US3722574A - Process of making magnesium oxide cores - Google Patents

Process of making magnesium oxide cores Download PDF

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Publication number
US3722574A
US3722574A US00158128A US3722574DA US3722574A US 3722574 A US3722574 A US 3722574A US 00158128 A US00158128 A US 00158128A US 3722574D A US3722574D A US 3722574DA US 3722574 A US3722574 A US 3722574A
Authority
US
United States
Prior art keywords
core
magnesium oxide
slurry
magnesium
investment casting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US00158128A
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English (en)
Inventor
J Anderson
J Perron
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Raytheon Technologies Corp
Original Assignee
United Aircraft Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by United Aircraft Corp filed Critical United Aircraft Corp
Application granted granted Critical
Publication of US3722574A publication Critical patent/US3722574A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C9/00Moulds or cores; Moulding processes
    • B22C9/10Cores; Manufacture or installation of cores
    • B22C9/105Salt cores

Definitions

  • the present invention relates to the production of hollow, superalloy parts by investment casting techniques and more particularly to the production of metal parts formed of cobalt or nickel superalloys and containing small and narrow apertures and passages in the castings.
  • a disposable pattern which is a replica of the part to be cast and which includes any necessary gates and risers, is usually dipped in a refractory slurry which hardens to form a smooth coating that serves as the mold face.
  • the precoating or dipcoating of the pattern usually is carried out by immersing the pattern in a suspension of a fine refractory powder in a suitable liquid binder that is capable of hardening during drying at room conditions. Following dipping, the excess slurry is drained from the pattern and the coating is stuccoed while wet with coarser refractory particles which help to set the coating.
  • a ceramic shell mold is usually prepared by repeating the dipping and stuccoing operations described above until a shell having a sufficient thickness to resist the stresses occuring in subsequent operations is built up around the pattern.
  • the usual thickness range is from one-eighth of an inch to one-half of an inch, although thinner or heavier shells may be formed for special situations.
  • the disposable pattern is removed from the mold which is then prepared for the casting operation.
  • the typical pattern materials used in the process have been either wax blends or plastics such as polystyrene and, occasionally, polyethylene.
  • a ceramic core usually formed of pressed silica, is disposed within the mold at an appropriate location. While these silica cores are quite useful, they are difficult to remove with a non-corrosive leaching media after the casting has been made. It can be appreciated that when very small or fine apertures or interstices are filled with an insoluble core material that difficulty can be encountered when attempting to totally remove the material with a non-corrosive leaching medium.
  • an aqueous solution of 12 to 30 w/o magnesium chloride is mixed with w/o magnesium oxide powder to form a thick slurry.
  • the slurry is poured into a plastic or rubber die having the configuration which is desired.
  • the components react to form a complex magnesium oxychloride cement which is relatively rigid, even in the unfired state.
  • the body is fired to convert the oxychloride to the oxide, generally at temperaturesbetween about 2,200 to 2,700 F.
  • a solid, rugged magnesium oxide core is produced which can be subsequently incorporated in an investment casting process.
  • the core which was formed is generally coated by dipping it in a slurry of finely divided zirconium oxide (having an average particle size below. microns) to prevent the reaction of the magnesium with any silicates from the exterior shell of the investment casting.
  • the core of magnesium oxide may be removed by playing a jet of live steam upon it or placing the part in an autoclave filled with water at a relatively high temperature. The magnesium oxide dissolves in the steam and other leaching agents need not be added for its removal.
  • the apertures or interstices are disposed within it.
  • magnesium chloride MgCl 6H O
  • magnesium oxide were added to 55 grams of solution and a magnesium oxychloride cement (plus MgO) was formed. This cement was poured into a plastic die to solidify. When solid, it was removed from the die and fired at a temperature of 2,700F. to convert the oxychloride to the oxide.
  • a method of forming a water-soluble core for use in the manufacture of hollow articles in investment casting processes said core being adapted to be disposed within the casting so that, upon removal, hollow passages remain, said method including the steps of: admixing an aqueous solution of magnesium chloride with magnesium oxide powder to form a slurry; pouring said slurry into a die of the desired shape and allowing said slurry to harden to form a body corresponding to the shape of said die; thing said body at a temperature of 2,2002,70()F. to oxidize said magnesium chloride and form a solid magnesium oxide core, said core being useful in said investment casting process.
  • a method of forming a water-soluble core for use in the manufacture of hollow articles in investment casting processes said core being adapted to be I disposed within the casting so that, upon removal, hollow passages remain, said method including the steps of: admixing an aqueous solution of magnesium chloride with magnesium oxide powder to form a slur-

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Mold Materials And Core Materials (AREA)
  • Molds, Cores, And Manufacturing Methods Thereof (AREA)
US00158128A 1971-06-29 1971-06-29 Process of making magnesium oxide cores Expired - Lifetime US3722574A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US15812871A 1971-06-29 1971-06-29

Publications (1)

Publication Number Publication Date
US3722574A true US3722574A (en) 1973-03-27

Family

ID=22566794

Family Applications (1)

Application Number Title Priority Date Filing Date
US00158128A Expired - Lifetime US3722574A (en) 1971-06-29 1971-06-29 Process of making magnesium oxide cores

Country Status (12)

Country Link
US (1) US3722574A (fr)
JP (1) JPS5524982B1 (fr)
AU (1) AU464359B2 (fr)
BE (1) BE785335A (fr)
CA (1) CA972920A (fr)
CH (1) CH538434A (fr)
DE (1) DE2220060C3 (fr)
FR (1) FR2143646B1 (fr)
GB (1) GB1325412A (fr)
IL (1) IL39070A (fr)
IT (1) IT956344B (fr)
SE (1) SE399371B (fr)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4073662A (en) * 1977-03-09 1978-02-14 General Electric Company Method for removing a magnesia doped alumina core material
US4604140A (en) * 1984-04-26 1986-08-05 Societe Nationale De L'amiante Foundry sands derived from serpentine and foundry molds derived therefrom
US5335717A (en) * 1992-01-30 1994-08-09 Howmet Corporation Oxidation resistant superalloy castings
US6776219B1 (en) 1999-09-20 2004-08-17 Metal Matrix Cast Composites, Inc. Castable refractory investment mold materials and methods of their use in infiltration casting
US20060243421A1 (en) * 2005-04-29 2006-11-02 United States Of America, Represented By Secretary Of The U.S. Army Soluble casting core for metal matrix composite components and method of producing thereof
WO2008125351A1 (fr) * 2007-04-16 2008-10-23 Innovaris Gmbh & Co. Kg Matériau support pour la fabrication de pièces à usiner
WO2008125352A1 (fr) 2007-04-16 2008-10-23 Innovaris Gmbh & Co. Kg Matériau support pour la fabrication de pièces à usiner
US7461684B2 (en) 2002-08-20 2008-12-09 The Ex One Company, Llc Casting process and articles for performing same
US8087450B2 (en) 2007-01-29 2012-01-03 Evonik Degussa Corporation Fumed metal oxides for investment casting
CN112222363A (zh) * 2020-10-20 2021-01-15 淄博建宗复合材料有限公司 利用熔融液体一次压铸成型的陶瓷盐芯及其制备方法

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2900429A1 (de) * 1979-01-08 1980-07-17 Klepsch Kunstgalerie Verfahren zur herstellung eines doppelwandigen, hohlen gegenstandes, insbesondere eines becherfoermigen gegenstandes aus glas o.dgl., form zur durchfuehrung des verfahrens und insbesondere nach dem verfahren hergestellter gegenstand

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1306572A (fr) * 1961-11-21 1962-10-13 Mo Och Domsjoe Ab Perfectionnements à la production de noyaux et de moules de fonderie
US3407864A (en) * 1965-06-12 1968-10-29 Schmidt Gmbh Karl Forming hollow cast articles
US3473599A (en) * 1965-01-19 1969-10-21 Doulton & Co Ltd Production of metal castings
US3643728A (en) * 1970-07-08 1972-02-22 United Aircraft Corp Process of casting nickel base alloys using water-soluble calcia cores

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1306572A (fr) * 1961-11-21 1962-10-13 Mo Och Domsjoe Ab Perfectionnements à la production de noyaux et de moules de fonderie
US3473599A (en) * 1965-01-19 1969-10-21 Doulton & Co Ltd Production of metal castings
US3407864A (en) * 1965-06-12 1968-10-29 Schmidt Gmbh Karl Forming hollow cast articles
US3643728A (en) * 1970-07-08 1972-02-22 United Aircraft Corp Process of casting nickel base alloys using water-soluble calcia cores

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4073662A (en) * 1977-03-09 1978-02-14 General Electric Company Method for removing a magnesia doped alumina core material
US4604140A (en) * 1984-04-26 1986-08-05 Societe Nationale De L'amiante Foundry sands derived from serpentine and foundry molds derived therefrom
US5335717A (en) * 1992-01-30 1994-08-09 Howmet Corporation Oxidation resistant superalloy castings
US6776219B1 (en) 1999-09-20 2004-08-17 Metal Matrix Cast Composites, Inc. Castable refractory investment mold materials and methods of their use in infiltration casting
US7461684B2 (en) 2002-08-20 2008-12-09 The Ex One Company, Llc Casting process and articles for performing same
US20060243421A1 (en) * 2005-04-29 2006-11-02 United States Of America, Represented By Secretary Of The U.S. Army Soluble casting core for metal matrix composite components and method of producing thereof
US20070131374A1 (en) * 2005-04-29 2007-06-14 U.S. Government, Represented By Secretary Of The Army Soluble Casting Core For Metal Matrix Composite Components and Method of Producing Thereof
US8087450B2 (en) 2007-01-29 2012-01-03 Evonik Degussa Corporation Fumed metal oxides for investment casting
WO2008125351A1 (fr) * 2007-04-16 2008-10-23 Innovaris Gmbh & Co. Kg Matériau support pour la fabrication de pièces à usiner
US20100304178A1 (en) * 2007-04-16 2010-12-02 Hermle Maschinenbau Gmbh Carrier material for producing workpieces
US20110091660A1 (en) * 2007-04-16 2011-04-21 Hermle Maschinenbau Gmbh Carrier material for producing workpieces
WO2008125352A1 (fr) 2007-04-16 2008-10-23 Innovaris Gmbh & Co. Kg Matériau support pour la fabrication de pièces à usiner
DE102007017754B4 (de) * 2007-04-16 2016-12-29 Hermle Maschinenbau Gmbh Verfahren zur Herstellung eines Werkstücks mit mindestens einem Freiraum
CN112222363A (zh) * 2020-10-20 2021-01-15 淄博建宗复合材料有限公司 利用熔融液体一次压铸成型的陶瓷盐芯及其制备方法

Also Published As

Publication number Publication date
DE2220060C3 (de) 1975-07-31
BE785335A (fr) 1972-10-16
CH538434A (fr) 1973-06-30
FR2143646A1 (fr) 1973-02-09
IL39070A (en) 1976-10-31
FR2143646B1 (fr) 1976-06-11
IT956344B (it) 1973-10-10
JPS5524982B1 (fr) 1980-07-02
DE2220060A1 (de) 1973-01-18
GB1325412A (en) 1973-08-01
SE399371B (sv) 1978-02-13
DE2220060B2 (de) 1974-12-05
AU4114972A (en) 1973-10-18
AU464359B2 (en) 1975-08-01
CA972920A (en) 1975-08-19
IL39070A0 (en) 1972-05-30

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