US3867664A - Electric discharge devices - Google Patents

Electric discharge devices Download PDF

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Publication number
US3867664A
US3867664A US434927A US43492774A US3867664A US 3867664 A US3867664 A US 3867664A US 434927 A US434927 A US 434927A US 43492774 A US43492774 A US 43492774A US 3867664 A US3867664 A US 3867664A
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United States
Prior art keywords
aluminium
alkali metal
halide
vessel
discharge
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Expired - Lifetime
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US434927A
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English (en)
Inventor
Alan George Chalmers
David Osborn Wharmby
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Thorn Electrical Industries Ltd
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Thorn Electrical Industries Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J61/00Gas-discharge or vapour-discharge lamps
    • H01J61/02Details
    • H01J61/12Selection of substances for gas fillings; Specified operating pressure or temperature
    • H01J61/18Selection of substances for gas fillings; Specified operating pressure or temperature having a metallic vapour as the principal constituent

Definitions

  • the present invention relates to high-pressure metal halide electrical discharge devices.
  • the discharge takes place in a gas atmosphere comprising a rare gas, mercury vapour and the halide of one or more elements.
  • the rare gas is present to make the discharge easier to'start.
  • the mercury pressure is usually inthe range of to 30 atmospheres.
  • Metal halide discharges comprising aluminium chloride, mercury and a rare gas (as described for example in British Pat. Nos. 1 190 833 and l 253 948) are known to have high efficacies and spectral power distributions that are continuous or quasi-continuous. They therefore have desirable colour rendering properties.
  • Other aluminium halides afford similar spectra although with lower efficacies.
  • the aluminium halide discharges suffer from having undesirable colour appearance, being either on the green side of white or having too high a colour temperature. Their arcs also tend to be constricted and this causes instability.
  • halides of one or more alkali metals are added to aluminium halide discharges in the presence of mercury and a rare gas.
  • the alkali halides introduced into the discharge filling modify the colour appearance, notably by lowering the colour temperature, whilst maintaining and in some cases increasing the efficacy, increasing the stability and maintaining adequate colour rendering properties.
  • Typical practical embodiments of the present invention are metal halide discharge lamps having a discharge vessel, usually made of fused silica,the wall of which is power loaded at 1 0-100 Wcm which contains a low partial pressure of rare gas, from O to30 mg.cm of mercury, an aluminium halide and an alkali metal halide such that the ratio of the number of molecules of alkali metal halide to aluminium halide (assumed for this purpose to be in the form of trihalide) is in the range 0.1 to 1.5.
  • Such embodiments normally contain sufficient aluminium and alkali metal halide in the discharge vessel for unevaporated aluminium halide and alkali metal halide to be present in the vessel during the operation of the lamp so that the vapours of the halides in the discharge are saturated. It is sometimes advantageous to add additional aluminium metal to prolong electrode life (as described in British Pat. No. l 253 948).
  • FIG. 1 is an emission spectrum of one example of a lamp according to the invention containing sodium chloride and aluminium chloride;
  • FIG. 2 shows onetype of discharge tube embodying the invention
  • FIG. 3 shows a second type of discharge tube embodying the invention mounted in a suitable lamp form.
  • sodium chloride and aluminium chloride are used in the discharge lamp, which also contains mercury and rare gas.
  • the total number of atoms of aluminium and sodium is preferably larger than the total number of chlorine atoms, since where the total number of metal atoms (aluminium and alkali metal) is greater than the number of chlorine atoms electrode erosion is reduced.
  • the preferred ranges for the constituents are: mercury 1030 mg cm', aluminium trihalide 5-100 [.LmOl cm', alkali metal halide 0.5 p.mol cm, with the preferred range for the ratio of the number of molecules of alkali metal halide to the number of molecules of aluminium chloride is 0.1 to 1.5 (all molecules being regarded as in the monomeric form).
  • a silica discharge tube 11 is closed at either end by pinches 12 which make hermetic seals around current leads 13. These current leads are connected to tungsten electrodes 14 which may incorporate an emitter material. The discharge takes place between these electrodes.
  • the discharge vessel has a length of 35mm, an internal diameter of 10mm and a volume of 2cm. The electrode separation is 27mm.
  • a similar discharge tube shown in FIG. 3, has a volume 4.3 cm, internal diameter l5mm,'length 35 mm and electrode separation 20 mm, and is mounted in an outer envelope 15 made from hard glass with a frame of a type that is known to inhibit migration of alkali atoms through the silica.
  • An auxiliary electrode 16 is provided for ease of starting. In both cases the temperature of the discharge tube ends may be increased by coating with zirconia or by any other suitable means.
  • the dosingcomponents for the discharge tubes of this invention may be introduced into the tubes in any convenient form.
  • the halogen may be dosed as a compound of mercury, e.g., Hg Cl or directly as the metal salt, e.g., AlCl or separately as metal and halogen, or in any other convenient way.
  • Alkali metals may be dosed directly, as the metal, or as halogen compounds e.g. NaCl, Nal, Cal.
  • EXAMPLE 1 The discharge space of a lamp as shown in FIG. 2 was dosed with l 1.3 m g Hg 3.3 mg A1 2.3 mg NaCl and filled with 20 torr of argon at room temperature. This-lamp was operated at a power of 400W when the light efficacy was 106 lmW and the lamp had a warm colour appearance. The colour temperature of this lamp was 3100K and the colour rendering obtained therewith was satisfactory.
  • EXAMPLE 2 The discharge space of a lamp as shown in FIG. 2 was dosed with 38.6 mg I-Ig Cl 10.9 mg Hg 3.8 mg Al 10.2 mg Nal At a power of 350W, the efficacy was 100 lmW". The colour temperature of the lamp was 2,450K and the lamp had a warm colour appearance.
  • EXAMPLE 3 A discharge tube similar to that shown in FIG. 2 but having a 6 mm bore, an electrode separation of 27 mm and a volume of 1 cm was dosed with 17.2 mg Hg Cl 9.7 mg Hg 3.8 mg Al 0.7 mg NaCl and filled with argon to 50 torr at room temperature. The lamp at 200W gave a light efficacy of 90-100 lmW. The discharge was stable and had no perceptible flicker.
  • amd a gass fill in said vessel comprising mercury vapour, rare gas, aluminium halide and at least one alkali metal halide.
  • a high-pressure electrical discharge vessel comprising:
  • a light-transmitting discharge vessel having a wall power loaded at between l0 and I00 Wcm during operation;
  • a gass fill in said vessel comprising a rare gas, mercury in the range 0 to 30 mg cm', an alkali metal halide and an aluminium halide, the alkali metal and aluminium halides being present in such quantities that the molar ratio of alkali metal halide to aluminium halide is from 0.1 to 1.5 and unevaporated aluminium and alkali metal halides are present during operation of the lamp.
  • a discharge lamp according to claim 2 wherein said gas fill comprises mercry in the range 10 to 30 mg cnf aluminium chloride or iodide in the range 5 to pmol cm" and sodium chloride or iodide in the range 0.5 to ,umol cm.
  • a discharge lamp according to claim 4 in which the total number of aluminium and alkali metal atoms is greater than the total number of halogen atoms.

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  • Discharge Lamp (AREA)
US434927A 1973-01-23 1974-01-21 Electric discharge devices Expired - Lifetime US3867664A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB346973A GB1444023A (en) 1973-01-23 1973-01-23 Electric discharge lamps

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US05/965,278 Reissue USRE30831E (en) 1973-01-23 1978-12-01 Electric discharge devices

Publications (1)

Publication Number Publication Date
US3867664A true US3867664A (en) 1975-02-18

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ID=9758912

Family Applications (1)

Application Number Title Priority Date Filing Date
US434927A Expired - Lifetime US3867664A (en) 1973-01-23 1974-01-21 Electric discharge devices

Country Status (14)

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US (1) US3867664A (it)
JP (1) JPS5837662B2 (it)
BE (1) BE810033A (it)
CA (1) CA988988A (it)
DE (1) DE2402760C3 (it)
DK (1) DK138969B (it)
FR (1) FR2214968B1 (it)
GB (1) GB1444023A (it)
IE (1) IE38771B1 (it)
IT (1) IT1003493B (it)
LU (1) LU69211A1 (it)
NL (1) NL182925C (it)
SE (1) SE383228B (it)
ZA (1) ZA74411B (it)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4135110A (en) * 1975-02-13 1979-01-16 Thorn Electrical Industries Limited Electrical discharge lamp
FR2538951A1 (fr) * 1982-12-29 1984-07-06 Gen Electric Commande des distributions radiales dans des lampes a decharge de forte puissance et procede de commande
US6157141A (en) * 1998-05-05 2000-12-05 Osram Sylvania Inc. Blue light electrodeless high intensity discharge lamp system

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2422411A1 (de) * 1974-05-09 1975-12-11 Philips Patentverwaltung Hochdruckquecksilberdampfentladungslampe
DE2826733C2 (de) * 1977-07-05 1982-07-29 General Electric Co., Schenectady, N.Y. Hochdruck-Metalldampf-Entladungslampe
US4591759A (en) * 1984-09-10 1986-05-27 General Electric Company Ingredients for solenoidal metal halide arc lamps
US4705987A (en) * 1985-10-03 1987-11-10 The United States Of America As Represented By The United States Department Of Energy Very high efficacy electrodeless high intensity discharge lamps

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3771009A (en) * 1971-12-27 1973-11-06 Gte Laboratories Inc Electrode discharge device with electrode-activating fill

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2102866A5 (it) * 1970-08-27 1972-04-07 Eclairage Lab

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3771009A (en) * 1971-12-27 1973-11-06 Gte Laboratories Inc Electrode discharge device with electrode-activating fill

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4135110A (en) * 1975-02-13 1979-01-16 Thorn Electrical Industries Limited Electrical discharge lamp
FR2538951A1 (fr) * 1982-12-29 1984-07-06 Gen Electric Commande des distributions radiales dans des lampes a decharge de forte puissance et procede de commande
US6157141A (en) * 1998-05-05 2000-12-05 Osram Sylvania Inc. Blue light electrodeless high intensity discharge lamp system

Also Published As

Publication number Publication date
NL7400944A (it) 1974-07-25
BE810033A (fr) 1974-05-16
GB1444023A (en) 1976-07-28
FR2214968B1 (it) 1978-10-27
FR2214968A1 (it) 1974-08-19
AU6481974A (en) 1975-07-24
DE2402760B2 (de) 1979-05-31
NL182925C (nl) 1988-06-01
DE2402760A1 (de) 1974-07-25
ZA74411B (en) 1974-11-27
IE38771L (en) 1974-07-23
JPS5837662B2 (ja) 1983-08-17
DE2402760C3 (de) 1980-01-31
SE383228B (sv) 1976-03-01
CA988988A (en) 1976-05-11
LU69211A1 (it) 1974-04-08
IT1003493B (it) 1976-06-10
DK138969C (it) 1979-05-28
IE38771B1 (en) 1978-05-24
JPS49104479A (it) 1974-10-03
DK138969B (da) 1978-11-20

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