US3619102A - Dyeing keratinic fibers with aqueous solutions of direct dyes and organic solvents - Google Patents
Dyeing keratinic fibers with aqueous solutions of direct dyes and organic solvents Download PDFInfo
- Publication number
- US3619102A US3619102A US743578A US3619102DA US3619102A US 3619102 A US3619102 A US 3619102A US 743578 A US743578 A US 743578A US 3619102D A US3619102D A US 3619102DA US 3619102 A US3619102 A US 3619102A
- Authority
- US
- United States
- Prior art keywords
- composition
- dyes
- alcohol
- amounts
- weight percent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/35—Ketones, e.g. benzophenone
- A61K8/355—Quinones
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
- A61Q5/065—Preparations for temporary colouring the hair, e.g. direct dyes
Definitions
- ABSTRACT A composition for dyeing keratinic fibers and particularly human hair which comprises, in aqueous solution, at least one direct dye having a poor affinity for the fiber at room temperature and an organic solvent which is inert to both the dye and the fiber. and corresponds to the formula DYEING KERATINIC FIBERS WITH AQUEOUS SOLUTIONS OF DIRECT DYES AND ORGANIC SOLVENTS
- This invention relates to a new process for dyeing animal fibers, and especially living or dead hair, and to a composition for carrying out that process.
- the process according to the invention makes it possible to substantially broaden the range of colorants which may be used, especially for dyeing hair, as a consequence of the fact that it assists and accelerates the coloration of the hair and the fixing of the dye while operating at the ambient temperature or at a moderate temperature (below 50 C.).
- the invention also permits satisfactory coloring effects to be produced with dyes which do not, at the above temperatures, have any great affinity for the hair, and this is a very important practical advantage.
- R represents an aliphatic hydrocarbon which may or may not have a branched chain and comprises at most eight carbon atoms
- n is a number between one and four inclusive.
- thioether alcohol such as thiodiglycol
- a ketoalcohol such, for example, as diacetone alcohol (up to 10 percent),
- An aromatic alcohol such as benzyl alcohol (up to 4 percent) or beta-phenylethyl alcohol (up to 1 percent),
- An alicyclic alcohol which may be homocyclic, such as cyclohexanol (up to 3 percent) or heterocyclic, such as furfuryl alcohol,
- organic solvents to which the present invention is directed act in the same way as those described in said prior patents so as to materially strengthen the coloring of the hair and assist in fixing of the dyes on the hair, either at room temperatures, or at the temperatures hereinbefore specified. They may be used as components of mixtures including the solvents described in the above two patents.
- R represents an alkyl radical which may have either a straight or branched chain and comprises three to eight carbon atoms, or phenyl (C H or benzyl (C6H5-CH2) or cyc1ohexyl(C H n is a number between one and four inclusive.
- Specific exemplary solvents of the above class are 3- amyloxyl,2-propanediol; 3-benzyloxy-l,2-propanediol and 3-phenoxyl ,2-propanediol.
- direct dyes is used to indicate any coloring substance capable of being fixed directly in its final color by the product being dyed, without requiring any additional chemical change such as oxidation, coupling,
- the direct dyes may be selected from among the types of dyes described in said prior patents, to wit:
- Nitro dyes which may be acid, slightly basic, or strongly basic, for example:
- ORASOL ClBA
- CFMC Color lndex, 2nd Ed, 1956, p.
- LANASYNE (SANDOZ) Color lndex, 2nd Ed, 1956,
- Acetoquinonc Light Red HZ (C.l. Disperse Red 17) Color index, 2nd Ed, 1956, Supplement. 1963.
- two or more such dyes may be associated in identical or different proportions, in the same dyeing solution, so as to produce various desired shades, and particularly the colors of natural hair.
- a composition for dyeing animal fibers at room temperature which comprises in aqueous solution at least one direct dye in amounts effective to dye said fibers and at least one organic solvent which is chemically inert with respect to said dye and the fiber which is to be colored, said solvent having the formula:
- R is selected from the group consisting of alkyl having three to eight carbon atoms, phenyl, benzyl, and cyclohexyl, and n is a number between one and four inclusive, and being present in amounts of 1-15 weight percent of said composition.
- said at least one direct dye is selected from the group consisting of nitro dyes, disperse dyes, solvent dyes, metallic dyes and basic dyes.
- said at least one direct dye is selected from the group consisting of nitro dyes, disperse dyes, solvent dyes, metallic dyes and basic dyes.
- said at least one direct dye is selected from the group consisting of a) a solvent having the formula R-(OCH,CH,),,OH wherein R represents alkyl having at most eight carbon atoms and n is a number between 1 and 4 inclusive, (b) butyl alcohol in amounts up to 5 weight percent of said composition, (c) thiodiglycol in amounts up to 10 weight percent of said composition, (d) diacetone alcohol in amounts up to 10 weight percent of said composition, (3) an aromatic alcohol selected from the group consisting of
- the method of dyeing hair which comprises the step of applying thereto an effective amount of a composition as claimed in claim 1, for a period of at least 15 minutes, and the rinsing and drying the hair.
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Emergency Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Coloring (AREA)
- Cosmetics (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
LU53850 | 1967-06-09 |
Publications (1)
Publication Number | Publication Date |
---|---|
US3619102A true US3619102A (en) | 1971-11-09 |
Family
ID=19725244
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US743578A Expired - Lifetime US3619102A (en) | 1967-06-09 | 1968-06-07 | Dyeing keratinic fibers with aqueous solutions of direct dyes and organic solvents |
Country Status (4)
Country | Link |
---|---|
US (1) | US3619102A (xx) |
FR (1) | FR1569213A (xx) |
GB (1) | GB1174741A (xx) |
LU (1) | LU53850A1 (xx) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4873079A (en) * | 1987-08-21 | 1989-10-10 | Clairol Incorporated | Hair coloring composition and its method of use |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
LU65539A1 (xx) * | 1972-06-19 | 1973-12-21 | ||
US5112359A (en) * | 1990-06-04 | 1992-05-12 | Clairol, Inc. | Hair colorants |
EP0801942B1 (de) * | 1996-04-20 | 1998-10-14 | GOLDWELL GmbH | Mittel zur Färbung und Tönung von menschlichen Haaren |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2983651A (en) * | 1955-12-10 | 1961-05-09 | Oreal | Dyeing of animal fibres |
US3261754A (en) * | 1956-04-21 | 1966-07-19 | Rapidol Ltd | Solvent dyeing of human hair |
US3480377A (en) * | 1964-05-06 | 1969-11-25 | Lever Brothers Ltd | Solvent dyeing of living human hair |
-
1967
- 1967-06-09 LU LU53850D patent/LU53850A1/xx unknown
-
1968
- 1968-06-07 GB GB27285/68A patent/GB1174741A/en not_active Expired
- 1968-06-07 FR FR1569213D patent/FR1569213A/fr not_active Expired
- 1968-06-07 US US743578A patent/US3619102A/en not_active Expired - Lifetime
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2983651A (en) * | 1955-12-10 | 1961-05-09 | Oreal | Dyeing of animal fibres |
US3261754A (en) * | 1956-04-21 | 1966-07-19 | Rapidol Ltd | Solvent dyeing of human hair |
US3480377A (en) * | 1964-05-06 | 1969-11-25 | Lever Brothers Ltd | Solvent dyeing of living human hair |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4873079A (en) * | 1987-08-21 | 1989-10-10 | Clairol Incorporated | Hair coloring composition and its method of use |
Also Published As
Publication number | Publication date |
---|---|
FR1569213A (xx) | 1969-05-30 |
LU53850A1 (xx) | 1969-04-22 |
DE1769533A1 (de) | 1972-10-19 |
GB1174741A (en) | 1969-12-17 |
DE1769533B2 (de) | 1975-08-14 |
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