US3919097A - Lubricant composition - Google Patents
Lubricant composition Download PDFInfo
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- US3919097A US3919097A US503686A US50368674A US3919097A US 3919097 A US3919097 A US 3919097A US 503686 A US503686 A US 503686A US 50368674 A US50368674 A US 50368674A US 3919097 A US3919097 A US 3919097A
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- lubricant composition
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- lubricant
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- oxyethylene
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/152—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen having a hydroxy group bound to a carbon atom of a six-membered aromatic ring
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M7/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made of other substances with subsequent freeing of the treated goods from the treating medium, e.g. swelling, e.g. polyolefins
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/02—Water
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- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/085—Phosphorus oxides, acids or salts
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/024—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings having at least two phenol groups but no condensed ring
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
- C10M2207/123—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms polycarboxylic
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/14—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/141—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings monocarboxylic
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/22—Acids obtained from polymerised unsaturated acids
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/107—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of two or more specified different alkylene oxides covered by groups C10M2209/104 - C10M2209/106
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
- C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
- C10M2219/085—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing carboxyl groups; Derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/041—Triaryl phosphates
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/045—Siloxanes with specific structure containing silicon-to-hydroxyl bonds
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/046—Siloxanes with specific structure containing silicon-oxygen-carbon bonds
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/047—Siloxanes with specific structure containing alkylene oxide groups
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/048—Siloxanes with specific structure containing carboxyl groups
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
- C10N2020/01—Physico-chemical properties
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- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/46—Textile oils
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions
Definitions
- ABSTRACT [52] US. Cl. 252/48 6; 252/89; 352/496; A lubricant for polyolefin carpet hacking containing a 252/52 R; 353/52 A copoly(oxyethyleneoxypropylenel glycol or mono- [5 [1 Int. Cl. ..Cl0M 1/38; ClOM 3/32; ether. a hindered phenol stabilizer, a coupling agent. a CIOM 5/28; ClUM 7/36 hulk Wetting agent and. optionally a corrosion inhibi [58] Field of Searchmm 252/486, 49.6 52 R. 52 A, tor suitable for use in carpets having a polyolefin 252/89 hacking.
- the lubricant composition of this invention prevents degradation of the carpet hacking while at ⁇ 56] References Cit d the same time. affording good luhricit during the car- UNITED STATES PATENTS pet manufacturing process 1629.310 l2/l97l Bailey et al. 352/49 (1 ll Claims. N0 Drawings 1 LUBRICANT COMPOSITION BACKGROUND OF THE INVENTION or ribbons and to reduce wear on the tufting needles. m
- the lubricant also prevents excessive heat build up on the needles which can cause fusion of the fiber polymer.
- the water soluble copoly(oxyethyleneoxypropylene) derivatives have been found effective for this use since they do not readily penetrate into the polyolefin as do lubricants such as mineral oil or the fatty acids or esters thereof.
- the advantages of the copoly(oxyethylene-oxypropylene) derivatives are their exceptionally good tufting lubricity and their water solubility since it is preferred to apply the lubricant to the backing from an aqueous bath.
- one of the great disadvantages of the use of these materials has been their tendency to degrade the strength properties of the polyolefin backing during heat aging of the carpet.
- the instant invention pertains to a lubricant composition for polyolefin carpet backings, such as polypropylene, having desirable thermal stability and lubricity that does not cause degradation of the polyolefin backing.
- This lubricant composition contains a major amount of a random or block copoly(oxyethylene-oxypropylene) glycol or monoether and minor amounts of a hindered phenol stabilizer, a coupling agent, a wetting agent and, optionally, a corrosion inhibitor, as hereinafter defined.
- a carpet backing is employed which can be either woven, spun bonded or needle punched.
- heat build up can become a problem and it is therefore necessary to use some form of lubrication to minimize the problem.
- This invention pertains to a specifically defined lubricant composition suitable for use in carpet manufacturing process in which the carpet backing is a polyolefin material, such as, polypropylene or blends thereof with other polyolefins or copolymers of polypropylene.
- the polypropylenes find particular favor in the industry because of the desirable properties of fibers, films, ribbons, etc., thereof.
- polypropylene carpet backing is intended to mean those backings containing polypropylene alone, blends thereof or copolymers thereof.
- the lubricant compositions of this invention When using the lubricant compositions of this invention they are employed in the conventional manner by applying them to the backing using any of the known procedures. The manner in which the lubricant is applied to the backing is of no critical importance.
- the block or random copoly(oxyethylene-oxypropylene) glycol or monoether thereof which makes up a 2 major amount of the lubricant composition is represented by the structural formula wherein R' is hydrogen or alkyl of from l to 12 carbon atoms, preferably 2 to 8 carbon atoms; q and r are integers, such that q comprises from 25 to 75 weight percent, preferably 35 to 65 weight percent, of the sum of q and r, and wherein said glycol or monoether has a number average molecular weight of from 500 to 30,000, preferably from 1000 to 5000.
- the concentration of this component in the lubricant composition should be above about 60 weight percent.
- An amount of from about 60 to 98 weight percent can be used, preferably from about 60 to about 94 weight percent and most preferably, from about to 80 weight percent.
- copoly(oxyethylene-oxypropylene) glycols and monoethers are well known and many of them are commercially available.
- copoly(oxyethylene-oxypropylene) glycols having average molecular weights of 750, 1,000, 2,200, 2,400, 3,300, 3,800, 4,000, 4,400 or 5,500 and the methyl, propyl, butyl, hexyl, 2-ethylhexyl, decyl and dodecyl monoethers thereof wherein the oxyethylene content therein can be 30, 38, 42, 50, 56, 64, 70 or mole percent.
- the hindered phenol stabilizers are present in the lubricant composition at a concentration of from about 0.1 to about 5 weight percent, preferably from about 0.2 to about 2 weight percent.
- These stabilizers are those represented by the structural formula wherein R is (i) an alkyl group of from I to about 6 carbon atoms, preferably 4 to 6 carbon atoms, and most preferably the tertiary butyl group when X is either -COOR' or or (ii) a hydrogen atom or an alkyl group of from 1 to about 6 carbon atoms, preferably 4 to 6 carbon atoms when X is R is alkyl of from about 6 to about 22 carbon atoms; preferably l2 to 18 carbon atoms and n and m are integers of from 2 to 4, preferably 2 or 3.
- hindered phenols defined by the above formula yield lubricant compositions which do not discolor the lubricant or the carpet backing on standing or on heat aging.
- other hindered phenols such as 2,6-di-t-butyl-4-methylphenol, 2,6-di-t-butylphenol, phenyl alpha-naphthylamine 2,2 -methylenebis-( 4-methyl-6-t-butylphenol 2,4-bis(4-hydroxy-3,5-di-t-butylphenoxy)-6-(n-octylthio)-l,3,5-tria.zine and l,3,5-trimethyl-2,4,6-tris(3,5- di-t-butylhydroxybenzyl)phenol, were found unsatisfactory and we were unable to produce thermally stable carpet backing lubricants with these materials.
- the lubricant composition contains a coupling agent to dissolve the hindered phenol stabilizer in both the copoly(oxyethylene-oxypropylene) glycol or monoether and the water with which it is diluted.
- This coupling agent is present in the lubricant composition at a concentration of from about 2 to about 35 weight percent, preferably from about 5 to about 30 weight percent.
- the suitable coupling agents are those represented by the structural formula R"O(CH CH O),,H wherein R" is alkyl of from about 8 to 22 carbon atoms, preferably from 1 l to 18 carbon atoms, phenyl or alkylphenyl wherein the alkyl group thereof has from 1 to about 18 carbon atoms, preferably from about 6 to l2 carbon atoms, and p is an integer having the value of from about 3 to about 40, preferably from 7 to 20.
- These compounds are well known and commercially available; they are the adducts of from about 9 to about 15 moles of ethylene oxide with C to C linear aliphatic alcohols or alkyl phenols such as octylphenol.
- lllustrative of commercial products are TER- GITOL Nonionic -8-9, or Nonionic NPX, lgepa] CA- 630 or RC-630 and Triton X-lOO.
- the lubricating composition also contains from about 0.05 to about 2.5 weight percent, preferably from about 0.1 to about 1 weight percent, of a bulk wetting agent which is a random copolymer of the following structure wherein Me is methyl, x is from about 15 to about 100, preferably from about to 75, d is from 5 to 30, preferably from about 7 to 20, b is from 0 to about 50, preferably from 0 to about 30, and y is from about 2.5 to about 7.5, preferably from about 3.2 to about 5.1.
- a bulk wetting agent which is a random copolymer of the following structure wherein Me is methyl, x is from about 15 to about 100, preferably from about to 75, d is from 5 to 30, preferably from about 7 to 20, b is from 0 to about 50, preferably from 0 to about 30, and y is from about 2.5 to about 7.5, preferably from about 3.2 to about 5.1.
- a corrosion inhibitor is not critical to this invention and it is used solely to prevent corrosion of machine parts. When present it can be present at a concentration up to about 10 weight percent, preferably from about 0.5 to 5 weight percent. Any of the known corrosion inhibitors that are miscible with the lubricant composition and used in the textile art can be used and illustrative thereof one can mention, tricresyl phosphite, triisopropanolamine, tetrapropenylsuccinic anhydride, sodium benzoate, the phosphate inhibitors, and the like.
- the lubricant compositions of this invention are produced by mixing the components by conventional mixing procedures.
- the manner of mixing is not critical. Normally, these compositions are diluted with water before they are applied to the fabric.
- the concentration thereof in the aqueous mixture can vary from about 5 to 30 weight percent, preferably from about 10 to 20 weight percent.
- the lubricant composition is applied to the fabric or carpet backing by any conventional means such as padding, dipping, roller coating, spraying or any other suitable procedure generally employed. After it has been applied to the carpet backing at a lubricant loading of from about 2 to 5 weight percent, the carpet is manufactured by conventional tufting or other procedure.
- the lubricant compositions of this invention were evaluated for their thermal stability and the inertness or prevention of degradation of carpet backing by padding woven polypropylene backing with a 20 weight percent aqueous mixture of the lubricant to obtain a 4 to 5 weight percent lubricant loading on the backing.
- the backing was then heat set in an oven at 350F. for two minutes and six inch (warp) by 1 inch (fill) strips were cut therefrom for evaluation.
- the strips were hung in an oven set at 230F. to 258F. with a 10 gram weight attached to the end of each strip.
- the heat aged samples were removed from the oven at different intervals and their tensile strengths were determined with an lnstron Tensile Tester by the procedure described in ASTM D 2646.
- a lubricant composition was containing 82.7 parts of the butyl monoether of the random copoly(oxyethylene-oxypropylene) glycol having an average molecular weight of about 4400 and containing 64 mole perccent oxyethylene units, 15 parts by weight of the adduct of 9 moles of ethylene oxide per mole of a C to C mixture of linear alcohols as the coupling agent, one part of stearyl beta-(3,5-di-t-butyl-4-hydroxyphenyl) propionate as the stabilizer, one part of tetrapropenylsuccinic anhydride as corrosion inhibitor and 0.3 part of Me SiO(Me,SiO)- MeOSiC l'MOC Hi)m(OCHCH,) OMeI SiMe,
- aqueous lubricant composition was prepared containing 20 weight percent of the above lubricant composition and this was padded on to polypropylene carpet backing fabric to obtain a 4 to 5 weight percent loading of the lubricant on the backing.
- the backing was heat set at 350F. for 2 minutes and then the tensile strength was determined on strips by the procedure previously described.
- Example 2 This shows that the lubricant composithat the lubricant composition of Example I can be tion of Example 2 can be used to lubricate the polyproused to lubricate the polypropylene carpet backing pylene carpet backing without fear of causing any degwithout fear of causing any significant degradation or radation or deterioration thereof. deterioration thereof. While Control IV showed no degradation, the non-lubricated carpet backing would 25 EXAMPLE 3 present problems during the carpet manufacturing pro- A lubricant composition was prepared containing cess.
- Example 1 An aqueous lubricant composition was prepared containing 20 weight percent of the above lubricant composition and this was padded on to polypropylene carpet backing fabric to obtain a 4 to 5 weight percent loading of the lubricant on the backing. The backing was heat set at 350F. for 2 minutes and then the tensile strength was determined on strips by the procedure previously described.
- Example 3 Tensile Strength at Break. lb. l 12 hours Lubricant Composition of Example 3 79 Control I less than I Control I] cu n o c mm tt mcmonn wherein R' is hydrogen or alkyl of from 1 to 12 carbon atoms; q and r are integers such that q comprises from 25 to 75 weight percent of the sum of q plus r, and wherein said glycol or monoether has a number average molecular weight of from 500 to 30,000; (B) from 0.1 to 5 weight percent of a stabilizer of the structure:
- R is (i) alkyl of l to 6 carbon atoms when X is COOR' or or (ii) hydrogen or alkyl of l to 6 carbon atoms when X is R R POO-) CH- Q R I!
- R is alkyl of from 6 to 22 carbon atoms; n and m are integers of from 2 to 4; (C) from 2 to 35 weight percent of a coupling agent of the structure:
- R" is alkyl of from 8 to 22 carbon atoms; phenyl or alkylphenyl wherein said alkyl group has from 1 to 18 carbon atoms; and p is an integer of from 3 to 40; (D) from 0.5 to 2.5 weight percent of a bulk wetting agent of the random structure:
- a lubricant composition as claimed in claim 1 wherein (A) is present at a concentration of from about to about 94 weight percent; (B) is present at a concentration of from 0.2 to 2 weight percent; (C) is present at a concentration of from 5 to 30 weight percent; (D) is present at a concentration of from 0.1 to l weight percent; and (E) is present at a concentration of from 0.5 to 5 weight percent.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Lubricants (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US503686A US3919097A (en) | 1974-09-06 | 1974-09-06 | Lubricant composition |
CA233,683A CA1046493A (en) | 1974-09-06 | 1975-08-18 | Carpet fiber lubricant compositions |
GB36584/75A GB1520463A (en) | 1974-09-06 | 1975-09-05 | Lubricant composition |
FR7527393A FR2283949A1 (fr) | 1974-09-06 | 1975-09-05 | Composition lubrifiante contenant un glycol de copolymere sequence ou statistique |
BE159767A BE833106A (fr) | 1974-09-06 | 1975-09-05 | Composition lubrifiante contenant un glycol de polymere sequence ou statistique |
IT7526974A IT1042333B (it) | 1974-09-06 | 1975-09-05 | Composizione lubrificante |
DE2539670A DE2539670C3 (de) | 1974-09-06 | 1975-09-05 | Schmiermittel |
JP10716775A JPS5321467B2 (ja) | 1974-09-06 | 1975-09-05 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US503686A US3919097A (en) | 1974-09-06 | 1974-09-06 | Lubricant composition |
Publications (1)
Publication Number | Publication Date |
---|---|
US3919097A true US3919097A (en) | 1975-11-11 |
Family
ID=24003099
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US503686A Expired - Lifetime US3919097A (en) | 1974-09-06 | 1974-09-06 | Lubricant composition |
Country Status (8)
Country | Link |
---|---|
US (1) | US3919097A (ja) |
JP (1) | JPS5321467B2 (ja) |
BE (1) | BE833106A (ja) |
CA (1) | CA1046493A (ja) |
DE (1) | DE2539670C3 (ja) |
FR (1) | FR2283949A1 (ja) |
GB (1) | GB1520463A (ja) |
IT (1) | IT1042333B (ja) |
Cited By (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4019990A (en) * | 1975-07-23 | 1977-04-26 | Allied Chemical Corporation | Production of polyester tire yarn polyglycol ether spin finish composition |
US4127490A (en) * | 1977-12-05 | 1978-11-28 | Basf Wyandotte Corporation | Fiber finish compositions |
US4134841A (en) * | 1978-03-10 | 1979-01-16 | Union Carbide Corporation | Fiber lubricants |
US4179544A (en) * | 1977-12-05 | 1979-12-18 | Basf Wyandotte Corporation | Fiber finish compositions |
US4288331A (en) * | 1979-06-13 | 1981-09-08 | Shell Oil Company | Lubricating compositions for primary backing fabrics used in the manufacture of tufted textile articles |
US4327144A (en) * | 1980-08-26 | 1982-04-27 | Southland Manufacturing Co., Inc. | Lubricator pad and method |
EP0054953A1 (en) * | 1980-12-22 | 1982-06-30 | Union Carbide Corporation | Lubricant compositions for finishing synthetic fibers |
US4348244A (en) * | 1978-10-20 | 1982-09-07 | Shell Oil Company | Lubricating compositions for primary backing fabrics used in the manufacture of tufted textile articles |
US4826615A (en) * | 1985-06-07 | 1989-05-02 | Exxon Chemical Patents Inc. | Lubricating oil composition containing dual additive combination for low temperature viscosity improvement (PTF-004) |
US4891145A (en) * | 1985-01-31 | 1990-01-02 | Exxon Chemical Patents Inc. | Lubricating oil composition |
US4954275A (en) * | 1981-02-19 | 1990-09-04 | Ciba-Geigy Corporation | Use of phenol-mercaptocarboxylic acid esters as stabilizers for lubricants |
US4957650A (en) * | 1985-06-07 | 1990-09-18 | Exxon Chemical Patents Inc. | Lubricating oil composition containing dual additive combination for low temperature viscosity improvement |
EP0516412A2 (en) * | 1991-05-28 | 1992-12-02 | Hercules Incorporated | Cardable hydrophobic polypropylene fiber |
US5370933A (en) * | 1992-01-31 | 1994-12-06 | Ppg Industries, Inc. | Soil release composition for use with polyester textiles |
US5510402A (en) * | 1992-02-24 | 1996-04-23 | Ciba-Geigy Corporation | Carboxylic acid esters of hydroxyphenylalkanols as stabilizers |
US5540953A (en) * | 1992-02-14 | 1996-07-30 | Hercules Incorporated | Process of preparing fabric comprising hydrophobic polyolefin fibers |
USRE35621E (en) * | 1989-05-30 | 1997-10-07 | Hercules Incorporated | Cardable hydrophobic polypropylene fiber, material and method for preparation thereof |
US5696061A (en) * | 1995-11-14 | 1997-12-09 | Basf Corporation | Self-cleaning polypropylene fabric weaving lubricant |
US5721048A (en) * | 1990-11-15 | 1998-02-24 | Fiberco, Inc. | Cardable hydrophobic polyolefin fiber, material and method for preparation thereof |
US5925434A (en) * | 1997-06-12 | 1999-07-20 | Bp Amoco Corporation | Tuftable backing and carpet construction |
US20060047048A1 (en) * | 2002-11-15 | 2006-03-02 | Motoyuki Sugiura | Graft copolymer composition, thermoplastic resin composition containing the same and molded object |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4813668B2 (ja) * | 2001-01-22 | 2011-11-09 | 株式会社Adeka | ポリアルキレングリコール系潤滑剤 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3629310A (en) * | 1969-08-28 | 1971-12-21 | Union Carbide Corp | Organo-siloxane-oxyalkylene block copolymers |
US3657309A (en) * | 1968-05-13 | 1972-04-18 | Ciba Geigy Corp | Alkylhydroxyphenylthiolalkanoates |
US3671433A (en) * | 1970-12-17 | 1972-06-20 | Dow Corning | Lubricant compositions |
US3832328A (en) * | 1966-08-18 | 1974-08-27 | Ciba Geigy Ag | Organic compositions stabilized with phenolic thiocarboxylic acid esters |
-
1974
- 1974-09-06 US US503686A patent/US3919097A/en not_active Expired - Lifetime
-
1975
- 1975-08-18 CA CA233,683A patent/CA1046493A/en not_active Expired
- 1975-09-05 FR FR7527393A patent/FR2283949A1/fr active Granted
- 1975-09-05 BE BE159767A patent/BE833106A/xx not_active IP Right Cessation
- 1975-09-05 JP JP10716775A patent/JPS5321467B2/ja not_active Expired
- 1975-09-05 GB GB36584/75A patent/GB1520463A/en not_active Expired
- 1975-09-05 IT IT7526974A patent/IT1042333B/it active
- 1975-09-05 DE DE2539670A patent/DE2539670C3/de not_active Expired
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3832328A (en) * | 1966-08-18 | 1974-08-27 | Ciba Geigy Ag | Organic compositions stabilized with phenolic thiocarboxylic acid esters |
US3657309A (en) * | 1968-05-13 | 1972-04-18 | Ciba Geigy Corp | Alkylhydroxyphenylthiolalkanoates |
US3629310A (en) * | 1969-08-28 | 1971-12-21 | Union Carbide Corp | Organo-siloxane-oxyalkylene block copolymers |
US3671433A (en) * | 1970-12-17 | 1972-06-20 | Dow Corning | Lubricant compositions |
Cited By (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4019990A (en) * | 1975-07-23 | 1977-04-26 | Allied Chemical Corporation | Production of polyester tire yarn polyglycol ether spin finish composition |
US4127490A (en) * | 1977-12-05 | 1978-11-28 | Basf Wyandotte Corporation | Fiber finish compositions |
US4179544A (en) * | 1977-12-05 | 1979-12-18 | Basf Wyandotte Corporation | Fiber finish compositions |
US4134841A (en) * | 1978-03-10 | 1979-01-16 | Union Carbide Corporation | Fiber lubricants |
US4348244A (en) * | 1978-10-20 | 1982-09-07 | Shell Oil Company | Lubricating compositions for primary backing fabrics used in the manufacture of tufted textile articles |
US4288331A (en) * | 1979-06-13 | 1981-09-08 | Shell Oil Company | Lubricating compositions for primary backing fabrics used in the manufacture of tufted textile articles |
US4327144A (en) * | 1980-08-26 | 1982-04-27 | Southland Manufacturing Co., Inc. | Lubricator pad and method |
EP0054953A1 (en) * | 1980-12-22 | 1982-06-30 | Union Carbide Corporation | Lubricant compositions for finishing synthetic fibers |
US4954275A (en) * | 1981-02-19 | 1990-09-04 | Ciba-Geigy Corporation | Use of phenol-mercaptocarboxylic acid esters as stabilizers for lubricants |
US4891145A (en) * | 1985-01-31 | 1990-01-02 | Exxon Chemical Patents Inc. | Lubricating oil composition |
US4826615A (en) * | 1985-06-07 | 1989-05-02 | Exxon Chemical Patents Inc. | Lubricating oil composition containing dual additive combination for low temperature viscosity improvement (PTF-004) |
US4957650A (en) * | 1985-06-07 | 1990-09-18 | Exxon Chemical Patents Inc. | Lubricating oil composition containing dual additive combination for low temperature viscosity improvement |
USRE35621E (en) * | 1989-05-30 | 1997-10-07 | Hercules Incorporated | Cardable hydrophobic polypropylene fiber, material and method for preparation thereof |
US5721048A (en) * | 1990-11-15 | 1998-02-24 | Fiberco, Inc. | Cardable hydrophobic polyolefin fiber, material and method for preparation thereof |
EP0516412A2 (en) * | 1991-05-28 | 1992-12-02 | Hercules Incorporated | Cardable hydrophobic polypropylene fiber |
US5403426A (en) * | 1991-05-28 | 1995-04-04 | Hercules Incorporated | Process of making cardable hydrophobic polypropylene fiber |
EP0516412A3 (en) * | 1991-05-28 | 1993-09-08 | Hercules Incorporated | Cardable hydrophobic polypropylene fiber |
EP0962583A2 (en) * | 1991-05-28 | 1999-12-08 | Hercules Incorporated | Cardable hydrophobic polyolefin fiber |
EP0962583A3 (en) * | 1991-05-28 | 2000-01-05 | Hercules Incorporated | Cardable hydrophobic polyolefin fiber |
US5370933A (en) * | 1992-01-31 | 1994-12-06 | Ppg Industries, Inc. | Soil release composition for use with polyester textiles |
US5540953A (en) * | 1992-02-14 | 1996-07-30 | Hercules Incorporated | Process of preparing fabric comprising hydrophobic polyolefin fibers |
US5545481A (en) * | 1992-02-14 | 1996-08-13 | Hercules Incorporated | Polyolefin fiber |
US5510402A (en) * | 1992-02-24 | 1996-04-23 | Ciba-Geigy Corporation | Carboxylic acid esters of hydroxyphenylalkanols as stabilizers |
US5696061A (en) * | 1995-11-14 | 1997-12-09 | Basf Corporation | Self-cleaning polypropylene fabric weaving lubricant |
US5925434A (en) * | 1997-06-12 | 1999-07-20 | Bp Amoco Corporation | Tuftable backing and carpet construction |
US20060047048A1 (en) * | 2002-11-15 | 2006-03-02 | Motoyuki Sugiura | Graft copolymer composition, thermoplastic resin composition containing the same and molded object |
Also Published As
Publication number | Publication date |
---|---|
BE833106A (fr) | 1976-03-05 |
JPS5153169A (ja) | 1976-05-11 |
CA1046493A (en) | 1979-01-16 |
DE2539670B2 (de) | 1977-11-10 |
FR2283949A1 (fr) | 1976-04-02 |
JPS5321467B2 (ja) | 1978-07-03 |
DE2539670C3 (de) | 1978-07-06 |
IT1042333B (it) | 1980-01-30 |
DE2539670A1 (de) | 1976-03-25 |
FR2283949B1 (ja) | 1979-06-22 |
GB1520463A (en) | 1978-08-09 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: MORGAN GUARANTY TRUST COMPANY OF NEW YORK, AND MOR Free format text: MORTGAGE;ASSIGNORS:UNION CARBIDE CORPORATION, A CORP.,;STP CORPORATION, A CORP. OF DE.,;UNION CARBIDE AGRICULTURAL PRODUCTS CO., INC., A CORP. OF PA.,;AND OTHERS;REEL/FRAME:004547/0001 Effective date: 19860106 |
|
AS | Assignment |
Owner name: UNION CARBIDE CORPORATION, Free format text: RELEASED BY SECURED PARTY;ASSIGNOR:MORGAN BANK (DELAWARE) AS COLLATERAL AGENT;REEL/FRAME:004665/0131 Effective date: 19860925 |