US3896251A - Outerwear fabric treatment - Google Patents

Outerwear fabric treatment Download PDF

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Publication number
US3896251A
US3896251A US38070273A US3896251A US 3896251 A US3896251 A US 3896251A US 38070273 A US38070273 A US 38070273A US 3896251 A US3896251 A US 3896251A
Authority
US
United States
Prior art keywords
groups
carbodiimide
fluoroaliphatic
radicals
percent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
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English (en)
Inventor
Dennis P Landucci
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Co
Original Assignee
Minnesota Mining and Manufacturing Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to GB5146874A priority Critical patent/GB1413052A/en
Priority to CH320273D priority patent/CH320273A4/xx
Priority to CH320273A priority patent/CH587381B5/xx
Priority to FR7307777A priority patent/FR2175027B1/fr
Priority to DE19732310801 priority patent/DE2310801C3/de
Priority to GB1062273A priority patent/GB1413051A/en
Priority to JP3050973A priority patent/JPS512560B2/ja
Priority to AU52962/73A priority patent/AU452397B2/en
Application filed by Minnesota Mining and Manufacturing Co filed Critical Minnesota Mining and Manufacturing Co
Priority to US05380702 priority patent/US3896251A/en
Priority to US05/554,420 priority patent/US4024178A/en
Priority to FR7513873A priority patent/FR2259854B1/fr
Application granted granted Critical
Publication of US3896251A publication Critical patent/US3896251A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/395—Isocyanates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/425—Carbamic or thiocarbamic acids or derivatives thereof, e.g. urethanes
    • D06M13/428—Carbamic or thiocarbamic acids or derivatives thereof, e.g. urethanes containing fluorine atoms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2164—Coating or impregnation specified as water repellent
    • Y10T442/2172—Also specified as oil repellent

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
US05380702 1972-03-06 1973-07-19 Outerwear fabric treatment Expired - Lifetime US3896251A (en)

Priority Applications (11)

Application Number Priority Date Filing Date Title
CH320273A CH587381B5 (ja) 1972-03-06 1973-03-05
FR7307777A FR2175027B1 (ja) 1972-03-06 1973-03-05
CH320273D CH320273A4 (ja) 1972-03-06 1973-03-05
GB1062273A GB1413051A (en) 1972-03-06 1973-03-05 Fabric treatment
JP3050973A JPS512560B2 (ja) 1972-03-06 1973-03-05
DE19732310801 DE2310801C3 (de) 1972-03-06 1973-03-05 Verfahren zur Erzeugung einer öl- und wasserabweisenden Ausrüstung auf Textilgut aus synthetischen Fasern
GB5146874A GB1413052A (en) 1972-03-06 1973-03-05 Fluoroaliphatic radical-containing carbodiimides
AU52962/73A AU452397B2 (en) 1972-03-06 1973-03-06 Carbodimide having fluoroliphatic radicals and its use in textile treatment
US05380702 US3896251A (en) 1972-03-06 1973-07-19 Outerwear fabric treatment
US05/554,420 US4024178A (en) 1972-03-06 1975-03-03 Fluoroaliphatic radical containing carbodiimides
FR7513873A FR2259854B1 (ja) 1972-03-06 1975-05-02

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US23218672A 1972-03-06 1972-03-06
US05380702 US3896251A (en) 1972-03-06 1973-07-19 Outerwear fabric treatment

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
US23218672A Continuation-In-Part 1972-03-06 1972-03-06

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US05/554,420 Division US4024178A (en) 1972-03-06 1975-03-03 Fluoroaliphatic radical containing carbodiimides

Publications (1)

Publication Number Publication Date
US3896251A true US3896251A (en) 1975-07-22

Family

ID=26925752

Family Applications (1)

Application Number Title Priority Date Filing Date
US05380702 Expired - Lifetime US3896251A (en) 1972-03-06 1973-07-19 Outerwear fabric treatment

Country Status (6)

Country Link
US (1) US3896251A (ja)
JP (1) JPS512560B2 (ja)
AU (1) AU452397B2 (ja)
CH (2) CH587381B5 (ja)
FR (2) FR2175027B1 (ja)
GB (2) GB1413052A (ja)

Cited By (77)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4144367A (en) * 1977-05-09 1979-03-13 Minnesota Mining And Manufacturing Company Carpet-treating compositions
US4414355A (en) * 1981-07-14 1983-11-08 Minnesota Mining And Manufacturing Company Wire coating composition
US4415694A (en) * 1981-07-14 1983-11-15 Minnesota Mining And Manufacturing Company Contact enhancing composition
US4455348A (en) * 1981-07-14 1984-06-19 Minnesota Mining And Manufacturing Company Wire coating composition
US4487876A (en) * 1981-07-14 1984-12-11 Minnesota Mining & Mfg Wire coating composition
US4540497A (en) * 1982-11-09 1985-09-10 Minnesota Mining And Manufacturing Company Fluoroaliphatic radical-containing, substituted guanidines and fibrous substrates treated therewith
EP0157611A1 (en) * 1984-04-02 1985-10-09 Minnesota Mining And Manufacturing Company Fluorochemical biuret compositions and fibrous substrates treated therewith
US4560487A (en) * 1982-12-20 1985-12-24 Minnesota Mining And Manufacturing Company Blends of fluorochemicals and fibrous substrates treated therewith
US4565641A (en) * 1982-11-09 1986-01-21 Minnesota Mining And Manufacturing Company Blend of fluorochemical guanidines and poly(oxyalkylenes)
US4566981A (en) * 1984-03-30 1986-01-28 Minnesota Mining And Manufacturing Company Fluorochemicals and fibrous substrates treated therewith: compositions of cationic and non-ionic fluorochemicals
US4606737A (en) * 1984-06-26 1986-08-19 Minnesota Mining And Manufacturing Company Fluorochemical allophanate compositions and fibrous substrates treated therewith
US4668726A (en) * 1984-03-30 1987-05-26 Minnesota Mining And Manufacturing Company Cationic and non-ionic fluorochemicals and fibrous substrates treated therewith
DE3607773A1 (de) * 1986-03-08 1987-09-10 Cassella Ag Fluoralkylliganden enthaltende polyurethane, verfahren zu ihrer herstellung und ihre zubereitungen und ihre verwendung
US4778915A (en) * 1985-10-16 1988-10-18 Atochem Fluoroacrylic monomers and polymers
US4920190A (en) * 1985-12-03 1990-04-24 Atochem Fluorinated carbamate polymers as hydrophobic and oleophobic agents
US5144056A (en) * 1985-12-03 1992-09-01 Atochem Fluorinated acrylic monomers as hydrophobic and oleophobic agents
US5258458A (en) * 1991-02-28 1993-11-02 Minnesota Mining And Manufacturing Company Composition for providing oil and water repellency
US5672651A (en) * 1995-10-20 1997-09-30 Minnesota Mining And Manufacturing Company Durable repellent fluorochemical compositions
US5698303A (en) * 1988-03-14 1997-12-16 Nextec Applications, Inc. Controlling the porosity and permeation of a web
US5728432A (en) * 1994-08-11 1998-03-17 Nisshinbo Industries, Inc. Treating reinforcing fibers with carbodiimide aqueous dispersion
US5817249A (en) * 1994-11-24 1998-10-06 Minnesota Minning And Manufacturing Company Carbodiimide compound and water repellent compositions
US5846604A (en) * 1988-03-14 1998-12-08 Nextec Applications, Inc. Controlling the porosity and permeation of a web
US5856245A (en) * 1988-03-14 1999-01-05 Nextec Applications, Inc. Articles of barrier webs
US5874164A (en) * 1988-03-14 1999-02-23 Nextec Applications, Inc. Barrier webs having bioactive surfaces
US5876792A (en) * 1988-03-14 1999-03-02 Nextec Applications, Inc. Methods and apparatus for controlled placement of a polymer composition into a web
US5912116A (en) * 1988-03-14 1999-06-15 Nextec Applications, Inc. Methods of measuring analytes with barrier webs
US5935637A (en) * 1989-03-10 1999-08-10 Nextec Applications, Inc. Method of feedback control for the placement of a polymer composition into a web
US5954902A (en) * 1988-03-14 1999-09-21 Nextec Applications, Inc. Controlling the porosity and permeation of a web
US5958137A (en) * 1989-03-10 1999-09-28 Nextec Applications, Inc. Apparatus of feedback control for the placement of a polymer composition into a web
US5998521A (en) * 1996-11-04 1999-12-07 3M Innovative Properties Company Aqueous fluoropolymer compositions and method of preparing the same
US6013795A (en) * 1996-11-04 2000-01-11 3M Innovative Properties Company Alpha-branched fluoroalkylcarbonyl fluorides and their derivatives
US6015838A (en) * 1996-11-04 2000-01-18 3M Innovative Properties Company Aqueous film-forming foam compositions
US6040251A (en) * 1988-03-14 2000-03-21 Nextec Applications Inc. Garments of barrier webs
US6071602A (en) * 1995-06-07 2000-06-06 Nextec Applications, Inc. Controlling the porosity and permeation of a web
US6083602A (en) * 1988-03-14 2000-07-04 Nextec Applications, Inc. Incontinent garments
US6309752B1 (en) 1991-04-02 2001-10-30 3M Innovative Properties Company Substrate having high initial water repellency and a laundry durable water repellency
US6312523B1 (en) 1988-03-14 2001-11-06 Nextec Applications, Inc. Apparatus of feedback control for the placement of a polymer composition into a web
US20030136938A1 (en) * 2001-12-04 2003-07-24 3M Innovative Properties Company Repellent fluorochemical compositions
US6606749B2 (en) * 1998-01-30 2003-08-19 Safety Components Fabric Technologies, Inc. Water resistant protective garment for fire fighters
US20030181572A1 (en) * 2001-05-21 2003-09-25 Tan Lian S. Emulsion polymerization of fluorinated monomers
US20030204015A1 (en) * 2002-04-17 2003-10-30 Burleigh Malcolm B. Repellent fluorochemical compositions
US6649719B2 (en) 2000-08-18 2003-11-18 3M Innovative Properties Company Degradable, amorphous, fluorochemical acrylate polymers
US20040077238A1 (en) * 2002-05-24 2004-04-22 Audenaert Frans A. Fluorochemical composition for treatment of a fibrous substrate
US20040077237A1 (en) * 2002-05-24 2004-04-22 Audenaert Frans A. Fluorochemical composition comprising perfluoropolyether and an extender for the treatment of fibrous substrates
US20040077775A1 (en) * 2002-05-24 2004-04-22 Audenaert Frans A. Fluorochemical composition comprising a fluorinated polymer and treatment of a fibrous substrate therewith
US6737489B2 (en) 2001-05-21 2004-05-18 3M Innovative Properties Company Polymers containing perfluorovinyl ethers and applications for such polymers
US20050085616A1 (en) * 2002-02-13 2005-04-21 Basf Aktiengesellschaft Aqueous dispersions consisting of polycarbodimides
US6890360B2 (en) 2001-12-17 2005-05-10 3M Innovative Properties Company Fluorochemical urethane composition for treatment of fibrous substrates
US20050171279A1 (en) * 2002-05-24 2005-08-04 Cote Linda G. Fluorochemical composition for treatment of a fibrous substrate
US20060094851A1 (en) * 2004-11-04 2006-05-04 Audenaert Frans A Carbodiimide compound and compositions for rendering substrates oil and water repellent
US7053148B2 (en) 2001-08-09 2006-05-30 Ciba Specialty Chemicals Corporation Compositions of polysiloxanes, fluoropolymers extenders
US20070073201A1 (en) * 2005-09-26 2007-03-29 3M Innovative Properties Company Orthopedic cast system and method
WO2008040428A2 (de) 2006-09-29 2008-04-10 Construction Research & Technology Gmbh Funktionalisiertes polyurethanharz, verfahren zu seiner herstellung sowie dessen verwendung
US20080116414A1 (en) * 2006-11-22 2008-05-22 3M Innovative Properties Company Fluorochemical composition for treatment of a fibrous substrate
US20090074975A1 (en) * 2007-09-14 2009-03-19 3M Innovative Properties Company Composition and method for imparting increased water repellency to substrates and substrates treated with same
US20090312517A1 (en) * 2006-12-29 2009-12-17 Yu Yang Process for preparing long-chain polymethylene halide telomers
US20100173085A1 (en) * 2007-06-08 2010-07-08 Jariwala Chetan P Blends of fluoroalkyl-containing ester oligomers with polydicarbodiimide(s)
WO2010093536A1 (en) 2009-02-12 2010-08-19 Ppg Industries Ohio, Inc. Polycarbodiimides having onium salt groups
US20110151738A1 (en) * 2009-12-17 2011-06-23 3M Innovative Properties Company Dimensionally stable nonwoven fibrous webs, melt blown fine fibers, and methods of making and using the same
WO2011075498A1 (en) 2009-12-18 2011-06-23 Ppg Industries Ohio, Inc. One-component, ambient curable waterborne coating compositions, related methods and coated substrates
US20110151737A1 (en) * 2009-12-17 2011-06-23 3M Innovative Properties Company Dimensionally stable nonwoven fibrous webs and methods of making and using the same
US20110189463A1 (en) * 2008-06-12 2011-08-04 Moore Eric M Melt blown fine fibers and methods of manufacture
WO2011109386A1 (en) 2010-03-02 2011-09-09 Ppg Industries Ohio, Inc. One-component, ambient curable waterborne coating compositions, related methods and coated substrates
CN103015179A (zh) * 2012-11-29 2013-04-03 常熟市三利经纬编织造有限公司 一种防水棉锦混纺织物的生产方法
US8858986B2 (en) 2008-06-12 2014-10-14 3M Innovative Properties Company Biocompatible hydrophilic compositions
US8889230B2 (en) 2006-08-31 2014-11-18 3M Innovative Properties Company Side chain fluorochemicals with crystallizable spacer groups
WO2016130352A1 (en) 2015-02-13 2016-08-18 3M Innovative Properties Company Fluorine-free fibrous treating compositions including a polycarbodiimide and an optional paraffin wax, and treating methods
US9487893B2 (en) 2009-03-31 2016-11-08 3M Innovative Properties Company Dimensionally stable nonwoven fibrous webs and methods of making and using the same
US9611572B2 (en) 2010-10-14 2017-04-04 3M Innovative Properties Company Dimensionally stable nonwoven fibrous webs, and methods of making and using the same
WO2018031534A1 (en) 2016-08-12 2018-02-15 3M Innovative Properties Company Fluorine-free fibrous treating compositions, treated substrates, and treating methods
WO2018048709A1 (en) 2016-09-07 2018-03-15 Ppg Industries Ohio, Inc. Methods for preparing powder coating compositions
US10294609B2 (en) 2015-02-13 2019-05-21 3M Innovative Properties Company Fluorine-free fibrous treating compositions including isocyanate-derived ethylenically unsaturated monomer-containing oligomers, and treating methods
WO2019108476A1 (en) 2017-11-30 2019-06-06 3M Innovative Properties Company Compositions, treating methods, and treated fibrous substrates
US10822500B2 (en) 2016-07-07 2020-11-03 Rudolf Gmbh Preparations as hydrophobing agents
WO2021037374A1 (en) 2019-08-30 2021-03-04 Transitions Optical, Ltd. Photochromic composition with polyol and poly(anhydride)
WO2021037375A1 (en) 2019-08-30 2021-03-04 Transitions Optical, Ltd. Photochromic film laminate
US20210196010A1 (en) * 2019-12-27 2021-07-01 Ykk Corporation Method for Manufacturing Fastener Stringer and Fastener Chain

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JPS5486564U (ja) * 1977-12-02 1979-06-19
JPS56165072A (en) * 1980-05-23 1981-12-18 Dainippon Ink & Chemicals Water and oil repellent process
JPS59130367A (ja) * 1983-09-30 1984-07-26 東レ株式会社 超極細繊維布帛使いの撥水・撥油性防水衣類
EP2692748B1 (de) 2012-08-03 2015-01-21 Philipps-Universität Marburg Hydro- und oleophobe Polymerblends

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US2941966A (en) * 1956-08-27 1960-06-21 Du Pont Carbodiimide polymers
US3150000A (en) * 1961-06-24 1964-09-22 Pfersee Chem Fab Method and means for treating textiles
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US3236672A (en) * 1962-02-12 1966-02-22 Arkansas Company Inc Durable water and oil repellency
US3256231A (en) * 1961-05-03 1966-06-14 Du Pont Polymeric water and oil repellents
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US3544537A (en) * 1968-05-31 1970-12-01 Du Pont Poly(perfluoroalkoxy)polyfluoroalkyl acrylate-type esters and their polymers
US3575899A (en) * 1969-07-28 1971-04-20 Minnesota Mining & Mfg Launderably removeable,soil and stain resistant fabric treatment
US3598514A (en) * 1969-02-27 1971-08-10 Stevens & Co Inc J P Methods of applying soil-release compositions to textile materials
US3816495A (en) * 1971-08-31 1974-06-11 Du Pont Polyfluorinated poly(vinyl isocyanates)

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US2941966A (en) * 1956-08-27 1960-06-21 Du Pont Carbodiimide polymers
US3256231A (en) * 1961-05-03 1966-06-14 Du Pont Polymeric water and oil repellents
US3150000A (en) * 1961-06-24 1964-09-22 Pfersee Chem Fab Method and means for treating textiles
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Cited By (115)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4144367A (en) * 1977-05-09 1979-03-13 Minnesota Mining And Manufacturing Company Carpet-treating compositions
US4414355A (en) * 1981-07-14 1983-11-08 Minnesota Mining And Manufacturing Company Wire coating composition
US4415694A (en) * 1981-07-14 1983-11-15 Minnesota Mining And Manufacturing Company Contact enhancing composition
US4455348A (en) * 1981-07-14 1984-06-19 Minnesota Mining And Manufacturing Company Wire coating composition
US4487876A (en) * 1981-07-14 1984-12-11 Minnesota Mining & Mfg Wire coating composition
US4565641A (en) * 1982-11-09 1986-01-21 Minnesota Mining And Manufacturing Company Blend of fluorochemical guanidines and poly(oxyalkylenes)
US4540497A (en) * 1982-11-09 1985-09-10 Minnesota Mining And Manufacturing Company Fluoroaliphatic radical-containing, substituted guanidines and fibrous substrates treated therewith
US4560487A (en) * 1982-12-20 1985-12-24 Minnesota Mining And Manufacturing Company Blends of fluorochemicals and fibrous substrates treated therewith
US4566981A (en) * 1984-03-30 1986-01-28 Minnesota Mining And Manufacturing Company Fluorochemicals and fibrous substrates treated therewith: compositions of cationic and non-ionic fluorochemicals
US4668726A (en) * 1984-03-30 1987-05-26 Minnesota Mining And Manufacturing Company Cationic and non-ionic fluorochemicals and fibrous substrates treated therewith
EP0157611A1 (en) * 1984-04-02 1985-10-09 Minnesota Mining And Manufacturing Company Fluorochemical biuret compositions and fibrous substrates treated therewith
US4668406A (en) * 1984-04-02 1987-05-26 Minnesota Mining And Manufacturing Company Fluorochemical biuret compositions and fibrous substrates treated therewith
US4748267A (en) * 1984-04-02 1988-05-31 Minnesota Mining And Manufacturing Company Fluorochemical biuret compounds and fibrous substrates treated therewith
US4606737A (en) * 1984-06-26 1986-08-19 Minnesota Mining And Manufacturing Company Fluorochemical allophanate compositions and fibrous substrates treated therewith
US4778915A (en) * 1985-10-16 1988-10-18 Atochem Fluoroacrylic monomers and polymers
US4920190A (en) * 1985-12-03 1990-04-24 Atochem Fluorinated carbamate polymers as hydrophobic and oleophobic agents
US5144056A (en) * 1985-12-03 1992-09-01 Atochem Fluorinated acrylic monomers as hydrophobic and oleophobic agents
DE3607773A1 (de) * 1986-03-08 1987-09-10 Cassella Ag Fluoralkylliganden enthaltende polyurethane, verfahren zu ihrer herstellung und ihre zubereitungen und ihre verwendung
US5912116A (en) * 1988-03-14 1999-06-15 Nextec Applications, Inc. Methods of measuring analytes with barrier webs
US5954902A (en) * 1988-03-14 1999-09-21 Nextec Applications, Inc. Controlling the porosity and permeation of a web
US5698303A (en) * 1988-03-14 1997-12-16 Nextec Applications, Inc. Controlling the porosity and permeation of a web
US6083602A (en) * 1988-03-14 2000-07-04 Nextec Applications, Inc. Incontinent garments
US6040251A (en) * 1988-03-14 2000-03-21 Nextec Applications Inc. Garments of barrier webs
US5846604A (en) * 1988-03-14 1998-12-08 Nextec Applications, Inc. Controlling the porosity and permeation of a web
US5856245A (en) * 1988-03-14 1999-01-05 Nextec Applications, Inc. Articles of barrier webs
US5874164A (en) * 1988-03-14 1999-02-23 Nextec Applications, Inc. Barrier webs having bioactive surfaces
US5876792A (en) * 1988-03-14 1999-03-02 Nextec Applications, Inc. Methods and apparatus for controlled placement of a polymer composition into a web
US6129978A (en) * 1988-03-14 2000-10-10 Nextec Applications, Inc. Porous webs having a polymer composition controllably placed therein
US6312523B1 (en) 1988-03-14 2001-11-06 Nextec Applications, Inc. Apparatus of feedback control for the placement of a polymer composition into a web
US5958137A (en) * 1989-03-10 1999-09-28 Nextec Applications, Inc. Apparatus of feedback control for the placement of a polymer composition into a web
US5935637A (en) * 1989-03-10 1999-08-10 Nextec Applications, Inc. Method of feedback control for the placement of a polymer composition into a web
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JPS48103900A (ja) 1973-12-26
FR2175027A1 (ja) 1973-10-19
GB1413051A (en) 1975-11-05
FR2259854B1 (ja) 1979-06-08
FR2259854A1 (ja) 1975-08-29
AU452397B2 (en) 1974-08-16
GB1413052A (en) 1975-11-05
DE2310801B2 (de) 1975-04-03
DE2310801A1 (de) 1973-09-20
JPS512560B2 (ja) 1976-01-27
AU5296273A (en) 1974-09-05
FR2175027B1 (ja) 1981-01-09
CH320273A4 (ja) 1976-09-15
CH587381B5 (ja) 1977-04-29

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