Classifications

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  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M3/00—Liquid compositions essentially based on lubricating components other than mineral lubricating oils or fatty oils and their use as lubricants; Use as lubricants of single liquid substances
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  • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
  • C10M2201/14—Inorganic compounds or elements as ingredients in lubricant compositions inorganic compounds surface treated with organic compounds
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  • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
  • C10M2207/10—Carboxylix acids; Neutral salts thereof
  • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
  • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
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  • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
  • C10M2207/10—Carboxylix acids; Neutral salts thereof
  • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
  • C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
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  • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
  • C10M2207/28—Esters
  • C10M2207/287—Partial esters
  • C10M2207/289—Partial esters containing free hydroxy groups
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  • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
  • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
  • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
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  • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
  • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
  • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
  • C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
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  • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
  • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
  • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
  • C10M2209/105—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only
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  • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
  • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
  • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
  • C10M2209/107—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of two or more specified different alkylene oxides covered by groups C10M2209/104 - C10M2209/106
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  • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
  • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
  • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
  • C10M2209/108—Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified
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  • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
  • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
  • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
  • C10M2209/109—Polyethers, i.e. containing di- or higher polyoxyalkylene groups esterified
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  • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
  • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
  • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
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  • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
  • C10M2215/12—Partial amides of polycarboxylic acids
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  • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
  • C10M2215/22—Heterocyclic nitrogen compounds
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  • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
  • C10M2215/22—Heterocyclic nitrogen compounds
  • C10M2215/221—Six-membered rings containing nitrogen and carbon only
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  • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
  • C10M2215/22—Heterocyclic nitrogen compounds
  • C10M2215/225—Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
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  • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
  • C10M2215/22—Heterocyclic nitrogen compounds
  • C10M2215/225—Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
  • C10M2215/226—Morpholines
• • C—CHEMISTRY; METALLURGY
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  • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
  • C10M2215/24—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions having hydrocarbon substituents containing thirty or more carbon atoms, e.g. nitrogen derivatives of substituted succinic acid
  • C10M2215/26—Amines
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  • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
  • C10M2215/24—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions having hydrocarbon substituents containing thirty or more carbon atoms, e.g. nitrogen derivatives of substituted succinic acid
  • C10M2215/30—Heterocyclic compounds
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  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
  • C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
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  • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
  • C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
  • C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
  • C10M2219/108—Phenothiazine
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  • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
  • C10M2223/06—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds
  • C10M2223/063—Ammonium or amine salts
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  • C10N2010/00—Metal present as such or in compounds
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  • C10N2010/02—Groups 1 or 11
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  • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
  • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
  • C10N2020/01—Physico-chemical properties
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  • C10N2040/00—Specified use or application for which the lubricating composition is intended
  • C10N2040/02—Bearings

Definitions

• Lubricant compositions comprising a synthetic base fluid of a polyoxy-alkylene compound gelled to a semifluid consistency, having a penetration value within the range of about 350 to about 450, reduce lubricant loss from imperfect gear-box seals etc. and possess good oxidation and good slip properties.
• the invention relates to semi-fiuid lubricant compositions and more particularly to synthetic base semi-fluid lubricant compositions comprising copolymers of oxyalkylene compounds.
• Lubricant compositions containing naturally occurring hydrocarbon base oils gelled to a grease consistency are well known. It is also well known that such greases are frequently unstable under working conditions and often undergo changes in their basic nature over the temperature range in which they are to be used. Consequently they require many varied and expensive additives if they are to meet minimal desirable lubricant standards. Furthermore, hydrocarbon base greases are not sufficiently fluid to provide adequate lubrication for todays advanced machinery. Conversely, the synthetic lubricant compositions of the invention are inherently stable over a wide range of working conditions and temperatures, providing excellent lubrication coupled with good oxidation and slip properties while requiring only minimal additives at elevated temperatures or where particularized characteristics are desired. They are particularly applicable as lubricants for gear sets, especially those in gear boxes which are'commonly described as being filled for life, they have also been found suitable for a Wide range of other applications discussed hereinafter.
• the present lubricant compositions comprise a synthetic base fluid gelled to a semi-fluid consistency and have penetrations of about 350 to 450.
• the synthetic base is a polyoxyalkylene compound obtained by condensing a plurality of alkylene oxide molecules with an organic compound containing from 2 to about 20 carbon atoms, and one or more suitably reactive hydrogen atoms, said organic compound can be alkyl, aryl, alkaryl, or aralkyl.
• Typical examples of some well known synthetic fluids are polyoxyalkylene glycols (e.g.
• Other such synthetic fluids are the conjugated sequential condensation products of propylene and ethylene oxides with compounds containing a singly reactive hydrogen atom.
• Y is the residue of an organic compound having from 2 to about 20 carbon atoms and one reactive hydrogen atom
• n has an average value of at least 6.4 as determined by hydroxyl number
• m has a value such that the oxyethylene group constitute about 1590% by weight of the compound with n and m having an upper limit of about 300.
• a further class of compounds included within the group of synthetic base fluids are the conjugated sequential condensation products of propylene and ethylene oxides with an organic compound containing a plurality of reactive hydrogen atoms.
• the preferred class of synthetic compounds for use in the lubricant composition of the invention are copolymers of ethylene oxide and propylene oxide and have the generalized formula:
• R can be either a hydrogen atom or an alkyl radical having from 1 to about 20 carbon atoms and x and y are respectively the number of ethylene oxide and propylene oxide monomers present in the copolymer each having a range from 5 to about 300 and preferably about 10 to 100. If the polymerization initiator used is water then R is a hydrogen atom and if the polymerization initiator is an alcohol R is the corresponding alkyl radical.
• These synthetic base media have properties that are desirable in lubricants, including good lubricity, high viscosity index, low pour point and volatility and good thermal stability. Representatives of this class of compound are available commercially under the trade name Oxilube.
• Preferred base fluids for lubricants according to the present invention are those designated Oxilube /140 and Oxilube 85/230 both of which are obtained from the polymerization of about 85% propylene oxide monomer and about 15% ethylene oxide monomer and have,
• compositions of the invention are of semi-fluid consistency, having a penetration value within the range of about 350 to about 450 (as determined by LP. 167/59T method), however, compositions having a rather narrower range of 385 to 450, and preferably of 420 to 450 may be particularly suitable when they are used in filled for life worm gear boxes.
• Hydrocarbon base greases will generally have lower penetration values and lower dropping points. Thus indicating a tendency toward unsatisfactory lubrication at a lower temperature.
• the specific penetration range (385 to 450) of the invention has proven extremely satisfactory over a wide range of uses and diverse applications. It is particularly important and vital to the invention that the lubricant have a semi-fluid consistency within such a penetration value range if the reduced leakage loss of the lubricant is to be realized.
• the lubricant compositions of the invention are gelled to the semi-fluid condition by the addition to the synthetic base fluid of an appropriate quantity of a gelling agent such as an alkali metal or alkaline earth metal soap of a fatty acid or substituted fatty acid (e.g. a hydroxy fatty acid). Mixtures of such soaps may be employed if desired.
• a gelling agent such as an alkali metal or alkaline earth metal soap of a fatty acid or substituted fatty acid (e.g. a hydroxy fatty acid).
• the acids from which the soaps are derived preferably contain from 12 to 24 carbon atoms and particularly from 16 to 22 carbon atoms in the molecule. Selection of an appropriate gelling agent is made in the light of knowledge, of particular properties required in the lubricant.
• the metal may be, for example, lithium,
• lithium salts are generally preferred because of their heat stability, and lithium 12-hydroxystearate is a particularly suitable gelling agent.
• gelling agents which may be employed instead of, or in conjunction with soaps to give the desired degree of fluidity are, for example, inorganic clays and silicas which have been rendered olephilic, as by a suitable coating procedure.
• the Bentone series of clays may be mentioned in this connection (treated bentonites).
• a disadvantage of the polyalkylene compounds used as base fluids in the present invention is that at the elevated temperatures encountered in gearboxes they produce odiferous and highly corrosive break-down products, which tend also to adversely affect the viscosity characteristics of the lubricant.
• -.It is, therefore, usual to incorporate in the base fluids of compositions of the invention, before they are subjected to high temperatures, such as during formulation of the lubricant compositions, an anti-oxidant.
• the anti-oxidant is commonly present in amounts up to about preferably up to 2.5% by weight of the total composition.
• a particularly suitable anti-oxidant is one selected from the group of compounds having the general formula:
• R and R are the same or different aromatic radicals having from 12 to about 40 carbon atoms, and R can be hydrogen or an alkyl, aryl alkaryl, aralkyl or cyanoalkyl radical having from 1 to about 20 carbon atoms.
• This group comprises three main sub-groups, viz: phenothiazine and substituted phenothiazines, thiophenlynaphthylamine and substituted thiophenylnaphthyl amines, and thio-dinaphthylamine and substituted thiodinaphthylamines.
• the first mentioned sub-group, and especially phenothiazine is the preferred anti-oxidant.
• aryl radicals contained in these materials may be substituted, for example, by alkyl, alkoxy or amino groups, and any amino groups in the compound may be substituted by alkyl, aryl, hydroxy or amino groups.
• Such antioxidants are well known in the art.
• a friction-reducing additive Any suitable additive which does not unduly impair the oxidation stability of the composition can be used.
• sorbitan mono-oleate Span 80
• Span 80 when used at concentrations of the order of 1% by weight of the total composition can give a substantial reduction in friction at very low speed, without any undue disadvantage as regards oxidation life.
• N-acyl sarcosines which compounds are available under the trade name Sarkosyl give good improvement in frictional properties coupled with good rusting resistance when used in quite low concentrations (of the order of 0.5% and preferably of the order of 0.3% by weight of the total composition).
• the preferred compound of this class in N-oleyl sarcosine (Sarkosyl O) which is N-oleylmethylamino acetic acid and is a liquid which is readily soluble in the composition of the invention.
• Such additives are conveniently added after any heat treatment to which the composition of the invention is subjected during formulation since they tend to be somewhat thermolabile.
• compositions of the invention are particularly useful as gear box lubricants because, as a consequence of their semi-fluid nature, loss of the lubricant from the gearbox by leakage from imperfect seals is significantly less than the loss that occurs when the ungelled synthetic base lubricant is employed, and indeed if seals are efiiciently designed and well fitted retention of the lubricant is sufficiently good for the gearbox to be described as filled for life.
• compositions of the invention because of their semi-fluid nature, good oxidation and good slip properties, have found application in, for example, packed universal joins (e.g. in vehicle steering mechanisms), in packed wheel bearings and in gear couplings, and they have also been found particularly advantageous as lubricants for metal drawing processes, such as in the drawing of copper tubing.
• a further advantage of the compositions of the invention is that being semi-fluid, they may be easily pumpable to constantly lubricated bearing surfaces.
• the incorporation into the lubricant of an extreme pressure additive has been found beneficial.
• the additive selected must, of course, be soluble in the synthetic fluid base. Many such additives are available and the expert will have no difiiculty in selecting a suitable additive for this purpose.
• a primary C -C amine salt of monochloromethyl phosphonic acid is particularly suitable.
• Such an additive is available commercially as MCMPA/ JMT.
• the proportion of the extreme pressure additive usually employed is small, commonly of the order of 0.1-0.5 preferably about 0.3% by weight of the total composition.
• a metal deactivator with such extreme pressure additives is desirable, and for this purpose it is preferred to use a small proportion of a 1,2,4-triazole.
• a 1,2,4-triazole Particularly suitable is a 3-amino-l,2,4-triazole as described in U.K. patent specification No. 1,124,904.
• Such triazoles may be used in a proportion of 0.001 to 2%, preferably 0.1-0.5 by weight of the total composition.
• Typical properties of a suitable polyalkylene base fluid are shown in the table below with and without the addition of 2% by weight of an anti-oxidant.
• Copolymer of ethylene oxide-propylene oxide (Oxilube 85/140) Nil 1.025 23.5 200 355 -25 Copolymer of ethylene oxide-propylene oxide (Oxilube 85/140+2%) wt. phena- Nil 1.025 144 23.1 200 405 25 thiamine.
• this fluid has suitable properties for use as a base oil for the present invention. It can also be seen that the addition of 2% by weight of phenothiazine anti-oxidant does not have any noticeable effect on the fluids properties, except that it effectively raises its fiashpoint by inhibiting oxidation during the determination, which would normally produce compounds giving rise to a lowered flash point.
• polyoxyal kylene fluids even when inhibited against oxidation, tend to show very high coefficients of friction, particularly when starting from rest.
• the test machine consists essentially of a 4 inch diameter bronze disc in loaded contact with a 2-inch diameter steel disc. The two discs rotate on parallel shafts in the same direction and at the same angular speed of rotation. The results are given in Table 2 below.
• EXAMPLE C Ethylene oxide-propylene oxide copolymer (Oxilube 85/ 140)+2% wt. phenothiazine+0.3% wt. N-oleylmethylamino acetic acid.
• N-acyl sarcosine additive as well as improving the frictional properties of the composition as demonstrated above, has the added advantage that the anti-rusting ability is similarly improved as shown in Table 3 which gives the results of rusting tests carried out according to an International Harvester Corporation (I.H.C.) method.
• the apparatus for this test is similar to that for ASTM D665 except that the cylindrical test piece is made entirely of steel instead of steel and plastic as in the latter.
• the test pieces have a temperature differential of 55 C. maintained along them so that water condenses. They are immersed in the oil for 30 minutes, then placed in the apparatus. The times taken for the first specks of rust to appear are recorded. Similar results were obtained using ASTM D665, The collected results are given in Table 3.
• the N-acyl sarcosine is added to a polyoxyalkylene base fluid (Oxilube 85/140) having 2% wt. of anti-oxidant henothiazine).
• the heat generated in the working gearbox is an important factor in lubricant effectiveness and the cooler running of boxes filled with a lubricant having a penetration value within the range of 420450 is shown by the results summarized in the following table.
• the unit was run at various loads to allow the temperature to stabilize.
• the following compositions were tested:
• EXAMPLE F Percent Ethylene oxide-propylene oxide copolymer (Oxilube 85 140) Phenothiazine 2 7
• EXAMPLE H A semi-fluid lubricant containing an extreme pressure additive was prepared having the following composition:
• This lubricant was used satisfactorily in a Bauer motorized industrial reduction gearbox, of a type having hardened steel on steel gears which is usually run under very severe conditions of speed and load.
• EXAMPLE I Percent Ethylene oxide-propylene oxide copolymer (Oxilube 85 /230) 94 Lithium-l2-hydroxystearate 3.8 Phenothiazine 1.9 N-oleylmethylamino acetic acid 0.3
• This lubricant was employed satisfactorily in a worm reduction gearbox having hardened steel on bronze gears.
• a semi-fluid lubricant composition adapted for use in filled for life gear boxes, consisting essentially of (1) a major amount of a synthetic base fluid which is a copolymer of ethylene oxide and propylene oxide having the following general formula:
• R is hydrogen or an alkyl radical having from one to about 20 carbon atoms and x and y respectively are the number of ethylene oxide and propylene oxide monomers present in the copolymer with each having a range from 2 to about 300, (2) a minor amount, sufficient to inhibit oxidation, of an antioxidant of the general formula where R and R are the same or different aromatic radicals having from 12 to about 40 carbon atoms, and R is hydrogen or an alkyl, aryl, alkaryl, aralkyl or cyanoalkyl radical having from 1 to about 20 carbon atoms, and (3) a minor amount of a suitable gelling agent selected from the group consisting of alkali metal soap, alkaline earth metal soap, clay, and silica, said lubricant having a penetration value of from 350 to about 450.
• composition of claim 1 wherein the anti-oxidant is thiodiarylamine.
• composition of claim 1 in which the anti-oxidant is phenothiazine or a hydrocarbon substituted phenothiazine.

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• Chemical & Material Sciences (AREA)
• Chemical Kinetics & Catalysis (AREA)
• General Chemical & Material Sciences (AREA)
• Oil, Petroleum & Natural Gas (AREA)
• Organic Chemistry (AREA)
• Lubricants (AREA)

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• 1968
  • 1968-11-20 GB GB5500068A patent/GB1294856A/en not_active Expired
• 1969
  • 1969-11-18 FR FR6939569A patent/FR2024899B1/fr not_active Expired
  • 1969-11-18 NL NL6917292.A patent/NL161812C/xx not_active IP Right Cessation
  • 1969-11-18 DE DE1957955A patent/DE1957955C3/de not_active Expired
  • 1969-11-18 BE BE741844D patent/BE741844A/xx unknown
  • 1969-11-18 SE SE15798/69A patent/SE363122B/xx unknown
  • 1969-11-19 US US878216A patent/US3663437A/en not_active Expired - Lifetime

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