US3697644A - Cosmetic composition - Google Patents

Cosmetic composition Download PDF

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Publication number
US3697644A
US3697644A US587387A US3697644DA US3697644A US 3697644 A US3697644 A US 3697644A US 587387 A US587387 A US 587387A US 3697644D A US3697644D A US 3697644DA US 3697644 A US3697644 A US 3697644A
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United States
Prior art keywords
water
solvent
composition
hair
cosmetic
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Expired - Lifetime
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US587387A
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English (en)
Inventor
Donald David Laiderman
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Gillette Co LLC
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Gillette Co LLC
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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/731—Cellulose; Quaternized cellulose derivatives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/732—Starch; Amylose; Amylopectin; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8164—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers, e.g. poly (methyl vinyl ether-co-maleic anhydride)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/54—Polymers characterized by specific structures/properties
    • A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
    • A61K2800/5422—Polymers characterized by specific structures/properties characterized by the charge nonionic

Definitions

  • This invention relates to stable aqueous cosmetic compositions containing substantially water-insoluble cosmetic materials and capable of depositing a smooth film of the cosmetic material on the skin or hair by means of a rinse-on application.
  • One object of the present invention is to provide a cosmetic composition in the form of an aqueous dispersion of a substantially water-insoluble film-forming material which composition is capable of being applied to the skin or hair and of depositing a thin smooth film of such material on the skin or hair when rinsed, i.e. diluted, with water.
  • Another object of the present invention is to provide a cosmetic composition capable of depositing on the skin or hair a thin smooth layer of a substantially waterinsoluble material which layer is resistant to subsequent removal by aqueous compositions.
  • a further object of the present invention is to provide a method of applying to the skin or hair a thin smooth layer of a substantially water-insoluble material, said method making use of an aqueous composition containing a minor proportion of organic solvent for said material.
  • compositions which comprise an emulsion having water thickened with a protective colloid in the external phase and having as the disperse phase a solution of the water-insoluble cosmetic material in a cosmetically acceptable organic solvent of special characteristics.
  • the substantially water-insoluble non-volatile cosmetic material is dissolved in an organic solvent in which it is soluble and this solution then dispersed in a thickened aqueous medium in which the thickener serves as a protective colloid to hold the dispersed phase in suspension for long periods of time.
  • the cosmetic materials which may be applied to the skin or hair in accordance with this invention include a wide variety of substantially water-insoluble nonvolatile materials which have utility in the cosmetic art.
  • substantially water-insoluble cosmetic materials is intended to include all those substantially colorless fats, oils, waxes, and polymers which have a cosmetic utility and a solubility in water at room temperature (23 C.) of less than 0.5% by weight.
  • examples of such materials are mineral oils derived from petroleum; fatty materials of vegetable or animal origin such as lanolin, sperm oil, coconut oil, olive oil, peanut oil and the like; saturated and unsaturated fatty acids and fatty alcohols having 10 or more carbon atoms; esters of fatty acids such as isopropyl myristate; and fatty amines such as stearylamine and amides thereof with fatty acids containing up to five carbon atoms.
  • animal waxes such as beeswax and spermaceti; the vegetable waxes such as carnauba, bayberry and candelilla; the mineral waxes including m'ontan, ozokerite, ceresin and paraffin and the synthetic waxes as exemplified by the medium molecular weight polyethylenes, polyethylene glycols, and polyoxyethylene esters such as sorbitan monostearate; and natural gums and resins such as shellac and benzoin.
  • animal waxes such as beeswax and spermaceti
  • the vegetable waxes such as carnauba, bayberry and candelilla
  • mineral waxes including m'ontan, ozokerite, ceresin and paraffin
  • synthetic waxes as exemplified by the medium molecular weight polyethylenes, polyethylene glycols, and polyoxyethylene esters such as sorbitan monostearate
  • natural gums and resins such as shellac and benzoin
  • synthetic polymeric cosmetic materials which may be formulated in accordance with the teachings of this invention include water-insoluble copolymers of vinyl pyrollidone with vinyl esters of fatty acids such as vinyl acetate, vinyl propionate, vinyl butyrate and the like; copolymers of vinyl alkyl ethers with maleic anhydride; copolymers of ethylene and maleic anhydride and esters such as cellulose acetate or cellulose butyrate.
  • esters of polysaccharides such as dextran, amylose, amylopectin, etc., with fatty acids containing 10 to 18 carbon atoms may be employed as the cosmetic material to yield skin creams capable of depositing on the hands a water barrier film highly resistant to aqueous detergent compositions.
  • the organic solvent employed in addition to being cosmetically acceptable and having the ability to dissolve the water-insoluble cosmetic material, must itself be either insoluble (i.e. less than 0.1% by weight at room temperature) in water (in which case it must be volatile) or soluble only to a limited extent.
  • the solvent should be soluble in water at room temperature to the extent of l to 10% by weight of the water; however, solvents having a solubility of up to 20% by weight in water have been found to be operable.
  • solvents which have been found to be satisfactory are benzyl alcohol; 2-ethy1-l ,3-hexanediol; bis(2-butoryethyl) ethers, butanol; isopropyl acetate; diethyl ketone, chloroform; carbon tetrachloride; and numerous others having the requisite solubility.
  • Solvents which are soluble in water to the extent of 0.1% by weight or more are readily removed from the skin or hair by rinsing with water to leave the film of cosmetic material.
  • Solvents which are less soluble in water must be volatile, i.e. must evaporate from the skin or hair during a relatively short period of time, e.g. a few seconds up to two minutes, at room temperature to leave a film of water-insoluble cosmetic material.
  • the amount of solvent used must be enough to dissolve or disperse all of the cosmetic material present; however, large excesses are preferably avoided.
  • solutions containing as little as 0.1% cosmetic material based on the weight of organic solvent may be used.
  • solutions containing 30 to 100% by weight of cosmetic material based on the weight of organic solvent may be employed.
  • up to 300% by weight of the cosmetic material may be employed based on the weight of the solvent.
  • the relative proportions of organic solvent and water may also vary over a wide range. It is normally preferred to limit the amount of solvent employed to that which is necessary to dissolve the water-insoluble cosmetic material. However, where desirable for esthetic or other reasons, the organic solvent may be present in larger amounts. In no event should this exceed 20% by weight of the total composition.
  • any of the well known water-soluble or dispersible protective colloids may be used in the formulation of the composition of this invention.
  • materials which may be used are the natural or synthetic watersoluble or water-dispersible gums such as guar, karaya, tragacanth, the alginates, Irish moss, and the like; cellulose derivatives including methyl cellulose, hydroxy methyl cellulose, hydroxy ethyl cellulose, sodium carboxymethyl cellulose, and the like; and vinyl polymers such as polyvinyl pyrollidone, polyvinyl alcohol,
  • the protective colloid is present in an amount sufficient to provide a relatively stable dispersion, as is well known in the art, usually from 0.1 to 5.0 percent based on the water, depending on the identity of the particular protective colloid used.
  • compositions in addition to the foregoing.
  • various medicaments such as germicides, anti-inflammatories, etc.; deodorants or anti-perspirants; sunscreen agents; perfumes; coloring dyes or pigments; optical brighteners; etc.
  • EXAMPLE 1 Parts by Weight Benzyl alcohol 5.0 Ethyl alcohol l.0 Half ethyl ester ofa l:l copolymer of vinylmethyl ether and maleic anhydride 0.5 stearyldimcthyl benzyl ammonium chloride 0.9 Hydroxyethyl cellulose 1.2 Triethanol amine 0.4 Polydimethylsiloxane oil 0.l Perfume 0.5 Water 90.4
  • the benzyl alcohol which has only limited solubility in water, serves as a solvent for the cosmetic material (the copolymer, the
  • the triethanol amine functions to control the pH of the composition.
  • a thickened water phase is separately prepared by adding the hydroxyethyl cellulose to the water and heating to S0 C. with agitation. After cooling to 30 C., the first composition is dispersed in the thickened water phase using vigorous stirring for two minutes at 30 C. The composition is then further agitated at a slow roll with no visible vortex until a uniform mixture is obtained. The perfume is then added and the composition agitated for 25 to 30 minutes more.
  • the resulting product is a body imparting hair rinse having a medium viscosity and a pH of about 7.3.
  • One tablespoon of the composition is worked with the fingers through a head of damp, towel blotted, freshly shampooed hair. After combing to distribute the rinse evenly, the hair is thoroughly rinsed with warm water. Microscopic examination of fibers so treated shows that a semi-continuous polymer film has been deposited. The film provides easy combing in both the wet and dry states and leaves the dried hair with an attractive luster and added body.
  • EXAMPLE 2 Parts by Weight Amylopectin decanoate Polydimethylsiloxane oil 2-ethyll ,3-hexane diol Diethylene glycol dibutyl ether Carboxypolymethylene (Carbopol 934) Sodium hydroxide Perfume Water
  • the 2-ethyl-l ,3-hexanediol and diethylene glycol dibutyl ether which have only limited solubility in water, serve as solvent for the cosmetic materials amylopectin decanoate, siloxane oil and perfume.
  • the carboxypolymethylene acts as the protective colloid.
  • the sodium hydroxide functions merely to adjust the pH to within the desired range of 6 to 8.
  • composition of this example is prepared in a manner analogous to that of Example 1.
  • the resulting product is a water barrier hand cream which is applied by rubbing into the skin followed by a warm water rinse.
  • the resulting film a mixture of amylopectin decanoate and polydimethylsiloxane, gives excellent protection against the effects of aqueous detergent compositions such as anionic dishwashing products.
  • This composition can also be prepared using 6% dibutyl carbitol as the sole organic solvent for the amylopectin decanoate and polymethylsiloxane oil. While the resulting product has barrier properties equal to the mixed solvent example, the emulsion is less creamy.
  • Example 3 The composition of Example 1 is prepared with the addition of another water insoluble cosmetic material,
  • a disperse dye Latyl Blue RB, Du Pont.
  • Rinse-on deposition of the composition onto a tress of white human hair yields a strong blue color in addition to the body and conditioning benefits described above.
  • the dyed composition can be readily removed by the usual shampoo procedure. Any desired shade can be achieved by the proper choice or blending of organic dyes or inorganic pigments.
  • EXAMPLE 4 EXAMPLE 5 Parts by Weight Lanolin 2.0 Benzyl alcohol 4.0 Hydroxycthyl cellulose 1.2 Perfume 0.3 Water 92.5
  • the lanolin and perfume cosmetic materials are dissolved in the benzyl alcohol solvent and the resulting solution dispersed in the aqueous hydroxyethyl cellulose as described in Example 1. Rinse-on deposition onto damp, shampooed hair yields a thin lustrous coating of lanolin oil, evenly distributed throughout the hair.
  • composition is prepared by dissolving the montan wax and perfume cosmetic materials in benzyl alcohol, then dispersing the solution in water containing carboxypolymethylene protective colloid, the sodium hydroxide being used to adjust the pH to within the desired range of 6 to 8. Rinse-on deposition onto skin or hair yields a thin even wax coating resistant to soap or shampoo removal.
  • the composition is prepared by dissolving the dextran stearate and perfume cosmetic materials in chloroform as the solvent, then dispersing the solution into water containing guar gum protective colloid.
  • the composition is applied by rubbing it onto the skin and allowing the chloroform and water to evaporate, leaving an evenly deposited film of polymer which is resistant to soap or shampoo removal.
  • An aqueous cosmetic composition adapted to be coated on the skin or hair and to deposit a thin film of water-insoluble cosmetic material comprising an aqueous medium containing from 0.1 to 5%, based on the weight of the water, of a water-soluble or water-dispersible protective colloid, and dispersed therein an organic solvent solution containing from 0.1 to 300%, based on the weight of the solvent, of cosmetic material which is a substantially colorless fat, oil, wax or polymer and which is less soluble in water at room temperature than 0.5% by weight, the maximum amount of said solvent being 20% by weight of the total composition, said solvent being volatile and less soluble in water than 0.1% by weight at room temperature or being soluble in water to an extent from 0.1 to 20% by weight at room temperature.
  • aqueous composition as claimed in claim 1 in which the solvent is a volatile solvent less soluble than 0.1% by weight in water.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Cosmetics (AREA)
US587387A 1966-10-18 1966-10-18 Cosmetic composition Expired - Lifetime US3697644A (en)

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US58738766A 1966-10-18 1966-10-18

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US (1) US3697644A (enrdf_load_stackoverflow)
CH (1) CH507001A (enrdf_load_stackoverflow)
DE (1) DE1617507A1 (enrdf_load_stackoverflow)
FR (1) FR1563677A (enrdf_load_stackoverflow)
GB (1) GB1168908A (enrdf_load_stackoverflow)
IT (1) IT944507B (enrdf_load_stackoverflow)
NL (1) NL6713915A (enrdf_load_stackoverflow)

Cited By (43)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3853464A (en) * 1969-08-11 1974-12-10 Oreal Human hair dyeing compositions containing diphenylamines
US3932610A (en) * 1971-12-06 1976-01-13 Lever Brothers Company Shampoo composition
US3939099A (en) * 1974-12-26 1976-02-17 Chesebrough-Pond's, Inc. Fragrance composition
US3953591A (en) * 1974-04-29 1976-04-27 The Procter & Gamble Company Fatty acid, polysiloxane and water-soluble polymer containing skin conditioning emulsion
US3957971A (en) * 1974-07-29 1976-05-18 Lever Brothers Company Moisturizing units and moisturizing compositions containing the same
US4008999A (en) * 1974-02-22 1977-02-22 Societe Anonyme Dite: L'oreal N,N-dialkylamino diphenylamines for dyeing keratinic fibers
US4158053A (en) * 1977-08-05 1979-06-12 Eli Lilly And Company Aqueous emulsion polymer nail coating formulations
US4268499A (en) * 1979-06-07 1981-05-19 Dow Corning Corporation Antiperspirant emulsion compositions
US4272516A (en) * 1976-11-08 1981-06-09 Societa Italo-Britannica-L. Manetti-H. Roberts Co. Process for improving transcutaneous and transfollicular absorption of cosmetic compositions
JPS57112319A (en) * 1980-03-10 1982-07-13 Procter & Gamble Hair conditioning composition
US4383988A (en) * 1978-04-28 1983-05-17 Anheuser-Busch, Incorporated Gelled antiperspirant
US4472297A (en) * 1982-03-01 1984-09-18 The Procter & Gamble Company Shampoo compositions containing hydroxypropyl guar gum
US4491539A (en) * 1981-06-04 1985-01-01 The Procter & Gamble Company Liquid cleansing product with skin feel additives
US4743440A (en) * 1973-11-08 1988-05-10 Lever Brothers Company Skin composition
US4818523A (en) * 1987-06-17 1989-04-04 Colgate-Palmolive Company Hair rinse conditioner
EP0166608A3 (en) * 1984-06-28 1989-07-05 The Procter & Gamble Company Liquid cleansing compositions
US4863725A (en) * 1982-10-27 1989-09-05 Deckner George E Novel clear oil-free moisturizer composition
US4867894A (en) * 1986-03-07 1989-09-19 Rohm Gmbh Pour point improving additives for mineral oils
US4873079A (en) * 1987-08-21 1989-10-10 Clairol Incorporated Hair coloring composition and its method of use
US4886660A (en) * 1987-06-11 1989-12-12 Colgate-Palmolive Company Shine hair conditioner
US5877144A (en) * 1996-03-01 1999-03-02 Sudzucker Aktiengesellschaft Mannheim/Ochsenfurt Aliphatic carboxylate esters of inulin
US6344183B2 (en) 1998-04-09 2002-02-05 National Starch And Chemical Investment Holding Corporation Aerosol hair cosmetic compositions containing non-ionically derivatized starches
US6413505B1 (en) 1998-04-09 2002-07-02 Nationa L Starch And Chemical Investment Holding Corporation Nonionically derivatized starches and their use in non-aerosol, low VOC hair cosmetic compositions
US6562325B2 (en) 1998-04-09 2003-05-13 National Starch And Chemical Investment Holding Corporation Use of stabilized starches in low VOC, polyacrylic acid-containing hair cosmetic compositions
US20030228378A1 (en) * 2002-06-05 2003-12-11 Hebert Rolland F. Water-soluble stable salts of petroselinic acid
US20060182697A1 (en) * 2005-01-18 2006-08-17 Boris Lalleman Composition for treating keratin fibers, comprising at least one aromatic alcohol, at least one aromatic carboxylic acid, and at least one protecting agent
US20090081141A1 (en) * 2007-09-21 2009-03-26 Exsymol S.A.M. Topical use of thiazolidine derivatives against consequences of oxidative stress of skin
EP2226063A2 (en) 2009-03-04 2010-09-08 Takasago International Corporation High intensity fragrances
US20120071525A1 (en) * 2007-07-17 2012-03-22 Byotrol Plc Anti-microbial composition
EP2620211A2 (en) 2012-01-24 2013-07-31 Takasago International Corporation New microcapsules
EP2832441A1 (en) 2013-07-29 2015-02-04 Takasago International Corporation Microcapsules
EP2832442A1 (en) 2013-07-29 2015-02-04 Takasago International Corporation Microcapsules
EP2832440A1 (en) 2013-07-29 2015-02-04 Takasago International Corporation Microcapsules
EP3211064A1 (en) 2016-02-24 2017-08-30 Takasago International Corporation Stimulating agent
EP3871765A1 (en) 2020-02-26 2021-09-01 Takasago International Corporation Aqueous dispersion of microcapsules, and uses thereof
EP3871766A1 (en) 2020-02-26 2021-09-01 Takasago International Corporation Aqueous dispersion of microcapsules, and uses thereof
EP3871764A1 (en) 2020-02-26 2021-09-01 Takasago International Corporation Aqueous dispersion of microcapsules, and uses thereof
EP3900697A1 (en) 2020-04-21 2021-10-27 Takasago International Corporation Fragrance composition
WO2022155054A1 (en) 2021-01-13 2022-07-21 Firmenich Incorporated Compositions that enhance the cooling effect
EP4094827A1 (en) 2021-05-27 2022-11-30 Takasago International Corporation Aqueous dispersion of microcapsules, and uses thereof
WO2022251628A1 (en) 2021-05-28 2022-12-01 Firmenich Incorporated Compositions that enhance the cooling effect
WO2024011086A1 (en) 2022-07-07 2024-01-11 Firmenich Incorporated Compositions that enhance the cooling effect
WO2024088925A1 (en) 2022-10-27 2024-05-02 Firmenich Sa Flavonoid compositions and uses thereof

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4069347A (en) * 1976-08-02 1978-01-17 Emery Industries, Inc. Compositions of quaternary ammonium derivatives of lanolin acids
GR74051B (enrdf_load_stackoverflow) * 1980-03-10 1984-06-06 Procter & Gamble
DE3234365A1 (de) * 1982-09-16 1984-03-22 Henkel KGaA, 4000 Düsseldorf Konditionierungsmittel fuer fettiges haar
DE3918615C2 (de) * 1989-06-07 1995-07-27 Woellner Werke Hautschutzsalbe auf der Basis einer wäßrigen Emulsion
GB9411530D0 (en) * 1994-06-09 1994-08-03 Quayle Rachel A Use of polymers as film-forming barrier materials

Cited By (54)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3853464A (en) * 1969-08-11 1974-12-10 Oreal Human hair dyeing compositions containing diphenylamines
US3932610A (en) * 1971-12-06 1976-01-13 Lever Brothers Company Shampoo composition
US4743440A (en) * 1973-11-08 1988-05-10 Lever Brothers Company Skin composition
US4822596A (en) * 1973-11-08 1989-04-18 Lever Brothers Company Skin composition
US4008999A (en) * 1974-02-22 1977-02-22 Societe Anonyme Dite: L'oreal N,N-dialkylamino diphenylamines for dyeing keratinic fibers
USRE29814E (en) * 1974-04-29 1978-10-24 The Procter & Gamble Company Lanolin fatty acids, polysiloxane and water-soluble polymer containing skin conditioning emulsion
US3953591A (en) * 1974-04-29 1976-04-27 The Procter & Gamble Company Fatty acid, polysiloxane and water-soluble polymer containing skin conditioning emulsion
US3957971A (en) * 1974-07-29 1976-05-18 Lever Brothers Company Moisturizing units and moisturizing compositions containing the same
US3939099A (en) * 1974-12-26 1976-02-17 Chesebrough-Pond's, Inc. Fragrance composition
US4272516A (en) * 1976-11-08 1981-06-09 Societa Italo-Britannica-L. Manetti-H. Roberts Co. Process for improving transcutaneous and transfollicular absorption of cosmetic compositions
US4158053A (en) * 1977-08-05 1979-06-12 Eli Lilly And Company Aqueous emulsion polymer nail coating formulations
US4383988A (en) * 1978-04-28 1983-05-17 Anheuser-Busch, Incorporated Gelled antiperspirant
US4268499A (en) * 1979-06-07 1981-05-19 Dow Corning Corporation Antiperspirant emulsion compositions
JPS57112319A (en) * 1980-03-10 1982-07-13 Procter & Gamble Hair conditioning composition
US4491539A (en) * 1981-06-04 1985-01-01 The Procter & Gamble Company Liquid cleansing product with skin feel additives
US4472297A (en) * 1982-03-01 1984-09-18 The Procter & Gamble Company Shampoo compositions containing hydroxypropyl guar gum
US4863725A (en) * 1982-10-27 1989-09-05 Deckner George E Novel clear oil-free moisturizer composition
EP0166608A3 (en) * 1984-06-28 1989-07-05 The Procter & Gamble Company Liquid cleansing compositions
US4867894A (en) * 1986-03-07 1989-09-19 Rohm Gmbh Pour point improving additives for mineral oils
US4886660A (en) * 1987-06-11 1989-12-12 Colgate-Palmolive Company Shine hair conditioner
US4818523A (en) * 1987-06-17 1989-04-04 Colgate-Palmolive Company Hair rinse conditioner
US4873079A (en) * 1987-08-21 1989-10-10 Clairol Incorporated Hair coloring composition and its method of use
US5877144A (en) * 1996-03-01 1999-03-02 Sudzucker Aktiengesellschaft Mannheim/Ochsenfurt Aliphatic carboxylate esters of inulin
US6344183B2 (en) 1998-04-09 2002-02-05 National Starch And Chemical Investment Holding Corporation Aerosol hair cosmetic compositions containing non-ionically derivatized starches
US6413505B1 (en) 1998-04-09 2002-07-02 Nationa L Starch And Chemical Investment Holding Corporation Nonionically derivatized starches and their use in non-aerosol, low VOC hair cosmetic compositions
US6562325B2 (en) 1998-04-09 2003-05-13 National Starch And Chemical Investment Holding Corporation Use of stabilized starches in low VOC, polyacrylic acid-containing hair cosmetic compositions
US20030228378A1 (en) * 2002-06-05 2003-12-11 Hebert Rolland F. Water-soluble stable salts of petroselinic acid
US6919088B2 (en) * 2002-06-05 2005-07-19 Rolland F. Hebert Water-soluble stable salts of petroselinic acid
US20060182697A1 (en) * 2005-01-18 2006-08-17 Boris Lalleman Composition for treating keratin fibers, comprising at least one aromatic alcohol, at least one aromatic carboxylic acid, and at least one protecting agent
US8790623B2 (en) * 2005-01-18 2014-07-29 Il'Oreal Composition for treating keratin fibers, comprising at least one aromatic alcohol, at least one aromatic carboxylic acid, and at least one protecting agent
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Also Published As

Publication number Publication date
IT944507B (it) 1973-04-20
DE1617507A1 (de) 1971-01-28
GB1168908A (en) 1969-10-29
CH507001A (de) 1971-05-15
FR1563677A (enrdf_load_stackoverflow) 1969-04-18
NL6713915A (enrdf_load_stackoverflow) 1968-04-19

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