US3880173A - Filter material for smoking article - Google Patents

Filter material for smoking article Download PDF

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Publication number
US3880173A
US3880173A US352674A US35267473A US3880173A US 3880173 A US3880173 A US 3880173A US 352674 A US352674 A US 352674A US 35267473 A US35267473 A US 35267473A US 3880173 A US3880173 A US 3880173A
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US
United States
Prior art keywords
strands
filter
filter material
material according
thickness
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US352674A
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English (en)
Inventor
Michael Hill
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FILTER MATERIALS Ltd A CORP OFDE
Original Assignee
Bridon Ropes Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bridon Ropes Ltd filed Critical Bridon Ropes Ltd
Application granted granted Critical
Publication of US3880173A publication Critical patent/US3880173A/en
Assigned to BRIDON PLC reassignment BRIDON PLC CHANGE OF NAME (SEE DOCUMENT FOR DETAILS). EFFECTIVE DATE: 2-22-82 UNITED KINGDOM Assignors: BRIDON LIMITED (CHANGED TO), BRITISH ROPES LIMITED (CHANGED TO)
Assigned to FILTER MATERIALS LIMITED, A CORP. OFDE reassignment FILTER MATERIALS LIMITED, A CORP. OFDE NUNC PRO TUNC ASSIGNMENT (SEE DOCUMENT FOR DETAILS). Assignors: BRIDON PLC
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H13/00—Other non-woven fabrics
    • D04H13/02—Production of non-woven fabrics by partial defibrillation of oriented thermoplastics films
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06—Use of materials for tobacco smoke filters
    • A24D3/08—Use of materials for tobacco smoke filters of organic materials as carrier or major constituent
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/42—Formation of filaments, threads, or the like by cutting films into narrow ribbons or filaments or by fibrillation of films or filaments
    • D01D5/423—Formation of filaments, threads, or the like by cutting films into narrow ribbons or filaments or by fibrillation of films or filaments by fibrillation of films or filaments
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4382—Stretched reticular film fibres; Composite fibres; Mixed fibres; Ultrafine fibres; Fibres for artificial leather
    • D04H1/43838—Ultrafine fibres, e.g. microfibres
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H13/00—Other non-woven fabrics
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T83/00—Cutting
    • Y10T83/02—Other than completely through work thickness
    • Y10T83/0237—Pricking

Definitions

  • ABSTRACT A filter material, particularly for tobacco-smoke filters. comprises fibrillated polyolefin sheet having main [30] Foreign Appmtanonfnonty Data 7 generally longitudinally-extending strands intercon- Apr.
  • fibrillated material of the kind referred to is unexpectedly effective as a tobaccosmoke filter material provided that it has certain special structural characteristics.
  • the special fibrillated material provides, tobacco-smoke filters which give better filtration per unit pressure drop, and better filtration and a lower pressure drop are obtainable with a lower weight of material.
  • the material permits of unexpectedly easy production of tobacco-smoke filters, being readily handled by conventional machinery. The same properties which render the material very effective as a tobacco-smoke filter also render it very effective for various other filtration purposes.
  • a filter material comprises fibrillated material of the kind referred to having main generally longitudinally-extending strands interconnected by interconnecting strands and having a substantial number of free ends formed by severing main strands and/or strands which would otherwise have constituted interconnecting strands, the strands having a thickness in the range 5 p. to 25 p. and at least 40 percent (preferably at least 70 percent) of the strands having a width not greater than their thickness.
  • the word thickness as used herein in relation to strands means the dimension in the same direction as the thickness of the film from which the material is produced.
  • the preferred strand thickness is about 14 p. (i.e., 14 microns).
  • the number of severed ends hereinbefore mentioned present in the fibrillated material of the kind referred to may be optimised to improve significantly the filtration efficiency of the filter material whilst retaining sufficient strength for conventional continuous tow afterprocessing.
  • the random disposal of these severed ends throughout the network effectively leads to a maximising of surface area which in turn gives improved filtration efficiencies.
  • the interconnecting strands preferably join the main strands at substantially regular spaced intervals. Thereby, if the material is expanded laterally, a network is produced which appears substantially regular, as distinct from a network in which the network has interconnections which are clearly randomly spaced and openings which randomly vary in size.
  • the polyolefin of which the polyolefin film is made may consist of polypropylene or polyethylene or a mixture of polypropylene and polyethylene or a copolymer of propylene and ethylene (see examples.
  • a whitening agent in the form of a solid material in finely divided form preferably titanium dioxide, may be incorporated in the polyolefin. It has surprisingly been found that such agents facilitate the production of very narrow strands as hereinbefore referred to.
  • the present invention also provides a tobacco smoke filter, and a cigarette having a tobacco-smoke filter, wherein the filter comprises a body of filter material as hereinbefore defined contained in a tubular outer sheet.
  • the filter comprises a body of filter material as hereinbefore defined contained in a tubular outer sheet.
  • said main strands extend axially (i.e.,
  • a binding agent is incorporated in the material, e.g., by spraying the agent on to the material.
  • the present invention also provides a method of making filter material as hereinbefore defined wherein said material is produced by passing said film over a roller having projecting pins thereon.
  • the pin arrangement, the arc of contact between the film and the roller, and the relative speed of the film and the roller are such as to produce a fibrillated material having the characteristics defined above.
  • a plurality of superimposed films are passed simultaneously over the roller so that fibrillation of all of the films occurs.
  • the requirements can be determined by calculation and/or routine experiment by an experienced worker in the field of fibrillation.
  • the fibrillation ration i.e., the ratio of the surface speed of the roller to the film speed
  • it is desirable for the fibrillation ration i.e., the ratio of the surface speed of the roller to the film speed to be within the range 1.05:1 to 3:1 and preferably 2:1 to 2.5:1.
  • pins are preferably arranged on the roller in parallel rows and in spaced staggered relationships, for example as specified in British Pat. No. 1,073,741. Thereby, on rotation of the roller the paths of travel of the pins in each row are different (i.e., laterally spaced from) the paths of travel of the pins in immediately adjacent rows.
  • each row of pins extends across the roller on a line which is inclined to a line parallel to the roller axis.
  • Each row may be ona sinusoidal line which extends across the roller in a direction parallel to the roller axis.
  • the pins may be arranged in pairs of parallel rows extending across the roller on lines inclined to lines parallel to the roller axis, immediately adjacent pairs of rows being oppositely inclined.
  • EXAMPLE 1 A copolymer of propylene and ethylene of Melt Index 0.8 containing approximately 20 percent by weight of copolymerised ethylene was extruded using a known blown film technique into a film of nominal 25 a thickness. The film so produced was slit to required width (e.g., 1] inches) and the slit film was passed through a standard heating and stretching (orientating) system where it was longitudinally orientated with a stretch ratio of 7:1 to produce a film of 14 p. thickness. The orientated film was passed round part of the periphery of a pinned fibrillating roller. The physical data of the roller and the operating conditions were as follows:
  • the fibrillated film which constituted filter material in accordance with the invention, was collected direct from the fibrillating stage by conventional means. Finally a number of (e.g., three) of the fibrillated films were combined to give the required final runnage (i.e., length per unit weight.)
  • the fibrillated film so produced was then submitted to a crimping process for example involving passage of the film through a stuffer box crimper in a conventional known manner.
  • a crimping process for example involving passage of the film through a stuffer box crimper in a conventional known manner.
  • Other conventional means of crimping for example gear tooth" crimping, false-twist crimping, etc., may also be used for inducing crimp in the fibrillated film.
  • FIG. 1 shows a piece of the fibrillated film in accordance with the invention expanded laterally to show the network formation before the crimping operation was carried out.
  • reference numeral 1 indicates main strands
  • 2 indicates interconnecting strands
  • 3 indicates free-ends.
  • FIG. 2 shows a cigarette 4 having a filter tip 5 made from filter material 6 in accordance with the invention in a tubular outer cover 7.
  • TEST 1 Tobacco smoke filters were made from fibrillated film in accordance with the invention made by the method hereinbefore described.
  • the fibrillated film which had a runnage of 182 feet per pound (8,175 tex), was converted into filter rods using a conventional filter rod making machine.
  • the filter rods were cut into filter tips of 15 mm length. Each filter tip contained 103 mg of fibrillated film.
  • the pressure drop of the filter was 5.6 cm of water gauge at an airflow of 1,050 ml per minute.
  • the filters were attached to cigarettes and were smoked using a smoking machine which took a puff of 35 ml volume and 2 seconds duration every minute.
  • a comparison of the weights of Total Particulate Matter (TPM) delivered from cigarettes having the filters with those from cigarettes without filter showed that the filter removed 40 percent of the TPM.
  • TEST 2 A 15 mm length of a commonly used cigarette filter Example 1, the filter pressure drop was 5.5 cm of water gauge, and the filter removed 35 percent of the TPM.
  • TEST 3 Filters were made and tested as in Example 1, but in this case the fibrillated film did not contain severed ends.
  • the filter contained 103 mg of fibrillated film and the pressure drop was 4.8 cm W.G. at a flow rate of 1,050 ml per minute.
  • the filtration efficiency for Total Particulate Matter was 35 percent.
  • EXAMPLE 2 A copolymer of propylene and ethylene of melt index 0.8 (containing 20 percent copolymerised ethylene) was formed by a known blown film technique using an oscillating die into a film of 28 p. thickness. The doublelayer of the film so produced was slit to required width (e.g., 6.4 inches). Three such widths of the doublelayer of the film were superimposed and passed through a standard heating and stretching (orientating) system where they were longitudinally orientated with a stretch ratio of 7:1 to produce films of 14 M thickness. The orientated films were passed round part of the periphery of a pinned fibrillating roller. the physical data of the roller and the operating conditions were as follows:
  • each filter rod 15 mm in length was found to contain 72 mg of fibrillated film.
  • the pressure drop of the filter was 4.2 of water gauge at an airflow of 1,050 ml per minute.
  • a filter material for a smoking article comprising fibrillated material in the form of filamentary material produced by splitting into a plurality of interconnected strands a polyolefin film which has been oriented in a longitudinal direction, said fibrillated material having main generally longitudinally-extending strands, interconnecting strands interconnecting the main strands, and a substantial number of free ends formed by severing main strands and/or strands which would otherwise have constituted interconnecting strands, the strands having a thickness in the range of 5 p. to ,u. and at least 40 percent of the strands having a width not greater than their thickness, the said material being shaped to conform to the smoke passageway of said article.
  • a filter material according to claim 1 in which at least 70 percent of the strands have a width not greater than their thickness.
  • a filter material according to claim-l which the strand thickness is approximately 14 microns.
  • a filter material according to claim 1 in which the polyolefin of which the material is made is selected from the group consisting of polypropylene, polyethylene, a mixture of polypropylene and polyethylene, and a copolymer of propylene and ethylene.
  • a filter material according to claim 1 in which a whitening agent in the form of a solid material in finely divided form is incorporated in the polyolefin of which the material is made.
  • a filter material according too claim 1 made from a plurality of superimposed polyolefin films which have been subjected to fibrillation while superimposed.
  • a tobacco-smoke filter comprising a body of filter material according to claim 1.
  • a filter according to claim 9 in which said main strands extend axially (i.e., longitudinally) along the filter.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Cigarettes, Filters, And Manufacturing Of Filters (AREA)
  • Filtering Materials (AREA)
  • Nonwoven Fabrics (AREA)
US352674A 1972-04-20 1973-04-19 Filter material for smoking article Expired - Lifetime US3880173A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1845772A GB1442593A (en) 1972-04-20 1972-04-20 Filter material

Publications (1)

Publication Number Publication Date
US3880173A true US3880173A (en) 1975-04-29

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ID=10112766

Family Applications (1)

Application Number Title Priority Date Filing Date
US352674A Expired - Lifetime US3880173A (en) 1972-04-20 1973-04-19 Filter material for smoking article

Country Status (13)

Country Link
US (1) US3880173A (nl)
BE (1) BE798515A (nl)
BR (1) BR7302890D0 (nl)
CA (1) CA1006783A (nl)
CH (1) CH577841A5 (nl)
DE (1) DE2319735C2 (nl)
DK (1) DK150961C (nl)
FI (1) FI56928C (nl)
GB (1) GB1442593A (nl)
HK (1) HK26579A (nl)
MY (1) MY7900195A (nl)
NL (1) NL179020C (nl)
ZA (1) ZA732630B (nl)

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2524273A1 (fr) * 1982-03-31 1983-10-07 Filtrona Ltd Filtre de fumee de tabac
US4736755A (en) * 1985-05-24 1988-04-12 Advanced Tobacco Products Method of loading nicotine into porous polymeric items
US4798570A (en) * 1982-12-09 1989-01-17 Hercules Incorporated Process for preparing filter rods
WO1990001578A1 (en) * 1988-08-10 1990-02-22 Philip Morris Products Inc. Crimped textile fibers and stuffer box apparatus and methods for crimping textile fibers
WO1990001577A1 (en) * 1988-08-10 1990-02-22 Philip Morris Products Inc. Method and apparatus for crimping polyolefin filter tow
WO1990001573A1 (en) * 1988-08-10 1990-02-22 Philip Morris Products Inc. Polyolefin filter tow and method of making it
US4903714A (en) * 1987-08-25 1990-02-27 R. J. Reynolds Tobacco Company Smoking article with improved mouthend piece
US4961415A (en) * 1987-01-16 1990-10-09 Kimberly-Clark Corporation Controlled draft and efficiency filter element for smoking articles
US5104367A (en) * 1988-08-10 1992-04-14 Filter Materials Limited Pinned rollers and process for manufacturing fibrillated film
US5269329A (en) * 1990-07-09 1993-12-14 Kimberly-Clark Corporation Method of producing tobacco flavored cigarette filter
US5538019A (en) * 1993-11-03 1996-07-23 Schweitzer-Mauduit International, Inc. Spunbond cigarette filter
US5711322A (en) * 1993-09-06 1998-01-27 Daicel Chemical Industries, Ltd. Tobacco filter material and a method of producing the same
US5817159A (en) * 1996-12-31 1998-10-06 Cahill; Scott A. Filter with interpenetrating polymer network that biodegrades
US20060227612A1 (en) * 2003-10-08 2006-10-12 Ebrahim Abedifard Common wordline flash array architecture
US20060276088A1 (en) * 2005-06-01 2006-12-07 Polymer Group, Inc. Profiled Structural Concrete Fiber Material And Building Products Including Same, And Methods
WO2012103327A1 (en) 2011-01-28 2012-08-02 R. J. Reynolds Tobacco Company Polymeric materials derived from tobacco

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2298281A2 (fr) * 1972-04-26 1976-08-20 Rothmans Of Pall Mall Filtre pour fumee de tabac
DE3129385A1 (de) * 1980-08-15 1982-06-03 Kennecott Engineered Systems Co., 44122 Cleveland, Ohio Praezisionswickelfilter
CS237872B1 (en) * 1983-06-09 1985-11-13 Rudolf Simo Cigarette filtration stick filling and method of this filling making
WO1987002719A1 (en) 1985-11-01 1987-05-07 Showa Denko Kabushiki Kaisha Conjugated fiber and water absorbing material using same fiber as base material, and methods of manufacturing them
ZA896002B (en) * 1988-08-10 1991-01-30 Philip Morris Prod Pinned rollers and processes for manufacturing fibrillated films
DE102017005427B4 (de) * 2017-05-31 2020-03-05 Askin Buyar Zigarette mit Aufheller

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3290207A (en) * 1962-08-22 1966-12-06 Du Pont Fibrillated fiber
US3302501A (en) * 1965-09-24 1967-02-07 Phillips Petroleum Co Method of fibrillating plastic film by passing the film through rotating piercing means
US3336174A (en) * 1965-04-06 1967-08-15 Eastman Kodak Co Method of making a fibrous filter product
US3393120A (en) * 1965-09-22 1968-07-16 Eastman Kodak Co Polyolefin tow for cigarette filters

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2847086A (en) * 1953-08-04 1958-08-12 Muller Paul Adolf Filtering material
US2966157A (en) * 1957-06-07 1960-12-27 Eastman Kodak Co Polyolefin tobacco smoke filters
US3012302A (en) * 1958-01-03 1961-12-12 Lorillard Co P Tobacco smoke filter manufacture
DE1560800A1 (de) * 1966-02-10 1971-01-07 Lutravil Spinnvlies Verfahren und Vorrichtung zur Herstellung von Mischvliesen durch Schmelzspinnen
DE1632182A1 (de) * 1966-02-24 1970-11-12 Chisso Corp Filter fuer Tabakrauch
NL134100C (nl) * 1966-03-31 1900-01-01

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3290207A (en) * 1962-08-22 1966-12-06 Du Pont Fibrillated fiber
US3336174A (en) * 1965-04-06 1967-08-15 Eastman Kodak Co Method of making a fibrous filter product
US3393120A (en) * 1965-09-22 1968-07-16 Eastman Kodak Co Polyolefin tow for cigarette filters
US3302501A (en) * 1965-09-24 1967-02-07 Phillips Petroleum Co Method of fibrillating plastic film by passing the film through rotating piercing means

Cited By (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2524273A1 (fr) * 1982-03-31 1983-10-07 Filtrona Ltd Filtre de fumee de tabac
US4798570A (en) * 1982-12-09 1989-01-17 Hercules Incorporated Process for preparing filter rods
US4736755A (en) * 1985-05-24 1988-04-12 Advanced Tobacco Products Method of loading nicotine into porous polymeric items
AU589182B2 (en) * 1985-05-24 1989-10-05 Pharmacia Leo, Inc. Nicotine dispenser with polymeric reservoir of nicotine
US4961415A (en) * 1987-01-16 1990-10-09 Kimberly-Clark Corporation Controlled draft and efficiency filter element for smoking articles
US4903714A (en) * 1987-08-25 1990-02-27 R. J. Reynolds Tobacco Company Smoking article with improved mouthend piece
WO1990001573A1 (en) * 1988-08-10 1990-02-22 Philip Morris Products Inc. Polyolefin filter tow and method of making it
US5316827A (en) * 1988-08-10 1994-05-31 Filter Materials Limited Crimped textile fibers and stuffer box apparatus and methods for crimping textile fibers
EP0357257A1 (en) * 1988-08-10 1990-03-07 Philip Morris Products Inc. Crimped textile fibers and stuffer box apparatus and methods for crimping textile fibers
EP0357258A1 (en) * 1988-08-10 1990-03-07 Philip Morris Products Inc. Method and apparatus for improving the crimping of polyolefin filter tow
EP0359387A1 (en) * 1988-08-10 1990-03-21 Philip Morris Products Inc. Polyolefin filter tow and method of making it
US4925602A (en) * 1988-08-10 1990-05-15 Filter Materials Limited Method for improving the crimping of polyolefin filter tow
WO1990001578A1 (en) * 1988-08-10 1990-02-22 Philip Morris Products Inc. Crimped textile fibers and stuffer box apparatus and methods for crimping textile fibers
US5020198A (en) * 1988-08-10 1991-06-04 Filter Materials Ltd. Crimped textile fibers and stuffer box apparatus and methods for crimping textile fibers
US5025815A (en) * 1988-08-10 1991-06-25 Filter Materials Limited Polyolefin filter tow and method of making it
US5104367A (en) * 1988-08-10 1992-04-14 Filter Materials Limited Pinned rollers and process for manufacturing fibrillated film
WO1990001577A1 (en) * 1988-08-10 1990-02-22 Philip Morris Products Inc. Method and apparatus for crimping polyolefin filter tow
US5269329A (en) * 1990-07-09 1993-12-14 Kimberly-Clark Corporation Method of producing tobacco flavored cigarette filter
US5711322A (en) * 1993-09-06 1998-01-27 Daicel Chemical Industries, Ltd. Tobacco filter material and a method of producing the same
US5967149A (en) * 1993-09-06 1999-10-19 Daicel Chemical Industries, Ltd Tobacco filter material and a method of producing the same
US5538019A (en) * 1993-11-03 1996-07-23 Schweitzer-Mauduit International, Inc. Spunbond cigarette filter
US5817159A (en) * 1996-12-31 1998-10-06 Cahill; Scott A. Filter with interpenetrating polymer network that biodegrades
US5998500A (en) * 1996-12-31 1999-12-07 Cahill; Scott A. Method of making a filter with interpenetrating polymer network that biodegrades
US20060227612A1 (en) * 2003-10-08 2006-10-12 Ebrahim Abedifard Common wordline flash array architecture
US20060276088A1 (en) * 2005-06-01 2006-12-07 Polymer Group, Inc. Profiled Structural Concrete Fiber Material And Building Products Including Same, And Methods
WO2012103327A1 (en) 2011-01-28 2012-08-02 R. J. Reynolds Tobacco Company Polymeric materials derived from tobacco
US8893725B2 (en) 2011-01-28 2014-11-25 R. J. Reynolds Tobacco Company Polymeric materials derived from tobacco

Also Published As

Publication number Publication date
BE798515A (fr) 1973-08-16
DK150961C (da) 1988-09-05
NL7305453A (nl) 1973-10-23
AU5458073A (en) 1974-10-17
GB1442593A (en) 1976-07-14
MY7900195A (en) 1979-12-31
DE2319735C2 (de) 1985-02-14
DK150961B (da) 1987-10-05
BR7302890D0 (pt) 1974-01-08
FI56928B (fi) 1980-01-31
NL179020C (nl) 1986-07-01
HK26579A (en) 1979-05-04
CA1006783A (en) 1977-03-15
FI56928C (fi) 1980-05-12
NL179020B (nl) 1986-02-03
CH577841A5 (nl) 1976-07-30
DE2319735A1 (de) 1973-10-25
ZA732630B (en) 1974-03-27

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Legal Events

Date Code Title Description
AS Assignment

Owner name: BRIDON PLC

Free format text: CHANGE OF NAME;ASSIGNORS:BRITISH ROPES LIMITED (CHANGED TO);BRIDON LIMITED (CHANGED TO);REEL/FRAME:005324/0736

Effective date: 19870218

Owner name: FILTER MATERIALS LIMITED, A CORP. OFDE, NEW YORK

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Effective date: 19880421