US3658985A - Oil and fluorescent dye containing luster imparting liquid shampoo - Google Patents

Oil and fluorescent dye containing luster imparting liquid shampoo Download PDF

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US3658985A
US3658985A US845521A US3658985DA US3658985A US 3658985 A US3658985 A US 3658985A US 845521 A US845521 A US 845521A US 3658985D A US3658985D A US 3658985DA US 3658985 A US3658985 A US 3658985A
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oil
hair
shampoo
alkyl
carbon atoms
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Frank Wesley Olson Jr
Karl Hutcheson Roberts
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Colgate Palmolive Co
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Colgate Palmolive Co
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A61Q5/065—Preparations for temporary colouring the hair, e.g. direct dyes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/22—Luminous paints
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/42—Colour properties
    • A61K2800/43—Pigments; Dyes
    • A61K2800/434—Luminescent, Fluorescent; Optical brighteners; Photosensitizers

Definitions

  • a liquid shampoo for improving the combing properties and luster of hair washed therewith comprising an aqueous detergent composition suitable for shampooing hair which contains oil from the group consisting of mineral oil, vegetable oil, animal oil and synthetic oil and a hair substantive fluorescent dye in proper proportions.
  • the present invention relates to a liquid shampoo for improving the combing properties and luster of all colors of hair which comprises an aqueous detergent composition suitable for use in shampooing hair which contains, in addition to the ingredients for cleaning and, if desired, for conditioning the hair, oil from the group consisting of mineral, vegetable, animal oils, and synthetic oils, and hair substantive fluorescent dye in proper proportions.
  • Detergent compositions for use in shampooing hair are of two general types.
  • One of these types includes shampoos which are formulated primarily for cleaning the hair and underlying skin and which will be referred to herein as cleaning type shampoos. These compositions do not include ingredients which are intended to be, or which are capable in any substantial measure of being, deposited on the hair during the shampooing operation.
  • Another type includes so called hair conditioning shampoos which do contain such ingredients.
  • Te present invention is equally applicable to shampoo compositions of both of these types.
  • a and B are different and represent oxygen and nitrogen
  • R represents individually hydrogen, alkyl groups having 1-6 carbon atoms, chlorine or fluorine.
  • the preferred oxazole dye is the one in which each R is hydrogen and it is referred to herein under the name Dye A.
  • the mineral oil used in compositions made in accordance with the invention may be any mineral oil that dissolves in the detergent compositions in suflicient proportions to function as described herein and may be a light to heavy hydrocarbon oil but is preferably a light mineral oil, such as a water-clear, completely saturated, mineral oil having a Saybolt viscosity of about 50-80 desirably 55-65 cps. at F., a specific gravity compared with water when the oil and water are at 25 C., of 0.831 to 0.871, a flash point of 280 F. minimum and a fire point of 305 F. minimum, as obtained by the Cleveland open cup method.
  • a light mineral oil such as a water-clear, completely saturated, mineral oil having a Saybolt viscosity of about 50-80 desirably 55-65 cps. at F., a specific gravity compared with water when the oil and water are at 25 C., of 0.831 to 0.871, a flash point of 280 F.
  • the mineral oil may be replaced in whole or part by olive oil or other comparable vegetable and animal oils such as linseed oil, castor oil, cottonseed oil, safllower oil, almond oil, peanut oil, coconut oil, lanolin derivatives such as lanolin esters, lanolin alcohols and ethylene oxide adducts thereof.
  • Synthetic oils i.e., esters of higher fatty acids having about 10-20 carbon atoms such as isopropyl myristate, palmitate and stearate may also be used.
  • the detergent system in which the oil and fluorescent dye or optical brightener are used in combination may be any suitable shampoo composition including compositions of the cleaning type and conditioning type.
  • a preferred detergent system for the cleaning type shampoos is one based on fatty alcohol sulfates such as triethanolammonium lauryl sulfate.
  • Other anionic detergents of the organic sulfuric acid reaction type i.e., the sulfated and sulfonated detergents (including suitable mixtures thereof) may also be used, such as the alkyl sulfates, including alkyl ether sulfates, having about 8 to 22, preferably 12 to 18 carbon atoms per molecule, e.g., cetyl sulfate and lauryl polyethenoxy (l-S EtO groups) sulfate; the aliphatic acyl-containing compounds wherein the acyl radical has about 8 to about 22 carbon atoms, and more particularly the aliphatic carboxylic ester type containing at least about 10 and preferably about 12 to about 16 carbon atoms to the molecule, such as water soluble salts of the sulfuric acid esters
  • the alkyl sulfonates include olefin sulfonates and paraifin sulfonates.
  • the aromatic sulfonate detergents may be mononuclear or polynuclear in structure, the aromatic nucleus being derived from benzene, toluene, xylene, phenol, cresols, naphthalene and the like.
  • the alkyl substituent on the aromatic nucleus may vary widely provided the desired detergent power of the active ingredient is preserved. While the number of sulfonic acid groups present on the nucleus may vary it is usual to have one such group present in order to preserve as much as possible a balance between the hydro philic and hydrophobic portions of the molecule.
  • suitable alkyl aromatic sulfonate detergents are higher alkyl aromatic sulfonates in which the higher alkyl substituent on the aromatic nucleus may be branched or straight-chain in structure comprising such groups as decyl, dodecyl, keryl, pentadecyl, hexadecyl, mixed long chain alkyls derived from long chain fatty materials, cracked paraffin wax olefins, polymers of lower monoolefins, and the like.
  • Preferred examples of this class are the higher alkyl mononuclear aryl sulfonates wherein the alkyl groups have about 8 to 22, and preferably about 12 to 18 carbon atoms.
  • anionic detergents which may be present, usually with a sulfate or sulfonate detergent of the kinds specified above, include water soluble salts of fatty acids and substituted fatty acids such as coconut and tallow soaps, salts of fatty acid amides of lower aliphatic amino acids such as glycine, sarcosine, and the like.
  • anionic detergents are to be used in the form of their water soluble salts such as the amine, alkali metal and alkaline earth metal salts. While the sodium and potassium salts and the like may be suitably employed, it is preferred to use the ammonium, lithium, amine including alkylolamine salts in view of their generally greater solubility in aqueous solution. More particularly it is preferred to use the ammonium, mono ethanolarnine, diethanolamine, triethanolamine salts and mixtures thereof because of the excellent results attained with their use, particularly with the higher alkyl sulfates, the higher fatty acid monoglyceride sulfates (and mixtures thereof) as the active ingredients.
  • the proportion of the anionic sulfate or sulfonate detergent in the liquid shampoo composition is generally at least about usually between 10-35% and preferably from 25%.
  • shampoo compositions containing the anionic sulfate and sulfonate type detergents are generally so elfective in removing soil and oily materials that the hair is left somewhat unmanageable unless other ingredients are present which modify this action.
  • modifying ingredients that may be present in the shampoo compositions are non-ionic surface active agents such as higher fatty alcohols, including ether alcohols, and fatty acid amides, particularly fatty acid alkylolamides.
  • Thes ingredients act to improve both the quantity and the quality of the foam produced during shampooing.
  • the fatty alcohols and the fatty acyl group in the amides may have from 8 to carbon atoms per molecule.
  • the alcohols used have from 12 to 16 carbon atoms per molcule while the fatty acids used in making the amides are preferably derived from coconut oil in which the major proportion of the fatty acids have 12 and 14 carbon atoms per molecule.
  • each alkylol group usually has up to about 3 carbon atoms. It is preferred to use the monoethanol amides of lauric and myristic acids but diethanolamides and isopropanolamides of fatty acids having about 10 to 14 carbon atoms in the acyl radical are satisfactory. Examples are capric, lauric, myristic and coconut 4 monoethanolamides, diethanolamides and isopropanolamides and mixtures thereof. There may be employed also the alklol amides which are substituted by additional alkylol groups, suitable examples being the above amides condensed with one or two moles of ethylene oxide.
  • the non-ionics may be present in the shampoo compositions up to about 10%, preferably up to about 4% of the alcohol and up to about 8% of the fatty acid alkylolamides.
  • cellulose ethers such as hydroxypropyl methyl cellulose and an electrolyte such as sodium chloride.
  • the proportion of cellulose ether used may vary from 0 to about 2%.
  • the electrolyte or salt content may vary from 0 to about 2%.
  • a pH of 5-9 preferably about 6.5-8.5 it is preferred to adjust the pH of detergent compositions based on anionic sulfate and sulfate detergents so that the composition is relatively close to neutral, e.g., a pH of 5-9 preferably about 6.5-8.5.
  • acidic materials such as citric acid and basic materials such as triethanolamine may be added to obtain the proper pH.
  • Citric acid also serves as a sequestering and bufiering agent and is frequently added for this purpose even if not needed for pH adjustment. Generally speaking minor proportions up to a maximum of about 2% of each of these ingredients is sufiiicent to obtain the desired pH adjustment.
  • any suitable dyes may be incorporated in the solution.
  • D&C yellow No. l in a 1% solution, may be added to a shampoo composi tion of the above type at a level of about 0.050% to produce a desirable yellow color.
  • a very attractive green color can be obtained by using about 0.2% FD&C yellow No. 5 (1% solution) and a 0.1% FD&C blue No. 1 (1% solution).
  • An amber color is obtained by using about 0.075% D&C orange No. 4 (1% solution) with 0.025% red No. 2 (0.1% solution).
  • An attractive blue color can be obtained by using 0.25% FD&C blue No. l (1% solution) and 0.050% D&C red No. 19 (0.1% solution).
  • a color preservative e.g., a compound which absorbs ultra violet light, e.g., a mixture of 2,2'-dihydroxy-4,4'-dimethoxy benzophenone and other tetra-substituted benzophenones, referred to hereafter as Preservative X, and 2,4-dihydroxy benzophenone, referred to hereafter as Preservative Y, and mixtures thereof.
  • Preservative X 2,2'-dihydroxy-4,4'-dimethoxy benzophenone and other tetra-substituted benzophenones
  • Preservative Y 2,4-dihydroxy benzophenone
  • These materials are very effective in small proportions and in general about 0.025% adequately protects the composition from color change on exposure of the composition to light during storage and use. They may be used, however, within broader ranges of about 0.01 to 0.1%.
  • Preservative X is preferred for all the above colors except blue for which Preservative Y is
  • a material which inhibits bacterial growth in the detergent compositions e.g., formaldehyde USP which is effective when about 0.1% is present.
  • Other preservatives may also be used.
  • perfume of a suitable type and odor in the composition for its cosmetic appeal to the user.
  • Perfume may be present within the range of 0-2%.
  • the liquid vehicle in which the foregoing ingredients are carried primarily in solution, is water which may be replaced in part by a lower aliphatic monohydric alcohol, e.g., ethyl, propyl, and isopropyl alcohols.
  • a lower aliphatic monohydric alcohol e.g., ethyl, propyl, and isopropyl alcohols.
  • lower aliphatic polyhydric alcohols such as propylene glycol and glycerine may be used.
  • Alcohol may be present within the range of about 010%.
  • deionized water so as to avoid discoloration and other adverse effects of the water hardness.
  • composition represents a preferred formulation for a shampoo formulated in accordance with the present invention utilizing a higher fatty alcohol sulfate as the detergent:
  • Natural fatty alcohol C -C 0.9 Coconut monoethanolamide 5.0 Mineral oil-extra light 2.0 Dye A 0.1 Color (Ext. D&C yellow #1, 1% solution) 0.05 Preservative X 0.025 Hydroxypropyl methyl cellulose 0.95 Citric acid (anhydrous) 0.25 Triethanolamine 0.7 Sodium chloride 0.8 Formaldehyde USP 0.1 Perfume 0.5 Ethyl alcohol (SD 40) 7.0 Deionized water, q.s.
  • the pH of this composition is about 7.0 and its viscosity is 45:5 seconds, as tested on a number 5 Raymond flow meter at 77 F.
  • This composition has a pH of about 7.5 and about the same viscosity as Example I.
  • compositions of the type described has a number of very desirable effects, including improved combing and better appearance.
  • the latter can be demonstrated by a so-called half head test.
  • skilled operators wash the hair on one side of the head of a female subject with a composition containing the mineral oil and fluorescent dye and the hair on the other half of the head with an identical composition except that there is no mineral oil and fluorescent dye present. Precautions are taken to prevent contamination of the hair on the other side of the head while the hair on one side is being shampooed. After shampooing the hair is set and dried, the rollers removed, the hair parted in the middle and combed down each side.
  • each subject is observed by ten female evaluators in sunlight, indirect sunlight, fluorescent light and ultra violet light. The evaluators are asked to indicate the preferred side of the head, or if no preference is found so to state.
  • each subject is given flwelve one teaspoonful applications of the two shampoos to each respective side of the head using city water to moisten and to rinse the hair.
  • the results of the test are given in Table I in which the shampoo containing the mineral oil and fluorescent dye is designated active and the same composition without them placebo.
  • the composition containing mineral oil and optical brightener is preferred to the commercial shampoo, because of a number of attributes possessed by or attributed to the Bright Side formula, including the following:
  • Ratio of Attributes preference Gives luster or shine to the hair 2:1 Highlights the natural color of the hair 2:1 Better lathering 3:2 Leaves the hair color naturally bright 3:2
  • Shampoos of the present invention can also be prepared utilizing a hair conditioning type shampoo as the base in which the oil and optical brightener are incorporated.
  • Some people who use shampoos of the cleaning type find that their hair is left in a statically electrified state in which the individual hairs repel each other or in a state in which simple combing produces such electrification. In either case the hair is diflicult to manage and cream rinses have been available commercially for use in such cases following the shampoo to improve the wet combing of the hair and reduce static.
  • the objective or hair conditioning shampoos is to make the use of a separate cream rinse unnecessary, but experience has shown that hair washed with such shampoos, thoroughly rinsed and then combed wet produces an undesirable foam on the comb.
  • the present invention substantially overcomes this difiiculty and gives improved wet combing and luster due to the combined effects of the presence of mineral oil and an optical dye.
  • Examples III, IV and V set forth satisfactory compositions of hair conditioning shampoos.
  • these conditioning shampoos contain a combination of detergents consisting of a higher alkyl amine oxide surfactant, an amphoteric surfactant, and a cationic surfactant.
  • the pH of these shampoos may be adjusted within the range of about to 9.6, preferably about 8.9 to 9.2.
  • These shampoos in the preferred pH range are quite compatible with materials used on hair, particularly resin-type hair sprays, and they are entirely suitable for use on hair that has been damaged by bleaches, hair waving and straightening compositions, exposure to sun and sea water, etc.
  • M as defined hereinafter may include hydrogen as well as the named cations.
  • Suitable higher alkyl amine oxides are those having the formula:
  • Typical higher alkyl groups which may be present include decyl, lauryl, myristyl, cetyl, stearyl, eicosyl or other higher alkyl groups of about -20 carbon atoms, derived for example from tallow, hydrogenated tallow, coconut oil, etc.
  • the amine oxides in which the average number of carbon atoms in the higher alkyl groups is above about have given compositions whose foams (produced during shampooing of the hair) have a creamier appearance, with a smaller bubble size.
  • R, and R are methyl groups, but other radicals, e.g., ethyl, hydroxyethyl or hydroxypropyl, may be used in place of one or both methyl groups.
  • the water-soluble, ampholytic or amphoteric detergents which can be used in the compositions of this invention generally contain a hyprophobic alkyl group of about 10 to carbon atoms, at least one anionic watersolubilizing group, e.g., carboxy, sulfo, sulfate, or phosphono, and at least one cationic group, e.g., non-quaternary nitrogen, quaternary ammonium, or quaternary phosphonium group, in their molecular structure.
  • the alkyl group may be straight chain or branched and the specific cationic atom may be part of a heterocyclic ring.
  • ampholytic detergents include the alkyl beta-aminopropionates, R N(H)C H COOM; the alkyl beta-aminodipropionates, R N(C H COOM) and the long chain imidazole derivatives sold under the trade name Miranol having the following formula:
  • R is an alkyl group of about 10 to 20 carbon atoms
  • R is an alkylene or hydroxyalkylene group containing 1 to 4 carbon atoms
  • M is a water-soluble cation, e.g., alkali metal, ammonium or alkylolammonium.
  • the higher alkyl group of the aminopropionates and iminodipropionates may be, for example, derived from coco fatty alcohol, lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, or blends of such alcohols; whereas the higher alkyl group of the imidazole derivatives is derived from coconut oil or tallow, Preferred detergents are sodium N-lauryl beta-aminopropionate, disodium N-lauryl beta-iminodipropionate, and the sodium salt of 2-lauryl-cycloimidium-1 hydroxyl, l-hydroxy-ethanoic acid, l-ethanoic acid.
  • amphoteric, imidazole detergents have the following structure:
  • R is a higher acyclic group of 7 to 17 carbon atoms and M is a water-soluble cation, e.g., sodium, potassium, ammonium, and mono-, dior tri-alkylolammonium.
  • the acyclic groups may be derived from coconut oil fatty acids (a mixture of fatty acids containing 8 to 18 carbon atoms), lauric fatty acid, and oleic fatty acid, and alkyl groups of 7 to 17 carbons are preferred acyclic groups.
  • Such detergents can be prepared by dehydrating the reaction product of a higher fatty acid and a hydroxyalkyl alkylene polyamine, e.g., beta-hydroxyethyl ethylene diamine, and neutralizing the resultant material as described in US. Pat. 2,267,965.
  • a hydroxyalkyl alkylene polyamine e.g., beta-hydroxyethyl ethylene diamine
  • amphoteric detergents are the sultaine and betaine types having the following general structure:
  • R is an alkyl group containing about 8 to 18 carbon atoms
  • R and R are lower alkyl groups containing 1 to 3 carbon atoms
  • R is an alkylene or hydroxyalkylene group containing about 1 to 4 carbon atoms
  • X is an anion selected from the group consisting of sO -(sultaiue) and COO (betaine).
  • Preferred compounds are I-(myristyl dimethylammonio) acetate and 1-(myristyl dimethylammonio)-2-hydroxypropane-3-sulfonate.
  • amphoteric detergents are usually supplied in the sodium, potassium, alkylolammonium or other salt form. It is preferred to use those amphoteric detergents which dissolve and foam readily in water at the pH of 8.89.6 and the most preferred amphoteric detergents are the higher alkyl beta-aminopropionate salts and the higher alkyl beta iminodipropionate salts.
  • Cationic detergents which may be used are the quaternary ammonium compounds having at least one long chain hydrophobic radical, e.g., alkyl radicals of 10-24 carbon atoms, in their molecular structure.
  • the higher alkyl group may be directly attached to the quaternary nitrogen or indirectly attached thereto through an imidazole group or an amidopropyl group.
  • Suitable quaternary ammonium salts are selected from the group consisting of higher alkyl quaternary ammonium salts having the following formulas:
  • R is a higher alkyl or alkenyl group containing an average of 10 to 24 carbon atoms
  • R is an alkyl or hydroxyalkyl group of 1 to 3 carbon atoms
  • R is an alkyl or hydroxyalkyl group of 1 to 3 carbon atoms or a benzyl group
  • X is an anion selected from the group consisting of chloride, methosulfate, bromide, phosphate, dialkyl phosphate, and acetate.
  • Preferred cationic compounds are Z-stearyl, l-methyl or l-hydroxyethyl, 1 stearylamido-ethyl imidazolinium methosulfate and tallowyl amidopropyl dimethyl hydroxyethyl ammonium chloride (tallowyl describes the mixture of C to C fatty acids obtained from tallow).
  • the quaternary ammonium compound is preferably one which is stable in aqueous solution or dispersion at pH 9 at room temperature and more preferably stable for at least a month at pH 9 at 120 F.
  • the preferred quaternary amonium compounds are free of ester linkages unstable under the foregoing conditions.
  • the watersoluble quaternary ammonium compound is most usually supplied as a chloride or methosulfate Best results have been thus far obtained with compositions whose proportions are in the following ranges (the ranges being in percent by weight of the shampoo composition): water-soluble quaternary ammonium detergent surfactant about 0.1l%, preferably about 1-6%; water soluble amphoteric detergent surfactant about 220%, preferably about 312% (calculated as the acidic form of the amphoteric material); water-soluble amine oxide detergent surfactant about 118%, preferably about 4-15 Generally the total amount of the detergents in the mixture is in the range of about l230%, preferably about 15-25%. It will be appreciated, of course, that the compositions may be supplied in more highly concentrated form, for subsequent dilution with water.
  • the pH of the composition may be adjusted to the level previously mentioned by the use of an alkaline material.
  • a water-soluble amine e.g. a substantially non-volatile amine such as an alkanolamine, preferably triethanolamine, may be used for this purpose, as may inorganic bases such as sodium hydroxide or potassium hydroxide.
  • the pH of the composition remains substantially constant on considerable dilution with water; in one typical case the pH (measured electrically) was 9.05 at 20% concentration, 9.01 at 10%, 9.00 at 5%, 8.98 at 2% and 8.97 at 1% concentration.
  • compositions of a wide range of viscosities may be produced from the combination of the foregoing ingredients. It is often desirable to add viscosity-adjusting ingredients.
  • viscosity-increasing materials there may be used long chain fatty amides, e.g. a monoethanolamide, diethanolamide or dimethylamide of a fatty acid of about to 16 carbon atoms such as lauric-myristic monoethanolamide or diethanolamide.
  • viscosity decreasing ingredients which also serve to lower the cloud point of the composition there may be used water-soluble solvents, such as polyhydric alcohols, e.g. propylene glycol or ethoxylated polypropylene glycol or lower alkyl ethers of such glycols.
  • the proportion of such ingredients is generally less than 5% of the total composition, e.g. about /24%.
  • Water-soluble protein may also be present in the compositions.
  • This ingredient in the compositions described above gives improved curl retention to the shampooed hair, while substantially retaining or improving the other desirable effects previously discussed.
  • this ingredient is a low molecular weight polypeptide obtained by hydrolysis of protein materials such as human and animal hair, horns, hides, hoofs gelatin, collagen, and the like. During hydrolysis the proteins are gradually broken down into their constituent polypeptides and amino acids by prolonged heating with acids, e.g., sulfuric acid, or alkalis, e.g., sodium hydroxide, or treatment with enzymes, e.g., peptidases.
  • acids e.g., sulfuric acid, or alkalis, e.g., sodium hydroxide
  • enzymes e.g., peptidases.
  • hydrolysis high molecular weight polypeptides are formed first and as hydrolysis proceeds these are converted progressively to simpler and simpler polypeptides to tripeptides, dipeptides, and finally to amido acids.
  • polypeptides derived from proteins are complex mixtures and in practice the average molecular weight of the hydrolysate will vary from (amino acids) to about 20,000. All satisfactory hydrolyzed polypeptides are characterized by water solubility.
  • compositions which contain soluble protein it is preferred to use hydrolyzed collagen of such low molecular weight as to be completely soluble in water, non-gelling, and non-denaturing with an average molecular weight below 15,000, preferably in the range of about 500 to 10,000.
  • the amount of protein used is preferably in the range of about Az3% most preferably about 1 to 2%.
  • the cosmetic properties of the shampoos of the hair conditioning type may be modified as desired by incorporating the coloring dyes, color and other preservative, perfumes, and the like as described above for shampoos of the cleaning types.
  • the proportion of oil, whether mineral, vegetable, animal, or synthetic in the composition should be sufficient to produce the desired effect, usually at least about 0.5% but not enough to produce a separate phase on standing.
  • the oil should be taken into the aqueous system, whether by dissolution or otherwise, so as to appear to the eye to be a single phase.
  • the upper limit may vary, depending on the nature of the oil and the ingredients and proportions of the aqueous system. Generally speaking the upper limit is less than 5%, often less than 3%, and an effective maximum is about 2%.
  • the present invention does not embrace the detergents or any of the ingredients per se, which may be chosen and formulated in accordance with the knowledge of the art, but rather the combination consisting essentially of (1) an aqueous detergent composition suitable for shampooing containing properly chosen ingredients in proper proportions, (2) oil (mineral, vegetable, synthetic and/or animal) and (3) fluorescent dyes in proper proportions to achieve the improved luster and combing properties.
  • an oil selected from the group consisting of mineral oil
  • a water-soluble anionic detergent selected from the group consisting of an alkyl sulfate, an aliphatic acyl sulfate, an alkyl sulfonate, an aliphatic acyl sulfonate, an alkylaryl sulfonate and an olefin sulfonate, said alkyl, aliphatic acyl, alkyla
  • a liquid shampoo as set forth in claim 6 which contains about to 25% by weight of said alkyl sulfate, about 1.5% to 2% by weight of mineral oil, and about 0.1% to 0.2% by weight of Z-styryl naphth(l,2-d) oxazole.
  • a liquid shampoo as set forth in claim 7 in which said alkyl sulfate is triethano'lammonium lauryl sulfate and which contains in addition up to 8% by weight of C C fatty acid mono-, diethanolamide or isopropanolamide and up to 10% by weight of a lower aliphatic monohydric or polyhydric alcohol, said shampoo composition being a single-phase liquid.
  • a liquid shampoo as set forth in claim 2 in which about 12% to about 30% by weight of detergent is present, said detergent being a mixture of 1% to 18% by weight of a higher alkyl amine oxide having the formula Br R2 N+O wherein R is alkyl containing an average of about 12 RiN(H) C2 4COOM R N(CzH C O 0M)2 and 18 CHz R 011 Ri( l l OH RzCOOM wherein R is alkyl of 10 to 20 carbon atoms, R is alkylene or hydroxyalkylene containing 1 to 4 carbon atoms, and M is a water-soluble cation selected from the group consisting of sodium, potassium, ammonium, and alkylolammonium, a Bic-17 HzC (] ⁇ R;
  • R is a higher acyclic group of 7 to 17 carbon atoms and M is a water-soluble cation selected from the group consisting of sodium, potassium, ammonium, and alkylolammonium, and
  • R;Il I -R4-X' wherein R is alkyl containing about 8 to 18 carbon atoms, R and R are lower alkyls of 1 to 3 carbon atoms, R, is alkylene or hydroxyalkylene containing 1 to 4 carbon atoms and X is S0 or 00 about 0.5% to 10% by weight of a quaternary ammonium salt selected from the group consisting of H R CON CHeC HzCH2N R2 wherein R is higher alkyl or alkenyl containing an average of 10 to 24 carbon atoms, R is alkyl or hydroxyalkyl of 1 to 3 carbon atoms, R is alkyl or hydroxyalkyl of 1 to 3 carbon atoms or benzyl, and X is an anion selected from the group consisting of chloride, methosulfate, bromide, phosphate, dialkyl phosphate, and acetate, said shampoo being of the conditioning type.
  • a liquid shampoo as set forth in claim 9 in which the proportion of said amine oxide is 4% to 15% by weight, the proportion of said amphoteric detergent is 3% to 12% by weight, and the proportion of said quaternary salt is 1% to 6% by weight.
  • a single-phase liquid shampoo consisting essentially of by weight about 6% to 12% of myristyl dimethyl amine oxide, 0.5% to 3% of tallowyl amidopropyl dimethyl hydroxyethyl ammonium chloride, 0.5% to 5% of lauric-myristic dicthanolamidc, 3% to 8% of N-lauryl- 13 myristyl beta-alanine, from 0.5% to 2% of an oil from the class consisting of extra-light mineral and olive oil, 0.1% to 0.2% of 2-styryl naphth(1,2-d)oxazole, and water.

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US845521A 1969-07-28 1969-07-28 Oil and fluorescent dye containing luster imparting liquid shampoo Expired - Lifetime US3658985A (en)

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US3929680A (en) * 1972-04-20 1975-12-30 Kao Corp Liquid detergent composition
US3943234A (en) * 1973-08-09 1976-03-09 The Procter & Gamble Company Acidic emollient liquid detergent composition
US3953462A (en) * 1973-10-29 1976-04-27 Xeerox Corporation Imaging process
US3979340A (en) * 1973-04-09 1976-09-07 Colgate-Palmolive Company Olefin sulfonate detergent compositions
US4137191A (en) * 1977-02-14 1979-01-30 Inolex Corporation Low-irritant surfactant composition
US4205103A (en) * 1975-05-14 1980-05-27 The Goodyear Tire & Rubber Company Process using same stable foam latex with built-in self gel mechanism and coating
US4329335A (en) * 1980-11-10 1982-05-11 Colgate-Palmolive Company Amphoteric-nonionic based antimicrobial shampoo
US4329334A (en) * 1980-11-10 1982-05-11 Colgate-Palmolive Company Anionic-amphoteric based antimicrobial shampoo
US4472297A (en) * 1982-03-01 1984-09-18 The Procter & Gamble Company Shampoo compositions containing hydroxypropyl guar gum
US4867971A (en) * 1988-04-22 1989-09-19 Colgate-Palmolive Company Low pH shampoo containing climbazole
US4986927A (en) * 1990-01-16 1991-01-22 Lyle Elton Spot and stain remover containing a major amount of a vegetable oil
US5051250A (en) * 1989-06-21 1991-09-24 Colgate-Palmolive Company Fiber conditioning compositions containing solubilized poly-lower alkylene
WO1991017237A1 (en) * 1990-04-27 1991-11-14 The Procter & Gamble Company Cleansing products
US5174927A (en) * 1990-09-28 1992-12-29 The Procter & Gamble Company Process for preparing brightener-containing liquid detergent compositions with polyhydroxy fatty acid amines
US5503779A (en) * 1995-03-20 1996-04-02 Colgate Palmolive Company High foaming light duty liquid detergent
US5679877A (en) * 1996-06-14 1997-10-21 Colgate-Palmolive Co. Thickened liquid cleaning composition containing an abrasive
US5707955A (en) * 1996-07-15 1998-01-13 Colgate-Palmolive Co. High foaming nonionic surfactant based liquid detergent
WO1999013833A1 (en) * 1997-09-17 1999-03-25 The Procter & Gamble Company Hair care compositions comprising optical brighteners and cationic compounds
WO1999013829A1 (en) * 1997-09-17 1999-03-25 The Procter & Gamble Company Shampoo compositions comprising optical brighteners and polyvalent cations
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WO1999013832A1 (en) * 1997-09-17 1999-03-25 The Procter & Gamble Company Hair care compositions comprising optical brighteners and water-insoluble high molecular weight oily compounds
WO1999013828A1 (en) * 1997-09-17 1999-03-25 The Procter & Gamble Company Shampoo compositions comprising optical brighteners and mild surfactant matrix
WO1999013848A1 (en) * 1997-09-17 1999-03-25 The Procter & Gamble Company Hair care compositions comprising optical brighteners and polymeric suspending agents
WO1999013849A1 (en) * 1997-09-17 1999-03-25 The Procter & Gamble Company Hair care compositions comprising optical brighteners and high melting point compounds
WO1999013826A1 (en) * 1997-09-17 1999-03-25 The Procter & Gamble Company Hair care compositions comprising polystyrylstilbenes
WO1999013847A1 (en) * 1997-09-17 1999-03-25 The Procter & Gamble Company Hair care compositions comprising optical brighteners and non-volatile solvents
WO1999013834A1 (en) * 1997-09-17 1999-03-25 The Procter & Gamble Company Hair care compositions comprising optical brighteners and perfume compounds
WO1999013845A1 (en) * 1997-09-17 1999-03-25 The Procter & Gamble Company Hair care compositions comprising optical brighteners which alter hair colors
WO1999013823A3 (en) * 1997-09-17 1999-08-12 Procter & Gamble Hair care compositions comprising optical brighteners and hair conditioning agents
US6527981B1 (en) * 1999-05-24 2003-03-04 Lonza Inc. Azole/amine oxide preservatives
US20040002550A1 (en) * 2002-06-28 2004-01-01 Mercurio Anthony Fred Post foaming compositions
EP1166753A3 (en) * 2000-06-27 2004-02-18 Kao Corporation Hair dye composition
EP1464328A1 (fr) * 2003-04-01 2004-10-06 L'oreal Composition de coloration pour matieres kéranitiques humaines comprenant un colorant fluorescent et un agent conditionneur insoluble, procédé et utilisation
US20040204331A1 (en) * 2003-04-14 2004-10-14 Colgate-Palmolive Company Antibacterial light duty liquid cleaning composition
US20040256598A1 (en) * 2003-04-01 2004-12-23 Gregory Plos Composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one compound comprising an acid functional group and processes therefor
US20040258641A1 (en) * 2003-04-01 2004-12-23 Gregory Plos Cosmetic composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one cationic polymer, and a dyeing process therefor
US20050008593A1 (en) * 2003-04-01 2005-01-13 Gregory Plos Dye composition comprising at least one fluorescent dye and a non-associative thickening polymer for human keratin materials, process therefor, and method thereof
US20050008594A1 (en) * 2003-04-01 2005-01-13 Gregory Plos Composiiton for dyeing human keratin materials, comprising at least one fluorescent dye and at least one polyol, process therefor and use thereof
US20050005368A1 (en) * 2003-04-01 2005-01-13 Gregory Plos Process for dyeing, with a lightening effect, human keratin fibers that have been permanently reshaped, using at least one composition comprising at least one fluorescent dye
US20050005371A1 (en) * 2003-04-01 2005-01-13 Chrystel Pourille-Grethen Method of dyeing human keratin materials with a lightening effect with compositions comprising at least one fluorescent dye and at least one amphoteric or nonionic surfactant, composition thereof, process thereof, and device therefor
US20050020465A1 (en) * 2003-07-23 2005-01-27 Colgate-Palmolive Company Liquid dish cleaning compositions
US20050031562A1 (en) * 2003-04-01 2005-02-10 Luc Gourlaouen Composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one associative polymer, process therefor and use thereof
US20050028301A1 (en) * 2001-09-28 2005-02-10 Florent Pastore Dyeing composition with a brightening effect for human kerationous fibres
US20050049157A1 (en) * 2003-08-29 2005-03-03 Kimberly-Clark Worldwide, Inc. Single phase color change agents
US20050076457A1 (en) * 2003-04-01 2005-04-14 Gregory Plos Composition for dyeing a human keratin material, comprising at least one fluorescent dye and at least one insoluble conditioning agent, process thereof, use thereof, and devices thereof
US20050098763A1 (en) * 2003-04-01 2005-05-12 Gregory Plos Composition for dyeing human keratin materials, comprising a fluorescent dye and a particular sequestering agent, process therefor and use thereof
US20050282721A1 (en) * 2003-07-23 2005-12-22 Gregory Szewczyk Liquid dish cleaning compositions
US20060010617A1 (en) * 2002-12-24 2006-01-19 Luc Gourlaouen Method for dyeing or coloring human keratin materials with lightening effect using a composition comprising at least one fluorescent compound and at least one optical brightener
US20060122092A1 (en) * 2003-08-28 2006-06-08 Gregory Szewczyk Liquid dish cleaning compositions
US7147673B2 (en) 2003-04-01 2006-12-12 L'oreal S.A. Composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one insoluble polyorganosiloxane conditioning polymer, process therefor and use thereof
US20060287215A1 (en) * 2005-06-17 2006-12-21 Mcdonald J G Color-changing composition comprising a thermochromic ingredient
US20070098767A1 (en) * 2005-11-01 2007-05-03 Close Kenneth B Substrate and personal-care appliance for health, hygiene, and/or environmental applications(s); and method of making said substrate and personal-care appliance
US20070098768A1 (en) * 2005-11-01 2007-05-03 Close Kenneth B Two-sided personal-care appliance for health, hygiene, and/or environmental application(s); and method of making said two-sided personal-care appliance
US20070142256A1 (en) * 2005-12-15 2007-06-21 Lang Frederick J Health-and-hygiene appliance comprising a dispersible component and a releasable component disposed adjacent or proximate to said dispersible component; and processes for making said appliance
US20070142263A1 (en) * 2005-12-15 2007-06-21 Stahl Katherine D Color changing cleansing composition
US20070238631A1 (en) * 2006-04-07 2007-10-11 Colgate-Palmolive Company Liquid cleaning composition having low viscosity
US7303589B2 (en) 2003-04-01 2007-12-04 L'oreal S.A. Process for dyeing human keratin fibers, having a lightening effect, comprising at least one fluorescent compound and compositions of the same
US20090288674A1 (en) * 2003-04-01 2009-11-26 L'oreal S.A. Cosmetic dye composition with a lightening effect for human keratin materials, comprising at least one fluorescent dye and at least one aminosilicone, and process of dyeing
US20090312227A1 (en) * 2008-06-17 2009-12-17 Colgate-Palmolive Light duty liquid cleaning compositions and methods of manufacture and use thereof
US20090312225A1 (en) * 2008-06-17 2009-12-17 Colgate-Palmolive Company Light Duty Liquid Cleaning Compositions and Methods of Manufacture and Use Thereof
US8067350B2 (en) 2005-12-15 2011-11-29 Kimberly-Clark Worldwide, Inc. Color changing cleansing composition
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DE4129926C1 (enrdf_load_stackoverflow) * 1991-09-09 1992-07-23 Kao Corporation Gmbh, 4000 Duesseldorf, De
JP3492738B2 (ja) * 1993-10-13 2004-02-03 サンスター株式会社 毛髪化粧料
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US3929680A (en) * 1972-04-20 1975-12-30 Kao Corp Liquid detergent composition
US3979340A (en) * 1973-04-09 1976-09-07 Colgate-Palmolive Company Olefin sulfonate detergent compositions
US3943234A (en) * 1973-08-09 1976-03-09 The Procter & Gamble Company Acidic emollient liquid detergent composition
US3953462A (en) * 1973-10-29 1976-04-27 Xeerox Corporation Imaging process
US4205103A (en) * 1975-05-14 1980-05-27 The Goodyear Tire & Rubber Company Process using same stable foam latex with built-in self gel mechanism and coating
US4137191A (en) * 1977-02-14 1979-01-30 Inolex Corporation Low-irritant surfactant composition
US4329335A (en) * 1980-11-10 1982-05-11 Colgate-Palmolive Company Amphoteric-nonionic based antimicrobial shampoo
US4329334A (en) * 1980-11-10 1982-05-11 Colgate-Palmolive Company Anionic-amphoteric based antimicrobial shampoo
US4472297A (en) * 1982-03-01 1984-09-18 The Procter & Gamble Company Shampoo compositions containing hydroxypropyl guar gum
US4867971A (en) * 1988-04-22 1989-09-19 Colgate-Palmolive Company Low pH shampoo containing climbazole
US5051250A (en) * 1989-06-21 1991-09-24 Colgate-Palmolive Company Fiber conditioning compositions containing solubilized poly-lower alkylene
US4986927A (en) * 1990-01-16 1991-01-22 Lyle Elton Spot and stain remover containing a major amount of a vegetable oil
WO1991017237A1 (en) * 1990-04-27 1991-11-14 The Procter & Gamble Company Cleansing products
US5174927A (en) * 1990-09-28 1992-12-29 The Procter & Gamble Company Process for preparing brightener-containing liquid detergent compositions with polyhydroxy fatty acid amines
US5503779A (en) * 1995-03-20 1996-04-02 Colgate Palmolive Company High foaming light duty liquid detergent
US5679877A (en) * 1996-06-14 1997-10-21 Colgate-Palmolive Co. Thickened liquid cleaning composition containing an abrasive
US5707955A (en) * 1996-07-15 1998-01-13 Colgate-Palmolive Co. High foaming nonionic surfactant based liquid detergent
WO1999013829A1 (en) * 1997-09-17 1999-03-25 The Procter & Gamble Company Shampoo compositions comprising optical brighteners and polyvalent cations
WO1999013834A1 (en) * 1997-09-17 1999-03-25 The Procter & Gamble Company Hair care compositions comprising optical brighteners and perfume compounds
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WO1999013832A1 (en) * 1997-09-17 1999-03-25 The Procter & Gamble Company Hair care compositions comprising optical brighteners and water-insoluble high molecular weight oily compounds
WO1999013828A1 (en) * 1997-09-17 1999-03-25 The Procter & Gamble Company Shampoo compositions comprising optical brighteners and mild surfactant matrix
WO1999013848A1 (en) * 1997-09-17 1999-03-25 The Procter & Gamble Company Hair care compositions comprising optical brighteners and polymeric suspending agents
WO1999013849A1 (en) * 1997-09-17 1999-03-25 The Procter & Gamble Company Hair care compositions comprising optical brighteners and high melting point compounds
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WO1999013847A1 (en) * 1997-09-17 1999-03-25 The Procter & Gamble Company Hair care compositions comprising optical brighteners and non-volatile solvents
WO1999013833A1 (en) * 1997-09-17 1999-03-25 The Procter & Gamble Company Hair care compositions comprising optical brighteners and cationic compounds
WO1999013845A1 (en) * 1997-09-17 1999-03-25 The Procter & Gamble Company Hair care compositions comprising optical brighteners which alter hair colors
WO1999013823A3 (en) * 1997-09-17 1999-08-12 Procter & Gamble Hair care compositions comprising optical brighteners and hair conditioning agents
US6527981B1 (en) * 1999-05-24 2003-03-04 Lonza Inc. Azole/amine oxide preservatives
EP1166753A3 (en) * 2000-06-27 2004-02-18 Kao Corporation Hair dye composition
US7217296B2 (en) 2001-09-28 2007-05-15 L'oreal S.A. Dyeing composition with a lightening effect for human keratin materials comprising at least one fluorescent dye
US20050028301A1 (en) * 2001-09-28 2005-02-10 Florent Pastore Dyeing composition with a brightening effect for human kerationous fibres
US20040002550A1 (en) * 2002-06-28 2004-01-01 Mercurio Anthony Fred Post foaming compositions
US20040116544A1 (en) * 2002-06-28 2004-06-17 Mercurio Anthony F. Post foaming compositions
US7261744B2 (en) 2002-12-24 2007-08-28 L'oreal S.A. Method for dyeing or coloring human keratin materials with lightening effect using a composition comprising at least one fluorescent compound and at least one optical brightener
US20060010617A1 (en) * 2002-12-24 2006-01-19 Luc Gourlaouen Method for dyeing or coloring human keratin materials with lightening effect using a composition comprising at least one fluorescent compound and at least one optical brightener
US20050031562A1 (en) * 2003-04-01 2005-02-10 Luc Gourlaouen Composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one associative polymer, process therefor and use thereof
US20090288674A1 (en) * 2003-04-01 2009-11-26 L'oreal S.A. Cosmetic dye composition with a lightening effect for human keratin materials, comprising at least one fluorescent dye and at least one aminosilicone, and process of dyeing
US20050008594A1 (en) * 2003-04-01 2005-01-13 Gregory Plos Composiiton for dyeing human keratin materials, comprising at least one fluorescent dye and at least one polyol, process therefor and use thereof
US20050005368A1 (en) * 2003-04-01 2005-01-13 Gregory Plos Process for dyeing, with a lightening effect, human keratin fibers that have been permanently reshaped, using at least one composition comprising at least one fluorescent dye
US20050005371A1 (en) * 2003-04-01 2005-01-13 Chrystel Pourille-Grethen Method of dyeing human keratin materials with a lightening effect with compositions comprising at least one fluorescent dye and at least one amphoteric or nonionic surfactant, composition thereof, process thereof, and device therefor
US7250064B2 (en) 2003-04-01 2007-07-31 L'oreal S.A. Dye composition comprising at least one fluorescent dye and a non-associative thickening polymer for human keratin materials, process therefor, and method thereof
US20040258641A1 (en) * 2003-04-01 2004-12-23 Gregory Plos Cosmetic composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one cationic polymer, and a dyeing process therefor
US20040256598A1 (en) * 2003-04-01 2004-12-23 Gregory Plos Composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one compound comprising an acid functional group and processes therefor
US7736631B2 (en) 2003-04-01 2010-06-15 L'oreal S.A. Cosmetic dye composition with a lightening effect for human keratin materials, comprising at least one fluorescent dye and at least one aminosilicone, and process of dyeing
US20050076457A1 (en) * 2003-04-01 2005-04-14 Gregory Plos Composition for dyeing a human keratin material, comprising at least one fluorescent dye and at least one insoluble conditioning agent, process thereof, use thereof, and devices thereof
US20050098763A1 (en) * 2003-04-01 2005-05-12 Gregory Plos Composition for dyeing human keratin materials, comprising a fluorescent dye and a particular sequestering agent, process therefor and use thereof
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US7208018B2 (en) 2003-04-01 2007-04-24 L'oreal Composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one associative polymer, process therefor and use thereof
US20050008593A1 (en) * 2003-04-01 2005-01-13 Gregory Plos Dye composition comprising at least one fluorescent dye and a non-associative thickening polymer for human keratin materials, process therefor, and method thereof
US7204860B2 (en) 2003-04-01 2007-04-17 L'oreal Composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one polyol, process therefor and use thereof
FR2853228A1 (fr) * 2003-04-01 2004-10-08 Oreal Composition de coloration pour matieres keratiniques humaines comprenant un colorant fluorescent et un agent conditionneur insoluble, procede et utilisation
US7198650B2 (en) 2003-04-01 2007-04-03 L'oreal S.A. Method of dyeing human keratin materials with a lightening effect with compositions comprising at least one fluorescent dye and at least one amphoteric or nonionic surfactant, composition thereof, process thereof, and device therefor
US7147673B2 (en) 2003-04-01 2006-12-12 L'oreal S.A. Composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one insoluble polyorganosiloxane conditioning polymer, process therefor and use thereof
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US7186278B2 (en) 2003-04-01 2007-03-06 L'oreal S.A. Composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one compound comprising an acid functional group and processes therefor
US7192454B2 (en) 2003-04-01 2007-03-20 L'oreal S.A. Composition for dyeing human keratin materials, comprising a fluorescent dye and a particular sequestering agent, process therefor and use thereof
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US7195651B2 (en) 2003-04-01 2007-03-27 L'oreal S.A. Cosmetic composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one cationic polymer, and a dyeing process therefor
US20060264349A1 (en) * 2003-04-14 2006-11-23 Thomas Connors Antibacterial light duty liquid cleaning composition
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US20050049157A1 (en) * 2003-08-29 2005-03-03 Kimberly-Clark Worldwide, Inc. Single phase color change agents
US7651989B2 (en) 2003-08-29 2010-01-26 Kimberly-Clark Worldwide, Inc. Single phase color change agents
US20060287215A1 (en) * 2005-06-17 2006-12-21 Mcdonald J G Color-changing composition comprising a thermochromic ingredient
US20070098768A1 (en) * 2005-11-01 2007-05-03 Close Kenneth B Two-sided personal-care appliance for health, hygiene, and/or environmental application(s); and method of making said two-sided personal-care appliance
US20070098767A1 (en) * 2005-11-01 2007-05-03 Close Kenneth B Substrate and personal-care appliance for health, hygiene, and/or environmental applications(s); and method of making said substrate and personal-care appliance
US7612031B2 (en) 2005-12-15 2009-11-03 Kimberly-Clark Worldwide, Inc. Health-and-hygiene appliance comprising a dispersible component and a releasable component disposed adjacent or proximate to said dispersible component; and processes for making said appliance
US20070142256A1 (en) * 2005-12-15 2007-06-21 Lang Frederick J Health-and-hygiene appliance comprising a dispersible component and a releasable component disposed adjacent or proximate to said dispersible component; and processes for making said appliance
US20070142263A1 (en) * 2005-12-15 2007-06-21 Stahl Katherine D Color changing cleansing composition
US8067350B2 (en) 2005-12-15 2011-11-29 Kimberly-Clark Worldwide, Inc. Color changing cleansing composition
US7470653B2 (en) 2006-04-07 2008-12-30 Colgate-Palmolive Company Liquid cleaning composition comprising an anionic/betaine surfactant mixture having low viscosity
US7449436B2 (en) 2006-04-07 2008-11-11 Colgate-Palmolive Company Liquid cleaning composition comprising an anionic/betaine surfactant mixture having low viscosity
US20070238631A1 (en) * 2006-04-07 2007-10-11 Colgate-Palmolive Company Liquid cleaning composition having low viscosity
US20090312227A1 (en) * 2008-06-17 2009-12-17 Colgate-Palmolive Light duty liquid cleaning compositions and methods of manufacture and use thereof
US20090312225A1 (en) * 2008-06-17 2009-12-17 Colgate-Palmolive Company Light Duty Liquid Cleaning Compositions and Methods of Manufacture and Use Thereof
US7718595B2 (en) 2008-06-17 2010-05-18 Colgate Palmolive Company Light duty liquid cleaning compositions and methods of manufacture and use thereof comprising organic acids
US8022028B2 (en) 2008-06-17 2011-09-20 Colgate-Palmolive Company Light duty liquid cleaning compositions and methods of manufacture and use thereof comprising organic acids
US8247362B2 (en) 2008-06-17 2012-08-21 Colgate-Palmolive Company Light duty liquid cleaning compositions and methods of manufacture and use thereof
US8309504B2 (en) 2008-06-17 2012-11-13 Colgate-Palmolive Company Light duty liquid cleaning compositions and methods of manufacture and use thereof

Also Published As

Publication number Publication date
FR2053194A1 (enrdf_load_stackoverflow) 1971-04-16
FR2053194B1 (enrdf_load_stackoverflow) 1974-08-09
NO133426C (enrdf_load_stackoverflow) 1976-05-05
IE34412B1 (en) 1975-04-30
DK125620B (da) 1973-03-19
GB1307644A (en) 1973-02-21
SE351564B (enrdf_load_stackoverflow) 1972-12-04
IT1035028B (it) 1979-10-20
ZA704430B (en) 1972-02-23
JPS4817362B1 (enrdf_load_stackoverflow) 1973-05-29
CH531884A (de) 1972-12-31
PH9268A (en) 1975-07-30
NO133426B (enrdf_load_stackoverflow) 1976-01-26
NL7011176A (enrdf_load_stackoverflow) 1971-02-01
BE753955A (fr) 1970-12-31
IE34412L (en) 1971-01-28
AT302534B (de) 1972-10-25
DE2034295A1 (de) 1971-02-11

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