US3668133A - Detergent oily agent adapted to be well adsorbed in fabrics and having detergency - Google Patents
Detergent oily agent adapted to be well adsorbed in fabrics and having detergency Download PDFInfo
- Publication number
- US3668133A US3668133A US51377A US3668133DA US3668133A US 3668133 A US3668133 A US 3668133A US 51377 A US51377 A US 51377A US 3668133D A US3668133D A US 3668133DA US 3668133 A US3668133 A US 3668133A
- Authority
- US
- United States
- Prior art keywords
- fabrics
- active agent
- agent
- mineral oil
- oily
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000004744 fabric Substances 0.000 title abstract description 49
- 239000003795 chemical substances by application Substances 0.000 title abstract description 31
- 239000003599 detergent Substances 0.000 title abstract description 11
- 239000004094 surface-active agent Substances 0.000 claims abstract description 37
- 239000002480 mineral oil Substances 0.000 claims abstract description 21
- 235000010446 mineral oil Nutrition 0.000 claims abstract description 19
- 230000007935 neutral effect Effects 0.000 claims abstract description 12
- 125000002091 cationic group Chemical group 0.000 claims abstract description 8
- 239000000203 mixture Substances 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 16
- -1 polyoxyethylene Polymers 0.000 abstract description 8
- 229920000742 Cotton Polymers 0.000 abstract description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 abstract description 4
- 239000003995 emulsifying agent Substances 0.000 abstract description 4
- 239000003921 oil Substances 0.000 description 20
- 235000019198 oils Nutrition 0.000 description 20
- 239000000243 solution Substances 0.000 description 17
- 238000001179 sorption measurement Methods 0.000 description 12
- 239000003463 adsorbent Substances 0.000 description 7
- 239000000126 substance Substances 0.000 description 6
- 239000004615 ingredient Substances 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 230000000274 adsorptive effect Effects 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 238000010306 acid treatment Methods 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 239000010721 machine oil Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000693 micelle Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000003929 acidic solution Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical class CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000005188 flotation Methods 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000008041 oiling agent Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- SFVFIFLLYFPGHH-UHFFFAOYSA-M stearalkonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 SFVFIFLLYFPGHH-UHFFFAOYSA-M 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/835—Mixtures of non-ionic with cationic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
- Y10S516/01—Wetting, emulsifying, dispersing, or stabilizing agents
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
- Y10S516/01—Wetting, emulsifying, dispersing, or stabilizing agents
- Y10S516/07—Organic amine, amide, or n-base containing
Definitions
- This invention relates to a novel oily agent for cotton and other fabrics. More specifically, the invention relates to a new and better oily agent capable of imparting both adsorbency and detergency to such fabrics, thereby to make them fit for the manual cleaning of various articles and typically for household or office use as mops.
- the fabrics when fabrics are immersed and stirred in emulsified water solutions of oils, the fabrics may absorb oils both efficiently and uniformly, but there is a positive drawback such that the fabrics need an acid pretreatment which causes processing trouble and impairment of cotton and other fabrics and the successful oil adsorption of the fabrics depends largely upon the skill regarding to dosages of acid, water and other additives.
- Another object of the invention is to provide novel oily agents that canbe readily adsorbed in the fabrics at a low temperature and in a comparatively short time, without need for any preor aftertreatments of the fabrics.
- Yet another object of the invention is to provide novel oily agents which contain an excellent detergent surface-active ability so that the fabrics treated therewith have a longsustained self-cleansing quality.
- Still another object of the invention is to provide novel oily agents each consisting essentially of a mineral oil containing a surface-active agent which becomes adsorbable when activated, and another surface-active agent capable of completely emulsifying the mineral oil in a neutral solution so that the mineral oil is adsorbed efficiently in the fabrics along with the other ingredients.
- the fabric was removed from the solution, dehydrated and desiccated by use of apparatuses available conventionally for the purposes, and then its weight was measured.
- the nearly complete absence of organic matter from the remaining water proves the fact that the fabric took up almost the whole of the other ingredients of the oily agent, too.
- C machine oil was used for the mineral oil; diethanol amide of the fatty acid of coconut oil for the particular nonionic surface-active agent; stearyl dimethylbenzil ammonium chloride for the cationic surface-active agent; and polyoxyethylene alkyl phenol ether for the normal nonionic surface-active agent.
- the most important matter of the present invention resides in the above-mentioned performance characteristics, that is, in that an adsorbent is activated in its neutral state, thereby to cause effective adsorption of the mineral oils, adsorptive substances and detergent substances in the fabric to be processed.
- oily agent of the present invention resides in the activation (by means of an emulsifier) of adsorbents contained therein in neutral solutions, so that not only the oils, but the adsorbent and detergent ingredients, too, of the oily agent are wastelessly adsorbed in fabrics treated therein.
- the oily agents according to the invention have various advantages such that preparation of the oily agent is very simple because of being able to be prepared at a low temperature and in a comparatively short period of time without necessity of any acid treatment, adsorbency of the oily agent is strong and uniform; damage of the fabric treated with the oily agent is avoided because of using no acid-treatment; and detergency of the fabric treated with the oily agent becomes excellent and effectively sustained, owing to well adsorption of any detergent in said fabric.
- An oil composition for impregnation of cellulosic wipes, fabrics or mops at substantially neutral pH comprising a neutral aqueous blend of mineral oil with a first nonionic surface-active agent, a cationic surface-active agent and a second nonionic surface-active agent; wherein said first nonionic surface-active agent is the diethanolamide of coconut oil fatty acids; said second nonionic surface-active agent is polyoxyethylene alkylphenol ether and said cationic surface-active agent is the quaternary, stearyl dimethylbenzyl ammonium chloride.
- composition according to claim 1 wherein said second nonionic surface-active agent is present in an amount by weight substantially equal to the combined weights of said first nonionic surface-active agent and said cationic surfaceactive agent and is sufficient to substantially completely em ulsify said mineral oil in neutral aqueous solutions.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP44051934A JPS4830039B1 (enrdf_load_stackoverflow) | 1969-06-30 | 1969-06-30 |
Publications (1)
Publication Number | Publication Date |
---|---|
US3668133A true US3668133A (en) | 1972-06-06 |
Family
ID=12900683
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US51377A Expired - Lifetime US3668133A (en) | 1969-06-30 | 1970-06-30 | Detergent oily agent adapted to be well adsorbed in fabrics and having detergency |
Country Status (2)
Country | Link |
---|---|
US (1) | US3668133A (enrdf_load_stackoverflow) |
JP (1) | JPS4830039B1 (enrdf_load_stackoverflow) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3740190A (en) * | 1971-08-23 | 1973-06-19 | Sun Oil Co | Antibacterial laundry oil and dust control oil composition |
EP0000234A1 (en) * | 1977-06-29 | 1979-01-10 | THE PROCTER & GAMBLE COMPANY | Low-phosphate detergent composition for fabric washing |
EP0000235A1 (en) * | 1977-06-29 | 1979-01-10 | THE PROCTER & GAMBLE COMPANY | Low-phosphate detergent composition for fabric washing |
EP0000595A1 (en) * | 1977-06-29 | 1979-02-07 | THE PROCTER & GAMBLE COMPANY | Low-phosphate detergent composition for fabric washing |
FR2400585A1 (fr) * | 1977-07-12 | 1979-03-16 | Procter & Gamble Europ | Compositions pour le traitement des textiles en milieu aqueux |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3105500A (en) * | 1959-08-04 | 1963-10-01 | American Cyanamid Co | Soil retaining finish for textiles |
US3175949A (en) * | 1962-01-08 | 1965-03-30 | Bristol Myers Co | Emulsion of mineral oil, lauric diethanolamide, and water |
US3200036A (en) * | 1962-08-17 | 1965-08-10 | Talb Ind Inc | Oiled dust cloth composition |
US3311659A (en) * | 1963-11-21 | 1967-03-28 | Rayette Faberge | Process for preparing higher fatty alkyl diloweralkyl benzyl ammonium halides |
US3391079A (en) * | 1964-06-10 | 1968-07-02 | Greenblatt Joseph | Treatment of cellulosic fabrics |
-
1969
- 1969-06-30 JP JP44051934A patent/JPS4830039B1/ja active Pending
-
1970
- 1970-06-30 US US51377A patent/US3668133A/en not_active Expired - Lifetime
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3105500A (en) * | 1959-08-04 | 1963-10-01 | American Cyanamid Co | Soil retaining finish for textiles |
US3175949A (en) * | 1962-01-08 | 1965-03-30 | Bristol Myers Co | Emulsion of mineral oil, lauric diethanolamide, and water |
US3200036A (en) * | 1962-08-17 | 1965-08-10 | Talb Ind Inc | Oiled dust cloth composition |
US3311659A (en) * | 1963-11-21 | 1967-03-28 | Rayette Faberge | Process for preparing higher fatty alkyl diloweralkyl benzyl ammonium halides |
US3391079A (en) * | 1964-06-10 | 1968-07-02 | Greenblatt Joseph | Treatment of cellulosic fabrics |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3740190A (en) * | 1971-08-23 | 1973-06-19 | Sun Oil Co | Antibacterial laundry oil and dust control oil composition |
US3740191A (en) * | 1971-08-23 | 1973-06-19 | Sun Oil Co | Antibacterial laundry oil and dust control oil composition |
EP0000234A1 (en) * | 1977-06-29 | 1979-01-10 | THE PROCTER & GAMBLE COMPANY | Low-phosphate detergent composition for fabric washing |
EP0000235A1 (en) * | 1977-06-29 | 1979-01-10 | THE PROCTER & GAMBLE COMPANY | Low-phosphate detergent composition for fabric washing |
EP0000595A1 (en) * | 1977-06-29 | 1979-02-07 | THE PROCTER & GAMBLE COMPANY | Low-phosphate detergent composition for fabric washing |
FR2400585A1 (fr) * | 1977-07-12 | 1979-03-16 | Procter & Gamble Europ | Compositions pour le traitement des textiles en milieu aqueux |
Also Published As
Publication number | Publication date |
---|---|
JPS4830039B1 (enrdf_load_stackoverflow) | 1973-09-17 |
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