec trical circuit.
  • buoyancy of float is of course a function of the specific gravity of the solution in which the sensor unit is immersed, so that increases and decreases in specific gravity will cause rising and falling of float 70, respectively, within the limits of its cage.
  • the weight of float 70 can be changed by adding or subtracting granular material, such as lead shot 86 in chamber through access plug 88 provided in upper end plate 76 of the float.
  • granular material such as lead shot 86 in chamber through access plug 88 provided in upper end plate 76 of the float.
  • the senor In order to provide a sensitivity in sensor unit 38 which is adequate for achieving a virtual steady-state etching rate in the etchant system which has been de scribed before, the sensor is designed to be completely submersed in the sump 18 of an etching chamber. In addition the total weight of float member 70 is carefully correlated with the displacement volume of the float. It will be apparent, of course, that if float 70 is to sink into resting position on stop 84, as seen in FIG. 2, when the sensor unit 38 is submersed, the relationship between the weight of float unit 70 and its total volume must produce an effective density which is at least equivalent to or slightly greater than the specific gravity of the $0 lution.
  • the weight of the constant volume of liquid displaced by float 70 increases correspondingly, thus producing a net buoyancy effect upon the float.
  • the desired sensitivity of the sensor should be of an order which will detect a change of around 0.002 in specific gravity of solution. In accordance with the present invention, this can be achieved by correlating two factors.
  • the effective float density is equivalent to a predetermined minimum specific gravity of the solution to be sensed; and secondly, by designing the float volume (expressed in cubic centimeters) to bear a numerical ratio of at least 200:l to such preselected minimum specific gravity.
  • a float actuated sensor adapted for total submersion in a liquid whose specific gravity is subject to change, said sensor being responsive to such changes in specific gravity above a predetermined minimum value and comprising in combination a magnetically operated read switch, a toroidal float,
  • a permanent ring magnet carried by said float and effective to actuate said switch in certain positions of said float relative to said switch, and an axial support structure for said float,
  • said support structure comprising an elongated tubular sleeve of non-magnetic material, and disc members removably secured to opposite ends of said sleeve and projecting peripherally therefrom,
  • said float comprising a closed hollow toroid. and said ring magnet being fixedly secured therein in concentric relation therewith, said float and magnet being axially received on said sleeve in free sliding relation thereto between said disc members, and said read switch being mounted internally of said sleeve in stationary relation thereto and having conductors leading out through at least one of said disc members for connecting said switch to an external electric circuit said float and magnet having a displacement volume and combined weight to produce an effective density approximately equal to that of the liquid at said predetermined minimum specific gravity value.
  • said float further having an axial dimension substantially shorter than the length of said sleeve to allow sliding movement of the float to occur between said discs, said total displacement volume when expressed in cubic centimeters bearing a numerical ratio of at least 200:1 relative to said predetermined specific gravity value.

Landscapes

  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • ing And Chemical Polishing (AREA)
  • Manufacturing Of Printed Circuit Boards (AREA)
  • Level Indicators Using A Float (AREA)
US356771A 1973-05-03 1973-05-03 Specific gravity monitor Expired - Lifetime US3922511A (en)

Priority Applications (9)

Application Number Priority Date Filing Date Title
US356771A US3922511A (en) 1973-05-03 1973-05-03 Specific gravity monitor
IL43928A IL43928A0 (en) 1973-05-03 1973-12-28 Specific gravity monitoring apparatus
AU64107/74A AU6410774A (en) 1973-05-03 1974-01-02 Specific gravity monitor
IT48107/74A IT1004311B (it) 1973-05-03 1974-02-01 Dispositivo di verifica o misura continua della densita o peso speci fioo di soluzioni
FR7403636A FR2228248B3 (fr) 1973-05-03 1974-02-04
BE140649A BE810725A (fr) 1973-05-03 1974-02-07 Appareil de controle de la densite d'un liquide
NL7402366A NL7402366A (fr) 1973-05-03 1974-02-21
JP2131574A JPS5425505B2 (fr) 1973-05-03 1974-02-22
DE2420496A DE2420496C3 (de) 1973-05-03 1974-04-25 Schwimmerbetätigter Sensor zur Überwachung des spezifischen Gewichts einer Flüssigkeit

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US356771A US3922511A (en) 1973-05-03 1973-05-03 Specific gravity monitor

Publications (1)

Publication Number Publication Date
US3922511A true US3922511A (en) 1975-11-25

Family

ID=23402899

Family Applications (1)

Application Number Title Priority Date Filing Date
US356771A Expired - Lifetime US3922511A (en) 1973-05-03 1973-05-03 Specific gravity monitor

Country Status (9)

Country Link
US (1) US3922511A (fr)
JP (1) JPS5425505B2 (fr)
AU (1) AU6410774A (fr)
BE (1) BE810725A (fr)
DE (1) DE2420496C3 (fr)
FR (1) FR2228248B3 (fr)
IL (1) IL43928A0 (fr)
IT (1) IT1004311B (fr)
NL (1) NL7402366A (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS503690A (fr) * 1973-05-03 1975-01-16
US5008083A (en) * 1988-08-30 1991-04-16 The United States Of America As Represented By The United States Department Of Energy Apparatus for centrifugal separation of coal particles

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2078977A (en) * 1930-04-29 1937-05-04 Samiran David Fluid density responsive device
US2118558A (en) * 1935-08-16 1938-05-24 Ellvin T Hanson Control device for storage batteries
US2264038A (en) * 1940-06-14 1941-11-25 Gen Electric Permanent magnet containing titanium
US2845799A (en) * 1955-02-21 1958-08-05 Walter A Emanuel Rugged sensitive hydrometer
US3258968A (en) * 1963-10-02 1966-07-05 Stewart Warner Corp Liquid level indicating device
US3661652A (en) * 1969-08-18 1972-05-09 Oldham International Ltd Apparatus for indicating the density of a fluid

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3922511A (en) * 1973-05-03 1975-11-25 Macdermid Inc Specific gravity monitor

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2078977A (en) * 1930-04-29 1937-05-04 Samiran David Fluid density responsive device
US2118558A (en) * 1935-08-16 1938-05-24 Ellvin T Hanson Control device for storage batteries
US2264038A (en) * 1940-06-14 1941-11-25 Gen Electric Permanent magnet containing titanium
US2845799A (en) * 1955-02-21 1958-08-05 Walter A Emanuel Rugged sensitive hydrometer
US3258968A (en) * 1963-10-02 1966-07-05 Stewart Warner Corp Liquid level indicating device
US3661652A (en) * 1969-08-18 1972-05-09 Oldham International Ltd Apparatus for indicating the density of a fluid

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS503690A (fr) * 1973-05-03 1975-01-16
JPS5425505B2 (fr) * 1973-05-03 1979-08-28
US5008083A (en) * 1988-08-30 1991-04-16 The United States Of America As Represented By The United States Department Of Energy Apparatus for centrifugal separation of coal particles

Also Published As

Publication number Publication date
NL7402366A (fr) 1974-11-05
DE2420496B2 (de) 1978-01-19
IL43928A0 (en) 1974-03-14
JPS5425505B2 (fr) 1979-08-28
JPS503690A (fr) 1975-01-16
FR2228248A1 (fr) 1974-11-29
DE2420496C3 (de) 1978-09-21
DE2420496A1 (de) 1974-11-21
FR2228248B3 (fr) 1976-11-26
IT1004311B (it) 1976-07-10
AU6410774A (en) 1975-07-03
BE810725A (fr) 1974-08-07

Similar Documents

Publication Publication Date Title
KR100226178B1 (ko) 비금속성 기판에 금속 도금막을 적용하는 방법
US4395302A (en) Metal dissolution process using H2 O2 --H2 SO4 etchant
EP0564780A1 (fr) Méthode et dispositif pour maintenir stable une solution de placage sans courant
US3868485A (en) Density sensing probe switch with adjustable float
US3922511A (en) Specific gravity monitor
JPH022951B2 (fr)
KR100618250B1 (ko) 도금장치 및 전자부품 실장용 필름 캐리어 테이프의제조방법
WO1997041409A1 (fr) Appareil a recipient a niveau de liquide automatique
JPH05315331A (ja) 半導体装置の製造方法及び洗浄装置
CA2022400C (fr) Methode pour accroitre la resistance d'isolement dans les circuits imprimes
US5297428A (en) Salt level monitoring device
CN111458328B (zh) 一种检测印制电路板残留铜层分布的方法
US3409466A (en) Process for electrolessly plating lead on copper
US3992152A (en) Gold plating test procedure
CN114126257B (zh) 一种电路板及其制造方法
CN211452747U (zh) 液浸传感装置
CN219757459U (zh) 废水用液位检测装置及压滤系统
CN215572188U (zh) 一种气体分析仪的炉头冷却装置
SU1362962A1 (ru) Сигнализатор температуры нагрева жидкости
CN216206761U (zh) 一种油位传感器的干簧管装配结构
CN118250896A (zh) 基于Tenting的超密线路基板及其制作方法
CN205454250U (zh) 一种高效pcb板自动蚀刻装置
Morris The Use and Control of Ammoniacal Etchants
SU1008619A1 (ru) Устройство дл нанесени покрытий на детали
JPS5753647A (en) Detecting apparatus of dew condensation