US3778127A - Sealing technique for gas panel - Google Patents

Sealing technique for gas panel Download PDF

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Publication number
US3778127A
US3778127A US00214298A US3778127DA US3778127A US 3778127 A US3778127 A US 3778127A US 00214298 A US00214298 A US 00214298A US 3778127D A US3778127D A US 3778127DA US 3778127 A US3778127 A US 3778127A
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Prior art keywords
sealing material
gas
sealing
rods
envelope
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US00214298A
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English (en)
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P Langston
R Tummala
D Wilson
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International Business Machines Corp
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International Business Machines Corp
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J9/00Apparatus or processes specially adapted for the manufacture, installation, removal, maintenance of electric discharge tubes, discharge lamps, or parts thereof; Recovery of material from discharge tubes or lamps
    • H01J9/24Manufacture or joining of vessels, leading-in conductors or bases
    • H01J9/26Sealing together parts of vessels
    • H01J9/261Sealing together parts of vessels the vessel being for a flat panel display

Definitions

  • ABSTRACT In a method for sealing a gaseous display and/0r memory device, an unfused, low-softening point glass rod sealant, arranged in a picture frame pattern, together with high-softening point glass spacing rods are positioned between a pair of aligned flat glass plates, and the resulting assembly is placed in an oven enclosure. The assembly is then heated above the softening point of the glass rod sealant which reflows and fuses the plates to establish a gas-filled envelope. As the sealing material softens, the upper plate settles u;on the spacing rods to thus establish a predetermined and uniform spacing within the envelope.
  • a gaseous display and/or memory device comprises an open panel configuration of electrically isolated but not physically isolated cells in which individual cells or sites are selected by energizing associated pairs of orthogonal drive lines disposed on opposite sides of a gasfilled envelope which, when appropriately and selectively energized, cause the gas in the sites between the selected conductors to ionize.
  • a gasfilled envelope In order to provide substantially uniform resolution over the entire display surface, it is essential that the space between opposing walls of the gas envelope be maintained substantially uniform and that the walls of the chamber be sealed to provide a gas-filled container. Ihitially, such panels were sealed using epoxy which produced outgassing, i.e., impurities in the gas mixture which substantially lowered the life of the panel.
  • the glass sealant material is selected to have viscosity sufficiently low to flow during the heat fusion cycling, and yet high enough so that it will not run off the voids during such cycling.
  • the panel is pumped down and backfilled during a bakeout operation to eliminate outgassing or other impurities, and the. tubular orifice projecting from one of the plates and utilized as a vehicle for evacnation and gas filling is tipped off, thereby sealing the gas within the panel.
  • vacuum and gas are coupled to the envelope while the exterior of the glass plates receives atmospheric pressure.
  • an object of the present invention is to provide an improved sealing method for a gaseous discharge device.
  • Another object of the present invention is to provide an improved gas panel assembly utilizing soft glass sealant and hard glass spacing rods.
  • An associated object of the present invention is to provide an improved process for providng a gas panel seal utilizing a soft glass rod sealant and a hard glass rod spacer wherein the upper plate settles upon the spacing rods during a bakeout operation thus establishing a predetermined and uniform spacing within the envelope.
  • FIG. I is a partially schematic perspective view of a gas panel constructed in accordance with the teaching of the instant invention.
  • FIGS. 24 are sectional views of the assembly of FIG. 1 before and after the heat fusion state of the assembly processing.
  • FIG. 5 is a schematic view of vacuum furnace apparatus utilized in the practice of the present invention to provide evacuation, gas-filling and heat-sealing stages.
  • FIG. 1 there is illustrated a gaseous discharge assembly fabricated in accordance with the teaching of the instant invention.
  • the panel assembly 1 consists of lower glass substrate 3 and an upper glass substrate 5 on which transverse passivated metallized conductor arrays 7 and 9, respectively, are formed.
  • Conductor arrays 7 and 9 may be formed on substrates 3 and 5 by a number of well-known processes such as photoetching, vacuum deposition, stencil screening, etc.
  • conductor arrays 7 and 9 may be wires or filaments of copper, gold, silver, aluminum or any other conductive metal or material, formed in situ conductor arrays of transparent, semi-transparent or opaque conductive material are preferred since they are more easily deposited on and adhered to the substrates 3, 5.
  • opaque chrome-copper-chrome conductors having a split conductor configuration such as that described in the foregoing application Ser. No. 214,348 are utilized in one of the conductor arrays as the preferred electrode configuration for maximum light output. While not evident in FIG. 1 since they are transparent, each of the conductor arrays 7 and 9 have dielectric layers 11 and 13 (FIG. 3) formed thereon.
  • the two metallized passivated dielectric coated front and rear glass plates 3 and 5 and exhaust tube 15 are formed into an integral structure by heat union of rod sealant 17 with dielectric plate coatings 11 and 13 of glass substrates 3 and 5, respectively.
  • the broken-away portion of FIG. 1 indicates an edge spacer rod 23, one of which would be utilized around each edge in the preferred embodiment shown in FIG. 1.
  • the fused seal is indicated in the broken-away section of FIG. 1 as element 25.
  • the dielectric layers 11 and 13 (FIG. 2), formed from sprayed and heated glass frit, cover the conductor arrays indicated schematically as 7 and 9 in FIG.
  • All glasses used in the fabrication of the subject panel such as the substrate, dielectric layers, orifice, orifice sealant, border sealant, etc., must have compatible thermal coefficients of expansion, albeit differing optical, physical, dielectric and heat-softening properties.
  • the glass substrates 3 and 5 have substantial thickness (e.g. onefourth inch), the only requirement for such support members being that they be nonconductive and good insulators and substantially transparent for display purposes. Ordinary inch commerical grade soda-limesilica glass is utilized in the preferred embodiment. While the panel illustrated in FIG. 1 is representative of a panel after scaling in accordance with the instant invention, reference is made to FIGS. 2-4 for a more complete description of the operation of the sealing process.
  • FIG. 2 the relative position of the glass plates 3 and 5 with their associated dielectric coated conductor arrays prior to the sealing process is illustrated. While shown exaggerated for ease of understanding, the relative size of sealing rod 17 with respect to the spacing rod 23 is illustrated. In a preferred embodiment constructed in accordance with the instant invention, the soft glass sealant 17 is approximately 40 mils in diameter, while the spacer rod 23 is approximately 7 mils in diameter. However, as noted previously, the configuration of the rods may vary, and other configurations of both sealing and spacing rods such as rectangular rods could be substituted for the circular rods illustrated in the preferred embodiment. When laid out in the general configuration shown in FIG.
  • the component parts of the panel are placed in an oven which is then heated to a temperature sufficient to produce wetting or melting of the low-softening point envelope sealant 17 which, as previously described, comprises in the preferred embodiment a single rod in the form of a picture frame positioned outside the normal display area of the panels.
  • the peripheral spacer rod 23 could comprise a single rod in the same general picture frame configuration or four or more separate spacer rods.
  • the unjoined assembly when positioned in the desired orientation shown generally in FIG. 2, is placed in an oven enclosure and then heated in accordance with the sequence more fully described hereinafter such that the soft glass sealant 17 softens, flows and fuses with the dielectric metallization coating layers 13 and 11.
  • the sealing rods are positioned beyond the viewing area of the panel and thus beyond the conductor configurations comprising conductor arrays 7 and 9, although this is not a requirement.
  • the upper plate 5 gradually settles against spacers 23, establishing the desired final dimensions of the gasfilled sealed envelope contained between the plates. While the weight of the upper plate 5 is normally adequate, a glass weight providing a pressure of up to 5 lbs. per square inch throughout the sealing area may be added to upper plate 5. Thickness and viscosity of the unfused envelope sealant are selected so that upon softening and flowing the sealant forms a uniform void-free lining around the rectangular parallelepiped gas enclosure space shown within the sealed area bounded by seal 25 in FIG. 1.
  • FIG. 3 An enlarged view of the left seal in FIG. 3 is illustrated in FIG. 4, and it will be appreciated that an identical sealing operation and sequence would simultaneously take place along the four edges to be sealed within the panel.
  • FIG. 5 the apparatus for providing the pumpdown, bakeout and backfill operation re-' quired to fabricate a gas panel is illustrated schematically in FIG. 5.
  • the gas from a gas source 29 is applied through conduit 31 and valve 33 to a metering valve 35 which controls the gas to the desired pressure.
  • a metering valve 35 which controls the gas to the desired pressure.
  • an electronic manometer 37 is also connected to the metering valve 35 to a vacuum system.
  • a mechanical pump comprising a portion of the vacuum system creates an initial vacuum below 50 TOR, while a diffusion pump also conventional creates a higher vacuum in the area of 10 to 10 TOR.
  • a bakeout cycle is provided in oven enclosure 41 to eliminate any remaining impurities within the gas panel, and following the vacuum bakeout the panel is backfilled with gas from the gas source 29.
  • the apparatus of FIG. 1 is considered adequate for an understanding of the present invention.
  • Typical parameters associated with the preferred embodiment of the subject invention are as follows: Glass plates 3 and 5 are conventional soda-limesilicate glass one-fourth inch in thickness.
  • the glass sealing rods 23 are a hard glass composition described more fully hereinafter which provide a uniform gas spacing of 7 mils.
  • Dielectric layers 11 and 13 may comprise 1 mil thick lead-borosilicate glass sprayed and fired at 600C.
  • Metallization conductors 7 and 9 are chrome-copper-chrome conductors having chrome layers of 1,000 angstroms and an intermediate copper layers of 10,000-20,000 angstroms which are passivated in a forming gas as described in the aforereferenced application Ser. No. 214,348.
  • the preferred dielectric material has the following composition:
  • the plates, plate sealant, spacer tubes and tube sealants are prepared, the upper plate having a hole for tube coupling and the interior surfaces of the plates metallized, i.e., having the metallic conductors deposited, etched and passivated and the lead-borosilicate powdered glass frit which comprises the dielectric layer sprayed and reflown over the conductors.
  • the component parts are then assembled in an unjoined state as shown in FIG. 2 and placed in the oven used only for temperature cycling to heat-fuse the components into an integral assembly.
  • the space confined by the joint assembly is evacuated and baked out to establish fusion of the tube sealant to the tube and outer surface of the rear plates and fusion of the soft rod sealant between the plates to dielectric coating of the plates. Details of the specific duration and temperature of the heating cycle are described in the aforereferenced copending application Ser. No. 214,348. This and the other steps of the process are performed with the exterior of assembly at atmospheric pressure.
  • the gas discharge device is checked for leaks and then coupled to the gas source as shown in FIG. 5 where the confined space in the panel is filled with gas.
  • the tube will then be tipped off or sealed, and the terminal connection processing completed.
  • the terminal connection processing comprises removing the dielectric and passivation coatings from the plate metallization at appropriate edge termination sites while the tests provided are the conventional tests applied to gas filled envelopes and familiar to those skilled in the art.
  • the dielectric layers 11 and 13 are 1 mil thick lead-borosilicate glass sprayed and fired at 600C, the metallization composition.chrome-copper-chrome having upper and lower layers of chrome 1,000 angstroms in thickness and an intermediate layer of copper 10,000 angstroms thick. Passivation is provided in forming gas with water vapor.
  • the surfaces of dielectrics l1 and 13 in contact with the gas may be formed from a refractory materialhaving a high secondary coefficient of emission as described in the aforenoted copending application Ser. No. 176,625.
  • a process for constructing a gaseous discharge display/storage device comprising assembling discrete parts, including transparent flat members with pre-processed printed circuit metallization and dielectric coating, a tubulation for exhausting and backfilling said gaseous discharge display storage device, spacer rods and heat fusible sealing material,
  • said heat fusible sealing material being in the form of a sealing red, the cross-sectional area of said sealing rod being substantially larger than the corresponding area of said spacer rods, and
  • a process for constructing a gas discharge display/storage device comprising the steps of arranging components, including transparent non conductive plates with pre-processed printed circuit metallization and dielectric coating, a tubulation member, transparent spacer means and heat fusible sealing material in unfused condition, the cross-sectional area of said sealing means being substantially greater than that of said transparent spacer means,
  • a process according to claim 5 including the further step of weighting the upper plate to facilitate the settling of said upper plate on said spacing rods.

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Manufacture Of Electron Tubes, Discharge Lamp Vessels, Lead-In Wires, And The Like (AREA)
  • Gas-Filled Discharge Tubes (AREA)
  • Devices For Indicating Variable Information By Combining Individual Elements (AREA)
  • Joining Of Glass To Other Materials (AREA)
US00214298A 1971-12-30 1971-12-30 Sealing technique for gas panel Expired - Lifetime US3778127A (en)

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US21429871A 1971-12-30 1971-12-30

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US (1) US3778127A (enrdf_load_stackoverflow)
JP (1) JPS539832B2 (enrdf_load_stackoverflow)
CA (1) CA1007052A (enrdf_load_stackoverflow)
DE (1) DE2247630C3 (enrdf_load_stackoverflow)
FR (1) FR2166228B1 (enrdf_load_stackoverflow)
IT (1) IT971735B (enrdf_load_stackoverflow)

Cited By (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3837724A (en) * 1971-12-30 1974-09-24 Ibm Gas panel fabrication
US3858284A (en) * 1972-05-08 1975-01-07 Ibm Method of spacing the plates of a gaseous discharge device
USB351672I5 (enrdf_load_stackoverflow) * 1973-04-16 1975-01-28
US3909094A (en) * 1974-01-16 1975-09-30 Ibm Gas panel construction
US4071287A (en) * 1976-03-15 1978-01-31 International Business Machines Corporation Manufacturing process for gaseous discharge device
US4119378A (en) * 1974-07-30 1978-10-10 Owens-Illinois, Inc. Segmented gas discharge display panel device and method of manufacturing same
US4125307A (en) * 1974-08-26 1978-11-14 Owens-Illinois, Inc. Method of making a gaseous discharge display panel with spacer beads in seal frame
US4139250A (en) * 1975-10-27 1979-02-13 U.S. Philips Corporation Gas discharge display panel and method of manufacturing the same
EP0008782A1 (en) * 1978-09-01 1980-03-19 E.I. Du Pont De Nemours And Company Process for providing overglaze for fired metallizations and AC plasma display panel comprising two overglazed substrates
US4346951A (en) * 1980-06-19 1982-08-31 Burroughs Corporation Method for providing a gas reservoir for a gas display panel
US4407658A (en) * 1981-03-02 1983-10-04 Beckman Instruments, Inc. Gas discharge display device sealing method for reducing gas contamination
US4588261A (en) * 1984-06-07 1986-05-13 Rca Corporation IR-CCD imager and method of making the same
US5562517A (en) * 1994-04-13 1996-10-08 Texas Instruments Incorporated Spacer for flat panel display
US5657607A (en) * 1989-08-23 1997-08-19 University Of Sydney Thermally insulating glass panel and method of construction
US5811926A (en) * 1996-06-18 1998-09-22 Ppg Industries, Inc. Spacer units, image display panels and methods for making and using the same
WO1998043280A1 (de) * 1997-03-21 1998-10-01 Patent-Treuhand-Gesellschaft für elektrische Glühlampen mbH Flachstrahler mit dielektrisch behinderter entladung und anordnung zur durchführung der elektroden in den entladungsraum
US5834891A (en) * 1996-06-18 1998-11-10 Ppg Industries, Inc. Spacers, spacer units, image display panels and methods for making and using the same
US5902652A (en) * 1993-06-30 1999-05-11 University Of Sydney Methods of construction of evacuated glazing
WO2001061721A1 (de) * 2000-02-15 2001-08-23 Patent-Treuhand-Gesellschaft für elektrische Glühlampen mbH Herstellungsverfahren für eine flache gasentladungslampe
RU2188463C1 (ru) * 2000-12-05 2002-08-27 Открытое акционерное общество "Научно-исследовательский институт газоразрядных приборов "Плазма" Газоразрядная индикаторная панель переменного тока
US6452323B1 (en) * 1999-09-20 2002-09-17 Omnion Technologies, Inc. Luminous gas discharge display having dielectric sealing layer
US6590332B1 (en) * 1999-08-06 2003-07-08 Samsung Sdi Co., Ltd. Plasma display panel including front and rear substrate assemblies
US20040100180A1 (en) * 2001-11-02 2004-05-27 Byrum Bernard W. Low voltage high efficiency illuminated display having capacitive coupled electrodes
US20050067956A1 (en) * 2003-09-25 2005-03-31 Doo-Young Kim Plasma display panel assembly
US20050116647A1 (en) * 2003-11-29 2005-06-02 Jin-Sub Kim Plasma display apparatus
US20060066238A1 (en) * 2004-09-24 2006-03-30 Seok-Gyun Woo Plasma display panel and plasma display device
US20060157274A1 (en) * 2002-03-22 2006-07-20 Stark David H Wafer-level hermetic micro-device packages
US20080042566A1 (en) * 2006-03-29 2008-02-21 Jung-Suk Song Plasma display panel
US20100034996A1 (en) * 2008-08-09 2010-02-11 Lawrence Mott Asymmetrical flexible edge seal for vacuum insulating glass
US20100175347A1 (en) * 2009-01-15 2010-07-15 Bettger Kenneth J Filament-strung stand-off elements for maintaining pane separation in vacuum insulating glazing units
US20100178439A1 (en) * 2009-01-15 2010-07-15 Eversealed Windows, Inc. Flexible edge seal for vacuum insulating glazing units
US7832177B2 (en) 2002-03-22 2010-11-16 Electronics Packaging Solutions, Inc. Insulated glazing units
US7989040B2 (en) 2007-09-14 2011-08-02 Electronics Packaging Solutions, Inc. Insulating glass unit having multi-height internal standoffs and visible decoration
US8950162B2 (en) 2010-06-02 2015-02-10 Eversealed Windows, Inc. Multi-pane glass unit having seal with adhesive and hermetic coating layer
US9328512B2 (en) 2011-05-05 2016-05-03 Eversealed Windows, Inc. Method and apparatus for an insulating glazing unit and compliant seal for an insulating glazing unit

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JPS4890199A (enrdf_load_stackoverflow) * 1972-02-26 1973-11-24
JPS4952576A (enrdf_load_stackoverflow) * 1972-09-20 1974-05-22
JPS5081562A (enrdf_load_stackoverflow) * 1973-11-20 1975-07-02
US4018490A (en) * 1975-07-07 1977-04-19 International Business Machines Corporation Gas discharge display panel fabrication
JPS5220249U (enrdf_load_stackoverflow) * 1975-07-31 1977-02-14
JPS5287975A (en) * 1976-01-19 1977-07-22 Hamamatsu Tv Co Ltd Method of manufacturing fluorescent display tube
JPS6048737B2 (ja) * 1977-03-30 1985-10-29 株式会社日立製作所 液晶表示装置の製造方法
JPS5536843A (en) * 1978-09-07 1980-03-14 Seiko Epson Corp Liquid display panel
JPS59176026U (ja) * 1983-05-10 1984-11-24 オリンパス光学工業株式会社 モ−タドライブ装置
JPS59176027U (ja) * 1983-05-11 1984-11-24 オリンパス光学工業株式会社 モ−タドライブ装置
DE19817478B4 (de) * 1998-04-20 2004-03-18 Patent-Treuhand-Gesellschaft für elektrische Glühlampen mbH Flache Entladungslampe und Verfahren zu ihrer Herstellung
DE19826809A1 (de) * 1998-06-16 1999-12-23 Patent Treuhand Ges Fuer Elektrische Gluehlampen Mbh Dielektrische Schicht für Entladungslampen und zugehöriges Herstellungsverfahren
FR2781308A1 (fr) * 1998-07-15 2000-01-21 Thomson Plasma Procede de realisation de moyens d'entretoisement pour panneaux de visualisation
DE19936864A1 (de) 1999-08-05 2001-02-15 Patent Treuhand Ges Fuer Elektrische Gluehlampen Mbh Verfahren zum Einsetzen eines Pumpstengels in ein Entladungsgefäß

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GB1247372A (en) * 1967-10-18 1971-09-22 Burroughs Corp Display panel
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US3340347A (en) * 1964-10-12 1967-09-05 Corning Glass Works Enclosed electronic device
US3559190A (en) * 1966-01-18 1971-01-26 Univ Illinois Gaseous display and memory apparatus
US3499167A (en) * 1967-11-24 1970-03-03 Owens Illinois Inc Gas discharge display memory device and method of operating
US3614509A (en) * 1969-05-07 1971-10-19 Westinghouse Electric Corp Large area plasma panel display device
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Cited By (48)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3837724A (en) * 1971-12-30 1974-09-24 Ibm Gas panel fabrication
US3858284A (en) * 1972-05-08 1975-01-07 Ibm Method of spacing the plates of a gaseous discharge device
USB351672I5 (enrdf_load_stackoverflow) * 1973-04-16 1975-01-28
US3914000A (en) * 1973-04-16 1975-10-21 Ibm Method of making tubeless gas panel
US3909094A (en) * 1974-01-16 1975-09-30 Ibm Gas panel construction
US4119378A (en) * 1974-07-30 1978-10-10 Owens-Illinois, Inc. Segmented gas discharge display panel device and method of manufacturing same
US4125307A (en) * 1974-08-26 1978-11-14 Owens-Illinois, Inc. Method of making a gaseous discharge display panel with spacer beads in seal frame
US4139250A (en) * 1975-10-27 1979-02-13 U.S. Philips Corporation Gas discharge display panel and method of manufacturing the same
US4071287A (en) * 1976-03-15 1978-01-31 International Business Machines Corporation Manufacturing process for gaseous discharge device
EP0008782A1 (en) * 1978-09-01 1980-03-19 E.I. Du Pont De Nemours And Company Process for providing overglaze for fired metallizations and AC plasma display panel comprising two overglazed substrates
US4346951A (en) * 1980-06-19 1982-08-31 Burroughs Corporation Method for providing a gas reservoir for a gas display panel
US4407658A (en) * 1981-03-02 1983-10-04 Beckman Instruments, Inc. Gas discharge display device sealing method for reducing gas contamination
US4588261A (en) * 1984-06-07 1986-05-13 Rca Corporation IR-CCD imager and method of making the same
US5657607A (en) * 1989-08-23 1997-08-19 University Of Sydney Thermally insulating glass panel and method of construction
US5902652A (en) * 1993-06-30 1999-05-11 University Of Sydney Methods of construction of evacuated glazing
US6103324A (en) * 1993-06-30 2000-08-15 The University Of Sydney Methods of construction of evacuated glazing
US5562517A (en) * 1994-04-13 1996-10-08 Texas Instruments Incorporated Spacer for flat panel display
US5811926A (en) * 1996-06-18 1998-09-22 Ppg Industries, Inc. Spacer units, image display panels and methods for making and using the same
US5834891A (en) * 1996-06-18 1998-11-10 Ppg Industries, Inc. Spacers, spacer units, image display panels and methods for making and using the same
WO1998043280A1 (de) * 1997-03-21 1998-10-01 Patent-Treuhand-Gesellschaft für elektrische Glühlampen mbH Flachstrahler mit dielektrisch behinderter entladung und anordnung zur durchführung der elektroden in den entladungsraum
US6590332B1 (en) * 1999-08-06 2003-07-08 Samsung Sdi Co., Ltd. Plasma display panel including front and rear substrate assemblies
US6913502B2 (en) 1999-08-06 2005-07-05 Samsung Sdi Co., Ltd. Method of fabricating plasma display panel
US6452323B1 (en) * 1999-09-20 2002-09-17 Omnion Technologies, Inc. Luminous gas discharge display having dielectric sealing layer
WO2001061721A1 (de) * 2000-02-15 2001-08-23 Patent-Treuhand-Gesellschaft für elektrische Glühlampen mbH Herstellungsverfahren für eine flache gasentladungslampe
RU2188463C1 (ru) * 2000-12-05 2002-08-27 Открытое акционерное общество "Научно-исследовательский институт газоразрядных приборов "Плазма" Газоразрядная индикаторная панель переменного тока
US20040100180A1 (en) * 2001-11-02 2004-05-27 Byrum Bernard W. Low voltage high efficiency illuminated display having capacitive coupled electrodes
US6836072B2 (en) 2001-11-02 2004-12-28 Electro Plasma, Inc. Low voltage high efficiency illuminated display having capacitive coupled electrodes
US7832177B2 (en) 2002-03-22 2010-11-16 Electronics Packaging Solutions, Inc. Insulated glazing units
US20060157274A1 (en) * 2002-03-22 2006-07-20 Stark David H Wafer-level hermetic micro-device packages
US7517712B2 (en) 2002-03-22 2009-04-14 Electronics Packaging Solutions, Inc. Wafer-level hermetic micro-device packages
US7550921B2 (en) * 2003-09-25 2009-06-23 Samsung Sdi Co., Ltd. Plasma display panel assembly
US20050067956A1 (en) * 2003-09-25 2005-03-31 Doo-Young Kim Plasma display panel assembly
US20050116647A1 (en) * 2003-11-29 2005-06-02 Jin-Sub Kim Plasma display apparatus
US7368871B2 (en) * 2003-11-29 2008-05-06 Samsung Sdi Co., Ltd. Plasma display apparatus with improved substrates
US20060066238A1 (en) * 2004-09-24 2006-03-30 Seok-Gyun Woo Plasma display panel and plasma display device
US7514869B2 (en) * 2004-09-24 2009-04-07 Samsung Sdi Co., Ltd. Plasma display panel and plasma display device
US20080042566A1 (en) * 2006-03-29 2008-02-21 Jung-Suk Song Plasma display panel
US7679288B2 (en) * 2006-03-29 2010-03-16 Samsung Sdi Co., Ltd. Plasma display panel
US7989040B2 (en) 2007-09-14 2011-08-02 Electronics Packaging Solutions, Inc. Insulating glass unit having multi-height internal standoffs and visible decoration
US20100034996A1 (en) * 2008-08-09 2010-02-11 Lawrence Mott Asymmetrical flexible edge seal for vacuum insulating glass
US8283023B2 (en) 2008-08-09 2012-10-09 Eversealed Windows, Inc. Asymmetrical flexible edge seal for vacuum insulating glass
US20100178439A1 (en) * 2009-01-15 2010-07-15 Eversealed Windows, Inc. Flexible edge seal for vacuum insulating glazing units
US20100175347A1 (en) * 2009-01-15 2010-07-15 Bettger Kenneth J Filament-strung stand-off elements for maintaining pane separation in vacuum insulating glazing units
US8329267B2 (en) 2009-01-15 2012-12-11 Eversealed Windows, Inc. Flexible edge seal for vacuum insulating glazing units
US8512830B2 (en) 2009-01-15 2013-08-20 Eversealed Windows, Inc. Filament-strung stand-off elements for maintaining pane separation in vacuum insulating glazing units
US8950162B2 (en) 2010-06-02 2015-02-10 Eversealed Windows, Inc. Multi-pane glass unit having seal with adhesive and hermetic coating layer
US9328512B2 (en) 2011-05-05 2016-05-03 Eversealed Windows, Inc. Method and apparatus for an insulating glazing unit and compliant seal for an insulating glazing unit
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JPS4879573A (enrdf_load_stackoverflow) 1973-10-25
CA1007052A (en) 1977-03-22
DE2247630C3 (de) 1982-03-04
JPS539832B2 (enrdf_load_stackoverflow) 1978-04-08
FR2166228B1 (enrdf_load_stackoverflow) 1975-03-28
DE2247630B2 (de) 1981-06-25
DE2247630A1 (de) 1973-12-20
IT971735B (it) 1974-05-10
FR2166228A1 (enrdf_load_stackoverflow) 1973-08-10

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