US3683227A - Low-pressure mercury-vapor gas-discharge fluorescent lamp with amalgam - Google Patents
Low-pressure mercury-vapor gas-discharge fluorescent lamp with amalgam Download PDFInfo
- Publication number
- US3683227A US3683227A US132392A US3683227DA US3683227A US 3683227 A US3683227 A US 3683227A US 132392 A US132392 A US 132392A US 3683227D A US3683227D A US 3683227DA US 3683227 A US3683227 A US 3683227A
- Authority
- US
- United States
- Prior art keywords
- mercury
- amalgam
- low
- fluorescent lamp
- per cent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 title abstract description 34
- 229910000497 Amalgam Inorganic materials 0.000 title abstract description 28
- 229910052753 mercury Inorganic materials 0.000 abstract description 16
- 239000000203 mixture Substances 0.000 abstract description 9
- 238000009472 formulation Methods 0.000 abstract description 8
- 229910052797 bismuth Inorganic materials 0.000 abstract description 7
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 abstract description 7
- 230000004907 flux Effects 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 3
- 239000000463 material Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- KUKRQWSFGQRZIN-UHFFFAOYSA-N [Bi].[Hg] Chemical class [Bi].[Hg] KUKRQWSFGQRZIN-UHFFFAOYSA-N 0.000 description 1
- CUBYNCOYOIEWFL-UHFFFAOYSA-N [Cd].[Sn].[Hg] Chemical compound [Cd].[Sn].[Hg] CUBYNCOYOIEWFL-UHFFFAOYSA-N 0.000 description 1
- BCETXQXQEAECAT-UHFFFAOYSA-N [Hg].[In].[Zn] Chemical compound [Hg].[In].[Zn] BCETXQXQEAECAT-UHFFFAOYSA-N 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- DGJPPCSCQOIWCP-UHFFFAOYSA-N cadmium mercury Chemical compound [Cd].[Hg] DGJPPCSCQOIWCP-UHFFFAOYSA-N 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- KZUJUDQRJCCDCM-UHFFFAOYSA-N indium mercury Chemical compound [In].[Hg] KZUJUDQRJCCDCM-UHFFFAOYSA-N 0.000 description 1
- -1 indium-cadmium-tin-mercury Chemical compound 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J61/00—Gas-discharge or vapour-discharge lamps
- H01J61/02—Details
- H01J61/24—Means for obtaining or maintaining the desired pressure within the vessel
Definitions
- the present invention relates to electric gasdischarge lamps, and more specifically to low-pressure mercury-vapor gas-discharge fluorescent lamps with an amalgam.
- This disadvantage is mainly traceable to the low partial pressure of the mercury vapor over the amalgam at temperatures below 30 C., because of which the resonance radiation responsible for the excitation of the phosphor is low in intensity.
- Another object of the invention is to provide a solid amalgam composition ensuring optimum performance for low pressure mercury-vapor gas-discharge fluorescent lamps at ambient temperatures below 30 C. by the proper choice of the amalgam formulation, this amalgam being suitable for lamps of any power rating and independent of the manner in which it may be disposed in a lamp.
- the present invention resides in that, in a mercury-vapor gas-discharge fluorescent lamp, use is made of an amalgam of the formulation: mercury, at. per cent; lead, 45 75 at. per cent; bismuth, 4O 05 at. per cent, ensuring an optimum lumnious flux in the temperature range from 10 to 35 C.
- Placement of the amalgam in a lamp is not critical
- curves A, B, and C are seen to have all a single peak in the temperature range from 30 to 35 C.
- the most attractive formulation appears to be the one containing 20 at. per cent mercury, 5 at. per cent bismuth, and 75 at per cent lead, because its luminous flux decreases gradually on moving into the region of higher temperatures.
- the yield of mercury vapor from the amalgam is mainly decided by its content of lead which acts as a kind of stabilizer of an optimum pressure of mercury vapor (3 X 10* mm Hg) in the lamp. Partly, the maintenance of this optimum pressure of mercury vapor is due to the formation of intermetallic mercury-bismuth compounds. In contrast to the classical chemical bonds ion and covalent, these compounds feature a specific metallic bond which invalidates the valence theory.
- the amalgam is prepared from inexpensive and abundant materials and compares favorably with any of prior-art amalgams for gas-discharge lamps in cost, low toxicity and superior performance.
- the lead of the amalgam only acts as a stabilizer of mercury-vapor yield and does not form any compounds with the mercury.
- the accompanying plot contains a curve, D, for a fluorescent lamp of equal power rating, using mercury.
Landscapes
- Discharge Lamp (AREA)
- Vessels And Coating Films For Discharge Lamps (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SU1429911A SU308671A1 (enrdf_load_stackoverflow) | 1970-05-25 | 1970-05-25 |
Publications (1)
Publication Number | Publication Date |
---|---|
US3683227A true US3683227A (en) | 1972-08-08 |
Family
ID=20452105
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US132392A Expired - Lifetime US3683227A (en) | 1970-05-25 | 1971-04-08 | Low-pressure mercury-vapor gas-discharge fluorescent lamp with amalgam |
Country Status (4)
Country | Link |
---|---|
US (1) | US3683227A (enrdf_load_stackoverflow) |
DE (1) | DE2118766C3 (enrdf_load_stackoverflow) |
GB (1) | GB1320590A (enrdf_load_stackoverflow) |
SU (1) | SU308671A1 (enrdf_load_stackoverflow) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4015162A (en) * | 1975-07-07 | 1977-03-29 | Westinghouse Electric Corporation | Fluorescent lamp having implanted amalgamative metal for mercury vapor regulation |
FR2343329A1 (fr) * | 1976-03-04 | 1977-09-30 | Philips Nv | Lampe a decharge dans la vapeur de mercure a basse pression |
WO2007146196A3 (en) * | 2006-06-09 | 2008-07-31 | Advanced Lighting Tech Inc | Bismuth-zinc-mercury amalgam, fluorescent lamps, and related methods |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE9210171U1 (de) * | 1992-07-29 | 1992-10-15 | Patent-Treuhand-Gesellschaft für elektrische Glühlampen mbH, 8000 München | Amalgamkörper bzw. Amalgambildnerkörper für eine Leuchtstofflampe |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3152278A (en) * | 1959-06-12 | 1964-10-06 | Patent Treuhand Ges Fuer Elektrische Gluehlampen Mbh | Fluorescent lamp with low melting amalgam filling |
US3160778A (en) * | 1961-04-07 | 1964-12-08 | Patent Treuhand Ges Fuer Elektrische Gluehlampen Mbh | Highly loaded low pressure mercury vapor discharge lamp |
US3526804A (en) * | 1967-10-27 | 1970-09-01 | Westinghouse Electric Corp | Fluorescent lamp or similar device containing an amalgam of tin-indium-mercury which controls the mercury vapor pressure during operation |
-
1970
- 1970-05-25 SU SU1429911A patent/SU308671A1/ru active
-
1971
- 1971-04-08 US US132392A patent/US3683227A/en not_active Expired - Lifetime
- 1971-04-17 DE DE2118766A patent/DE2118766C3/de not_active Expired
- 1971-04-19 GB GB2704271*A patent/GB1320590A/en not_active Expired
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3152278A (en) * | 1959-06-12 | 1964-10-06 | Patent Treuhand Ges Fuer Elektrische Gluehlampen Mbh | Fluorescent lamp with low melting amalgam filling |
US3160778A (en) * | 1961-04-07 | 1964-12-08 | Patent Treuhand Ges Fuer Elektrische Gluehlampen Mbh | Highly loaded low pressure mercury vapor discharge lamp |
US3526804A (en) * | 1967-10-27 | 1970-09-01 | Westinghouse Electric Corp | Fluorescent lamp or similar device containing an amalgam of tin-indium-mercury which controls the mercury vapor pressure during operation |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4015162A (en) * | 1975-07-07 | 1977-03-29 | Westinghouse Electric Corporation | Fluorescent lamp having implanted amalgamative metal for mercury vapor regulation |
FR2343329A1 (fr) * | 1976-03-04 | 1977-09-30 | Philips Nv | Lampe a decharge dans la vapeur de mercure a basse pression |
WO2007146196A3 (en) * | 2006-06-09 | 2008-07-31 | Advanced Lighting Tech Inc | Bismuth-zinc-mercury amalgam, fluorescent lamps, and related methods |
Also Published As
Publication number | Publication date |
---|---|
GB1320590A (en) | 1973-06-13 |
SU308671A1 (enrdf_load_stackoverflow) | 1973-10-26 |
DE2118766A1 (de) | 1971-12-09 |
DE2118766B2 (enrdf_load_stackoverflow) | 1974-05-02 |
DE2118766C3 (de) | 1974-11-28 |
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