US3860502A - Electrodeposition of tin - Google Patents

Electrodeposition of tin Download PDF

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Publication number
US3860502A
US3860502A US454057A US45405774A US3860502A US 3860502 A US3860502 A US 3860502A US 454057 A US454057 A US 454057A US 45405774 A US45405774 A US 45405774A US 3860502 A US3860502 A US 3860502A
Authority
US
United States
Prior art keywords
acid
plating
ensa
tin
naphthol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US454057A
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English (en)
Inventor
William R Johnson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
United States Steel Corp
Original Assignee
United States Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to AR257005A priority Critical patent/AR205914A1/es
Application filed by United States Steel Corp filed Critical United States Steel Corp
Priority to US454057A priority patent/US3860502A/en
Priority to CA214,244A priority patent/CA1034076A/en
Priority to ZA00747706A priority patent/ZA747706B/xx
Priority to AU76045/74A priority patent/AU483323B2/en
Priority to PH16617A priority patent/PH10766A/en
Priority to DE2459428A priority patent/DE2459428C2/de
Priority to ES433440A priority patent/ES433440A1/es
Priority to BR2/75A priority patent/BR7500002A/pt
Priority to HU75UE00000060A priority patent/HU172102B/hu
Priority to GB63775A priority patent/GB1432127A/en
Priority to YU0031/75A priority patent/YU36999B/xx
Publication of US3860502A publication Critical patent/US3860502A/en
Application granted granted Critical
Priority to IT67264/75A priority patent/IT1027443B/it
Priority to BE153223A priority patent/BE825373A/xx
Priority to PL1975178329A priority patent/PL96074B1/pl
Priority to TR18571A priority patent/TR18571A/xx
Priority to NLAANVRAGE7503088,A priority patent/NL187124C/xx
Priority to RO7581771A priority patent/RO69176A/ro
Priority to FR7509313A priority patent/FR2265877B1/fr
Priority to JP50036531A priority patent/JPS5760435B2/ja
Assigned to USX CORPORATION, A CORP. OF DE reassignment USX CORPORATION, A CORP. OF DE MERGER (SEE DOCUMENT FOR DETAILS). Assignors: UNITED STATES STEEL CORPORATION (MERGED INTO)
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00—Electroplating: Baths therefor
    • C25D3/02—Electroplating: Baths therefor from solutions
    • C25D3/30—Electroplating: Baths therefor from solutions of tin
    • C25D3/32—Electroplating: Baths therefor from solutions of tin characterised by the organic bath constituents used

Definitions

  • ABSTRACT A method for the electroplating of steel strip in a tin plating bath utilizing therein a brightening agent comg i; prising ethoxylated-naphthol sulfonic acid, wherein the ethylene oxide to naphthol ratio is 6 or 7:1.
  • the electrodeposition of tin can be effected in a variety of acid plating electrolytes.
  • all such plating processes in commercial use require at least three components: (1) an acid source, (2) a soluble tin salt and (3) one or more organic addition agents for the production of smooth, adherent and lustrous deposits of tin.
  • various polyalkylene oxides have been known to be effective. Examples of such brightening agents are shown in (1.8. Pat. No. 2,457,152.
  • the FIGURE is a graph illustrating the superior shelf life of the brightening agents of this invention.
  • the conductivity of the electrolyte is decreased by such excessive amounts of foam. Equally important, as the chain length is increased. the permissible plating range becomes narrower. That is,
  • FIGURE shows the amounts of tar-residue encountered in both phenosulfonic and sulfuric acid baths with ENSA-S and ENSA-6 brightening agents It may be seen that, in using the ENSA-S product, the amount of tar-residue encountered increases markedly after a storage period of about weeks, while no such increase is noted with the ENSA-6 product after a period of more than one year in duration.
  • a naphthol should generally be employed, since the B variety is known to be toxic.
  • the resulting adduct i.e. EN-6 or EN7
  • EN-6 or EN7 is then sulfonated at a temperature of 5090C, preferably about 8085C, with sulfuric acid having a concentration of at least about 90%, preferably 92-98%.
  • the temperature employed should be approximately inverse to the concentration of the H 50 That is, temperature should be maintained in the upper end of its range when acid concentration approaches about 90%. However, as the concentration of the acid employed increases. temperature should then be maintained at correspondingly lower temperatures, so that the temperature should be about 50C when an acid concentration of about oleum is employed.
  • the ENSA6 and ENSA-7 brightening agents of this preferably 3 to 5 g/l, of ENSA6 or ENSA7 prepared in the manner prescribed above and (3) about 6 to 30 g/l, of free acid (calculated as H 50
  • the acid may be added either as H or phenolsulfonic acid.
  • the temperature of the bath may vary from about 83 to 145F, preferably about to F.
  • An electrolyzing current of at least about 50 amps/ft. is passed to the substrate as cathode in sufficient stages to form an electroplated tin coating of desired thickness.
  • n 6 or 7
  • said agent having been prepared by the ethoxylation of a or ,8 naphthol with said n mols of ehtylene oxide and thereafter, at a temperature within the range 50C 90C, sulfonating the resultant product with sulfuric acid, the concentration of which is at least about 90 percent.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electroplating And Plating Baths Therefor (AREA)
US454057A 1974-03-25 1974-03-25 Electrodeposition of tin Expired - Lifetime US3860502A (en)

Priority Applications (20)

Application Number Priority Date Filing Date Title
AR257005A AR205914A1 (es) 1974-03-25 1974-01-01 Bano para el recubrimiento electrolitico de substratos ferrosos y metodo para la preparacion de un acido sulfonico de naftol etoxilado utilizado en el misma
US454057A US3860502A (en) 1974-03-25 1974-03-25 Electrodeposition of tin
CA214,244A CA1034076A (en) 1974-03-25 1974-11-20 Addition agent for acid tinplating
ZA00747706A ZA747706B (en) 1974-03-25 1974-12-03 Improved addition agent for acid tinplating
AU76045/74A AU483323B2 (en) 1974-03-25 1974-12-04 Electrodeposotion of tin
PH16617A PH10766A (en) 1974-03-25 1974-12-12 Improved addition agent for acid tinplating
DE2459428A DE2459428C2 (de) 1974-03-25 1974-12-16 Verfahren zur Herstellung eines Glanzbildners für saure galvanische Zinnbäder und dessen Verwendung
ES433440A ES433440A1 (es) 1974-03-25 1974-12-30 Perfeccionamientos introducidos en el chapado electroliticode sustratos ferreos.
BR2/75A BR7500002A (pt) 1974-03-25 1975-01-02 Aperfeicoamento na eletro deposicao de substratos ferrosos com um revestimento de estanho
HU75UE00000060A HU172102B (hu) 1974-03-25 1975-01-06 Sposob poluchenija olovjanistogo pokrytija na stali
GB63775A GB1432127A (en) 1974-03-25 1975-01-07 Addition agent for acid tin electroplating
YU0031/75A YU36999B (en) 1974-03-25 1975-01-09 Process for obtaining brightening agents for tin coatings, electrolytically applied on steel sheet and band surfaces
IT67264/75A IT1027443B (it) 1974-03-25 1975-01-31 Procedimento per la stagnatura di lastre e bande d acciaio
BE153223A BE825373A (fr) 1974-03-25 1975-02-10 Additif pour l'etamage electrolytique en bain acide
PL1975178329A PL96074B1 (pl) 1974-03-25 1975-02-24 Sposob galwanicznego pokrywania cynowa powloka przedmiotow zelaznych
TR18571A TR18571A (tr) 1974-03-25 1975-03-11 Asitle kalay kaplanmasina mahsus katki maddesi
NLAANVRAGE7503088,A NL187124C (nl) 1974-03-25 1975-03-14 Werkwijze voor het bereiden van een glansmiddel voor zure galvanische tinbaden en werkwijze voor het vertinnen van ferrosubstraten.
RO7581771A RO69176A (ro) 1974-03-25 1975-03-24 Baie galvanica acida de stanare lucioasa
FR7509313A FR2265877B1 (ro) 1974-03-25 1975-03-25
JP50036531A JPS5760435B2 (ro) 1974-03-25 1975-03-25

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US454057A US3860502A (en) 1974-03-25 1974-03-25 Electrodeposition of tin

Publications (1)

Publication Number Publication Date
US3860502A true US3860502A (en) 1975-01-14

Family

ID=23803119

Family Applications (1)

Application Number Title Priority Date Filing Date
US454057A Expired - Lifetime US3860502A (en) 1974-03-25 1974-03-25 Electrodeposition of tin

Country Status (19)

Country Link
US (1) US3860502A (ro)
JP (1) JPS5760435B2 (ro)
AR (1) AR205914A1 (ro)
BE (1) BE825373A (ro)
BR (1) BR7500002A (ro)
CA (1) CA1034076A (ro)
DE (1) DE2459428C2 (ro)
ES (1) ES433440A1 (ro)
FR (1) FR2265877B1 (ro)
GB (1) GB1432127A (ro)
HU (1) HU172102B (ro)
IT (1) IT1027443B (ro)
NL (1) NL187124C (ro)
PH (1) PH10766A (ro)
PL (1) PL96074B1 (ro)
RO (1) RO69176A (ro)
TR (1) TR18571A (ro)
YU (1) YU36999B (ro)
ZA (1) ZA747706B (ro)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0319997A1 (en) * 1987-12-10 1989-06-14 LeaRonal, Inc. Tin, lead or tin/lead alloy electrolytes for high speed electroplating
US5066367A (en) * 1981-09-11 1991-11-19 Learonal Inc. Limiting tin sludge formation in tin or tin/lead electroplating solutions
US5174887A (en) * 1987-12-10 1992-12-29 Learonal, Inc. High speed electroplating of tinplate
US5427677A (en) * 1994-02-18 1995-06-27 Learonal, Inc. Flux for reflowing tinplate
US5814202A (en) * 1997-10-14 1998-09-29 Usx Corporation Electrolytic tin plating process with reduced sludge production
EP1754805A1 (en) * 2005-08-19 2007-02-21 Rohm and Haas Electronic Materials LLC Tin electroplating solution and tin electroplating method

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4511631A (en) * 1984-04-13 1985-04-16 Toyo Kohan Co., Ltd. Metallic chromium-nickel-hydrated chromium oxide-coated tin free steel and process for the production thereof
JPS63162894A (ja) * 1986-12-26 1988-07-06 Nippon Mining Co Ltd リフロ−錫めつき材の製造方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2457152A (en) * 1943-07-07 1948-12-28 Du Pont Electrodepositing composition and bath

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2457152A (en) * 1943-07-07 1948-12-28 Du Pont Electrodepositing composition and bath

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5066367A (en) * 1981-09-11 1991-11-19 Learonal Inc. Limiting tin sludge formation in tin or tin/lead electroplating solutions
EP0319997A1 (en) * 1987-12-10 1989-06-14 LeaRonal, Inc. Tin, lead or tin/lead alloy electrolytes for high speed electroplating
US4880507A (en) * 1987-12-10 1989-11-14 Learonal, Inc. Tin, lead or tin/lead alloy electrolytes for high speed electroplating
US5174887A (en) * 1987-12-10 1992-12-29 Learonal, Inc. High speed electroplating of tinplate
US5427677A (en) * 1994-02-18 1995-06-27 Learonal, Inc. Flux for reflowing tinplate
US5814202A (en) * 1997-10-14 1998-09-29 Usx Corporation Electrolytic tin plating process with reduced sludge production
EP1754805A1 (en) * 2005-08-19 2007-02-21 Rohm and Haas Electronic Materials LLC Tin electroplating solution and tin electroplating method
US20070068823A1 (en) * 2005-08-19 2007-03-29 Rohm And Haas Electronic Materials Llc Tin electroplating solution and tin electroplating method
US20100038254A1 (en) * 2005-08-19 2010-02-18 Rohm And Haas Electronic Materials Llc Tin electroplating solution and tin electroplating method
CN1928164B (zh) * 2005-08-19 2010-05-12 罗门哈斯电子材料有限公司 锡电镀液及锡电镀方法

Also Published As

Publication number Publication date
ES433440A1 (es) 1976-11-16
AU7604574A (en) 1976-06-10
HU172102B (hu) 1978-05-28
BR7500002A (pt) 1975-12-16
IT1027443B (it) 1978-11-20
JPS5760435B2 (ro) 1982-12-20
RO69176A (ro) 1981-08-17
DE2459428A1 (de) 1975-10-02
PH10766A (en) 1977-09-05
NL7503088A (nl) 1975-09-29
YU3175A (en) 1982-02-25
YU36999B (en) 1984-08-31
JPS50130648A (ro) 1975-10-16
DE2459428C2 (de) 1985-05-23
NL187124B (nl) 1991-01-02
PL96074B1 (pl) 1977-12-31
CA1034076A (en) 1978-07-04
NL187124C (nl) 1991-06-03
FR2265877B1 (ro) 1978-12-08
ZA747706B (en) 1975-12-31
TR18571A (tr) 1977-04-11
GB1432127A (en) 1976-04-14
FR2265877A1 (ro) 1975-10-24
AR205914A1 (es) 1976-06-15
BE825373A (fr) 1975-08-11

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Legal Events

Date Code Title Description
AS Assignment

Owner name: USX CORPORATION, A CORP. OF DE, STATELESS

Free format text: MERGER;ASSIGNOR:UNITED STATES STEEL CORPORATION (MERGED INTO);REEL/FRAME:005060/0960

Effective date: 19880112