US3722574A - Process of making magnesium oxide cores - Google Patents
Process of making magnesium oxide cores Download PDFInfo
- Publication number
- US3722574A US3722574A US00158128A US3722574DA US3722574A US 3722574 A US3722574 A US 3722574A US 00158128 A US00158128 A US 00158128A US 3722574D A US3722574D A US 3722574DA US 3722574 A US3722574 A US 3722574A
- Authority
- US
- United States
- Prior art keywords
- core
- magnesium oxide
- slurry
- magnesium
- investment casting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C9/00—Moulds or cores; Moulding processes
- B22C9/10—Cores; Manufacture or installation of cores
- B22C9/105—Salt cores
Definitions
- the present invention relates to the production of hollow, superalloy parts by investment casting techniques and more particularly to the production of metal parts formed of cobalt or nickel superalloys and containing small and narrow apertures and passages in the castings.
- a disposable pattern which is a replica of the part to be cast and which includes any necessary gates and risers, is usually dipped in a refractory slurry which hardens to form a smooth coating that serves as the mold face.
- the precoating or dipcoating of the pattern usually is carried out by immersing the pattern in a suspension of a fine refractory powder in a suitable liquid binder that is capable of hardening during drying at room conditions. Following dipping, the excess slurry is drained from the pattern and the coating is stuccoed while wet with coarser refractory particles which help to set the coating.
- a ceramic shell mold is usually prepared by repeating the dipping and stuccoing operations described above until a shell having a sufficient thickness to resist the stresses occuring in subsequent operations is built up around the pattern.
- the usual thickness range is from one-eighth of an inch to one-half of an inch, although thinner or heavier shells may be formed for special situations.
- the disposable pattern is removed from the mold which is then prepared for the casting operation.
- the typical pattern materials used in the process have been either wax blends or plastics such as polystyrene and, occasionally, polyethylene.
- a ceramic core usually formed of pressed silica, is disposed within the mold at an appropriate location. While these silica cores are quite useful, they are difficult to remove with a non-corrosive leaching media after the casting has been made. It can be appreciated that when very small or fine apertures or interstices are filled with an insoluble core material that difficulty can be encountered when attempting to totally remove the material with a non-corrosive leaching medium.
- an aqueous solution of 12 to 30 w/o magnesium chloride is mixed with w/o magnesium oxide powder to form a thick slurry.
- the slurry is poured into a plastic or rubber die having the configuration which is desired.
- the components react to form a complex magnesium oxychloride cement which is relatively rigid, even in the unfired state.
- the body is fired to convert the oxychloride to the oxide, generally at temperaturesbetween about 2,200 to 2,700 F.
- a solid, rugged magnesium oxide core is produced which can be subsequently incorporated in an investment casting process.
- the core which was formed is generally coated by dipping it in a slurry of finely divided zirconium oxide (having an average particle size below. microns) to prevent the reaction of the magnesium with any silicates from the exterior shell of the investment casting.
- the core of magnesium oxide may be removed by playing a jet of live steam upon it or placing the part in an autoclave filled with water at a relatively high temperature. The magnesium oxide dissolves in the steam and other leaching agents need not be added for its removal.
- the apertures or interstices are disposed within it.
- magnesium chloride MgCl 6H O
- magnesium oxide were added to 55 grams of solution and a magnesium oxychloride cement (plus MgO) was formed. This cement was poured into a plastic die to solidify. When solid, it was removed from the die and fired at a temperature of 2,700F. to convert the oxychloride to the oxide.
- a method of forming a water-soluble core for use in the manufacture of hollow articles in investment casting processes said core being adapted to be disposed within the casting so that, upon removal, hollow passages remain, said method including the steps of: admixing an aqueous solution of magnesium chloride with magnesium oxide powder to form a slurry; pouring said slurry into a die of the desired shape and allowing said slurry to harden to form a body corresponding to the shape of said die; thing said body at a temperature of 2,2002,70()F. to oxidize said magnesium chloride and form a solid magnesium oxide core, said core being useful in said investment casting process.
- a method of forming a water-soluble core for use in the manufacture of hollow articles in investment casting processes said core being adapted to be I disposed within the casting so that, upon removal, hollow passages remain, said method including the steps of: admixing an aqueous solution of magnesium chloride with magnesium oxide powder to form a slur-
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Mold Materials And Core Materials (AREA)
- Molds, Cores, And Manufacturing Methods Thereof (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US15812871A | 1971-06-29 | 1971-06-29 |
Publications (1)
Publication Number | Publication Date |
---|---|
US3722574A true US3722574A (en) | 1973-03-27 |
Family
ID=22566794
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US00158128A Expired - Lifetime US3722574A (en) | 1971-06-29 | 1971-06-29 | Process of making magnesium oxide cores |
Country Status (12)
Country | Link |
---|---|
US (1) | US3722574A (fr) |
JP (1) | JPS5524982B1 (fr) |
AU (1) | AU464359B2 (fr) |
BE (1) | BE785335A (fr) |
CA (1) | CA972920A (fr) |
CH (1) | CH538434A (fr) |
DE (1) | DE2220060C3 (fr) |
FR (1) | FR2143646B1 (fr) |
GB (1) | GB1325412A (fr) |
IL (1) | IL39070A (fr) |
IT (1) | IT956344B (fr) |
SE (1) | SE399371B (fr) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4073662A (en) * | 1977-03-09 | 1978-02-14 | General Electric Company | Method for removing a magnesia doped alumina core material |
US4604140A (en) * | 1984-04-26 | 1986-08-05 | Societe Nationale De L'amiante | Foundry sands derived from serpentine and foundry molds derived therefrom |
US5335717A (en) * | 1992-01-30 | 1994-08-09 | Howmet Corporation | Oxidation resistant superalloy castings |
US6776219B1 (en) | 1999-09-20 | 2004-08-17 | Metal Matrix Cast Composites, Inc. | Castable refractory investment mold materials and methods of their use in infiltration casting |
US20060243421A1 (en) * | 2005-04-29 | 2006-11-02 | United States Of America, Represented By Secretary Of The U.S. Army | Soluble casting core for metal matrix composite components and method of producing thereof |
WO2008125351A1 (fr) * | 2007-04-16 | 2008-10-23 | Innovaris Gmbh & Co. Kg | Matériau support pour la fabrication de pièces à usiner |
WO2008125352A1 (fr) | 2007-04-16 | 2008-10-23 | Innovaris Gmbh & Co. Kg | Matériau support pour la fabrication de pièces à usiner |
US7461684B2 (en) | 2002-08-20 | 2008-12-09 | The Ex One Company, Llc | Casting process and articles for performing same |
US8087450B2 (en) | 2007-01-29 | 2012-01-03 | Evonik Degussa Corporation | Fumed metal oxides for investment casting |
CN112222363A (zh) * | 2020-10-20 | 2021-01-15 | 淄博建宗复合材料有限公司 | 利用熔融液体一次压铸成型的陶瓷盐芯及其制备方法 |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2900429A1 (de) * | 1979-01-08 | 1980-07-17 | Klepsch Kunstgalerie | Verfahren zur herstellung eines doppelwandigen, hohlen gegenstandes, insbesondere eines becherfoermigen gegenstandes aus glas o.dgl., form zur durchfuehrung des verfahrens und insbesondere nach dem verfahren hergestellter gegenstand |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1306572A (fr) * | 1961-11-21 | 1962-10-13 | Mo Och Domsjoe Ab | Perfectionnements à la production de noyaux et de moules de fonderie |
US3407864A (en) * | 1965-06-12 | 1968-10-29 | Schmidt Gmbh Karl | Forming hollow cast articles |
US3473599A (en) * | 1965-01-19 | 1969-10-21 | Doulton & Co Ltd | Production of metal castings |
US3643728A (en) * | 1970-07-08 | 1972-02-22 | United Aircraft Corp | Process of casting nickel base alloys using water-soluble calcia cores |
-
1971
- 1971-06-29 US US00158128A patent/US3722574A/en not_active Expired - Lifetime
-
1972
- 1972-02-02 CA CA133,814A patent/CA972920A/en not_active Expired
- 1972-03-21 GB GB1317872A patent/GB1325412A/en not_active Expired
- 1972-03-24 IL IL39070A patent/IL39070A/en unknown
- 1972-03-28 FR FR7211411A patent/FR2143646B1/fr not_active Expired
- 1972-04-14 SE SE7204854A patent/SE399371B/xx unknown
- 1972-04-14 AU AU41149/72A patent/AU464359B2/en not_active Expired
- 1972-04-21 CH CH599272A patent/CH538434A/fr not_active IP Right Cessation
- 1972-04-24 DE DE2220060A patent/DE2220060C3/de not_active Expired
- 1972-06-08 IT IT25385/72A patent/IT956344B/it active
- 1972-06-23 BE BE785335A patent/BE785335A/fr unknown
- 1972-06-24 JP JP6361772A patent/JPS5524982B1/ja active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1306572A (fr) * | 1961-11-21 | 1962-10-13 | Mo Och Domsjoe Ab | Perfectionnements à la production de noyaux et de moules de fonderie |
US3473599A (en) * | 1965-01-19 | 1969-10-21 | Doulton & Co Ltd | Production of metal castings |
US3407864A (en) * | 1965-06-12 | 1968-10-29 | Schmidt Gmbh Karl | Forming hollow cast articles |
US3643728A (en) * | 1970-07-08 | 1972-02-22 | United Aircraft Corp | Process of casting nickel base alloys using water-soluble calcia cores |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4073662A (en) * | 1977-03-09 | 1978-02-14 | General Electric Company | Method for removing a magnesia doped alumina core material |
US4604140A (en) * | 1984-04-26 | 1986-08-05 | Societe Nationale De L'amiante | Foundry sands derived from serpentine and foundry molds derived therefrom |
US5335717A (en) * | 1992-01-30 | 1994-08-09 | Howmet Corporation | Oxidation resistant superalloy castings |
US6776219B1 (en) | 1999-09-20 | 2004-08-17 | Metal Matrix Cast Composites, Inc. | Castable refractory investment mold materials and methods of their use in infiltration casting |
US7461684B2 (en) | 2002-08-20 | 2008-12-09 | The Ex One Company, Llc | Casting process and articles for performing same |
US20060243421A1 (en) * | 2005-04-29 | 2006-11-02 | United States Of America, Represented By Secretary Of The U.S. Army | Soluble casting core for metal matrix composite components and method of producing thereof |
US20070131374A1 (en) * | 2005-04-29 | 2007-06-14 | U.S. Government, Represented By Secretary Of The Army | Soluble Casting Core For Metal Matrix Composite Components and Method of Producing Thereof |
US8087450B2 (en) | 2007-01-29 | 2012-01-03 | Evonik Degussa Corporation | Fumed metal oxides for investment casting |
WO2008125351A1 (fr) * | 2007-04-16 | 2008-10-23 | Innovaris Gmbh & Co. Kg | Matériau support pour la fabrication de pièces à usiner |
US20100304178A1 (en) * | 2007-04-16 | 2010-12-02 | Hermle Maschinenbau Gmbh | Carrier material for producing workpieces |
US20110091660A1 (en) * | 2007-04-16 | 2011-04-21 | Hermle Maschinenbau Gmbh | Carrier material for producing workpieces |
WO2008125352A1 (fr) | 2007-04-16 | 2008-10-23 | Innovaris Gmbh & Co. Kg | Matériau support pour la fabrication de pièces à usiner |
DE102007017754B4 (de) * | 2007-04-16 | 2016-12-29 | Hermle Maschinenbau Gmbh | Verfahren zur Herstellung eines Werkstücks mit mindestens einem Freiraum |
CN112222363A (zh) * | 2020-10-20 | 2021-01-15 | 淄博建宗复合材料有限公司 | 利用熔融液体一次压铸成型的陶瓷盐芯及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
DE2220060C3 (de) | 1975-07-31 |
BE785335A (fr) | 1972-10-16 |
CH538434A (fr) | 1973-06-30 |
FR2143646A1 (fr) | 1973-02-09 |
IL39070A (en) | 1976-10-31 |
FR2143646B1 (fr) | 1976-06-11 |
IT956344B (it) | 1973-10-10 |
JPS5524982B1 (fr) | 1980-07-02 |
DE2220060A1 (de) | 1973-01-18 |
GB1325412A (en) | 1973-08-01 |
SE399371B (sv) | 1978-02-13 |
DE2220060B2 (de) | 1974-12-05 |
AU4114972A (en) | 1973-10-18 |
AU464359B2 (en) | 1975-08-01 |
CA972920A (en) | 1975-08-19 |
IL39070A0 (en) | 1972-05-30 |
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